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Microwave irradiation synthesis of CoFe2O4/rGO to activate peroxymonosulfate for the degradation of 2-aminobenzothiazole in water

Environ. Sci.: Water Res. Technol., 2024, 10,2946-2960
DOI: 10.1039/D4EW00459K, Paper
Wei Wei, Shiqian Gao, Feiyue Qian, Chongjun Chen, Youyi Wu
CoFe2O4/rGO MNPs synthesized via an in situ microwave irradiation method were used as a heterogeneous catalyst to activate PMS for the degradation of ABT. Its mechanism was explored, and the catalytic system was applied to real water samples.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Philippine dictator set to be buried at heroes' cemetery

"There will be no state funeral. It will be very simple, the body will be carried on a hearse then brought to his tomb," Mr. Albayalde said.




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Windfall tax on crude petroleum slashed to zero

The last such revision took place effective August 31 when the windfall tax on crude petroleum was set at ₹1,850 per tonne




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Revealing degradation mechanisms in 3D/2D perovskite solar cells under photothermal accelerated ageing

Energy Environ. Sci., 2024, 17,8313-8324
DOI: 10.1039/D4EE03869J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zijian Peng, Andrej Vincze, Fabian Streller, Vincent M. Le Corre, Kaicheng Zhang, Chaohui Li, Jingjing Tian, Chao Liu, Junsheng Luo, Yicheng Zhao, Andreas Späth, Rainer Fink, Thomas Heumüller, Andres Osvet, Ning Li, Martin Stolterfoht, Larry Lüer, Christoph J. Brabec
Three-dimensional/two-dimensional (3D/2D) heterojunctions in perovskite solar cells exhibit excellent optoelectronic properties and enhanced stability under mild ageing conditions.
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De-templated crystallization in 2D perovskites for enhanced photovoltaic efficiency

Energy Environ. Sci., 2024, 17,8284-8292
DOI: 10.1039/D4EE03272A, Paper
Fang Zeng, Zhenhuang Su, Weiyu Kong, Feng Li, Yuhang Liang, Xingmo Zhang, Tao Wang, Lin Zhang, Yuze Lvtao, Runkai Liu, Xingyu Gao, Jun Huang, Xudong Yang, Rongkun Zheng
A de-templated crystallization strategy using a stable intermediate to promote out-of-plane crystallization of layered 2D perovskites was proposed, in favor of highly efficient and stable perovskite solar cells.
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Heterojunction lithiation engineering and diffusion-induced defect passivation for highly efficient Sb2(S,Se)3 solar cells

Energy Environ. Sci., 2024, 17,8402-8412
DOI: 10.1039/D4EE03135K, Paper
Cong Liu, Anweng Gong, Chen Zuo, Tao Liu, Xiaoyang Liang, Donglou Ren, Kai Shen, Jianzha Zheng, Qifan Xue, Zhiqiang Li, Ruud E. I. Schropp, Bingsuo Zou, Yaohua Mai
A heterojunction lithiation strategy has been developed to achieve a certified efficiency of 10.50%, which is the record efficiency for all of the Sb-based solar cells.
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Synergistic enhancement of charge extraction and heat dissipation in inverted perovskite solar cells via n-doped top interlayers

Energy Environ. Sci., 2024, 17,8304-8312
DOI: 10.1039/D4EE02836H, Paper
Sangmi Park, Sang Young Jeong, Jaehoon Kim, Heunjeong Lee, Hye Seung Kim, Young Wook Noh, Ye In Kim, Shinuk Cho, Joon Sang Kang, Han Young Woo, Myoung Hoon Song
n-Doping the fullerene-based interlayer in perovskite solar cells enhances heat dissipation and charge extraction by improving thermal/electrical conductivity, and energy level alignment, which boosts photovoltaic performance and stability.
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Efficient 1.77 eV-bandgap perovskite and all-perovskite tandem solar cells enabled by long-alkyl phosphonic acid

Energy Environ. Sci., 2024, 17,8219-8227
DOI: 10.1039/D4EE02483D, Paper
Hongling Guan, Shiqiang Fu, Guojun Zeng, Weiqing Chen, Chen Wang, Hongsen Cui, Dexin Pu, Peng Jia, Weiwei Meng, Guojia Fang, Weijun Ke
Incorporating dodecylphosphonic acid additives into 1.77 eV-bandgap perovskites enabled single-junction solar cells to achieve a PCE of 20.2%. Tandem cells further reached impressive PCEs of 27.41% (two-terminal) and 28.65% (four-terminal).
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Perspectives for sustainability analysis of scalable perovskite photovoltaics

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03956D, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xueyu Tian, Samuel D. Stranks, Jinsong Huang, Vasilis M. Fthenakis, Yang Yang, Fengqi You
We propose a multi-scale analytics and modeling framework to fill the gap in integrating circular solar economy principles with ecosystem and climate commitments, enabling a holistic sustainability analysis of perovskite PVs.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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Stress regulation via surface micro-etching and reconstruction for enhancing triple-cation perovskite solar cells with an efficiency of 25.54%

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04248D, Paper
Yang Ding, Erming Feng, Siyuan Lu, Jianhui Chang, Caoyu Long, Sichao Tong, Hengyue Li, Junliang Yang
A surface micro-etching and reconstruction strategy is developed to regulate the stresses in a perovskite film, achieving a benign transition from tensile stress to compressive stress.
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Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
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Regulating the Crystallization of Mixed-Halide Perovskites by Cation Alloying for Perovskite-Organic Tandem Solar Cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03045A, Paper
Mingqian Chen, Yanxun Li, Zixin Zeng, Ming Liu, Tao Du, Xiaofeng Huang, Leyu Bi, Jiarong Wang, Wenlin Jiang, Yidan An, Sai Wing Tsang, Jun Yin, Shengfan Wu, Alex K. Y. Jen
Halide segregation and energy loss pose significant challenges for wide-bandgap perovskite solar cells, impairing their photovoltage and device stability. These issues are often exacerbated by inferior film quality and inhomogeneous...
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Metastable interphase induced pre-strain compensation enables efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03801K, Paper
Hongyu Xu, Yun Xiao, Karim A Elmestekawy, Pietro Caprioglio, Qiuyang Li, Qixuan Zhong, Yongqiang Ji, Tianyu Huang, Haoming Yan, Yingguo Yang, Laura M Herz, Qihuang Gong, Henry Snaith, Rui Zhu, Lichen Zhao
High-efficiency metal halide perovskite solar cells (PSCs) include the rigid substrates with low thermal-expansion coefficients (TECs), resulting in a significant TEC mismatch with the perovskites with high TECs at the...
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Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
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Depressing charge recombination in hybrid perovskites by introducing a dynamic electron/energy relay couple towards enhanced photocatalytic hydrogen production

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03864A, Paper
Jiaqi Liu, Yuxin Xie, Yongxin Jiao, Hefeng Zhang, Junhui Wang, Yuying Gao, Xu Zong
Extraordinary photocatalytic hydrogen evolution is achieved on methylammonium lead iodide perovskites by introducing a dynamic Cu/(CuI2) couple as the electron/energy relay station and the Pt co-catalyst as the charge/energy-releasing promotor.
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Decoupling light- and oxygen-induced degradation mechanisms of Sn–Pb perovskites in all perovskite tandem solar cells

Energy Environ. Sci., 2024, 17,8557-8569
DOI: 10.1039/D4EE02427C, Paper
Open Access
Yang Bai, Ruijia Tian, Kexuan Sun, Chang Liu, Xiting Lang, Ming Yang, Yuanyuan Meng, Chuanxiao Xiao, Yaohua Wang, Xiaoyi Lu, Jingnan Wang, Haibin Pan, Zhenhua Song, Shujing Zhou, Ziyi Ge
This study showed PEHCl-CN can enhance the strength of Sn–I, resulting in good light stability. The subsequent doping of MBI resulted in good air stability. This enables the integrated 2T all-perovskite device to achieve an efficiency of 27.9%.
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Trimming defective perovskite layer surfaces for high-performance solar cells

Energy Environ. Sci., 2024, 17,8582-8592
DOI: 10.1039/D4EE03585B, Paper
Chanhyeok Kim, Kihoon Kim, Youngmin Kim, Nikolai Tsvetkov, Nam Joong Jeon, Bong Joo Kang, Hanul Min
The defect density on the top surface of the perovskite thin film was significantly higher than that in the bulk. A trimming solvent treatment removed the defective top surface, substantially reducing the defect concentration and strain.
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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
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An energy-efficient tellurium electrode enabled by a Cs2TeI6 perovskite structure for durable aqueous Zn–Te batteries

Energy Environ. Sci., 2024, 17,8633-8642
DOI: 10.1039/D4EE02916J, Paper
Jinye Li, Chengjun Lei, Pengjie Jiang, Chen Xu, Tingting Liu, Xiao Liang
CsI in 2 M ZnSO4 aqueous electrolyte facilitates the formation of Cs2TeI6 perovskite phase for Te electrode, effectively suppressing Te4+ hydrolysis and sustaining fast redox kinetics in multi-electron transfer Zn–Te aqueous batteries.
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Water-induced spinodal decomposition of mixed halide perovskite captured by real-time liquid TEM imaging

Energy Environ. Sci., 2024, 17,8745-8755
DOI: 10.1039/D4EE03381G, Paper
Nicolas Folastre, Mohammad Ali Akhavan Kazemi, Kirill Cherednichneko, Arash Jamali, Jean Rousset, Frédéric Sauvage, Arnaud Demortière
Segmented images showing the live degradation of CsMAFA particles in contact with water molecules. The formed particles are CsPb2Br5 and PbI2 resulting from the spinodal decomposition of perovskite before dissolution/recrystallization process.
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Grease trap waste valorization through hydrothermal liquefaction and anaerobic digestion: a circular approach to dairy wastewater treatment

Energy Environ. Sci., 2024, 17,8926-8941
DOI: 10.1039/D4EE02245A, Paper
Daniela V. Cabrera, Ingrid Adema-Yusta, María J. Santibañez, Crispin Celis, Jefferson W. Tester, Rodrigo A. Labatut
Integrating hydrothermal liquefaction (HTL) with anaerobic digestion (AD) and recycling a fraction of the resulting wastewater (AP) in the HTL allows for recovering 85% of the energy contained in the grease waste while reducing its COD to 700 mg L−1.
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High-entropy doping for high-performance zero-cobalt high-nickel layered cathode materials

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE05020G, Paper
Jiahui Zhou, Jiehui Hu, Xia Zhou, Zhen Shang, Yue Yang, Shengming Xu
Considering the high price and scarcity of cobalt resource, zero-cobalt, high-nickel layered cathode material (LNM) have been considered as the most promising material for next-generation high-energy-density lithium-ion batteries (LIBs). However,...
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Suppressed Surface Lattice Vacancies and Distortion Through Lattice Anchoring for Efficient FAPbI3 Perovskite Quantum Dot Solar Cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04112G, Paper
Mingxu Zhang, Xinyi Mei, Guoliang Wang, Junming Qiu, Zhimei Sun, Xiaoliang Zhang
Formamidinium lead triiodide perovskite quantum dots (FAPbI3 PQDs) exhibit outstanding optoelectronic characteristics for new-generation solar cells. However, the PQD seriously suffers from surface lattice vacancies and lattice distortion, resulting in...
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Surface-deprotonated ultra-small SnO2 quantum dots for high-performance perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03193H, Paper
Wuchen Xiang, Yiheng Gao, Bobo Yuan, Shuping Xiao, Rui Wu, Yiran Wan, Zhiqiang Liu, Liang Ma, Xiang-Bai Chen, Weijun Ke, Guojia Fang, Pingli Qin
SnO2 electron transport layers (ETLs) have improved perovskite solar cell (PSC) efficiencies but face issues with surface protonation, leading to energy loss and instability. We developed ultra-small (2.5 nm) SnO2...
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Bomb threat to private school in Erode declared hoax




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Woman councillor allegedly harassed in Feroke municipality

Shanoobiya Niyas, representing Ward 14 of the municipality, had shifted her allegiance from RJD to IUML recently




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Erode Corporation begins second phase of encroachment removal




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Weavers’ stage protest in Erode, dispersed by police




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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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Selective aerobic oxidative C–C bond cleavage using a high-entropy oxide-derived multimetallic catalyst

React. Chem. Eng., 2024, 9,967-973
DOI: 10.1039/D3RE00525A, Paper
Shaoyuan Guo, Xinli Tong, Jipeng Wang, Hang Tang
A stable and efficient high entropy catalyst is developed for the selective oxidative C–C bond cleavage in the presence of O2.
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Biomass-based graphene aerogel for the removal of emerging pollutants from wastewater

React. Chem. Eng., 2024, 9,753-776
DOI: 10.1039/D3RE00526G, Review Article
Vijayendra Kumar Tripathi, Manish Shrivastava, Jaya Dwivedi, Raju Kumar Gupta, Lokesh Kumar Jangir, Kumud Malika Tripathi
This review article provides a detailed overview of the synthesis techniques of biomass-based graphene aerogels and highlights the influence of fabrication parameters on the performance of the resulting aerogels for wastewater treatment applications.
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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
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Determination of intermediates and products of the uranyl aerosol formation in UF6 hydrolysis in the gas phase

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian Mark Salvador, Jason M. Richards, Shannon M. Mahurin, Meng-Dawn Cheng, Joshua A. Hubbard
A graphical representation of the uranyl aerosol formation.
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Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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Abnormal enterohepatic circulation of bile acids caused by fructooligosaccharide supplementation along with a high-fat diet

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03353A, Paper
Fang Zeng, Shi He, Ying Sun, Xue Li, Kaiyang Chen, Hongbin Wang, Shuli Man, Fuping Lu
Fructooligosaccharide (FOS) is a widely used prebiotic and health food ingredient, but few reports have focused on its risk to specific populations.
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Shatianyu (Citrus grandis L. Osbeck) whole fruit alleviated loperamide-induced constipation via enhancing gut microbiota-mediated intestinal serotonin secretion and mucosal barrier homeostasis

Food Funct., 2024, 15,10614-10627
DOI: 10.1039/D4FO02765E, Paper
Mei Deng, Jiamin Ye, Ruifen Zhang, Shuai Zhang, Lihong Dong, Dongxiao Su, Mingwei Zhang, Fei Huang
The effects of Citrus grandis Shatianyu whole fruit powder enriched in flavonoids and dietary fiber on loperamide-induced constipation after a 4-week administration in the diet, together with possible microbiota-mediated mechanisms were explored.
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Selenium-mediated alleviation of skeletal muscle atrophy through enterotype modulation in mice

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03889D, Paper
Yixin Cheng, Xiaofan Liu, Yingao Hao, Shixu Wang, FangFang Wu, Lingzhuo Zhao, Du Peng, Du Yawen, Sun Sheng, Li Jianguo, Guangxu Ren
Selenium element improves dexamethasone-induced skeletal muscle atrophy by affecting enterotype.
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Dynamic changes in the gel properties, microbial community, and volatile flavor profile of Spanish mackerel (Scomberomorus niphonius) sausages inoculated with Lactiplantibacillus plantarum CY1-2

Food Funct., 2024, 15,11060-11071
DOI: 10.1039/D4FO03841J, Paper
Xinran Lv, Wenyu Wu, Shuilin Liu, Lili Ding, Anqi Ren, Le An, Fengling Bai, Jianrong Li, Xuepeng Li, Shumin Yi
This study aimed to examine the dynamic changes in the gel properties, microbial diversity, and volatile flavor compounds (VFCs) of Spanish mackerel sausages inoculated with Lactiplantibacillus plantarum CY1-2 during fermentation.
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Dietary supplementation of pterostilbene, a major component in small berries, prevents alcohol-induced liver injury associated with lipid accumulation and inflammation

Food Funct., 2024, 15,11206-11219
DOI: 10.1039/D4FO03898C, Paper
Jia-Yi Dou, Sai-Hu Liu, Jia Guo, Chen-Yu Wang, Xu Dai, Li-Hua Lian, Zhen-Yu Cui, Ji-Xing Nan, Yan-Ling Wu
Pterostilbene (PTE), a natural stilbene found in small berries, exhibits multiple pharmacological activities, particularly antioxidant and anti-inflammatory activities.
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The Boy And The Heron Review

The Boy And The Heron offers a thrilling joyride inside Hayo Miyazaki's unquantifiable imagination, applauds Sukanya Verma.




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Education not a prerogative of the ‘upper caste‘, says Siddaramaiah

Ramayana, Mahabharata authored by “lower castes”, says CM




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Bomb threat to hotel in Erode




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Mohanlal: An Emperor Defeated By Love

'Once Mohanlal's ever-swelling entourage grasped his enormous worth, once it realized that the innate Mohanlal appeal could be profited from, it set about to exploit, to make uproars, to create the Mohanlal brand.''And he wasn't meant to be a brand. He was meant to be an artist, a tireless explorer of the unique seas inside him,' asserts Sreehari Nair.




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A Numerous and Brilliant Assembly: A Colonial Williamsburg Musical Sampler

Selected performances from nine of Colonial Williamsburg's recordings, including fife and drum marches, chamber music, slave chants, and tavern songs.




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Science for All | What are Trojan asteroids?

The Hindu’s weekly Science for All newsletter explains all things Science, without the jargon.




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Unexpected link between nickel toxicity, cholesterol levels found

In a new study, fungi that lacked the Sre1 protein were found to be highly sensitive to nickel; the gene that encodes for this protein is conserved in all animals, including humans




ero

The tragic hero

Events leading up to Keechaka’s death was well captured in ‘Keechakavadham’.




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Taneja Aerospace & Aviation Ltd. - Board Meeting Intimation for Consideration And Approval Of The Un-Audited Financial Results(Standalone And Consolidated) For The Quarter Ended June 30, 2019.