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IndusInd Bank shares plunge 17%; Mcap erodes by ₹15,572 crore amid disappointing earnings

By www.thehindu.com
Published On :: Fri, 25 Oct 2024 11:51:35 +0530

Total income rose to ₹14,871 crore in the quarter under review, from ₹13,530 crore in the same period a year ago, IndusInd Bank said in a regulatory filing


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Organic/inorganic heterostructures templated by interfacial instability-driven BCP colloids in deformable emulsion droplets

By pubs.rsc.org
Published On ::

Soft Matter, 2024, 20,8174-8180
DOI: 10.1039/D4SM00921E, Communication
Yuqing Song, Nan Yan, Lingli Wan, Jingjing Li, Ye Gao
Core–shell colloids are self-assembled in emulsion droplets driven by interfacial instability, which serve as excellent scaffolds for designing organic/inorganic heterostructures.
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Nature of barriers determines first passage times in heterogeneous media

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Soft Matter, 2024, 20,8353-8362
DOI: 10.1039/D4SM00908H, Paper
Moumita Dasgupta, Sougata Guha, Leon Armbruster, Dibyendu Das, Mithun K. Mitra
The nature of barriers control the first passage times in heterogenous media. For entropic barriers, the first passage times increases monotonically with increasing number of barriers, while for energetic barriers, passage times show a non-monotonic behaviour with increasing barriers.
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Thickness-dependent response of aerosol-jet-printed ultrathin high-aspect-ratio electrochemical microactuators

By pubs.rsc.org
Published On ::

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00886C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ji Zhang, Jeremy J. Baumberg, Sohini Kar-Narayan
Trilayer electrochemical actuators comprising an electrolyte layer sandwiched between two electrode layers have been shown to exhibit large deformations at low actuation voltages. Here we report aerosol-jet printing (AJP) of...
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5 tips to help you reduce cholesterol

By www.rediff.com
Published On :: Wed, 15 May 2024 16:48:52 +0530

While the causes for high cholesterol are many, there are simple ways to reduce it, says rediffGURU Dr Karthiyayani Mahadevan.


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Alone in the Abyss / directed by: Claudie Ottawa ; produced by: Manon Barbeau, Patricia Bergeron, Manon Barbeau, Yves Bisaillon, Ravida Din ; production agencies: Corporation Wapikoni mobile (Montreal), National Film Board of Canada (Montreal)

By darius.uleth.ca
Published On ::

Montreal : National Film Board of Canada, 2018


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Zeroing in on methane diplomacy, at COP29

By www.thehindu.com
Published On :: Sat, 02 Nov 2024 00:08:00 +0530

The Baku meet is an opportunity for India to fast-track its efforts in reducing methane emissions


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‘Zero-error entrance test:’ Union Education Minister urges support from states for exam reforms

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 16:59:28 +0530


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Remo: Heroine worship

By www.thehindu.com
Published On :: Fri, 07 Oct 2016 23:11:51 +0530

‘Remo’ is less about convincing us that a man can become a woman than reminding us Sivakarthikeyan has become a star.


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A peek at Kokūn’s zero-waste, naturally-dyed apparel

By www.thehindu.com
Published On :: Fri, 26 May 2023 16:22:10 +0530

Zero-waste apparel dyed with home-grown rhubarb and madder is the forte of Mridu Mehra Tiwari’s brand Kokūn, which just launched its Spring collection and a men’s range


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Label Erode’s debut collection blends the GI-tagged jamakkalam with Jimi Hendrix’s music

By www.thehindu.com
Published On :: Thu, 17 Aug 2023 20:02:47 +0530

How a Mumbai-based fashion label is reviving the GI-tagged Bhavani jamakkalam through its debut collection


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Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01681E, Research Article
Lu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai Zhou
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.
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I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01801J, Research Article
Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
An I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.
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Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01841A, Research Article
Xunhua Wang, Jianhua Wang, Xiaoxun Li
A gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.
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Total synthesis of spiro Ganoderma meroterpenoids spiroapplanatumines B, D, F, and H

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, 11,6333-6339
DOI: 10.1039/D4QO01147C, Research Article
Jia-Hao Zhang, Wen-Cai Luo, Wen-Tao Chen, Yu-Tao He, Ya-Jian Hu
The first total synthesis of spiroapplanatumines B, D, F, and H as well as the possibly undiscovered natural product spiroapplanatumine R has been achieved.
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Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, 11,6385-6392
DOI: 10.1039/D4QO01243G, Research Article
Jinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian Chen
A cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.
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Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, 11,6534-6557
DOI: 10.1039/D4QO01686F, Review Article
Jinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun Xie
This review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.
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Catalyst-free C–H methylation of heteroarenes enabled by electron donor–acceptor complex photoactivation

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01309C, Research Article
Jiayang Wang, Baoer Shao, Haixia Ge, Huiyu Xue, Xiangyuan Ding, Yuqi Li, Peiyao Sheng
A visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.
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Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01627K, Research Article
Bo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long Zhu
We report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.
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Investigation of the titanium-mediated catalytic enantioselective oxidation of aryl benzyl sulfides containing heterocyclic groups

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35105-35113
DOI: 10.1039/D4RA07088G, Paper
Open Access
Maria Annunziata M. Capozzi, Angel Alvarez-Larena, Joan F. Piniella Febrer, Cosimo Cardellicchio
Enantiopure benzyl heteroaryl sulfoxides were obtained by asymmetric oxidation. However, two benzimidazolyl sulfoxides were found to be conglomerates.
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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
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Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35490-35497
DOI: 10.1039/D4RA06404F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lili Xie, Haiyan Qiu, Yuxin Chen, Yingxue Lu, Yanyan Chen, Lanlan Chen, Shanwen Hu
A zero-dimensional halide perovskite in micron scale is constructed to gain a deeper understanding of phase transformation mechanism and better fluorescence applications.
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Advanced oxidative degradation of monoethanolamine in water using ultraviolet light and hydrogen peroxide

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,33223-33232
DOI: 10.1039/D4RA05590J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Atif Khan, Saima Yasin, Hamayoun Mahmood, Shabana Afzal, Tanveer Iqbal
Development of an eco-friendly and commercially feasible method for monoethanolamine (MEA) degradation in aqueous phase using ultraviolet/hydrogen peroxide (UV/H2O2) advanced oxidation process (AOP).
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Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
Open Access
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
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Synthesis and in vitro assessment of gold nanoparticles conjugated with extracts, sterols and pure compounds derived from marine sponges from the Indian and Pacific Oceans

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36115-36131
DOI: 10.1039/D4RA04068F, Paper
Open Access
Avin Ramanjooloo, Devesh Bekah, Samson A. Adeyemi, Philemon Ubanako, Lindokuhle Ngema, Yahya E. Choonara, David E. Williams, Elena A. Polishchuk, Raymond J. Andersen, Archana Bhaw-Luximon
The synthesis of gold nanoparticles using extracts, sterols and pure compounds from marine sponges.
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Exploring heterocyclic scaffolds in carbonic anhydrase inhibition: a decade of structural and therapeutic insights

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35769-35970
DOI: 10.1039/D4RA06290F, Review Article
Open Access
Nafeesa Naeem, Amina Sadiq, Gehan Ahmed Othman, Habab M. Yassin, Ehsan Ullah Mughal
Heterocyclic compounds represent a prominent class of molecules with diverse pharmacological activities.
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Investigation of variable range hopping and dielectric relaxation in GdCrO3 orthochromite perovskites

By pubs.rsc.org
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RSC Adv., 2024, 14,36161-36172
DOI: 10.1039/D4RA06104G, Paper
Open Access
Mohamed Youssef Gneber, Imen Elhamdi, Jalel Messoudi, Radhia Dhahri, Foudil Sahnoune, Mosbah Jemmali, Magdy Hussein, Essebti Dhahri, Benilde Faria Oliveira Costa
This study investigates the structural, electrical, and dielectric properties of GdCrO3 (GCO) compounds. X-ray diffraction analysis confirmed the formation of the perovskite phase of GCO, crystallizing with the Pbnm space group.
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Cs2ZnCl4: a lead-free all-inorganic perovskite with a large dielectric permittivity

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36253-36263
DOI: 10.1039/D4RA04755A, Paper
Open Access
Imen Romdhane, Asma Ajmi, Mohamed Ben Bechir, Regis Barille, Abdallah Ben Rhaiem
In recent years, inorganic perovskite materials based on metallic halides have attracted significant attention due to their non-toxicity and ease of synthesis, making them suitable for various applications.
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Improving the catalytic performance of Co/BaCeO3 catalyst for ammonia synthesis by Y-modification of the perovskite-type support

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36281-36294
DOI: 10.1039/D4RA06251E, Paper
Open Access
Magdalena Zybert, Hubert Ronduda, Wojciech Patkowski, Andrzej Ostrowski, Kamil Sobczak, Wioletta Raróg-Pilecka
The beneficial effect of Y3+ ions incorporated into BaCeO3 support structure stems from the strengthening of the electron-donating ability, i.e., better charge transfer from the support to the active metal, enhancing N2 dissociation.
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600 schools with zero, low enrolment shut in Arunachal Pradesh

By www.thehindu.com
Published On :: Wed, 24 Jul 2024 16:55:43 +0530

The Arunachal Pradesh Government is planning to close more such schools with zero or low enrolment


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PIX: Sajid Khan's heroics save the day for Pakistan

By www.rediff.com
Published On :: Wed, 16 Oct 2024 19:05:50 +0530

IMAGES from Day 2 of the second Test played between Pakistan and England in Multan on Wednesday.


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PIX: Noman's heroics lead Pak to series-leveling win

By www.rediff.com
Published On :: Fri, 18 Oct 2024 14:16:16 +0530

Pakistan beat England by 152 runs in the second Test in Multan on Friday to level the three-match series at 1-1.


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Serie A leader Napoli scores late to beat struggling Lecce and Atalanta routs Verona

By www.thehindu.com
Published On :: Sun, 27 Oct 2024 05:15:00 +0530

Serie A leader Napoli has needed a late score from captain Giovanni Di Lorenzo to secure a 1-0 victory over struggling Lecce


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Bulk photovoltaic effect in a zero-dimensional room-temperature molecular ferroelectric [C8N2H22]1.5[Bi2I9]

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02698E, Paper
Zhibo Chen, Tianhong Luo, Jinrong Wen, Zhanqiang Liu, Jingshan Hou, Yongzheng Fang, Ganghua Zhang
Non-toxic molecular ferroelectrics have attracted significant interest due to their unique flexibility, low costs, and environmental friendliness. However, the variety of such materials with narrow bandgaps and above room temperature...
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Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02469A, Paper
Zhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei Qin
Heteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.
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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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Exploring the versatility of MoSe2/WS2 heterostructures

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Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02075H, Paper
Tuan V. Vu, Dat D. Vo, Cuong Q. Nguyen, Nguyen N. Hieu, Huynh V. Phuc, Chuong V. Nguyen
Two-dimensional materials and their combined heterostructures have paved the way for numerous next-generation electronic and optoelectronic applications.
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Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02650K, Communication
Katherine Merkel, Alyssa V. B. Santos, Scott Simpson
DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
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Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02645D, Paper
Ketan Maru, Sarita Kalla, Ritambhara Jangir
The study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...
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A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper
Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
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Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper
Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
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Complete actor vs method hero

By www.thehindu.com
Published On :: Sun, 29 Sep 2024 02:50:00 +0530

When Sivaji Ganesan fans locked horns with Dilp Kumar admirers


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With nothing to lose, India will be a dangerous side now, says Ajay Jadeja

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 05:35:00 +0530

Ajay Jadeja, emphasising India’s edge, said: “We may not reach the World Test Championship final, but I believe we can secure the series win.


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Hat-trick hero Ferguson says 'insane' T20 win massive for NZ against SL

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 05:49:13 +0530

New Zealand were only able to put a modest score on the board as Sri Lanka spinner Wanindu Hasaranga took 4-17 despite being clearly hampered by injury


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Premier League referee David Coote suspended over derogatory remarks against Liverpool

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 10:31:30 +0530

Two videos circulating on social media appear to show David Coote giving his personal opinion on Jurgen Klopp and Liverpool when asked by another unidentified man.


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Synergistic effect of the heterojunction g-C3N4/Bi2MoO6/clinoptilolite to enhance the photocatalytic degradation of antibiotics in water in the presence of persulfate

By pubs.rsc.org
Published On ::

Environ. Sci.: Water Res. Technol., 2024, 10,2665-2687
DOI: 10.1039/D4EW00549J, Paper
Phuong Thu Le, Thu Phuong Nguyen, Thi Hai Do, Hong Nam Nguyen, Thi Mai Thanh Dinh, Thi Thuy Phan, Toshiki Tsubota, Trung Dung Nguyen
Proposed mechanism of OTC photocatalytic degradation by the CNBC-30/PDS/Vis system.
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Mathematical modeling to size anaerobic stabilization ponds intended for slaughterhouse wastewater treatment – the role of temperature and hydraulic retention time

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Environ. Sci.: Water Res. Technol., 2024, 10,2882-2896
DOI: 10.1039/D4EW00557K, Paper
P. E. S. Soldera, R. F. Dantas, E. Fagnani
A new mathematical model for constructing anaerobic stabilization pond treatment systems for high organic load wastewater, based on biochemical oxygen demand, temperature and hydraulic retention time, is discussed.
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