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Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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Revealing the effect of host–guest complementarity in supramolecular monofunctional platinum(II) drugs

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02012J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shib Shankar Paul, Jan Novotný, Jakub Jakubec, Kateřina Petrláková, Pia Jurček, Klára Rašková, Michaela Kuchynka, Michal Masařík, Petr Kulhánek, Radek Marek
Host–guest complementarity is shown to influence the chemical activation by aquation and the biological activity of platinum(II) drugs.
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Modulating the birefringence of two-dimensional hybrid lead bromide perovskites using pyridine derivative cations

Inorg. Chem. Front., 2024, 11,7853-7859
DOI: 10.1039/D4QI01547A, Research Article
Li-Ling Zhang, Hua Huang, Qingran Ding, Hui-Ping Xiao, Qing-Yan Liu, Yu-Ling Wang
Crystal structures and optoelectronic performance of hybrid two-dimensional lead bromide halide perovskites are elaborately regulated by pyridyl cations, which achieve a significantly enhanced birefringence of 0.315 (550 nm) for crystal 2.
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Deep learning-enabled detection of rare circulating tumor cell clusters in whole blood using label-free, flow cytometry

Lab Chip, 2024, 24,2237-2252
DOI: 10.1039/D3LC00694H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nilay Vora, Prashant Shekar, Taras Hanulia, Michael Esmail, Abani Patra, Irene Georgakoudi
We present a deep-learning enabled, label-free flow cytometry platform for identifying circulating tumor cell clusters in whole blood based on the endogenous scattering detected at three wavelengths. The method has potential for in vivo translation.
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Surfactant-induced alterations in optoelectronic properties of perylene diimide dyes: modulating sensing responses in the aqueous environment

Soft Matter, 2024, 20,3044-3052
DOI: 10.1039/D3SM01694C, Paper
Animesh Pal, Nilanjan Dey
The compartmentalization effect of microheterogeneous systems, like surfactant aggregates, showcases altered optoelectronic properties of a perylene diimide-based chromogenic dye (PDI-Ala) compared to bulk water.
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Lock-Key Microfluidics: Simulating Nematic Colloid Advection along Wavy-Walled Channels

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D3SM01536J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Karolina Wamsler, Louise C Head, Tyler Nathan Shendruk
Liquid crystalline media mediate interactions between suspended particles and confining geometries, which not only has potential to guide patterning and bottom-up colloidal assembly, but can also control colloidal migration in...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Illuminating cisplatin-induced ferroptosis in non-small-cell lung cancer with biothiol-activatable fluorescent/photoacoustic bimodal probes

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01656D, Paper
Li Xu, Hongwen Liu, Yi Kong, Lingyun Li, Jia Li, Kang Li, Shuzhi Liang, Bolin Chen
Using activatable NIR fluorescent/PA bimodal probes, we successfully monitored real-time biothiol changes during ferroptosis in NSCLC cells and tumors, revealing enhanced ferroptosis with the combined use of erastin and cisplatin.
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Lattice thermal conductivity reduction in Ca3AlSb3 and Ca5Al2Sb6 by manipulating the covalent tetrahedral chain

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03574G, Paper
Chi Zhang, Wenya Zhai, Jingyu Li, Jianbo Zhu, Zengfu Ou, Lanwei Li, Peng-Fei Liu, Xiaobing Liu, Yuli Yan, Yongsheng Zhang
Exploring the origins of low thermal conductivity in Ca–Al–Sb compounds reveals structural interactions that enhance phonon scattering. Strategies involve substituting heavier atoms to disrupt covalent chains, thereby reducing thermal conductivity.
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Correlating Negative Thermal Expansion and Thermal Conductivity in Two-dimensional Carbon-based Materials

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03776F, Paper
Soumya Mondal, Ayan Datta
Negative thermal expansion (NTE) is a fascinating phenomenon where certain materials contract upon heating. The phonon transport properties of two-dimensional carbon-based allotropes are poorly understood in terms of their NTE...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Calculating maintenance charges

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm




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Correlating concerted cations with oxygen redox in rechargeable batteries

Chem. Soc. Rev., 2024, 53,3561-3578
DOI: 10.1039/D3CS00550J, Review Article
Shiqi Wang, Lifan Wang, David Sandoval, Tongchao Liu, Chun Zhan, Khalil Amine
This review underscores the critical importance of oxygen redox and elucidates the precise commonalities of cations in regulating oxygen redox.
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What could be the low-temperature limit of atomic layer deposition of platinum using MeCpPtMe3 and oxygen?

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04679J, Communication
Hao Van Bui, Anh Phan Nguyen, Manh Duc Dang, Truong Duc Dinh, Patricia J. Kooyman, J. Ruud Van Ommen
Room-temperature atmospheric-pressure ALD enables the deposition of highly dispersed Pt sub-nanometer clusters on a gram-scale quantity of TiO2 nanopowder.
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Fabrication of gelatin hydrogels using pre-coordinated lanthanide complexes via imine crosslinking

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication
Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Site-specific acetyl modification of 2'-OH of RNA by an oligonucleotide acetylating reagent

Chem. Commun., 2024, 60,13440-13442
DOI: 10.1039/D4CC04672B, Communication
Hirotaka Murase, Mio Eto, Jeongsu Lee, Yosuke Taniguchi, Shuhei Imoto, Shigeki Sasaki
A novel oligonucleotide acetylating-reagent that induces a site-specific RNA acetylation through duplex formation has been developed.
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Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
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Regulating water decontamination and food safety by a reusable, nano-sized MOF@cotton@chitosan composite through nanomolar detection of the drug nitroxinil and organoarsenic feed additive p-arsanilic acid

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00066H, Paper
Subhrajyoti Ghosh, Debjit Mal, Shyam Biswas
MOF@cotton@chitosan composite for nanomolar fluorescence sensing of nitroxinil drug and p-arsanilic acid in real samples is presented.
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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A multi-technique analysis of gelatin biodegradation on the surface of core–shell nanoparticles by Alteromonas macleodii extracellular proteases

Environ. Sci.: Nano, 2024, 11,1429-1441
DOI: 10.1039/D3EN00523B, Paper
Sergio Fernández-Castillo Suárez, Cécile Courrèges, Javier Jiménez-Lamana, Simon Godin, Sophie Nolivos, Régis Grimaud, Luisa Ronga, Joanna Szpunar, Joachim Allouche
Multi-technique characterization at the nanoscale of gelatin biodegradation on the surface of core–shell nanoparticles by extracellular proteases.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Officials violating service rules will face action, says Revenue Minister

Minister was responding to questions by mediapersons in connection with the recent Facebook posts by IAS officer N. Prasanth against his senior colleague A. Jayathilak




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Latin Catholic Church criticises government for delay in resolving Munnambam land dispute; calls for all- party meeting

Expresses solidarity with the agitating families




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Dual luminescence and infrared circularly polarized luminescence up to 900 nm with platinum complexes bearing a helical donor–acceptor ligand

Mater. Chem. Front., 2024, 8,3799-3806
DOI: 10.1039/D4QM00632A, Research Article
Open Access
Pablo Vázquez-Domínguez, Maher Horojat, Eva Suits, Francisco José Fernández de Córdova, Nicolas Vanthuyne, Denis Jacquemin, Abel Ros, Ludovic Favereau
Engineering the intramolecular charge transfer character of ligands in axially chiral arylisoquinolines platinum(II) complexes leads to both fluorescence and phosphorescence emissions in solution, with NIR CPL that extends up to almost 850 nm.
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Correction: Enhancing the chemotherapeutic efficacy of platinum prodrug nanoparticles and inhibiting cancer metastasis by targeting iron homeostasis

Nanoscale Horiz., 2024, 9,2067-2068
DOI: 10.1039/D4NH90069C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fang Ding, Lingpu Zhang, Hao Chen, Haiqin Song, Shiguo Chen, Haihua Xiao
The content of this RSS Feed (c) The Royal Society of Chemistry




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Calculating common maintenance charges

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm




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Calculating maintenance costs

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm



  • Q & A

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Modulating the band gap of a pyrazinoquinoxaline-based metal–organic framework through orbital hybridization for enhanced visible light-driven CN bond construction

J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper
Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Regulating NO2 adsorption at ambient temperature by manipulating copper species as binding sites in copper-modified SSZ-13 zeolites

J. Mater. Chem. A, 2024, 12,30329-30339
DOI: 10.1039/D4TA04399E, Paper
Open Access
Mingzhe Sun, Tianqi Wang, Calvin Ku, Aamir Hanif, Tian Tian, Bernt Johannessen, Qinfen Gu, Ziyi Li, Patrick Sit, Jin Shang
A Cu-modified SSZ-13 zeolite for enhanced NO2 adsorption at ambient temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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Regulating oxygen redox reactions in lithium-rich materials via an Al2O3-doped ZnO layer for enhanced stability and performance

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper
Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al2O3-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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Latin Wedding Traditions

There are a lot of unique Latin wedding traditions that can be found around the costa rican brides online globe. Some are classic, while others can be up-to-date and made to suit your own personal style and personal preferences. Whatever you decide on, it’s a good thought to think about the traditions which have been […]




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Arte, Mujer y Memoria: Online Exhibition Museum of Latin American Art

For example, the comparison with the OECD appears limited by the fact that the Chilean indicator focusses on all employed individuals aged 15 years old, or above, whereas the OECD indicator covers the entire population between years. This caveat withstanding, the extent of the gap in Chile is wider than the OECD average. At nine […]




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A strain-sensitive neuromorphic device emulating mechanoreception for different skin sensitivities

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03607G, Communication
Shubhanshi Mishra, Bhupesh Yadav, Giridhar U. Kulkarni
A strain-sensitive neuromorphic device mimics mechanoreception, adapting to skin-like sensitivities. Embedded Au microwires in PDMS detect strain and display neuromorphic functionalities, closely replicating biological mechanosensory functions.
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Promoting productivity in Latin America



  • Solutions & Co

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Regulating India’s regressive health insurance

Why India’s health insurance models frustrate and exclude a large part of the population.



  • Policy & Issues

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Hierarchical porous dual-mode thermal management fabrics achieved by regulating solar and body radiations

Mater. Horiz., 2024, 11,1760-1768
DOI: 10.1039/D3MH01938A, Communication
Chuntao Lan, Jia Meng, Chongxiang Pan, Luyao Jia, Xiong Pu
A PTM fabric with cooling and heating abilities is achieved by simultaneously regulating solar and body radiations. The hierarchical porous fabric is suitable for various scenarios (e.g., indoors/outdoors, summer/winter, low/high latitude areas).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pakistan contemplating pulling out 4 embassy officials: report




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Stimulating Peer Effects? Evidence from a Research Cluster Policy [electronic journal].




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Some Principles for Regulating Cyber Risk [electronic journal].




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Revista Latinoamericana de Recursos Naturales [electronic journal].




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Remote Sensing Conference (LAGIRS), IEEE Latin American GRSS & ISPRS [electronic journal].

IEEE / Institute of Electrical and Electronics Engineers Incorporated




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Regulating Platform Fees under Price Parity [electronic journal].




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Regulating False Disclosure [electronic journal].




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Regulating Cancellation Rights with Consumer Experimentation [electronic journal].




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Latin American Journal of Trade Policy [electronic journal].

Universidad de Chile




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Journal of Circulating Biomarkers [electronic journal].

SAGE Publications




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Financial spillovers of international monetary policy: Six hypotheses on the Latin American case, 2010-2016 [electronic journal].




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Estimating and Simulating a SIRD Model of COVID-19 for Many Countries, States, and Cities [electronic journal].

National Bureau of Economic Research




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Colonization, Early Settlers and Development: The Case of Latin America [electronic journal].




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2020 IEEE Latin American GRSS & ISPRS Remote Sensing Conference (LAGIRS) [electronic journal].

IEEE / Institute of Electrical and Electronics Engineers Incorporated




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Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00493K, Research Article
Fenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin Zhang
The co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.
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