Sector performance was varied, with IT stocks gaining momentum while realty and energy sectors faced pressure

In a video that has gone viral on social media, Yadav, along with team-mate Rinku Singh, is seen posing for a photo with the fan. The fan then asks, 'Why don't you come to Pakistan?'

Actor Dipika Chikhlia, who was seen playing the role of Sita in Ramayan, was introduced to an unmatched popularity that has not faded even today. In an earlier interview, she had revealed how people in the villages would still refer to her as Sita and would even try touching her feet! However, given a choice today, Sita would not be the character she would like to play.

In a recent conversation, Dipika revealed she had evolved as an actor, and would rather be interested to play Kaikeyi, lord Ram's stepmother who insisted her husband Dashratha to send Ram, Lakshman and Sita to an exile for 14 years. Dipika added that playing a negative career was an entirely different experience and she was fond of playing roles that let her explore herself as an artist.

Actor Sunil Lahiri, who played Lakshman's character, said he'd still pick the same role, but if he had another choice, he would like to get into the shoes of Ravana as the character had many shades and would give an actor many varieties to perform.

As the nationwide lock-down began, Doordarshan started re-airing some of its most popular TV shows, Ramayan being the first one. On April 16, it became the world's most watched TV show, with 7.7 crore viewers.

United Bank of India and NIIT Institute of Finance Bankingand Insurance Training (IFBI)

Total hiring by top-four Indian IT companies in the September quarter stood at 14,421, a decline of 43 pct from a year-ago period, mainly due to a slowdown in growth of these companies, says a report.

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Invitation Only Research Event

Event participants

HE Professor Kwaku Danso-Boafo, High Commissioner for Ghana to the United Kingdom
Chair: Alex Vines OBE, Research Director, Area Studies and International Law; Head, Africa Programme, Chatham House

The credit score algorithm now monitors your three-year credit history compared to the earlier two-year period. It also has new credit attributes along with other additional features.

In April, Prime Minister Narendra Modi in a telephonic conversation with South African President Cyril Ramaphosa had conveyed India’s "full support" to the African continent to deal with fighting the spread of COVID-19.

Delhi recorded the maximum temperature of 40.9 degrees centigrade on Saturday, the IMD said. Due to the Western Disturbance, the IMD in its weather summary and forecast bulletin predicted isolated to scattered rain over the Western Himalayan region and plains of Northwest India, with peak activity on May 10, 2020.

Coronavirus numbers explained: New cases start dipping  The Indian Express

Rival parties to the conflict in South Sudan are putting military gains ahead of political settlement, a top U.N. official told the Security Council.

A decision from the U.S. State Department to expel Syrian diplomats from the country was long overdue, members of the House Foreign Affairs Committee said.

China and the United States both supported a draft United Nations Security Council resolution confronting the coronavirus pandemic on Thursday and it was "shocking and regretful" that Washington changed its mind on Friday, a Chinese diplomat said.

China and the United States both supported a draft United Nations Security Council resolution confronting the coronavirus pandemic on Thursday and it was "shocking and regretful" that Washington changed its mind on Friday, a Chinese diplomat said.

For more than six weeks the 15-member council has been trying to agree on a text that ultimately aims to back a March 23 call by U.N. chief Antonio Guterres for a ceasefire in global conflicts so the world can focus on the pandemic.

Divestment activity jumped nearly four times to $145.03 million from $36.99 million a year ago, SC data shows.

The post Malaysia’s PE, VC sector sees slight dip in total fund commitment in 2019 appeared first on DealStreetAsia.

Coalition backbencher wants to know why ambassador threatened a trade boycott after Australia called for international inquiry into coronavirus

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Diplomatic tensions between Australia and China may be reignited with an extraordinary threat by a Coalition backbencher to summons the Chinese ambassador to answer questions from a parliamentary committee.

While the attempt to compel the ambassador to appear at a hearing in Canberra is almost certain to fail because of diplomatic immunity, the push interrupts a pause in public sparring between the two governments over the response to Covid-19.

Several government hospitals denied admission to Suresh, an auto-driver in Bengaluru, before a Twitter user highlighted his ordeal and prompted the DIPR to provide help.

With new owners, falling viewers and spiralling costs, Formula One is at a crossroads

And In the matter of : Dipraj @ Dipu Chhetri & Ors.

... Petitioners Mr. Navanil De .. for the Petitioners Mr. Neguive Ahmed ..for the State The petitioners undertake to affirm and stamp the petition as per the Rules within 48 hours of resumption of normal functioning of the court. The petition is taken up through video conference on the basis of such undertaking. The case of the first petitioner appears to be on a different footing than the two other petitioners. Though the names of the two other petitioners were mentioned in the initial complaint and in the eye witness' account, the first petitioner is neither named nor did the eye witness allude to him.

India's fuel consumption fell almost 46 per cent in April as all petroleum products, except LPG, saw massive demand erosion following the nationwide lockdown that halted economic activity and travel. The demand, which showed signs of pick up in the last 10 days of April after the government allowed resumption of economic activity beyond the urban municipal limit, is likely to rebound in second half of May as more areas are opened. India's fuel consumption fell 45.8 per cent to 9.929 million tonnes in April, down from 18.32 million tonnes fuel consumed in the same month a year back, according to official data released by the petroleum ministry. Fuel consumption during March, when travel restrictions began to be imposed to curb the spread of coronavirus, stood at 16.08 million tonnes. Petrol sales were down 60.43 per cent to 9,73,000 tonnes in April. The demand for the fuel had fallen 64 per cent in first half of the month, but there was some pick up in sales after reopening of some ...

Washington has halted funding for the WHO, a UN agency, after President Donald Trump accused it of being "China-centric" and promoting China's "disinformation" about the outbreak, assertions the WHO denies.

Fewer women in India now suffer from cervical cancer - counted among the worst of killers. However, breast cancer cases have shot up alarmingly.

Ever since the lockdown has been announced, mythological show, Ramayan and its actors are hitting headlines for one or the other reason. As the viewers are aware, Doordarshan had re-aired Ramayan during lockdown on popular demand. The iconic show broke all

China and the United States both supported a draft United Nations Security Council resolution confronting the coronavirus pandemic on Thursday and it was "shocking and regretful" that Washington changed its mind on Friday, a Chinese diplomat said.

Diphu-Guwahati bus service resumes

Corporation used lockdown period to clear accumulated garbage in various places

Munusamy, 26, was reportedly murdered in Gummidipoondi on Friday, by his neighbour Sanjay after a fight broke out between them, since the former refus

Petrol sales were down 60.43 per cent to 9,73,000 tonnes in April

The enzyme 4-hydroxy-tetrahydrodipicolinate synthase (DapA) is involved in the production of lysine and precursor molecules for peptidoglycan synthesis. In a multistep reaction, DapA converts pyruvate and l-aspartate-4-semialdehyde to 4-hydroxy-2,3,4,5-tetrahydrodipicolinic acid. In many organisms, lysine binds allosterically to DapA, causing negative feedback, thus making the enzyme an important regulatory component of the pathway. Here, the 2.1 Å resolution crystal structure of DapA from the thermoacidophilic methanotroph Methylacidiphilum fumariolicum SolV is reported. The enzyme crystallized as a contaminant of a protein preparation from native biomass. Genome analysis reveals that M. fumariolicum SolV utilizes the recently discovered aminotransferase pathway for lysine biosynthesis. Phylogenetic analyses of the genes involved in this pathway shed new light on the distribution of this pathway across the three domains of life.

In the crystal structure of the title compound, [Sn(C42H26N6)(C7H5O2)2], the SnIV ion is located on a crystallographic inversion centre and is octa­hedrally coordinated with an N4O2 set. Four N atoms of the porphyrin ring form the equatorial plane while the axial positions are occupied by two O atoms from benzoate anions. The molecular packing of the title complex involves non-classical hydrogen bonds of the types C—H⋯O and C—H⋯N, leading to a three-dimensional network structure.

In the title compound, C29H26ClNO4, the di­hydro­pyridine ring adopts a shallow boat conformation. The mean plane of the di­hydro­pyridine ring (all atoms) subtends dihedral angles of 66.54 (1), 73.71 (1) and 79.47 (1)° with the two phenyl rings and the chloro­phenyl ring, respectively. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into [001] chains.

In the title compound, C29H23ClN2O, the 5-chloro­phenol ring and the imidazole ring are nearly coplanar, with a dihedral angle of 15.76 (9)° between them. The ethyl­phenyl ring and the two phenyl rings subtend angles of 71.09 (7), 43.95 (5) and 36.53 (9)°, respectively, with the imidazole plane. An intra­molecular O—H⋯N hydrogen bond supports the mol­ecular conformation, and an inter­molecular C—H⋯O inter­action, originating from an ortho-phenyl H atom, stabilizes the packing arrangement. In addition, a weak C—H⋯π inter­action, also involving an ortho-phenyl H atom, is observed.

The title salt, (PMIM)2[Ni(P2S8)2] (PMIM = 3-methyl-1-propyl-1H-imidazol-3-ium, C7H13N2+), consists of a nickel–thio­phosphate anion charge-balanced by a pair of crystallographically independent PMIM cations. It crystallizes in the monoclinic space group P21/n. The structure exhibits the known [Ni(P2S8)2]2− anion with two unique imidazolium cations in the asymmetric unit. Whereas one PMIM cation is well ordered, the other is disordered over two orientations with refined occupancies of 0.798 (2) and 0.202 (2). The salt was prepared directly from the elements in the ionic liquid [PMIM]CF3SO3. Whereas one of the PMIM cations is well behaved (it does not exhibit disorder even in the propyl side chain), the other is found in two overlapping positions. The refined occupancies for the two orientations are roughly 80:20. Here, too, there appears to be little disorder in the propyl arm.

In the title compound, C20H21NO, the dihedral angle between the phenyl ring is 47.5 (1)° and the piperidine ring adopts a chair conformation. In the crystal, mol­ecules are linked by C—H⋯π inter­actions into dimers with the mol­ecules related by twofold symmetry.

The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C25H20), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulvene (C25H20), 6-mesityl-3-di­phenyl­fulvene (C27H24) and 6-(2,3,4,5,6-penta­methyl­phen­yl)-1,3-di­phenyl­fulvene (C29H28). The bond lengths are typical of those observed in related fulvenes. A network of C—H⋯π ring inter­actions consolidates the packing in each structure.

The title compound, C21H16N2O2, consists of an imidazolidine unit linked to two phenyl rings and two prop-2-yn-1-yl moieties. The imidazolidine ring is oriented at dihedral angles of 79.10 (5) and 82.61 (5)° with respect to the phenyl rings, while the dihedral angle between the two phenyl rings is 62.06 (5)°. In the crystal, inter­molecular C—HProp⋯OImdzln (Prop = prop-2-yn-1-yl and Imdzln = imidazolidine) hydrogen bonds link the mol­ecules into infinite chains along the b-axis direction. Two weak C—HPhen⋯π inter­actions are also observed. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (43.3%), H⋯C/C⋯H (37.8%) and H⋯O/O⋯H (18.0%) inter­actions. Hydrogen bonding and van der Waals inter­actions are the dominant inter­actions in the crystal packing. Computational chemistry indicates that the C—HProp⋯OImdzln hydrogen-bond energy in the crystal is −40.7 kJ mol−1. Density functional theory (DFT) optimized structures at the B3LYP/6–311G(d,p) level are compared with the experimentally determined mol­ecular structure in the solid state. The HOMO–LUMO behaviour was elucidated to determine the energy gap.

The title compounds, 8-amino-6-methyl-3,4-diphenyl-1H-isochromen-1-one, C22H17NO2, (I), and 8-amino-3,4-diethyl-6-methyl-1H-isochromen-1-one, C14H17NO2, (II), are new isocoumarin derivatives in which the isochromene ring systems are planar. Compound II crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. In I, the two phenyl rings are inclined to each other by 56.41 (7)° and to the mean plane of the 1H-isochromene ring system by 67.64 (6) and 44.92 (6)°. In both compounds, there is an intra­molecular N—H⋯O hydrogen bond present forming an S(6) ring motif. In the crystal of I, mol­ecules are linked by N—H⋯π inter­actions, forming chains along the b-axis direction. A C—H⋯π inter­action links the chains to form layers parallel to (100). The layers are then linked by a second C—H⋯π inter­action, forming a three-dimensional structure. In the crystal of II, the two independent mol­ecules (A and B) are linked by N—H⋯O hydrogen bonds, forming –A–B–A–B– chains along the [101] direction. The chains are linked into ribbons by C—H⋯π inter­actions involving inversion-related A mol­ecules. The latter are linked by offset π–π inter­actions [inter­centroid distances vary from 3.506 (1) to 3.870 (2) Å], forming a three-dimensional structure.

The crystal and mol­ecular structures of the title CuII complex, isolated as a dihydrate, [Cu(C21H14N3O3)2]·2H2O, reveals a highly distorted coordination geometry inter­mediate between square-planar and tetra­hedral defined by an N2O2 donor set derived from two mono-anionic bidentate ligands. Furthermore, each six-membered chelate ring adopts an envelope conformation with the Cu atom being the flap. In the crystal, imidazolyl-amine-N—H⋯O(water), water-O—H⋯O(coordinated, nitro and water), phenyl-C—H⋯O(nitro) and π(imidazol­yl)–π(nitro­benzene) [inter-centroid distances = 3.7452 (14) and 3.6647 (13) Å] contacts link the components into a supra­molecular layer lying parallel to (101). The connections between layers forming a three-dimensional architecture are of the types nitro­benzene-C—H⋯O(nitro) and phenyl-C—H⋯π(phen­yl). The distorted coordination geometry for the CuII atom is highlighted in an analysis of the Hirshfeld surface calculated for the metal centre alone. The significance of the inter­molecular contacts is also revealed in a study of the calculated Hirshfeld surfaces; the dominant contacts in the crystal are H⋯H (41.0%), O⋯H/H⋯O (27.1%) and C⋯H/H⋯C (19.6%).

In the crystal structure of the title compound, (C5H6N)[Cr(NCS)4(C5H5N)2]·C5H5N, the CrIII ions are octa­hedrally coordinated by four N-bonding thio­cyanate anions and two pyridine ligands into discrete negatively charged complexes, with the CrIII ion, as well as the two pyridine ligands, located on crystallographic mirror planes. The mean planes of the two pyridine ligands are rotated with respect to each other by 90°. Charge balance is achieved by one protonated pyridine mol­ecule that is hydrogen bonded to one additional pyridine solvent mol­ecule, with both located on crystallographic mirror planes and again rotated by exactly 90°. The pyridinium H atom was refined as disordered between both pyridine N atoms in a 70:30 ratio, leading to a linear N—H⋯N hydrogen bond. In the crystal, discrete complexes are linked by weak C—H⋯S hydrogen bonds into chains that are connected by additional C—H⋯S hydrogen bonding via the pyridinium cations and solvent mol­ecules into layers and finally into a three-dimensional network.

In the title compound, C22H27NO, the piperidine ring adopts a chair conformation. The dihedral angles between the mean plane of the piperidine ring and the phenyl rings are 89.78 (7) and 48.30 (8)°. In the crystal, mol­ecules are linked into chains along the b-axis direction by C—H⋯O hydrogen bonds. The DFT/B3LYP/6–311 G(d,p) method was used to determine the HOMO–LUMO energy levels. The mol­ecular electrostatic potential surfaces were investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots were used to analyse the inter­molecular inter­actions in the mol­ecule.

Insights were obtained into the structure of the 4-hydroxy-tetrahydrodipicolinate synthase from the thermoacidophilic methanotroph Methylacidiphilum fumariolicum SolV and the phylogeny of the aminotransferase pathway for the biosynthesis of lysine.

By now, most of the United States has started to feel the first cool caresses of winter. Everything is pumpkin spiced, and the last crickets […]

The post Feathered diplomats unite pupils in North and Central America appeared first on Smithsonian Insider.

India saw a 62 per cent decline in job hiring in the month of April, led by hotel/restaurant/travel/airlines industries that saw a massive -90 per cent less hiring activity that the same month last year.