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Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02507A, Research Article
Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
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Chelating Coordination Modulation Method for the Synthesis of Ti-MOF Single Crystals

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00436A, Research Article
Hui-Zi Li, Shangda Li, Fei Wang, Jian Zhang
Despite titanium-based metal-organic frameworks (Ti-MOFs) are promising as efficient photocatalysts, the high reactivity of titanium ions makes the synthesis and structure determination of new Ti-MOFs quite challenging. In this study,...
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
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NaVSeO5: Synergistic Combinations to Excellent Birefringent Materials

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00513A, Research Article
Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong
The novel NaVSeO5 birefringent crystals were successfully synthesized using a multifunctional group synergistic strategy, which combines a two-dimensional layered structure, consisting of stereochemically active lone pairs [SeO3], and anomalous [VO6]...
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National Mission on Edible Oil to help increase production to 25 mt by 2030-31: SEA

Over 60 per cent of edible oil requirement is now met through imports, which is a cause for concern, says SEA president Sanjeev Asthana




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Shift toward EVs could disrupt global oil market: International Energy Agency report

As China's rapid switch to electricity plays a significant role in disrupting the oil market, oil companies find they can sell more of their product to India




nation

Arya.ag bags $19.8 million from US International Development Finance Corporation

These funds will be utilised to connect farmers and FPOs with buyers across the country




nation

Ahmedabad to host third National Spice Conference on Nov 15,16

The event’s stated goal is to help farmers understand the importance of sustainable spice production and quality assurance




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Hyderabad to host international poultry expo from November 27

A technical seminar with the theme ‘Unlocking Poultry Potential’ will be held on November 26




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Cochin International Airport announces winter schedule with 1,576 weekly operations 

As per the new winter schedule, the total number of weekly services to UAE alone will be 134




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Schneider Electric to provide energy management solutions to Noida International Airport

The technologies will help optimise energy efficiency, reduce operational costs and minimise environmental impact




nation

Direct flights open up new overseas destinations, Indian arrivals rise in double digits

While revenge travel fueled post-Covid 19 pandemic travel recovery, easier visa norms and increased air connectivity are boosting demand




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Mangaluru International Airport records highest-ever passenger and air traffic movements in October 2024

The airport logged 1,538 air traffic movements, significantly up from 1,433 in September 2024




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Air India Express plans more international flights; to have over 110 planes by March 25

The airline, which recently completed the merger of AIX Connect with itself, has a fleet of around 90 aircraft and the count is expected to cross 110 by the end of this fiscal




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Musician Nadaka on the geet-taar, a string instrument he crafted, and his fascination for Indian classical music

Nadaka says the geet-taar, with its integration of four instruments, helps him play the nuances and micro-tones of Carnatic music.




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Noida International Airport joins UN Global Compact




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Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05998K, Edge Article
Open Access
Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi Guan
Utilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.
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The Effect of gem-Difluorination on the Conformation and Properties of a Model Macrocyclic System

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05424E, Edge Article
Open Access
Laurent Knerr, Thomas Cogswell, Marie. Ahlqvist, Richard James Lewis, Anneli Nordqvist, Christian Sköld
Conformational control of drug candidates to engineer improved potency and ADME properties is an ongoing area of research. Macrocyclic rings tend to offer a greater degree of rigidity than non-cyclised...
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Pd(II)-Catalyzed Enantioselective C-H Olefination and Photoregulation of Sterically-Hindered Diarylethenes

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05375C, Edge Article
Open Access
Guanlun Zhang, Xu Wu, Shiyu Mao, Mengqi Li, Honglong Hu, Bing-Feng Shi, Weihong Zhu
Sterically-hindered diarylethenes with intrinsic chirality have shown great potential in chiral signal regulation, light-controlled liquid crystals (LCs), etc. Their unique enantiospecific phototransformation between axial chirality of ring-open isomer and central...
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M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06324D, Edge Article
Open Access
Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. Reek
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
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Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05014B, Edge Article
Open Access
Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei He
Modulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.
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Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06581F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijun You, Daniel Roth, Lutz Greb
A structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.
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Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04629C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo Poli
The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...
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nation

When imagination and real life collide

Nidhi Dalmia’sHarpbrings to the fore the real-life conflicts faced by people in ’60s India




nation

Back to Basics: Have you filed in nomination for your MF?

Non-submission of ‘choice of nomination’ shall not result in freezing of MF folios for existing investors. But, you have more to lose not doing it




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Recent tweaks by SEBI in norms pertaining to nominations

A brief explainer on the amendments pertaining to investors recently brought in




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Cool Jew Named National Jewish Book Award Finalist

Congratulations to author Lisa Alcalay Klug, recipient of an honor in the "Jewish Pulitzers." Her book, Cool Jew: The Ultimate Guide for Every Member of the Tribe, published by Andrews McMeel in September 2008, has been named a 2008 National Jewish Book Awards finalist.

Cool Jew is a loving and irreverent celebration of Jewish culture. In addition to its fervent call for positive Jewish identity and affiliation, and embrace of Jewish multiculturalism, language, and more, the 250-page humor book also chronicles contemporary Jewish arts and culture with approximately 400 images. These include original line drawings, vintage Israeli and Jewish posters, t-shirt designs, kabbalistic paintings from Israel, album covers, kitsch and more. Cool Jew also features extensive back-of-the-book resource guides on ways to enjoy Jewish community called "Da Tribe Online" and contemporary Jewish music called "Da Heebster Jewkebox."

Cool Jew placed in the category of "Contemporary Jewish Life and Practice." It is the only humor book among the 2008 National Jewish Book Award honorees.

Each year, the National Jewish Book Awards honor some of the best and most exciting authors in the field of Jewish literature. After more than fifty years of presenting these awards, hundreds of books have received the prestigious National Jewish Book Award, including titles by the top authors on the American Jewish literary scene. For the full list of winners and finalists, click here.

The 58th Annual National Jewish Book Awards Ceremony will be held at 7:30 pm, March 5th at the Center for Jewish History in New York City. The ceremony is free and open to the public.

This is the second honor for author Lisa Alcalay Klug since the September release of her first book. She was previously named Erma Bombeck Humor Writer of the Month by the University of Dayton.



  • Cool Jew
  • Jewish Book Awards
  • Lisa Alcalay Klug

nation

HC allows medical termination of pregnancy of minor rape survivor

Division Bench passed the order while allowing an appeal filed against a single judge’s order declining permission. Medical board said that termination of pregnancy was most appropriate




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Cabinet clears ₹2,254 crore for national forensic infra enhancement scheme

Under this scheme, the MHA will establish campuses of the National Forensic Sciences University and central forensic science laboratories in the country




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Govt announces guidelines for funding testing facilities under National Green Hydrogen Mission

With a budget of ₹200 crore till FY26, the scheme aims to support the development of standards and regulatory frameworks in the Green Hydrogen sector.




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Government schemes catapulting India to become developed nation: Amit Shah

Modi government has ended “policy paralysis” and transformed India into an economic bright spot, says Union Home Minister Amit Shah




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'Nation is proud of you': West Bengal Guv to GRSE on laying keels of two NGOPVS




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What is elimination inflammation diet that helped Vidya Balan lose weight?

Chronic inflammation can cause weight gain, fatigue, and pain. It is linked to serious conditions like diabetes and heart disease.




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Combination targeted treatment produces lasting remissions in people with resistant aggressive B-cell lymphoma

More than half of clinical trial participants treated with venetoclax, ibrutinib, prednisone, obinutuzumab, and lenalidomide (ViPOR) had substantial tumor shrinkage. Of those, 38% had tumors that disappeared completely.




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Why ‘one nation, one election’ would strike a blow against federalism | Data

The idea of simultaneous elections is untenable if its impact on existing Assemblies and the three-tier system is considered.




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West Asian nations hold the highest number of Indians in jails abroad | Data

Nearly 9,500 Indians are currently lodged in prison across 89 nations




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Chess Olympiad | Absolute domination by both Indian teams, says Harikrishna




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International hockey set to return to New Delhi after 10 years; veteran players Zafar Iqbal, Harbinder Singh hail Indian team

Mr. Iqbal, a gold medallist at the 1980 Moscow Olympics and captain of the 1982 Asian Games silver-winning Indian team, is hopeful for growth of Indian hockey after the bronze medals in the Tokyo and Paris Olympics.




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New National champion Nandhidhaa sets sights on becoming a GM




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French boxing quits international body to keep its fighters at Olympics

The IOC took over running the boxing competition at this year’s Paris Olympics.




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Iranian charged for plotting Trump assassination tasked with targeting Israeli tourists in Sri Lanka: U.S authority

Shakeri is an Islamic Revolutionary Guard Corps (IRGC) asset, remains at large and is believed to reside in Tehran, Iran




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President-elect Donald Trump chooses Elise Stefanik as Ambassador to United Nations

Nikki Haley, who challenged Mr. Trump for the GOP nomination, was among those who previously held the role in his first term.




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Trump asks Mike Waltz, China hawk, to be national security adviser

There are concerns on Capitol Hill about Donald Trump tapping members of the House, where the final tally is still uncertain




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DYFI appeals to APPSC to postpone Group-II Mains examination by a month




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Two-day 6th National Women’s Conference in Vijayawada from November 22

Objective of the meet is to explain to women their legal right to work in a safe environment; more than 200 delegates working in various public sector organisations to attend




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Kondamodu-Perecherla National Highway project in A.P. gets Centre’s nod

The Union Ministry has approved the bid submitted by RRS Infra, amounting to ₹506.88 crore.




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Nitrogen-doped biomass-derived carbon dots for fluorescence determination of sunset yellow

Anal. Methods, 2024, 16,2063-2070
DOI: 10.1039/D3AY01944F, Paper
Qian Zhang, Xiaoqi Wang, Lili Yuan, Lina Yu, Congying Shao, Hongxing Jia, Shun Lu
Schematic of preparation of N-CDs and their sensing mechanism for sunset yellow.
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