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Two independent candidates file nominations for Vizianagaram local body MLC seat




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MRF consolidated Q2 net skids 20% to ₹471 cr. on input cost hike




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Chola Finance consolidated Q2 net rises 27% to ₹1,125 crore




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TVS Supply Chain Solutions posts consolidated Q2 net profit of ₹11 crore




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Kidaari: new genre of 'Aruvaa Christie'?

It’s not a good sign when the story seems less interested in suspense than in sickles whooshing down every few minutes.




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Adidas Switch FWD review | Switches forward by mending past and present

The Adidas Switch Fwd series effectively blends the soft EVA foam with the harder TPU plate to give a comfortably cushioned midsole for running on city roads




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Embassy REIT Q2 NOI up 12%; raises leasing guidance for FY25

Over half of its properties across Bengaluru, Mumbai and Chennai saw an average occupancy of around 95 per cent




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DLF Q2 consolidated net profit up 121 per cent

Consolidated revenues saw a 48 per cent increase y-o-y to ₹2,181 crore. It stood at ₹1,477 crore in the year-ago-period.




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Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01681E, Research Article
Lu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai Zhou
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01801J, Research Article
Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
An I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01628A, Research Article
Feng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min Lin
A novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iridium/palladium dual photocatalysis for oxidative decarboxylative esterification of alcohols using α-keto acids

Org. Chem. Front., 2024, 11,6367-6379
DOI: 10.1039/D4QO01452A, Research Article
Subal Mondal, Soumya Mondal, Debabrata Halder, Siba P. Midya, Ankan Paul, Pradyut Ghosh
Herein, we report an unprecedented oxidative decarboxylative C–O cross-coupling reaction for the esterification of feedstock α-keto carboxylic acids and alcohols under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes

Org. Chem. Front., 2024, 11,6385-6392
DOI: 10.1039/D4QO01243G, Research Article
Jinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian Chen
A cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions

Org. Chem. Front., 2024, 11,6437-6443
DOI: 10.1039/D4QO01265H, Research Article
Dabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou Cai
In this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Regio- and stereoselective azidation of activated N-allenamides: an entry to α, β, γ and δ-amido-azides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01802H, Research Article
Dorian Schutz, Maxime Hourtoule, Laurence Miesch
A totally controlled regiodivergent azidation of activated N-allenamides is described, offering a broad range of diverse functionalized amido-azide derivatives.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district




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The Complete to Planning Your Estate in Florida: A Step-by-Step Plan to Protect Your Assets, Limit Your Taxes, and Ensure Your Wishes are Fulfilled for Florida Residents

What happens to your estate after you are gone is very much within your control. Estate planning is not only for the wealthy; it is for everyone. It is simply the process of deciding where your assets are to be distributed after your death. For those people who wish to preserve their assets for designated […]




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Investigation of the titanium-mediated catalytic enantioselective oxidation of aryl benzyl sulfides containing heterocyclic groups

RSC Adv., 2024, 14,35105-35113
DOI: 10.1039/D4RA07088G, Paper
Open Access
Maria Annunziata M. Capozzi, Angel Alvarez-Larena, Joan F. Piniella Febrer, Cosimo Cardellicchio
Enantiopure benzyl heteroaryl sulfoxides were obtained by asymmetric oxidation. However, two benzimidazolyl sulfoxides were found to be conglomerates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Transient crystallisation of rare earth carbonates during the hydrothermal oxidation of siderite

RSC Adv., 2024, 14,35305-35322
DOI: 10.1039/D4RA05212A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maddin M., Rateau R., Szucs A. M., Terribili L., Rodriguez-Blanco J. D.
The researchers investigated the interaction between multi-component rare earth element-bearing aqueous solutions and siderite grains under hydrothermal conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Design, synthesis, biological evaluation, and in silico studies of novel N-substituted-2-(3,4,5-trimethoxyphenyl)-1H-benzo[d]imidazole-6-carboxamides as promising anticancer agents

RSC Adv., 2024, 14,35323-35335
DOI: 10.1039/D4RA04492D, Paper
Open Access
Navid Dastyafteh, Manica Negahdaripour, Mohammad Hosein Sayahi, Mina Emami, Younes Ghasemi, Elham Safaei, Homa Azizian, Zahra Pakrouh Jahromi, Mehdi Asadi, Mohammad Reza Mohajeri-Tehrani, Fateme Zare, Minoo Shahidi, Zahra Pooraskari, Sayed Mahmoud Sajjadi-Jazi, Bagher Larijani, Mohammad Mahdavi, Sara Ranjbar
Synthesis and cytotoxicity evaluation of novel benzimidazoles were explained. The most potent derivative was subjected to cell cycle, apoptosis, and in silico investigations. Compound 5o proved to be a promising anticancer agent.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A mild and convenient protocol for the synthesis of quinoxalin-2(1H)-ones and benzimidazoles

RSC Adv., 2024, 14,35386-35390
DOI: 10.1039/D4RA06887D, Paper
Open Access
Zhenbiao Luo, Mingyuan Wang, Guidong Jiang, Xinye Wang, Liang Zhao, Zhihui Hu, Honghe Li, Qing Ji
We present a mild and simple method for the cyclization of N-protected o-phenylenediamines with carbonyl compounds in the presence of trifluoroacetic acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




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N-doped carbon quantum dots for the selective detection of OCl− ions, bioimaging, and the production of Fe3O4 nanoparticles utilized in the synthesis of substituted imidazole

RSC Adv., 2024, 14,35448-35459
DOI: 10.1039/D4RA06474G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Namrata Priyadarshini Hota, Sathiyanarayanan Kulathu Iyer
Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using o-phenylenediamine and L-tartaric acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Advanced oxidative degradation of monoethanolamine in water using ultraviolet light and hydrogen peroxide

RSC Adv., 2024, 14,33223-33232
DOI: 10.1039/D4RA05590J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Atif Khan, Saima Yasin, Hamayoun Mahmood, Shabana Afzal, Tanveer Iqbal
Development of an eco-friendly and commercially feasible method for monoethanolamine (MEA) degradation in aqueous phase using ultraviolet/hydrogen peroxide (UV/H2O2) advanced oxidation process (AOP).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes

RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
Open Access
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Preparation and antioxidant properties of tannic acid/copper ion nanozyme hybrid nanofibrous membranes

RSC Adv., 2024, 14,35743-35753
DOI: 10.1039/D4RA05314A, Paper
Open Access
Qiao Wu, Jingshu Xiao, Hu Zhuang, Fenghai Zhao, Ruoxi Li, Duntie Zhang
A Cu/TA nanosheet was prepared by Cu2+ -mediated oxidative coupling inducing the self-assembly of a Cu-TA coordination complex network, which exhibits multienzyme like activity and enables the preparation of antioxidant membranes by electrospinning.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Avinash Sable overwrites own meet record, Kushare consolidates Paris spot

The national record holder Avinash Sable, who has already attained the Paris Olympic qualifying standard, clocked 8:31.75 to overwrite his own previous meet record of 8:33.19, set five years ago in Lucknow.




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Sebastian Coe, multi-millionaire Johan Eliasch among seven candidates for IOC presidency

The IOC, with 111 members currently, is in charge of the Olympic Games and the multi-billion dollar industry linked to the world's biggest multi-sports event.




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FACTBOX-Who are the candidates running in the US presidential election?

The upcoming elections in the United States on November 5 have the world on the edge of their seats as they heat up, here is a brief overview of who they are




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Nobel Peace Prize awarded to Japanese atomic bombing survivors’ group Nihon Hidankyo

We wish to honour all survivors who, despite physical suffering and painful memories, have chosen to use their costly experience to cultivate hope and engagement for peace, says Jørgen Watne Frydnes, chair of the Norwegian Nobel Committee




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Hurricane Milton leaves 16 dead and millions without power in Florida

The hurricane, among the most intense in the Atlantic, has incurred a lowered insurance cost estimate of $30 to $60 billion.




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Fighting India lose 0-1 to formidable Iran in AFC U20 Asian Cup Qualifiers

The top teams of the 10 groups, along with the five best second-place finishers, will qualify for the AFC U20 Asian Cup 2025 in China




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Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02197E, Paper
Vandana Kardam, Vaibhav Bhatt, Kshatresh Dubey
Arylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02650K, Communication
Katherine Merkel, Alyssa V. B. Santos, Scott Simpson
DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications

Dalton Trans., 2024, 53,17852-17863
DOI: 10.1039/D4DT02538E, Paper
Kelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. Toledo
A structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene

Dalton Trans., 2024, 53,17880-17892
DOI: 10.1039/D4DT02544J, Paper
Zhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing Cui
Three novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites

Dalton Trans., 2024, 53,18021-18026
DOI: 10.1039/D4DT02421D, Paper
Afif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki Motohashi
The oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors

Dalton Trans., 2024, 53,17783-17788
DOI: 10.1039/D4DT02336F, Communication
Danijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. Swiegers
Ca-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.
The content of this RSS Feed (c) The Royal Society of Chemistry




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BJP poll agent writes to EC against Shiggaon Congress candidate




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Nov 20 Maharashtra election: 4,140 candidates in fray; 2,938 withdraw nominations




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Saturday’s Bengaluru races advanced to Friday




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Tata Motors Q2 consolidated net profit declines 11% to ₹3,343 crore

The company had posted a consolidated net profit of ₹3,832 crore in the same quarter of the last fiscal, Tata Motors said in a regulatory filing.




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Palakkad Assembly by-poll: CPI(M)-BJP move to exploit ‘dissension’ in Congress over Mamkootathil’s candidature

The parties spotlight a letter ostensibly written by the District Congress Committee to the party’s national leadership requesting K. Muraleedharan’s candidature in Palakkad. Mr. Muraleedharan later confirms that his name was on the DCC list.




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Poet Satchidanandan to gradually end his public life, cites memory issue




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The business of holidaying

Kavinder Singh on how Mahindra Holidays delivers on its vacation ownership model




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How do they meet holiday expenses?

Be it saving for a vacation or banking on surplus income, going it alone or through agents, people budget for travel in their own way. Here’s how




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Decisions, preferences, and heuristics [electronic resource] : an introduction to economic psychology and behavioral economics / Pere Mir-Artigues (Professor of Microeconomics, University of Lleida, Spain).

Cheltenham, UK ; Northampton, MA : Edward Elgar Publishing, [2023]




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Jharkhand Election 2024: Full List Of Candidates And Their Constituencies

Jharkhand Election 2024 Candidates List: A total of 1,211 candidates remain in the contest for the Jharkhand Assembly Elections.