Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight

Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication

Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li⁺[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04938A, Communication

Junqing Wang, Xiaoyi Lai, Yongzhi Zhou, Lei Hua, Weiguo Zhu, Pengfei Duan, Yafei Wang
Two orange-red emission circularly polarized thermally activated delayed fluorescence emitters (R)-ad-PXZ/(S)-ad-PXZ were synthesized. The solution processable device exhibits the maximum external quantum efficiency of 9.0% and g_EL value of 10⁻³.
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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Mol. Syst. Des. Eng., 2024, 9,1155-1166
DOI: 10.1039/D4ME00071D, Paper

Laura Le Bras, Yves L. Dory, Benoît Champagne
An α-synuclein aggregate with the PreNAC and NACore areas, responsible for the aggregation, highlighted.
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ06001B, Paper

Wanxi Yang, Wencai Peng, Han Li, Jin Mao, Liqiang Qian, Qingyu Zhang
HKUST-1 with high crystallinity has been successfully synthesized by solvothermal method using Cu(NO3)2·3H2O as a copper source, 1,3,5-benzenetricarboxylic acid as organic ligand, and N,N-dimethylformamide as solvent. HKUST-1 exhibited a typical...
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper

Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ01096E, Paper

Liwen Wang, Guanghui Zhang, Ruishu Zhang, Siqi Yang, Wenjuan Huang, Xiangbai Chen
Co₃O₄ hollow polyhedra have a high specific surface area and mesoporous structure. The Co₃O₄ gas sensor has excellent sensing performance and selectivity for xylene.
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New J. Chem., 2024, 48,7256-7264
DOI: 10.1039/D3NJ05906E, Paper

Hele Hua, Jing Yang, Rui Li, Yunfang Wang, Caimei Fan, Jianxin Liu, Yawen Wang
The BiOBr/CGFS photocatalysts were synthesized at ambient temperature by a simple hydrolysis method with zero pre-treatment of CGFS. CGFS led to the improvement of the quantum efficiency of BiOBr and further promoted the photocatalytic performance.
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New J. Chem., 2024, 48,7356-7361
DOI: 10.1039/D4NJ00886C, Paper

Zefeng Li, Caihang Zhang, Yingxuan Zheng, Ping Deng, Yan Yu
The palladium-catalyzed solvent-free and ligand-free oxidative homocoupling reactions of aryl boronic acids via ball-milling are developed to synthesize a series of biphenyl-derived organic fluorescent materials.
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New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper

Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00906H, Critical Review

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Zexiao Zheng, Juhua He, Zuyao Zhang, Ashutosh Kumar, Musharib Khan, Cheuk Wai Lung, Irene M. C. Lo
The critical review covers the applications, associated mechanisms, challenges, and prospects of magnetically recyclable nanophotocatalysts in photocatalysis-related processes.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper

Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper

Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper

Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO₂ can improve the performance of TiO₂ in the photocatalytic degradation of organic pollutants.
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Environ. Sci.: Nano, 2024, 11,1462-1476
DOI: 10.1039/D3EN00701D, Paper

Wenjian Mao, Dengjun Wang, Pan Wu, Jian Zhu, Peng Liao, Kaidi Lai, Zihan Ding, Yuqin Zhang, Zhongxu He, Ruyi Zheng, Yonglin Chen
Schematic diagram of the mechanism of Fe–NOM–Sb(V) colloids formation and transport in the natural environment.
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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00134F, Paper

Wenhui Bai, Hongze Lu, Yang Liu, Xue Yuan, Yuejie Ai, Lidong Wang, Zhe Chen
As an antibiotic drug, sulfamethoxazole (SMX) is a nitrogen-containing and sulfur-containing heterocyclic compound, which is an endocrine disruptor and difficult to be biodegraded. Not only can it exist stably in...
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CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper

Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H₄DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00200H, Paper

Kai Jiang, Lingyan Xu, Rongjin Shang, Lu Liang, Yingming Wang, Zhentao Qin, Wanqi Jie
High-quality TPB single crystals were obtained without obvious step-like growth morphology. The TPB devices could present α-particle and γ-ray spectral responses with high energy resolution, showing potential for direct radiation detection.
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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper

Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper

Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication

Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight

Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper

Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication

Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00281D, Review Article

Bubul Das, Anjali Dahiya, Bhisma K Patel
: Owing to their unique structural features, isothiocyanates (ITCs) are a class of highly useful and inimitable reagents as the N=C=S group serves both as electrophile and nucleophile in organic...
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Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00236A, Review Article

Goverdhan Mehta, Saumitra Sengupta, Srihari Pabbaraja
Often referred to as “second genome”, human microbiome is at the epicenter of a complex inter-habitat biochemical network, such as the “gut-brain axis”, which have emerged as significant determinant of...
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00171K, Review Article

Bor-Cherng Hong, Ranadheer Reddy Indurmuddam
This review summarizes recent developments in visible-light or near-visible-light photocatalysis reactions enabled by the TBADT catalyst.
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Mater. Chem. Front., 2024, 8,3587-3595
DOI: 10.1039/D4QM00465E, Research Article

ChengLong Wen, Jun Yuan, Zhiguo Zhang, Dongxu Li, Yuqian Zhou, Wanqiang Liu, Zaichun Zhou, Yungui Li, Lihui Jiang, Yingping Zou
Three acceptors with different aromatic side chains were synthesized and the photovoltaic performance effects of steric hindrances were studied. BTP-1-iPr better matches the energy level of PM6, obtaining higher V_OC, FF and PCE of 17.19%.
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Mater. Chem. Front., 2024, 8,3509-3527
DOI: 10.1039/D4QM00358F, Review Article

Junmei Li, Yinan Fan, Ruigan Zhang, Demao Ban, Zhixuan Duan, Xiaoyuan Liu, Lifang Liu
Metal–organic frameworks (MOFs) have become a research hotspot for effective adsorption and degradation of chemical warfare agents (CWAs) and toxic industrial chemicals (TICs).
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Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00567H, Review Article

Jun Wu, Xingchen Ding, Xiashi Zhu
This review mainly summarises the progress in the preparation methods of organic compound/g-C₃N₄. Various materials such as different types of organic compound/g-C₃N₄ composites and their related energy and environmental applications are discussed.
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Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00735B, Research Article

Shumeng Wang, Hongqiang Dong, Guanfei Gong, Siyi Lin, Jiahao Zhao, Zhennan Tian, Ya Lu, Xuguan Bai, Meimei Zhang, Lu Wang, Kang-Da Zhang, Shigui Chen
A novel class of [N⋯I⋯N]⁺ halogen-bonded XOFs were synthesized using imidazole ligands. XOF-TIB showed strong adsorption capacity and selectivity for anionic dyes, with excellent stability and reusability for environmental remediation.
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Nanoscale Horiz., 2024, 9,1853-1854
DOI: 10.1039/D4NH90063D, Editorial

Chao Wang
This article highlights the recent work of Biju, Takano et al. (Nanoscale Horiz., 2024, 9, 1128–1136, https://doi.org/10.1039/D4NH00134F) on using a unique bio-catalytic nanoparticle shaping method for preparing mesoscopic particles.
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Nanoscale Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4NH00487F, Review Article

yi Wei, Zhixiang Liu, Guangzhao Qin
In inorganic crystals, phonons are the elementary excitations describing the collective atomic motions. The study of phonons plays an important role in terms of understanding thermal transport behavior and acoustic...
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Nanoscale Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4NH00525B, Review Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Alessio Zuliani, Victor Ramos, Alberto Escudero, Noureddine Khiar
The unique features of metal-organic frameworks (MOFs) such as biodegradability, reduced toxicity and high surface area offer the possibility of developing smart nanosystems for biomedical applications through the simultaneous functionalization...
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J. Anal. At. Spectrom., 2024, 39,2903-2916
DOI: 10.1039/D4JA00292J, Paper

Open Access

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Alex Wangeci, Maria Knadel, Olga De Pascale, Mogens H. Greve, Giorgio S. Senesi
Evaluating the performance of handheld LIBS for determination of soil properties across a continental scale.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07077A, Paper

Weisheng Zhang, Chen-Xing Zhang, Xianhe Chen, H.J. Yin, Wenli Hu, Shilin Mei, Chang-Jiang Yao
Sodium dual ion batteries (SDIBs) have received considerable attention recently for large-scale energy storage systems due to their low cost and inherent safety. Nevertheless, SDIBs remain a subject of investigation,...
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J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper

Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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J. Mater. Chem. A, 2024, 12,30862-30871
DOI: 10.1039/D4TA04729J, Paper

Open Access

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Li-Chung Kin, Andreas Distler, Oleksandr Astakhov, Bakary Kone, Hans Kungl, André Karl, Tsvetelina Merdzhanova, Rüdiger-A. Eichel, Christoph J. Brabec, Uwe Rau
Generalized framework for the design of indoor power units for autonomous Internet of Things (IOT) devices results in record efficiency combination of organic PV and sodium ion battery.
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J. Mater. Chem. A, 2024, 12,30558-30566
DOI: 10.1039/D4TA06146B, Paper

Qingya Wei, Yuanyuan Li, Weikun Chen, Qinhao Shi, Shaofeng Zhu, Wensheng Yan, Yingping Zou
A low-cost pentacyclic fused-ring SMA, BZ4F-ch1, was designed with a cyclohexyl side-chain, which achieved a high device efficiency over 16% with an FF over 80%. Besides, the highest PCE/MOC value of 3.56 revealed remarkable cost-effectiveness.
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J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper

Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper

Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper

Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper

Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper

Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO₃⁻ and H₂O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH₃ yield.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication

Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper

Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06028H, Review Article

Open Access

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Febri Baskoro, Santosh U. Sharma, Andre Lammiduk Lubis, Hung-Ju Yen
Lithium-ion batteries stand at the forefront of energy storage technologies, facilitating the transition towards sustainable and electrified systems. To meet the increasing demands for energy density, safety, and longevity, the...
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper

Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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