organic

President's Cancer Panel: Organic Foods Reduce Environmental Risks

President's Cancer Panel: Organic Foods Reduce Environmental Risks




organic

"The conversation was very organic": Seema Sajdeh on discussing her relationship with Vikram with her son Nirvaan

Seema Sajdeh has opened up about how discussing relationship with beau Vikram with her son Nirvaan was "cathartic"




organic

Growing Organic Broccoli At Home In Six Easy Steps

A green vegetable that is closely related to cabbage, Brussels sprouts, kale, and cauliflower, broccoli is packed with vitamins, minerals, fibre, and antioxidants. It is often used in salads, and it is also edible raw. Among broccoli's most significant benefits is





organic

Critical review of fluorescence and absorbance measurements as surrogates for the molecular weight and aromaticity of dissolved organic matter

Environ. Sci.: Processes Impacts, 2024, 26,1663-1702
DOI: 10.1039/D4EM00183D, Critical Review
Open Access
Julie A. Korak, Garrett McKay
Optical surrogates are used to characterize dissolved organic matter composition like aromaticity and molecular weight. We both review the genesis of surrogate-composition relationships and critically evaluate additional supporting evidence.
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organic

Critical insights into data curation and label noise for accurate prediction of aerobic biodegradability of organic chemicals

Environ. Sci.: Processes Impacts, 2024, 26,1780-1795
DOI: 10.1039/D4EM00431K, Paper
Open Access
Paulina Körner, Juliane Glüge, Stefan Glüge, Martin Scheringer
The newly developed classifier has a balanced accuracy of 94.2%, better than any other classification model for aerobic biodegradability so far. During the model development, some data points needed to be excluded due to a very high variance.
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organic

Organic aerosol formation from 222 nm germicidal light: ozone-initiated vs. non-ozone pathways

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00384E, Paper
Open Access
Matthew B. Goss, Jesse H. Kroll
Ozone production can explain most indoor air quality impacts of 222 nm germicidal ultraviolet light (GUV222). However, GUV222 causes more new particle formation than is explained by ozone chemistry.
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organic

Mobility of biochar-derived dissolved organic matter and its effects on sulfamerazine transport through saturated soil porous media

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00143E, Paper
Mengya Liu, Xiaochen Liu, Yalu Hu, Qiang Zhang, Usman Farooq, Zhichong Qi, Laotao Lu
Dissolved organic matter (DOM) released from biochar may impact antibiotic mobility and environmental fate in subsurface environments.
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organic

Mapping inorganic crystal chemical space

Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00063C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hyunsoo Park, Anthony Onwuli , Keith Butler, Aron Walsh
The combination of elements from the Periodic Table defines a vast chemical space. Only a small fraction of these combinations yields materials that occur naturally or are accessible synthetically. Here,...
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organic

A novel cerium-based metal-organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02225D, Research Article
Open Access
Xiangdi Zeng, Zi Wang, Meng He, Wanpeng Lu, Wenyuan Huang, Bing An, Jiangnan Li, Li Mufan, Ben Spencer, Sarah Day, Floriana Tuna, Eric J L McInnes, Martin Schroder, Sihai Yang
Phenylacetylene is a detrimental impurity in the polymerisation of styrene, capable of poisoning catalysts even at ppm levels and significantly degrading the quality of polystyrene. The semi-hydrogenation of phenylacetylene to...
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organic

Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article
Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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organic

Reconstruction and immobilization of polymolybdate induced by metal-organic coordination units for enhanced electrocatalytic hydrogen generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02311K, Research Article
Jingyi Ma, Zhihan Chang, Xue Xi, Juju Liang, Yuchun Lin, Yaling Zhu, Xiuli Wang
Electrocatalytic water cracking for hydrogen evolution has drawn the concern from researchers owing to its high efficiency. Polymolybdate has excellent redox behaviors and O-rich surface, becoming attractive electrocatalytic materials. In...
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organic

Realizing efficient broadband near-infrared emission under blue light excitation in Sb3+-doped zero-dimensional organic tin(IV)-based metal halides via coordination structure modulation

Inorg. Chem. Front., 2024, 11,7979-7990
DOI: 10.1039/D4QI01904K, Research Article
Bao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou
Here, we report a new NIR emitter of Sb3+-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.
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organic

Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

Inorg. Chem. Front., 2024, 11,7756-7774
DOI: 10.1039/D4QI02232G, Review Article
Hangwei Jia, Xueling Hou, Shilie Pan
The calculated polarizability anisotropy, hyperpolarizability and HOMO–LUMO gap of optically active groups.
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organic

Metal–organic framework micro-nano reactors as armour of Escherichia coli for hydrogen production in air

Inorg. Chem. Front., 2024, 11,8070-8077
DOI: 10.1039/D4QI02119C, Research Article
Yun Fan, Junyang Yan, Siyao Zhang, Ruifa Su, Baoli Zha, Weina Zhang
The MOF shell of an E. coli@ZIF-8 micro–nano reactor, used as armour for E. coli, not only protects the internal E. coli and improves its survival rate, but also delays the transport of oxygen to enable E. coli to produce hydrogen in air.
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organic

Linker engineering in mixed-ligand metal–organic frameworks for simultaneously enhanced benzene adsorption and benzene/cyclohexane separation

Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article
Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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organic

Active molecular units in metal organic frameworks for artificial photosynthesis

Inorg. Chem. Front., 2024, 11,7682-7755
DOI: 10.1039/D4QI01363H, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Subrata Mandal, Sahar Yoosefi, Alexander K. Mengele, Sven Rau, Andrea Pannwitz
Metal–organic frameworks (MOFs) integrate photoactive and catalytic entities within a 3D structure. This review classifies photocatalytic MOFs by photosensitizer and catalyst localization and their roles in artificial photosynthesis.
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organic

Optimizing the spin qubit performance of lanthanide-based metal–organic frameworks

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02324B, Research Article
Xiya Du, Lei Sun
Reducing the spin concentration, spin-orbit coupling strength, and ground spin state of lanthanide ions embedded in metal–organic frameworks improves their spin qubit performance.
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organic

Ionic-liquid/metal-organic-framework composites: Synthesis and emerging sustainable applications

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02383H, Review Article
Maiyong Zhu
Ionic liquids (ILs) as emerging solvents have demonstrated a significant prospective in green chemistry, which can be used as green solvent, high efficiency catalyst, electrolyte, and so on. Metal–organic frameworks...
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organic

Lithium extraction by metal–organic frameworks

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02228A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zongsu Han, Joshua Rushlow, Yihao Yang, Jiatong Huo, Wei Shi, Hong-Cai Zhou
Lithium extraction attracts great attention due to the rising demand for batteries, but faces challenges related to low natural abundance and environmental concerns. MOFs show promise in lithium extraction, benefitting from customizable structures.
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organic

Integrated high performance microfluidic organic analysis instrument for planetary and space exploration

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00012A, Paper
Anna L. Butterworth, Matin Golozar, Zachary Estlack, Jeremy McCauley, Richard A. Mathies, Jungkyu Kim
This work presents the design, fabrication, and automation of our space flight-format microfabricated sample processing and capillary electrophoresis analysis instrument.
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organic

Freezing-enhanced chlorination of organic pollutants for water treatment

RSC Adv., 2024, 14,12218-12224
DOI: 10.1039/D4RA00081A, Paper
Open Access
Duanyang Wu, Junxue Li, Jing Xu, Wei Cheng
Freezing-accelerated chlorination was observed for different organic pollutants and the chlorine/freezing system shows potential feasibility for water treatment in cold environments.
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organic

Insoluble low-impedance organic battery cathode enabled by graphite grafting towards potassium storage

RSC Adv., 2024, 14,12658-12664
DOI: 10.1039/D4RA01420K, Paper
Open Access
Xiaolei Sun, Xianhui Yi, Ling Fan, Bingan Lu
Insoluble polymerized organic electrode is developed and wrapped in graphite sheets, which possesses low-impedance and realized a cycling life of over 1500 cycles. This work provides insights for exploring high-performance organic cathodes.
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organic

The untold story of starch as a catalyst for organic reactions

RSC Adv., 2024, 14,12676-12702
DOI: 10.1039/D4RA00775A, Review Article
Open Access
Masoud Sadeghi
Starch as catalyst for organic reactions.
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organic

Current status of controlled onco-therapies based on metal organic frameworks

RSC Adv., 2024, 14,12817-12828
DOI: 10.1039/D4RA00375F, Review Article
Open Access
Yixuan Yang, Xiaofeng Dai
Most MOFs for controllable cancer treatment act as drug delivery vehicle and/or anti-cancer agent. Molecules with anti-cancer roles such as chemotherapies, gases, peptides or nucleic acids can be loaded into MOFs that decompose in cancer cells or in the TME to release its cargoes.
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organic

Use of benzothiophene ring to improve the photovoltaic efficacy of cyanopyridinone-based organic chromophores: a DFT study

RSC Adv., 2024, 14,12841-12852
DOI: 10.1039/D3RA06817J, Paper
Open Access
Iqra Shafiq, Muhammad Khalid, Gul Maria, Nadeem Raza, Ataualpa A. C. Braga, Saifullah Bullo, Mohamed Khairy
The benzothiophene based chromophores (A1D1–A1D5) with A–π–A configuration were designed via end-capped tailoring with benzothiophene type acceptors using reference compound (A1R).
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organic

The influence of hydrogen bonding on the structure of organic–inorganic hybrid catalysts and its application in the solvent-free epoxidation of α-olefins

RSC Adv., 2024, 14,12853-12863
DOI: 10.1039/D4RA01399A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hong-Bin Ju, Li-Zhi Zhang, De-Bao Li, Tao Geng, Ya-Jie Jiang, Ya-Kui Wang
Different reaction routes with the influence of hydrogen bonding and without hydrogen bonding.
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organic

Unexpected reversal of reactivity in organic functionalities when immobilized together in a metal–organic framework (MOF)

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00185G, Communication
Pricilla Matseketsa, Donovan Mafukidze, Lahiru Pothupitiya, Udo P. Otuonye, Yasemin Çimen Mutlu, Boris B. Averkiev, Tendai Gadzikwa
The reactivity of hydroxyl-bearing MOF linkers with isocyanates is influenced by their mutual confinement with amine-bearing linkers within the pores of the framework.
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organic

Mechanical properties and molecular adhesion exhibited by inorganic–organic composite elastomers

Polym. Chem., 2024, 15,4196-4203
DOI: 10.1039/D4PY00879K, Paper
Naoki Yamashita, Ryohei Ikura, Kenji Yamaoka, Nobu Kato, Masanao Kamei, Kentaro Ogura, Minoru Igarashi, Hideo Nakagawa, Yoshinori Takashima
Organic–inorganic composite elastomers with reversible cross-links formed by β-cyclodextrin and adamantane (Ad) were prepared. Excess Ad units improve the mixability of polydimethylsiloxane and poly(ethyl acrylate) to increase the healing ratio.
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organic

Vinylene-linked fully conjugated porous organic polymers based on difluoroboron β-diketonate complexes for green and efficient photocatalysis

Polym. Chem., 2024, 15,4281-4287
DOI: 10.1039/D4PY00947A, Paper
Wenshuo Xu, Zehao Zhao, Yiqiong Liu, Dongxin Yang, Weitao Gong
Two distinct vinylene-linked fully conjugated POPs were achieved by reacting difluoroboron β-diketonate complexes with reactive methyl groups and a carbazole-bearing aldehyde.
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organic

Simple oxime functionalized fluorene polymers for organic solar cells

Polym. Chem., 2024, 15,4474-4481
DOI: 10.1039/D4PY00919C, Paper
Open Access
Abdullah Adewale Adeoba, Xiangyu Shen, Fuzhen Bi, Jianan Niu, Mingxin Sun, Shuguang Wen, Xichang Bao
A novel oxime-functionalized fluorene is used as an acceptor unit with a BDT donor in conjugated D–A polymers. Organic solar cell devices made with a Y6 non-fullerene acceptor give a power conversion efficiency of 10.71%.
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organic

Single-ion quasi-solid-state electrolytes based on sulfonimide-functionalized covalent organic framework

Polym. Chem., 2024, 15,4529-4541
DOI: 10.1039/D4PY00352G, Paper
Haomin Wu, Wencan Ma, Xin Huang, Yifeng Cai, Junheng Li, Qiaobo Liao, Kai Xi, Qiuhong Zhang, Xudong Jia
The COF based SIQSSEs with a high ionic conductivity of 4.3 × 10−4 S cm−1, a high LTN of 0.90. A high initial capacity (150.3 mA h g−1), high retention (99% after 100 cycles), good cycling stability and rate performance in Li/LFP battery test.
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organic

Metal–organic frameworks: potential synergies with cold atmospheric plasmas for cancer control

J. Mater. Chem. B, 2024, 12,10770-10785
DOI: 10.1039/D4TB00968A, Review Article
Xiaofeng Dai, Yixuan Yang
MOFs can act as cargo-carriers, nano-enzymes, and magnetic MOFs. CAPs, interacting with cell receptors to generate primary and secondary 1O2, may synergize with MOFs for oncotherapy via acting as cargos, substrates, and magnetic sensing agents.
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organic

Chemically engineered exogenous organic reactions in living cells for in situ fluorescence imaging and biomedical applications

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01925C, Review Article
Gang Song, Zhiwen Yang, Yiming Huang, Haotian Bai, Fengting Lv, Shu Wang
Key intracellular in situ synthesis processes, including the synthesis of near-infrared fluorescent dyes, intracellular oxidative cross-linking, polymerization, and bioorthogonal reactions, as well as their biomedical applications were summarized.
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organic

Improving the sulfite-detection performance of a fluorescent probe via post-synthetic modification with a metal–organic framework

J. Mater. Chem. B, 2024, 12,11251-11258
DOI: 10.1039/D4TB01754D, Paper
Jing-Yi Shi, Bin Wang, Xin-Yue Cui, Xiao-Wei Hu, Hai-Liang Zhu, Yu-Shun Yang
In this work, a post-synthetic modification strategy was attempted to improve the performance of the probe for sulfite detection.
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organic

Detection of several volatile organic compounds through Ar+ induced chemical ionisation using inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS)

Analyst, 2024, 149,5174-5183
DOI: 10.1039/D4AN00996G, Paper
Takafumi Hirata, Kyoko Kobayashi, Hui Hsin Khoo, Osamu Shikino, Hisashi Asanuma
A new analytical technique for detection of organic compounds using inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS) is described.
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organic

Performance of functionalized graphene oxide with organic radical scavengers in proton exchange membranes

Phys. Chem. Chem. Phys., 2024, 26,27817-27828
DOI: 10.1039/D4CP03151B, Paper
Yu Hu, Jiaxing Wang, Shuai Wang, Yuan Feng
A diazonium salt reaction is used to prepare benzoic acid-functionalized graphene oxide as a bi-functional filler for a Nafion membrane, and the corresponding composite membrane has improved chemical durability and proton conductivity.
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organic

Morphology optimization via pre-aggregation and miscibility matching in PM6:L8-BO ternary organic solar cells

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03206C, Paper
Chuyue Wei, Junwei Zhang, Jing Deng, Xiangyan Yang, Jiahui Luo, Zixiao Xu, Lin Zhang, Shuaishuai Yuan, Weihua Zhou
Pre-aggregation and miscibility matching accounting for morphology optimization in ternary organic solar cells based on a PM6:L8-BO system.
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organic

A hydrogen passivation strategy for the electrocatalytic chlorine evolution reaction on metal–organic frameworks: a theoretical insight

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03153A, Paper
Jiake Fan, Lei Yang, Hui Li, Zijian Sun, Mengyun Mei, Weihua Zhu
The chlorine evolution reaction (CER) is a crucial solution for treating chlorine-containing wastewater, a type of wastewater generated during the chemical production process.
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organic

A Comprehensive Guide for Accurate Conformational Energies of Microsolvated Li+ Clusters with Organic Carbonates

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03487B, Paper
Arseniy A. Otlyotov, Andrey Moshchenkov, Timofey P. Rozov, Anna A. Tuma, Alexander S. Ryzhako, Yury Minenkov
Organic carbonates and their mixtures are frequently used in electrolyte solutions in lithium-ion batteries. Rationalization and tuning of the related Li+ solvation processes are rooted in the proper identification of...
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organic

Thermally activated structural phase transitions and processes in metal–organic frameworks

Chem. Soc. Rev., 2024, 53,3606-3629
DOI: 10.1039/D3CS01105D, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Celia Castillo-Blas, Ashleigh M. Chester, David A. Keen, Thomas D. Bennett
The structural knowledge of metal–organic frameworks is crucial for understanding and developing new efficient materials for industrial implementation.
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organic

Visible photons as ideal reagents for the activation of coloured organic compounds

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01129A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lorenzo Di Terlizzi, Luca Nicchio, Stefano Protti, Maurizio Fagnoni
In search for the perfect wave(length). This review is dedicated to recent efforts in the development of visible light driven photochemical strategies occurring in coloured organic compounds.
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organic

Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01050C, Review Article
Qiaoqiao Zhang, Yong Wang, Pierre Braunstein, Jian-Ping Lang
Olefinic coordination polymers were used as universal single crystal platforms for precise organic synthesis, in situ mechanism exploration and photochemical applications.
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organic

Peptide hydrogen-bonded organic frameworks

Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review
Open Access
Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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organic

Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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organic

Hydrazone-linked Covalent Organic Frameworks for Fluorescence Detection of Hg2+

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication
Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
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organic

Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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organic

Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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organic

Catalytic applications of organic–inorganic hybrid porous materials

Chem. Commun., 2024, 60,13325-13335
DOI: 10.1039/D4CC04284K, Feature Article
Maodi Wang, Huicong Dai, Qihua Yang
Insights into the synergistic effects of different active sites of organic–inorganic hybrid porous materials for thermal- and photo-catalysis were discussed.
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organic

Constructing efficient organic solar cells by highly volatile solid additives with controlled phase morphology

Chem. Commun., 2024, 60,13424-13427
DOI: 10.1039/D4CC04675G, Communication
Yueheng Liu, Yetai Cheng, Shenbo Zhu, Zhengdong Wei, Chenyi Zhang, Shuyue Song, Xinyue Cui, Ya-Nan Chen, Andong Zhang, Yahui Liu, Hao Lu, Huawei Hu, Zhishan Bo
We synthesized two highly volatile and low-cost solid additives, PT and TFT.
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