J. Mater. Chem. C, 2024, 12,17403-17410
DOI: 10.1039/D4TC03192J, Paper

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Xiangyu Shen, Xiaoning Wang, Jianxiao Wang, Rulin Wang, Yonghai Li, Fuzhen Bi, Xichang Bao
Efficient and easily repeatable organic solar cells were fabricated based on a highly mixed tolerant acceptor in a high boiling point solvent.
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J. Mater. Chem. C, 2024, 12,17411-17418
DOI: 10.1039/D4TC03459G, Paper

Zhi-Zhong Zhang, Zi-Lin He, Qing-Peng Peng, Jing-Hua Chen, Bang Lan, Dai-Bin Kuang
A large size TBP₂MnBr₄ transparent ceramic is prepared by the melt processing method, which shows a high transmittance of >80% in the wavelength range of 350 nm to 800 nm, for realizing a high-resolution (16 lp mm⁻¹) X-ray imaging.
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J. Mater. Chem. C, 2024, 12,17554-17562
DOI: 10.1039/D4TC03085K, Paper

Jina Lee, Yeonju Jeong, Sunhee Lee, Yi Sak Lee, Bubae Park, Taekyung Kim, Won-Sik Han
Two derivatives of o-carborane, CAPCb and CAMCb, were synthesized and utilized in the fabrication of white OLED devices that exhibit cool white emission and specific CIE coordinates.
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J. Mater. Chem. C, 2024, 12,17429-17438
DOI: 10.1039/D4TC03144J, Paper

Hongye Li, Song Yang, Huangzhong Yu
A novel ZnO:NADH composite electron transport layer is constructed, and the efficiency of organic solar cells (OSCs) with PM6:L8-BO as the active layer has improved from 17.43% to 18.21%.
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J. Mater. Chem. C, 2024, 12,17668-17675
DOI: 10.1039/D4TC03277B, Paper

Chen Chen, Dingqin Hu, Peihao Huang, Chun Hong Mak, Heng Liu, Hongliang Lei, Xue Jiang, Yulu Li, Fengyi Yu, Kaihuai Tu, Hsien-Yi Hsu, Xinhui Lu, Haiyan Chen, Zeyun Xiao
We developed a pyridine-based solvent additive targeting the acceptor moiety. This additive fine-tunes the aggregation, crystallinity, and stacking of the active layer through stronger non-covalent interactions with the acceptor.
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J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03814B, Paper

Ruijing Fu, Junpeng Gao, Pinsen Zhang, Lingrui Wang, Bo Wang, Guangxia Wang, Xiaoshuang Li, youchao Kong, Qingguang Zeng, Guanjun Xiao
Manganese (Mn)-based organic-inorganic metal halides (OIMHs) are extensively employed in various optical applications due to their non-toxicity, superior optical properties, and tunable emission advantages. Developing effective strategies to enhance the...
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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC02970D, Paper

Chu Chu, Wenjing Zhang, Xuehua Yan, Yingnan Yan, Jianmei Pan, Zohreh Shahnavaz, Jamile Mohammadi Moradian
The specific capacitance of NCA₁₅-MOF/NF was 1317 F g⁻¹, which was significantly higher compared to the NCA₀-MOF/NF. After 15 000 charge–discharge cycles, the NCA₁₅-MOF/NF retained 89% of its initial specific capacitance.
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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03273J, Review Article

Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu, Yanxiang Wang
Metal–organic frameworks (MOFs) are regarded as potential candidate materials for the cathodes of aqueous zinc-ion batteries. This review presents the applications of MOFs and their derivatives in the cathodes of aqueous zinc-ion batteries.
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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper

Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH₂ nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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Chem. Soc. Rev., 2024, 53,10741-10760
DOI: 10.1039/D4CS00539B, Review Article

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Morgan Regnier, Clara Vega, Dimitris I. Ioannou, Timothy Noël
Utilizing electrons directly offers significant potential for advancing organic synthesis by facilitating novel reactivity and enhancing selectivity under mild conditions.
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00521J, Tutorial Review

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Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu, Jianchun Jiang
Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement.
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Chem. Soc. Rev., 2024, 53,11207-11227
DOI: 10.1039/D4CS00443D, Review Article

Zhe Li, Hongwen Liu, Xiao-Bing Zhang
An overview of the recent advances in reactive oxygen species-mediated organic long-persistent luminophores, including their history, working mechanisms, design strategies, and biomedical applications.
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Chem. Soc. Rev., 2024, 53,10970-11003
DOI: 10.1039/D4CS00599F, Review Article

Rui Qu, Xiqun Jiang, Xu Zhen
Versatile energy inputs, including light, X-ray and ultrasound, activate organic molecular probes to undergo different delay mechanisms, including charge separation, triplet exciton stabilization and chemical trap, for delayed photon emission.
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Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00024B, Paper

V. Perraud, D. R. Blake, L. M. Wingen, B. Barletta, P. S. Bauer, J. Campos, M. J. Ezell, A. Guenther, K. N. Johnson, M. Lee, S. Meinardi, J. Patterson, E. S. Saltzman, A. E. Thomas, J. N. Smith, B. J. Finlayson-Pitts
This study shows that volatile and semi-volatile organic gases are emitted during light and heavy braking. These emissions will remain as we transition to zero exhaust emission vehicles and must be included in air pollution and climate assessments.
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Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D3RP00188A, Paper

Lyniesha Ward, Fridah Rotich, Jeffrey R. Raker, Regis Komperda, Sachin Nedungadi, Maia Popova
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Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D4RP00277F, Paper

Elizabeth B. Vaughan, Saraswathi Tummuru, Jack Barbera
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Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article

Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
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Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00161C, Communication

Liming Xu, Yong Liu, Xiaoyang Xuan, Xingtao Xu, Yuquan Li, Ting Lu, Likun Pan
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
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Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication

Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
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Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication

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Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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Mater. Horiz., 2024, 11,1832-1837
DOI: 10.1039/D4MH90029D, Commentary

Anthony K. Cheetham, Paul D. Bristowe, Satoshi Tominaka, Fengxia Wei
Cheetham et al. reflect on one of their first Materials Horizons papers (Mater. Horiz., 2016, https://doi.org/10.1039/C6MH00053C) published in the journal and discuss how their work may have influenced the research field.
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Nat. Prod. Rep., 2024, Advance Article
DOI: 10.1039/D4NP00037D, Review Article

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Claire A. Batty, Victoria K. Pearson, Karen Olsson-Francis, Geraint Morgan
This review highlights how discovering and analysing VOCs in extreme environments on Earth can help identify biosignatures and unravel complex patterns in metabolic data that could help identify life on other planetary bodies.
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Inorg. Chem. Front., 2024, 11,1998-2006
DOI: 10.1039/D4QI00113C, Research Article

Mengna Li, Benlai Wu, Maochun Hong
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI90021A, Profile

This profile article showcases researchers who have contributed an article to the Inorganic Chemistry Frontiers Emerging Investigator Series.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article

Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00500G, Research Article

Qingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang Tao
Recently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article

Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO₂ reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article

Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article

Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
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Inorg. Chem. Front., 2024, 11,2471-2478
DOI: 10.1039/D4QI00233D, Research Article

Bingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli Lü
An efficient strategy is proposed to construct PQD/polymer organic–inorganic nanohybrids by PET-RAFT polymerization-mediated PISA and the nanohybrid assemblies can maintain excellent luminescence originating from PQDs with enhanced stability.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article

Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article

Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article

Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na⁺ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article

Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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Chem. Sci., 2024, 15,17739-17759
DOI: 10.1039/D4SC05489J, Perspective

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Upasana Deori, Gyana Prakash Nanda, Caroline Murawski, Pachaiyappan Rajamalli
The evolution of next-generation HF-OLED technology and current challenges.
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Chem. Sci., 2024, 15,17781-17798
DOI: 10.1039/D4SC05205F, Review Article

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Pengfei Wu, Mengting Guo, Ran-Wei Zhang, Qing Huang, Guibin Wang, Ya-Qian Lan
The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
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Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04589K, Edge Article

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Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique Pourpoint
The stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06213B, Edge Article

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Shiguo Zhang, Guanyu Liu, Zhichao Mao, Shanfeng Xue, Qikun Sun, Wenjun Yang
Synthesized CDIA and ODIA via cyclization, obtained long-lived RTP polymers with lifetimes of 2146 and 2656 ms. Experimental and theoretical data show cyclization effectively restrains intramolecular rotation and stabilizes triplet populations.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article

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Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06103A, Edge Article

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Yuheng Fu, Bingbing Xie, Miaoxia Liu, Shaojuan Hou, Qunyan Zhu, Alexander Kuhn, Lin Zhang, Wensheng Yang, Neso Sojic
A novel bipolar electrochemistry approach for wireless dual-color ECL emission at the water/organic interface is developed. This system overcomes spatial limitations of conventional methods, enabling imaging of complex multiphase environments.
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Anal. Methods, 2024, 16,1968-1984
DOI: 10.1039/D4AY00117F, Minireview

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Shuai Li, Yaoxuan Li, Shiji Zhang, Haixiao Fang, Ze Huang, Duoteng Zhang, Aixiang Ding, Kajsa Uvdal, Zhangjun Hu, Kai Huang, Lin Li
In this review, we primarily summarized four temperature-response strategies. Then, we further analyzed the chemical modifications and biological applications of the probes. Finally, we have provided a prospective on the future development of probes.
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