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Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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Fabrication of gelatin hydrogels using pre-coordinated lanthanide complexes via imine crosslinking

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication
Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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Self-assembled superstructures derived from suitably substituted phenanthro[9,10-d] imidazole-based Zn(II)/Cd(II) complexes for selective detection of acetone

New J. Chem., 2024, 48,7456-7468
DOI: 10.1039/D4NJ00450G, Paper
Mallayasamy Siva, Sheethal Sasi, Priya Rana, Raj Kumar Bera, Yuvaraj Sivalingam, Priyadip Das
Newly synthesized (L1)2M, (L2)2M, and (L3)2M (M = Zn(II)/Cd(II)) self-assembled into well-ordered superstructures and exhibited promising potential for developing a new class of sensor devices for human health monitoring and environmental safety measurements.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of copper(II) complex-functionalized Fe3O4@ISNA (ISNA = isonicotinic acid) as a magnetically recoverable nanomaterial: catalytic studies in alcohol oxidation and nitrophenol reduction, and TD-DFT studies

New J. Chem., 2024, 48,7308-7322
DOI: 10.1039/D3NJ05440C, Paper
Rimpa Mondal, Aratrika Chakraborty, Ennio Zangrando, Madhulata Shukla, Tanmay Chattopadhyay
The synthesis of a magnetically separable nanocatalyst Fe3O4@ISNA@CuL1 used as a catalyst for oxidation of alcohols and reduction of nitrophenols.
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Magnesium(II) complexes supported by indole- and pyrrole-containing Schiff-base ligands: syntheses, structures, and applications as precatalysts in the hydroboration of nitriles and alkynes

New J. Chem., 2024, 48,7125-7133
DOI: 10.1039/D4NJ00492B, Paper
Mengxiang Wu, Ling Chen, Xiaohan Yang, Yahong Li
Five magnesium compounds were synthesized. They are active precatalysts for the hydroboration of nitriles and alkynes. The catalytic reactions feature mild reaction conditions, excellent functional group tolerance, and high yields.
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Copper(II) complexes of sterically hindered phenolic Schiff bases: synthesis, characterization, interaction with biomolecules, and antioxidant and antimicrobial activity

New J. Chem., 2024, 48,7134-7147
DOI: 10.1039/D4NJ00430B, Paper
Iveta S. Turomsha, Maxim Y. Gvozdev, Nikolai P. Osipovich, Viktoryia A. Staravoitava, Dmitriy I. Shiman, Natalia V. Loginova
Phenolic Schiff bases and their Cu(II) complexes have been synthesized and characterized by physicochemical methods. The complexes exhibit low cell toxicity and high antioxidant and antibacterial activity, as evidenced by molecular docking studies.
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Influence of the secondary ligand, phenanthroline, on the antioxidant and pro-oxidant and cytotoxic effects of the oxidovanadium(IV)/naringin complex

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00655K, Paper
Andrés G. Restrepo, Angel L. Huamani, Alexandra Velásquez Bravo, Pablo J. González, Luciana G. Naso, Evelina G. Ferrer, Patricia A. M. Williams
Replacement of phen in [VO(Narg)2] induces greater π electronic delocalization, thus improving antioxidant action. However, due to its lipophilic character, cellular uptake of V is increased, leading to enhanced pro-oxidant and anticancer effects.
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Synthesis, structure, and properties of helical bis-Zn(II) complexes of hexapyrrolic ligands

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00019F, Paper
Pinky Chauhan, Poornenth Pushpanandan, Mangalampalli Ravikanth
Bis(3-pyrrolyl BODIPY)s were used to prepare rare examples of hexapyrrolic ligands by demasking BF2 units. The hexapyrrolic ligands, without isolating, were used to prepare novel examples of double-stranded bis-Zn(II) helicate complexes.
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Solvent-polarity-controlled assembly of polynuclear titanium-calixarene complexes: constructing isolated {Ti7}, {Ti13}, {Ti24} and {Tb2Ti13} clusters

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01275A, Paper
Yanyan Wang, Ying Xiong, Wuping Liao
The assembly of polynuclear titanium-calixarene complexes is based on Ti4–C8A SBUs.
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Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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Modi asked Ratan Tata to shift aircraft complex from Maharashtra to Gujarat: Sharad Pawar

Opposition accuses Mahayuti government of taking all development projects out of Maharashtra




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Siloxane-containing phosphine (oxide) ligands for enhanced catalytic activity of cobalt complexes for hydrosilylation reactions

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00333K, Paper
Peng Liu, Jiajian Peng, Ying Bai, Jiayun Li
A series of siloxane-containing phosphine (oxide) ligands have been designed and synthesized.
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Reduction of sulfoxides catalyzed by the commercially available manganese complex MnBr(CO)5

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00204K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Leal Lourenço, Ana Cristina Fernandes
A new methodology for the reduction of a wide variety of aliphatic and aromatic sulfoxides catalyzed by the air-stable, cheap and commercially available manganese catalyst MnBr(CO)5 with excellent yields is...
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Charge-transfer inclusion complex formation of the tropylium cation with prism[6]arenes

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00423J, Communication
Guojiao Zhang, Channi Cheng, Zhengxiang Li, Dezhi Zhao, Chengyou Han
We report that charge-transfer (CT) inclusion complexes were formed between prism[6]arenes and tropylium cation. Additionally, the CT complex showed Cl/Ag+ responsiveness which can be easily monitored by the naked eye.
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complex

How entrepreneurial innovation is helping HR solve complex problems

Players like Mynoticeperiod, Hackerearth, e-poise and Merajob are expected to play a role in changing the HR start-up ecosystem




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Dual luminescence and infrared circularly polarized luminescence up to 900 nm with platinum complexes bearing a helical donor–acceptor ligand

Mater. Chem. Front., 2024, 8,3799-3806
DOI: 10.1039/D4QM00632A, Research Article
Open Access
Pablo Vázquez-Domínguez, Maher Horojat, Eva Suits, Francisco José Fernández de Córdova, Nicolas Vanthuyne, Denis Jacquemin, Abel Ros, Ludovic Favereau
Engineering the intramolecular charge transfer character of ligands in axially chiral arylisoquinolines platinum(II) complexes leads to both fluorescence and phosphorescence emissions in solution, with NIR CPL that extends up to almost 850 nm.
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(WO + ICG)@PLGA@lipid/plasmid DNA nanocomplexes as core–shell vectors for synergistic genetic/photothermal therapy

Mater. Chem. Front., 2024, 8,3747-3757
DOI: 10.1039/D4QM00330F, Research Article
Yang Bai, Guoqing Feng, Qingbin Yang, Tingting Hua, Bowen Li, Hao-Lin Guo, Yuan Liu, Qing Yuan, Niansong Qian, Bin Zheng
(WO + ICG)@PLGA@PL could not only achieve a synergistic therapy effect of gene delivery and photothermal effect but also effectively inhibit tumor growth.
The content of this RSS Feed (c) The Royal Society of Chemistry




complex

11 Levels of Origami: Easy to Complex

Origami artist and physicist Robert J. Lang explains origami in 11 levels of difficulty. From a simple, traditional cicada to an extremely intricate one, watch how Robert J. Lang demonstrates and breaks down everything that goes into the art of origami.




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3 Levels of Cocktail Complexity with Comedian Chris Redd | WIRED Brand Lab

BRANDED CONTENT | Produced by WIRED Brand Lab for Jim Beam Black | Comedian Chris Redd tests whether high-tech bar tools help make a tastier cocktail. #sponsored by Jim Beam Black®




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10 Levels of Ice Sculpture: Easy to Complex

Ice sculptor Shintaro Okamoto explains the art of sculpting ice in 10 levels of difficulty. The angelfish is one of the most historical designs in the ice sculpting community, so it's the perfect place to start. Shintaro explains how you can create an angelfish design in increasing levels of complexity, from using simple hand tools to CNC machining the piece. 3D ice printing footage courtesy of McGill University.




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13 Levels of Beatboxing: Easy to Complex

2005 Female World Beatbox Champion Butterscotch explains the art of beatboxing in 13 levels of difficulty. Starting with just the bass drum, Butterscotch layers more and more vocal drums and instruments on top of each other until she starts adding real, live instruments as well.




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11 Levels of Self-Portraiture: Easy to Complex

Artist TM Davy explains how to draw a self-portrait in 11 levels of increasing complexity. Starting off with the ubiquitous "solar head" and moving on to portraits that implement light, shadow and color, TM Davy deftly describes how a drawing evolves through materials and techniques. TM Davy is an New York-based artist and a professor at the School of Visual Arts. To see more of his work visit: http://www.tmdavy.com/ and @tmdavy on Instagram.




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Jacob Collier Plays The Same Song In 18 Increasingly Complex Emotions

Jacob Collier plays and transforms a familiar tune through a variety of different emotions. Jacob takes "Londonderry Air" (more popularly known as "Danny Boy") and pulls the song through many twists and turns as he transmutes the piece on the fly. How does the song sound "angry," or "sad"? How about with more complex emotions, like "disruptive" or "betrayed"? For more Jacob Collier, visit http://www.JacobCollier.com and Jacob's musical universe ➡ https://jacobcollier.lnk.to/Follow




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26 Levels of Yo-Yo Tricks: Easy to Complex

Yo-yo champion Harrison Lee explains yo-yo tricks in 26 levels of difficulty. Starting with tricks using an unresponsive yo-yo, Harrison progresses until he's popping the yo-yo into the air, and dancing the string in and out of the yo-yo's axle.




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22 Levels of Cardistry: Easy to Complex

Cardistry pioneers Dan and Dave Buck explain cardistry in 22 levels of difficulty. From a foundational Z-Grip to complicated cuts like the Leno, watch how these two card innovators demonstrate and break down everything that goes into the art of card handling.




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24 Levels of Balisong Flipping: Easy to Complex

SAFETY DISCLAIMER: Talent is a trained expert at operating these knives. Anyone who is not a trained professional and is learning to operate these knives should only use a dull trainer knife to prevent injury. Professional balisong flipper Corbin Lovins explains balisong tricks in 24 levels of difficulty.




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13 Levels of Pumpkin Carving: Easy to Complex

Pumpkin carving master James Hall explains pumpkin carving in 13 spooky levels of difficulty. The 2-time 'Halloween Wars' winner breaks down a variety of pumpkin carving techniques, ranging from simple to incredibly complex.




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21 Levels of Dunking: Easy to Complex

Professional dunker C.J. Champion explains dunking in 21 levels of difficulty. From from standard, basic dunk on an 8 foot hoop to jumping over whole other people, watch as C.J. breaks down all there is to know about the art of dunking a basketball.




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15 Levels of Pool: Easy to Complex

Professional pool player Tony Robles explains eight-ball pool in 15 levels of difficulty, from easy to complex. Tony explains everything from the most basic fundamentals of pool, to dazzling trick shots that only the most skilled pool players can pull off.




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12 Levels of Graffiti: Easy to Complex

Artist Carlos Mare (aka Mare 139) explains graffiti in 12 levels of difficulty, from easy to complex. Carlos explains everything from the simple tags and throwies to how he crafts a masterpiece using a variety of advanced spraying techniques.




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15 Levels of Turntablism: Easy to Complex

Turntablism is the art of using the turntable as a musical instrument. DJ Shortkut explains turntablism in 15 levels of difficulty, from easy to complex. Shortkut starts with the very basics of scratching all the way to complicated techniques like beat juggling. Director: Tim Cruz Director of Photography: Grant Bell Editor: Cory Stevens Talent: DJ ShortKut Producer: Adam Davis-McGee Line Producer: Joseph Buscemi Associate Producer: Melissa Cho Production Manager(s): Peter Brunette, Andressa Pelachi Casting Producer: Nick Sawyer Camera Operator: Oliver Lukacs Audio: Paul Cornett Production Assistant: Eric Bittencourt Props: Modernica Props Post Production Supervisor(s): Nicholas Ascanio, Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Billy Ward Music Supervisor: Lindsay Capacio Archive Credits: Getty Images Special Thanks: True Sound Recording




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11 Levels of Prosthetic Makeup: Easy to Complex

Professional prosthetic makeup artist Meg Wilbur explains special effects makeup in 11 levels of difficulty, from easy to complex. Special effects makeup is a really broad category, so Meg defines complexity as increasingly elaborate flourishes, texture and detail in her work. Meg goes over everything from temporary tattoos to prosthetic face applications and dry-brushing. MEG WILBUR: https://www.instagram.com/littlemonsterdoll/?hl=en BRITTANY TURPEN: https://www.instagram.com/brittanyyynicole/ ANDREW SCOTT MILLER: https://www.instagram.com/andrewscottmiller/ Director: Tim Cruz Director of Photography: Ricardo Pomares Editor: Louville Moore Talent: Meg Wilbur Producers: Adam Davis-McGee, Katherine Wzorek Line Producer: Joseph Buscemi Associate Producer: Melissa Cho Production Managers: Peter Brunette, Andressa Pelachi Production Coordinator: Carol Wachockier Set Decorator: Leah Waters-Katz Audio: Paul Cornett Cam Op/Gaffer: Nick Massey Production Assistants: Phillip Arliss, Devin Beckwith, Ariel Labasan Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Diego Rentsch Special Thanks: Meg's Assistant Brittany Turpen, model Andrew Miller




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Levels of Knot Tying: Easy to Complex

J.D. Lenzen, the inventor of fusion knotting, explains knot tying in 15 levels of difficulty, from easy to complex. J.D. starts from the very beginning, with overhead, bowline, and square knots, and moves all the way into more advanced knots that are created in combination with many other different types of knots. Director: Maya Dangerfield Director of Photography: Florian Pilsl Editor: Richard Trammell Talent: JD Lenzen Producer: Katherine Wzorek Line Producer: Joseph Buscemi Associate Producer: Melissa Cho Production Manager: Eric Martinez Production Coordinator: Fernando Davila Audio: Simon Gordon Cam Op/Gaffer: Shreyans Zaveri Production Assistant: Nathan Vega Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Diego Rentsch




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13 Levels of Drumming: Easy to Complex

Professional drummer and educator Larnell Lewis explains drumming in 13 levels of difficulty, from easy to complex. The Snarky Puppy percussionist explains how drum techniques build upon each other as the easiest levels incorporate the hi-hat, bass and snare drums, and more difficult levels include polyrhythms, the floor tom, ride cymbals, syncopation and much more. Director: Sean Dacanay Director of Photography: Paul Neal Editor: Jordan Calig Talent: Larnell Lewis Producer: Maya Dangerfield Line Producer: Joseph Buscemi Associate Producer: Samantha Vélez Production Manager: Eric Martinez Production Coordinator: Fernando Davila Sound Engineer: George Seara Audio: Alain Letourneau Cam Op: Jerome W. Tan Gaffer: Jason Ballesteros Production Assistant: Gavin Lee Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Billy Ward Audio Mix Engineer: Ben Lindell




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21 Levels of Pen Spinning: Easy to Complex

Champion pen spinner Peter Davis explains pen spinning in 21 levels of difficulty, from easy to complex. Pen spinning is a lot like juggling, and Peter goes over some simple techniques like charging and wipers before moving onto more complicated moves like threading and charge removal.




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Jacksepticeye Asks His AI Clone Increasingly Complex Questions

WIRED invited Jacksepticeye to have a conversation with his AI-powered digital clone, prompting it with increasingly complex questions and commands. How well can ‘JacksepticAI’ mimic the genuine article—and what does the real Jacksepticeye think of the results?




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21 Levels of Ballet: Easy to Complex

Professional ballerina Joy Womack explains ballet turns in 21 levels of difficulty, from the easiest to most complex.




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25 Levels of Freestyle Soccer: Easy to Complex

Freestyle Soccer World Champion Caitlyn Schrepfer demonstrates and explains her freestyle soccer skills in 25 levels of difficulty, from the easiest to most complex.




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9 Levels of Pickpocketing: Easy to Complex

Attenzione, pickpockets! Magician Ben Seidman demonstrates and explains pickpocketing techniques in 9 levels of difficulty, from the easiest to most complex. From a traditional outside jacket pocket snatch to stealing someone's neck tie in broad daylight, this sleight-of-hand expert shows us how master pickpockets execute petty theft. Director: Maya Dangerfield Director of Photography: Dominik Czaczyk Editor: Jordan Calig Expert: Ben Seidman Creative Producer: Katherine Wzorek Line Producer: Joseph Buscemi Associate Producer: Kameryn Hamilton Production Manager: Peter Brunette Production & Equipment Manager: Kevin Balash Production Coordinator: Kariesha Kidd Camera Operator: Josh Andersen; Omar Elgohary Sound Mixer: Kari Barber Production Assistant: Fernando Barajas; Brock Spitaels Hair & Make-Up: Vanessa Renee Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Additional Editor: Jason Malazia Assistant Editor: Justin Symonds




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11 Levels of Holiday Gift Wrapping: Easy to Complex

Sophie Liard, an expert gift wrapper and author of "The Folding Lady," demonstrates and explains a variety of gift wrapping techniques in 11 levels of difficulty, from the easiest to most complex. From a traditional box with a bow to concealing a soccer ball in a wrapping paper gift bag, this expert shows us how to add some spark to your gifting this holiday season. Director: Maya Dangerfield Director of Photography: Eric Brouse Editor: Richard Trammell Expert: Sophie Liard Creative Producer: Katherine Wzorek Line Producer: Joseph Buscemi Associate Producer: Kameryn Hamilton Production Manager: D. Eric Martinez Production Coordinator: Fernando Davila Casting Producer: Nick Sawyer Camera Operator: Jack Belisle Gaffer: Mar Alfonso Sound Mixer: Lily Van Leeuwen Production Assistant: Caleb Clark Hair & Make-Up: Yev Wright-Mason Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Justin Symonds




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Bifunctional conjugated polymer photocatalysts for visible light water oxidation and CO2 reduction: function- and site-selective hybridisation of Ru(II) complex catalysts

J. Mater. Chem. A, 2024, 12,30279-30288
DOI: 10.1039/D4TA04014G, Paper
Kotaro Ishihara, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Shunsuke Nozawa, Akinori Saeki, Ryu Abe
Function-/site-selective hybridisation of two specific Ru(II) complex catalysts on donor–acceptor conjugated polymers enables bifunctional visible-light water oxidation and CO2 reduction.
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Stimulus-responsive multifunctions in a zinc(II) sulfate complex: photochromism, photoswitching nonlinear optical properties, amine detection and visual film application

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04169K, Paper
Shuai Liang, Shi-Kun Yan, Yu-Xuan Wen, Yan-Rui Zhao, Jin Zhang, Ji-Xiang Hu
A novel complex combining photo- and amine-induced chromic, switchable photoluminescence, and photomodulated nonlinear optical properties has been prepared using electron-rich sulfate and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine.
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Reconstruction of residential complex

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm




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Aggregation-induced emission organic metal halide complex for X-ray scintillation

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication
Open Access
Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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Some Simple Economics of Patent Protection for Complex Technologies [electronic journal].




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Measuring Regulatory Complexity [electronic journal].




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Journal of Physics: Complexity [electronic journal].

IOP Publishing Limited




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The good, the bad, and the complex: product design with asymmetric information [electronic journal].