Inorg. Chem. Front., 2020, 7,1651-1666
DOI: 10.1039/C9QI01388A, Research Article

Yindi Zhang, Xi Chen, Dongdong Song, Daokun Zhong, Xiaolong Yang, Yuanhui Sun, Boao Liu, Guijiang Zhou, Zhaoxin Wu
Unsymmetric Ir(III) complexes with 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene and phenylsulfonyl groups showing high EL efficiencies.
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Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article

Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01478K, Research Article

Sriram Sundaresan, Jonathan A. Kitchen, Sally Brooker
Linear correlation of the hydrophobic alkyl tail length R employed in [Fe^II(L^H-OR)(NCBH₃)₂] with the spin crossover switching temperature is a very convenient method of predictably tuning the iron(II) spin state.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00232A, Research Article

Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Minguez Espallargas, Lauro J. Q. Maia, Gisane Gasparotto, Ricardo Costa de Santana, Walter Cañón-Mancisidor
A series of hybrid organo-inorganic mononuclear lanthanoid complexes, [n-NBu₄]₃[LnH(PW₁₁O₃₉)(phen)₂]·H₂O, denoted as LM⁴-1-Ln^† (Ln = Dy^III, Tb^III, Eu^III, Nd^III, Er^III, Ho^III and Gd^III), were synthesized via hydrothermal synthesis and were structurally...
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Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article

Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)₄]²⁻ complexes within π-acidic cavities.
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Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article

Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Inorg. Chem. Front., 2020, 7,1864-1871
DOI: 10.1039/D0QI00224K, Research Article

Cheng Zhang, Ruilin Guan, Xinxing Liao, Cheng Ouyang, Jiangping Liu, Liangnian Ji, Hui Chao
A dinuclear complex [(ppy)Ir(tpy)PtCl]²⁺ (Ir–Pt) can exhibit strong antitumor activity towards cisplatin-resistant cancer cells and induce cell necrosis via mtDNA damage and mitochondrial dysfunction.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article

Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article

Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00553C, Edge Article

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Xin Luo, Christophe Lachance-Brais, Amy Bantle, Hanadi F. Sleiman
The AGLO strategy generates complex gold nanostructures with user-designed morphologies in solution, using only a simple 2D DNA origami sheet as a versatile transient template. The products are robust and stable as standalone gold nanostructures.
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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00646G, Edge Article

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Shubham Deolka, Orestes Rivada, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin, Julia R Khusnutdinova
We report selective formation of heterobimetallic Pt^II/Cu^I complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another...
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Chem. Sci., 2020, 11,4322-4331
DOI: 10.1039/C9SC05589D, Edge Article

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Hikaru Aramoto, Motofumi Osaki, Subaru Konishi, Chiharu Ueda, Yuichiro Kobayashi, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
A hydrogel actuator with a 1:2 host–guest complex controlled by redox stimuli has been developed to realize faster and larger deformation.
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Chem. Sci., 2020, 11,4531-4531
DOI: 10.1039/D0SC90075C, Correction

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Angelo Frei, Johannes Zuegg, Alysha G. Elliott, Murray Baker, Stefan Braese, Christopher Brown, Feng Chen, Christopher G. Dowson, Gilles Dujardin, Nicole Jung, A. Paden King, Ahmed M. Mansour, Massimiliano Massi, John Moat, Heba A. Mohamed, Anna K. Renfrew, Peter J. Rutledge, Peter J. Sadler, Matthew H. Todd, Charlotte E. Willans, Justin J. Wilson, Matthew A. Cooper, Mark A. T. Blaskovich
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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01290D, Edge Article

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Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P Cramer
A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...
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Lab Chip, 2020, Advance Article
DOI: 10.1039/D0LC00059K, Paper

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Christian G. M. van Dijk, Maarten M. Brandt, Nikolaos Poulis, Jonas Anten, Matthijs van der Moolen, Liana Kramer, Erik F. G. A. Homburg, Laura Louzao-Martinez, Jiayi Pei, Merle M. Krebber, Bas W. M. van Balkom, Petra de Graaf, Dirk J. Duncker, Marianne C. Verhaar, Regina Luttge, Caroline Cheng
We present a microfluidic vascular device. Vascular cells in a 3D-ECM environment support hemodynamic flow and enable monocyte interaction.
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Lab Chip, 2020, Advance Article
DOI: 10.1039/D0LC00069H, Paper

W. Hampton Henley, Nathan A. Siegfried, J. Michael Ramsey
Encoded beads carrying primer pairs for nucleic acid targets are used for sample preparation and multiplexed-in-space digital PCR quantification.
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DOI: 10.1021/acs.jcim.0c00088

DOI: 10.1021/acs.jcim.0c00161

DOI: 10.1021/acs.jcim.9b01161

Metallomics, 2020, Advance Article
DOI: 10.1039/C9MT00312F, Paper

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Trang Q. Nguyen, Joshua E. Kim, Hayley N. Brawley, Paul A. Lindahl
Labile metal pools in the cytosol of yeast, including those of iron, copper, zinc, and manganese, can be detected and characterized using size-exclusion chromatography with online ICP-MS.
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Metallomics, 2020, Advance Article
DOI: 10.1039/D0MT00008F, Paper

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Laura K. Stultz, Alexandra Hunsucker, Sydney Middleton, Evan Grovenstein, Jacob O’Leary, Eliot Blatt, Mary Miller, James Mobley, Pamela K. Hanson
Proteomic analysis reveals that the anticancer ruthenium KP1019 induces proteotoxic, genotoxic, and oxidative stress responses in Saccharomyces cerevisiae.
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Metallomics, 2020, Advance Article
DOI: 10.1039/D0MT00006J, Paper

Sebastiano Masuri, Enzo Cadoni, Maria Grazia Cabiddu, Francesco Isaia, Maria Giovanna Demuru, Lukáš Moráň, David Buček, Petr Vaňhara, Josef Havel, Tiziana Pivetta
The novel complex Cu(phen)₂(salubrinal)(ClO₄)₂ shows high free radical scavenging activity and good cytotoxic activity and induces cell death through ER-stress.
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Metallomics, 2020, Accepted Manuscript
DOI: 10.1039/D0MT00064G, Paper

Diana Fontinha, Silvia Andreia Sousa, Tânia S. Morais, Miguel Prudêncio, Jorge Leitão, Yann Le Gal, Dominique Lorcy, Rafaela Silva, Mariana Velho, Dulce Belo, Manuel Almeida, Joana Guerreiro, Teresa Pinheiro, Fernanda M. Marques
The anticancer, antimicrobial and antiplasmodial activities of six gold(III) bis(dithiolene) complexes were studied. Complexes (1-6) showed relevant anticancer properties against A2780/A2780cisR ovarian cancer cells (IC50 values of 0.08-2 µM), also...
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Metallomics, 2020, 12,504-513
DOI: 10.1039/C9MT00192A, Paper

Qiong Wu, Shuang-Yan Zhang, Si-Yan Liao, Jie-Qiong Cao, Wen-Jie Zheng, Li Li, Wen-Jie Mei
A novel approach has been proposed to develop a potent gene carrier system for enantioselectivity on the self-assembly of G-quadruplex DNA promoted by chiral Ru(II) complexes, and the different assembled nanostructures of cellular uptake to the nucleus and cytoplasm.
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Metallomics, 2020, 12,547-561
DOI: 10.1039/C9MT00272C, Paper

Adriana Pereira Mundim Guedes, Francyelli Mello-Andrade, Wanessa Carvalho Pires, Maria Alice Montes de Sousa, Paula Francinete Faustino da Silva, Mariana S. de Camargo, Hendryk Gemeiner, Menegário A. Amauri, Clever Gomes Cardoso, Paulo Roberto de Melo Reis, Elisângela de Paula Silveira-Lacerda, Alzir A. Batista
Antimetastatic activity, high selectivity and cytotoxicity for human tumor cell lines make ruthenium(II) complexes attractive for the development of new chemotherapeutic agents for cancer treatment.
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Metallomics, 2020, 12,491-503
DOI: 10.1039/D0MT00054J, Paper

Samantha E. Huffman, Gideon K. Yawson, Samuel S. Fisher, Paige J. Bothwell, David C. Platt, Marjorie A. Jones, Christopher G. Hamaker, Michael I. Webb
Alzheimer's Disease (AD) is a devastating neurodegenerative disorder where one of the commonly observed pathological hallmarks is extracellular deposits of the peptide amyloid-β (Aβ).
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DOI: 10.1021/acscatal.0c01406

DOI: 10.1021/acscatal.0c00127

Anal. Methods, 2020, Accepted Manuscript
DOI: 10.1039/D0AY00363H, Paper

Victoria V Volchek, Semen Nikolaevich Berdyugin, Olga Vasil`evna Shuvaeva, Dmitriy Sheven, Danila Vasilchenko, Sergey Korenev
A mixture of rhodium(III) hydroxocomplexes formed during the polycondensation process in alkaline media has been fully characterized by the hyphenated high performance liquid chromatography with electrospray ionization mass spectrometry (HPLC-ESI-MS)....
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RSC Med. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0MD00068J, Research Article

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Felix Torres, Dhiman Ghosh, Dean Strotz, Celestine Chi, Ben Davis, Julien Orts
Recently we have established an NMR Molecular Replacement method, which is capable of solving the structure of the interaction site of protein-ligand complexes in a fully automated manner. While the...
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DOI: 10.1021/acs.analchem.9b05659

DOI: 10.1021/acs.analchem.0c00649

DOI: 10.1021/acs.analchem.0c00772

DOI: 10.1021/acs.nanolett.0c01225

Org. Chem. Front., 2020, 7,997-1005
DOI: 10.1039/C9QO01544B, Research Article

Ioannis Stylianakis, Olalla Nieto Faza, Carlos Silva López, Antonios Kolocouris
The mechanism of indole and carbazole formation via a formal [4 + 2] cycloaddition strategy is dominated by the protodeauration step.
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Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00354A, Research Article

Indranil Chatterjee, Sourav Roy, Suman Pradhan, Krishan Kumar
An organocatalytic cascade vinylogous double 1,6-addition strategy for the synthesis of chiral chroman derivatives is reported. The cascade reaction follows oxa-Michael/1,6-addition reactions between ortho-hydroxyphenyl-substituted para-quinone methadies and 2,4-dienal derivatives to...
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