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Strain-induced charge delocalization achieves ultralow exciton binding energy toward efficient photocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05873A, Edge Article
Open Access
Junyuan Duan, Yinghe Zhao, Yu Wu, Youwen Liu, Junnian Chen, Ruoou Yang, Jiazhao Huang, Chuanqi Luo, Mao Wu, Xiaodong Zheng, Pengyu Li, Xueliang Jiang, Jianguo Guan, Tianyou Zhai
A novel approach of strain-induced charge delocalization is developed to significantly reduce the exciton binding energy of Ta2O5 nanorods to below ambient thermal energy, leading to a remarkable enhancement in photocatalytic hydrogen evolution.
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Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04629C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo Poli
The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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In debt funds, the focus is on high-quality credit strategies: Rahul Goswami, CIO-India Fixed Income, Franklin Templeton Mutual Fund

Rahul Goswami, CIO &MD - India Fixed Income, Franklin Templeton Asset Management, on what investors can expect on the debt side from the AMC and on his rate cut expectations




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Franklin Templeton India makes a debt fund comeback: Should you invest in its ultra short duration NFO?

The ultra short duration scheme is a new offering from the fund house after a long gap




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Two youngsters from Kochi determined to smash their disabilities on the badminton court

Atul Krishna and Jyothish Kumar defy physical limitations to excel in badminton, inspiring with their determination and talent.




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About 10 lakh tonnes of legacy waste awaiting scientific remediation




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Government reduces windfall tax on crude oil to ₹5,700 per tonne

The tax, levied as Special Additional Excise Duty (SAED), aims to moderate the impact of rising oil prices on consumers.




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Mercedes-Benz GLE 450: Milestone-Class

More than 25 years after it was introduced as the M-Class, the GLE still looks pretty promising in its latest avatar




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Panel to inventory jewellery, precious stones in the Ratna Bhandar of the Shree Jagannath Temple in Puri

Arijit Pasayat, former Supreme Court judge, will head the 12-member committee 




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Denmark Open badminton: Indian challenge ends in women’s and mixed doubles

Both the Indian pairs is action — Treesa Jolly and Gayatri Gopichand (women’s doubles) and B Summeth Reddy and N Sikki Reddy (mixed doubles) — suffered heartbreak three-game defeats in their opening contests




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CWG 2026: Hockey, shooting, cricket, badminton among major sports axed

The move is a massive setback to India's medal prospects given that bulk of the country's medals came from the removed disciplines in the past editions.




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Is Tanvi Patri the next big thing in Indian women’s badminton?




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Democrat Marie Gluesenkamp Perez wins reelection in Washington’s closely watched 3rd District

First-term Democrat Marie Gluesenkamp Perez has won reelection in Washington state’s closely watched 3rd Congressional District




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Brampton police arrests SFJ Canada coordinator in Hindu temple violence case

Investigators from the 21 Division Criminal Investigations Bureau and Strategic Investigation Team (SIT) have arrested and charged Inderjeet Gosal of Brampton, the Peel Police statement said




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ISKCON organises 'chariot parade' in Houston; draws criticism

Puri Govardhan Peeth spokesperson said the event was a "conspiracy against our religion"




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Amid threats of violent protests, Brampton Triveni temple cancels life certificate event

“We are deeply saddened that Canadians now feel unsafe coming to Hindu Temples in Canada”




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SRM University-AP wins men’s south zone badminton tournament




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 Milestones and U-turns: On the government in its third term

The optics of the 100-day mark cannot conceal changed dynamics for the BJP




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Udhayanidhi lays foundation stone for infrastructure development projects in Thanjavur district

Buildings at the Government Arts and Science College, Thirukkattupalli, construction of compound wall and an indoor stadium at the Government Rajah Serfoji College, Thanjavur, are among the projects




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583: Language Models, AI, and Digital Gardens with Maggie Appleton

Maggie Appleton talks with us about her work at Elicit, working with large and small language models, how humans vet the responses from AI, the discussion around the Soggoth meme in AI, using Discord as UI, what to do if your boss wants AI in your app, and why does she call her blog a digital garden?




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586: Micro.blogging with Manton Reece

Manton Reece, creator of Micro.blog, stops by to talk about the history of Micro.blog, what it's written in, how it handles feeds coming in and going out, cross-posting, authentication, and the somewhat hidden features of Micro.blog: bookmarking, bookshelves, and even podcasting.




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India's climate policies expected to reduce CO2 emissions by around 4 billion tonnes by 2030: Report

The study by Delhi-based independent think tank Council on Energy, Environment and Water (CEEW) said policies for India's power, residential and transport sectors have already saved 440 million tonnes of carbon dioxide (MtCO2) between 2015 and 2020.




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ARRL Recognizes University of Scranton During Amateur Radio Station Dedication

The University of Scranton in Pennsylvania has a new amateur radio station, W3USR. A dedication was held at the university’s Loyola Science Center on Friday, October 25, 2024, led by Dr. Nathaniel Frissell, W2NAF, an associate professor of physics and electrical engineering, and club advisor for the University of Scranton Amateur Radio Club.

The new W3USR University of Scranton Amateur Radio Sta...




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The certainty trap [electronic resource] : why we need to question ourselves more--and how we can judge others less / Ilana Redstone ; foreword by Joe Walsh.

Durham, North Carolina : Pitchstone Publishing, [2024]




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Redington promoter sells over 5% stake

Redington promoter sells over 5%stake for Rs.219 crore




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Geometrical impacts of platonic particles on nematic liquid crystal dynamics

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00870G, Paper
Stiven Villada-Gil, Monirosadat Sadati, Juan D. Ospina-Correa, Daniel A. Olaya-Muñoz, Juan P. Hernández-Ortiz, José A. Martínez-González
In this work, we studied the defect dynamics of platonic-like colloidal particles immersed in a nematic liquid crystal under flow conditions, analyzing the behavior of disclinations for each of these polyhedra.
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How to Create a CSS-Only Toggle Button

With the growing eco-system of CSS, designers, and developers are continually seeking ways to leverage its power for interactive UI elements. One such element is the toggle button, an essential interactive component. While more complex features might require JavaScript or …




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Creating Ghost Buttons with CSS

In recent years, ghost buttons have solidified their position as a trendy and elegant element. Characterized by their transparent nature and minimalist outline, ghost buttons, also known as “empty” or “naked” buttons, offers a sleek, clean aesthetic that can improve …




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Create Neon Style Buttons Using CSS

CSS truly is a remarkable tool in a web designer’s toolkit, capable of bringing even the most vibrant creative visions to life. Today, we’re immersing ourselves in the radiant world of neon style buttons, showcasing the impressive spectrum of CSS …




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Ripple Button Effect Using Pure CSS

Google’s Material Design guidelines introduced the ripple effect, a subtle animation that indicates user action. The ripple effect rapidly gained popularity in web design as a sophisticated visual feedback form that refines user interaction, particularly on buttons. Today, we’ll show …




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Montblanc and Ferrari’s new pen is inspired by the carmaker’s iconic Daytona SP3

Montblanc has reimagined the limited edition fountain pen Montblanc Ferrari Stilema SP3 LE 599’s ink-filling mechanism behind a semi-translucent red blade



  • Life & Style

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Caninabis / directed by: Kaj Pindal ; produced by: Gaston Sarault ; production agency: National Film Board of Canada (Montreal)

Montreal : National Film Board of Canada, 2018




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Bernoulli's fallacy [electronic resource] : statistical illogic and the crisis of modern science / Aubrey Clayton.

New York : Columbia University Press, [2021]




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Probability, choice, and reason [electronic resource] / Leighton Vaughan Williams.

Boca Raton, FL : CRC Press, 2022.




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Topics in Banach space theory [electronic resource] / Fernando Albiac, Nigel J. Kalton

New York : Springer, 2005




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Symbiosis launches dual degree MBA in partnership with Macquarie University and Aston University




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University of Southampton Delhi ready for its first intake




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Norton Motorcycles announces top level changes




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Mindspace REIT to build 3 data centres for Princeton Digital Group

The REIT has already developed two data centers for PDG with an area of 6.3 lakh square feet and the current contract will add 10 lakh square feet to its portfolio




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Towards the total synthesis of mandelalide B: construction of the tetrahydrofuran/α-hydroxyl lactone fragment

Org. Chem. Front., 2024, 11,6353-6357
DOI: 10.1039/D4QO01433B, Research Article
Jia-Lei Yan, Jie Yu, Yingying Cheng, Mingze Yang, Zhengshuang Xu, Tao Ye
A stereocontrolled synthesis of the tetrahydrofuran/α-hydroxy lactone fragment of mandelalide B has been accomplished. The synthesis features a Horner-Wadsworth-Emmons fragment assembly strategy and a highly stereospecific iodine-induced cyclization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01771D, Research Article
Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
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Livingstone rises to the occasion as England levels ODI series against West Indies

England finished its successful run chase on 329-5 in the second one-day international with 15 balls remaining




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Milestone for Indian diaspora poets

English language poets of the Indian diaspora were celebrated at a recent event in London.




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The Complete to Planning Your Estate in Washington: A Step-by-Step Plan to Protect Your Assets, Limit Your Taxes, and Ensure Your Wishes are Fulfilled for Washington Residents

What happens to your estate after you are gone is very much within your control. Estate planning is not only for the wealthy; it is for everyone. It is simply the process of deciding where your assets are to be distributed after your death. For those people who wish to preserve their assets for designated […]




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Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Naga tribes body issues deadline to Nagaland government for feedback on autonomous territory

The Eastern Nagaland People’s Organisation wants the creation of Frontier Nagaland Territory comprising six districts of the northeastern State bordering Myanmar




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Masood, Shafique hit tons; Pakistan dominate Day 1

Captain Shan Masood smashed 153 and forged a 253-run partnership with fellow centurion Abdullah Shafique as Pakistan dominated Day 1 of the first Test against England on Monday.




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PIX: Root, Brook smash tons; England pile on the runs

Joe Root and Harry Brook's centuries powered England's strong reply on Day 3 of the first Test in Multan.