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Assessing aspects of solution-based chemical synthesis to convert waste Si solar cells into nanostructured aluminosilicate crystals

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edita Garskaite, Math Bollen, Enock Mulenga, Mathis Warlo, Glenn Bark, Espen Olsen, Dalia Brazinskiene, Denis Sokol, Dietrich Buck, Dick Sandberg
An affordable, scalable, and easily adoptable solution-based processing route provides a potential way of converting waste Si solar cells into aluminosilicate minerals to contribute to sustainability in the solar energy value chain.
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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A novel one-dimensional Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructure fabricated by a single-nozzle electrospinning technique and its low color drift property at high temperature

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00149D, Paper
Shanshan Cong, Zhuang Tian, Hongquan Yu, Sai Xu, Lihong Cheng, Baojiu Chen, Tianshuo Liu
1D Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructures were fabricated by a simple single-nozzle electrospinning method. These materials exhibit excellent luminescent stability and lower color drift performance at high temperatures.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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S-scheme heterojunction based on CuWO4/WO3 microspheres with improved photocatalytic property under visible light

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00301B, Paper
Yangang Sun, Jianhua Ge, jiaqi xu, Jinguo Wang
Dye wastewater green treatment has always been one of the research hotspots in the environmental protection and remediation field. The photocatalytic degradation and mineralization of organic dyes are considered to...
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Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00221K, Communication
Open Access
Sumea Klokic, Benedetta Marmiroli, Denys Naumenko, Giovanni Birarda, Simone Dal Zilio, Miriam de J. Velásquez-Hernández, Paolo Falcaro, Lisa Vaccari, Heinz Amenitsch
Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage.
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3-(3,5-Dinitrophenyl)-5-amino-1,2,4-oxadiazole: synthesis, structure and properties of a novel insensitive energetic material

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00201F, Paper
Binshan Zhao, Baolong Kuang, Mou Sun, Tingwei Wang, Chao Zhang, Meiqi Xu, Cong Li, Zujia Lu, Jian-guo Zhang
A novel heat-resistant energetic compound 3-(3,5-dinitrophenyl)-5-amino-1,2,4-oxadiazole with low mechanical sensitivity on the basis of combining dinitrobenzene and aminooxadiazole was synthesized through a simple method in this work.
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Highly efficient and durable P, Ru–CeO2 self-supporting electrodes toward industrial-level hydrogen production

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00143E, Paper
Wenguang Ma, Xiaodong Yang, Yanru Xu, Cuncheng Li, Yiqiang Sun, Qi Shen, Zhixin Sun
The electrolysis of seawater has become a preferred method for hydrogen production since the current shortage of freshwater resources, offering an effective strategy to address the energy crisis.
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Flux growth and characterization of gallium-rare earth borates

CrystEngComm, 2024, 26,2180-2189
DOI: 10.1039/D3CE01269G, Paper
Victor V. Maltsev, Elizaveta V. Koporulina, Elena A. Volkova, Diana D. Mitina, Anna I. Jiliaeva, Vladimir L. Kosorukov, Alexey E. Afanasev, Daniil A. Naprasnikov
YGa3(BO3)4 single crystals were grown from a K2Mo3O10-based flux, and also RGa3(BO3)4 (R = Y, Pr–Yb) spontaneous crystals (RGB) were obtained by a high-temperature flux growth technique from a complex R2O3–Bi2O3–B2O3–Ga2O3 solvent.
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Synthesis and photophysical properties of charge transfer cocrystals based on TCNB and fluorene and its derivatives

CrystEngComm, 2024, 26,2155-2165
DOI: 10.1039/D3CE01208E, Paper
Wenxiu Yao, Pengfei Wu, Yidan Xie, Xinyu Shen, Shuwei Xia, Liangmin Yu
A series of charge transfer cocrystals with fluorescence properties involving 1,2,4,5-tetracyanobenzene as acceptor, fluorene, 2-bromofluorene, carbazole and 2-bromocarbazole as donor were synthesized via cocrystal design strategies.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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Shortening CN⋯Br–Csp3 halogen bonds via π-stacking

CrystEngComm, 2024, 26,2131-2135
DOI: 10.1039/D4CE00307A, Communication
Open Access
Kamil Kupietz, Rosa M. Gomila, Thierry Roisnel, Antonio Frontera, Rafael Gramage-Doria
An extremely short N⋯Br distance between a nitrile group and a Csp3-linked bromine atom was encountered in the solid-state and rationalized by DFT calculations, which emphasized the role of π-stacking for bringing both partners at close proximity.
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Elon Musk signals Twitter's headquarters may not stay in San Francisco

San Francisco officials said they would investigate Twitter after six former employees alleged that the company broke laws by turning its headquarters into a ‘Twitter Hotel’




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Twitter is refusing to pay its Google Cloud bills: Report

Twitter hosts some services on its server and houses others on the cloud platforms of Amazon and Google.




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Elon Musk says Twitter video app for smart TVs is 'coming'

Musk responded to a tweet suggesting that a Twitter video app is needed.




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Twitter's new chief plans to bring advertisers back to platform

Twitter CEO Yaccarino is planning to launch full-screen, sound-on video ads.




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Users shift to third-party apps as Twitter makes verification necessary for TweetDeck access

Meta’s Threads app, seen as a formidable competitor to Twitter, has garnered over 10 million sign-ups within seven hours of launch, offering features similar to Twitter and attracting users from Instagram.




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Twitter threatens to sue Meta over Threads: report

Meta, which launched Threads on Wednesday, looks to take on Elon Musk's Twitter by taking advantage of Instagram's billions of users




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Meta's Twitter rival Threads overtakes ChatGPT as fastest-growing platform

Threads bears a strong resemblance to Twitter, as do numerous other social media sites that have cropped up in recent months as users have chafed at Musk's management of the service




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Musk says Twitter is losing cash because advertising is down; company is carrying heavy debt

Need to reach positive cash flow before we have the luxury of anything else: Elon Musk




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Artists take government to court over 'chilling' tech laws

Kunal Kamra, who for nearly a decade has satirised politics and social norms in his routines, is fighting an amendment to the IT rules that allows the government to order social media platforms to take down any news that its fact-checking unit identifies as "fake or false or misleading"




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Three reasons why HTC One has a headstart




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Two-quarters of no disruptions will help revive entry-level bike and cars segments: FADA chief  

The EV segment needs to deliver good quality products, said Vinkesh Gulati




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India to register 14% growth in seafood exports products valued at close to $8.86 b in FY23

MPEDA looking to ramp up seafood exports into newer markets




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Edible oil imports up 28% in July as traders buy more RBD palmolein, soya oil

Global decline in their prices aid the trend




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Export growth decelerates in July as global uncertainty rises

Imports rise sharply, trade deficit almost triples




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India, Bangladesh to start negotiating free trade pact this year

Modi, Hasina sign 7 MoUs in areas such as water sharing, railway infra, judicial officers training, science & tech




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Windfall profit tax on crude oil hiked, levy on export of diesel cut

The export tax on jet fuel or ATF, which was set at ₹5 a litre in the last review on November 1, has not been altered




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GST payers get communication to first show irreversible ITC and then reverse, experts advise caution in filing Nov GSTR-3B

In August 2022 this year, Central Board of Indirect Taxes & Custom (CBIC) issued a detailed clarification on reporting of information about reversal of ITC as well as ineligible ITC




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India’s FTAs with EU, UK, Canada may not bring in significant gains, says report

Insignificant market access, introduction of new issues, a double whammy




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Goyal calls for self-regulation in entertainment industry

The Minister added that the government is making efforts to simplify the permission mechanism for shooting of content at various locations in the country




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Centre to invest over ₹380 crore to deepen draft depth at Cochin port

Eyes Cochin port as an alternative trans-shipment hub to Colombo




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FinMin claims enough opportunity given to trade unions to present views during pre-budget consultations

FinMin officials say issue raised by the Trade Unions is politically motivated




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Centre brings 15 additional departments under ED’s info sharing arrangement

Several legal experts see this giving untrammelled powers to the ED




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CAGs of India, Chile sign MoU to support capacity building

Murmu is currently on an official visit to Chile




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Kirit Parikh panel submits report on gas prices, suggests pricing freedom beginning Jan 2026

ONGC and Oil India will be paid a price linked to imported oil but it will have a minimum or floor price of $4 per million British thermal unit and a cap or ceiling price of $6.5




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Cheaper to live in India than US, UK and Germany: SBI report

If the household budget/ cost of living was Rs 100 in September 2021, it has increased by Rs 12 in both the US and India, but it has increased by Rs 20 in Germany and Rs 23 in the UK: Report




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Make in Odisha summit: Investments worth over ₹5-lakh cr to flow into State

Govt launches new policy; aims to make the State a destination choice for industrial enterprises




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India imports 46.14 lakh tonnes of urea in Apr-Nov this fiscal

During the first eight months, urea production stood at 187 lakh tonnes




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In a relief for India Inc, MCA extends virtual AGMs till September 2023

Also, the MCA allowed companies to hold EGMs via video conference until September 30, 2023




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India exports ₹2,400 cr of jewellery to Australia under FTA

This is the second FTA with Australia in this year and has a lot of potential for exporting finished products as they are largely a raw material and intermediate producing country: Piyush Goyal




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Micro & small enterprises corner 55% of total orders placed on GeM portal

Procurement of goods and services from GeM has crossed ₹1-lakh cr so far this fiscal on account of an increase in buying activities by different ministries and departments




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India will be a global price setter in fertilisers by 2024: Mandaviya

‘We will bring down DAP prices to below the $650/tonne level this month’, he said




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Rare earth elements and critical minerals will be next geopolitical battleground: Survey

Shift to clean energy will boost demand




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How a Dharavi-based housemaid inspired rural financial start-up Jai Kisan 

The digital financial services firm eyes onboarding 1 million farmers before fiscal end




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After weak December quarter, winter products begin seeing an uptick in demand

Demand for winterwear apparel segment has also witnessed an uptick in the past few days




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India has no plans to import wheat for now - Piyush Goyal

Government has sold around 6 mmt of wheat to local bulk buyers since June 1




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India withstood geopolitical shocks; will navigate future uncertainties too: MPC's Jayanth R Varma

Global growth expected to come down to 2.9 per cent in 2024




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Five heart-pounding ways to spend your Swiss adventure

The resort town of Interlaken is not just about idyllic lake cruises