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[ASAP] Straightforward Access to 2-Iodoindolizines via Iodine-Mediated Cyclization of 2-Pyridylallenes

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00418




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[ASAP] Photo-oxidation of Cyclopentadiene Using Continuous Processing: Application to the Synthesis of (1<italic toggle="yes">R</italic>,4<italic toggle="yes">S</italic>)-4-Hydroxycyclopent-2-en-1-yl Acetate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00066




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[ASAP] Catalyst-Free Cyclization- and Curtius Rearrangement-Induced Functional Group Transformation: An Improved Synthetic Strategy of First-in-Class ATX Inhibitor Ziritaxestat (GLPG-1690)

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00511




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Gold-catalyzed domino cyclization enabling construction of diverse fused azaspiro tetracyclic scaffolds: a cascade catalysis mechanism due to a substrate and counterion

Catal. Sci. Technol., 2020, 10,2415-2426
DOI: 10.1039/D0CY00120A, Paper
Yunhe Li, Xiang Zhao
The detailed mechanism and origins of gold-catalyzed domino cyclization to diverse fused azaspiro tetracyclic scaffolds by cooperative dual catalysis and cascade catalysis are systematically studied.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00593B, Paper
Marta Navarro, Luis F. Sánchez-Barba, Andrés Garcés, Juan Fernández-Baeza, Israel Fernández, Agustín Lara-Sánchez, Ana M. Rodríguez
The binuclear aluminum complexes [AlR22-NN';κ2-NN')AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ligand photodissociation in Ru(II)–1,4,7-triazacyclononane complexes enhances water oxidation and enables electrochemical generation of surface active species

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02575H, Paper
Hussein A. Younus, Nazir Ahmad, Ibrahim Yildiz, Serge Zhuiykov, Shiguo Zhang, Francis Verpoort
Ligand transformations involved in metal complexes during water oxidation (WO), such as ligand decomposition, partial oxidation, or complete dissociation have been reported, however, ligand photodissociation has not been reported yet.
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Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic degradation of tetracycline hydrochloride over rugby-like β-Ga2O3 with a 3D hierarchically assembled porous structure for environmental remediation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00562B, Paper
Lingxing Zeng, Jiaqi Wang, Qingrong Qian, Qinghua Chen, Xin-Ping Liu, Yongjin Luo, Hun Xue, Zhaohui Li
A novel rugby ball-like β-Ga2O3 photocatalyst with a 3D hierarchically assembled porous structure was constructed via a facile precipitation–calcination method. The as-synthesized Ga2O3 exhibits a high photocatalytic efficiency compared to commercial Ga2O3 and Degussa P25.
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Prometryn induces apoptotic cell death through cell cycle arrest and oxidative DNA damage

Toxicol. Res., 2019, 8,833-841
DOI: 10.1039/C9TX00080A, Paper
Qiaoyun Liu, Longsheng Wang, Hanwen Chen, Bo Huang, Jiawei Xu, Ying Li, Paul Héroux, Xinqiang Zhu, Yihua Wu, Dajing Xia
Prometryn induces oxidative stress-mediated DNA damage; Prometryn induces S phase of cell cycle arrest; Prometryn induces Bax-dependent apoptosis in BEAS-2B cells.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cyclodextrin-based superparamagnetic host vesicles as ultrasensitive nanobiocarriers for electrosensing

Nanoscale, 2020, 12,9884-9889
DOI: 10.1039/D0NR01702G, Paper
Jose Muñoz, Núria Crivillers, Bart Jan Ravoo, Marta Mas-Torrent
Magnetic cyclodextrin vesicles (mCDVs) have been used as novel electrochemical biorecognition probes for the picomolar determination of thyroxine (T4), using a magneto nanocomposite carbon-paste electrode (mNC-CPE) as a transducer platform.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The design of an autonomous recycling robot




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Two women stand with their bicycles




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Young woman riding a bicycle down a residential street, probably in Charlottesville




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Woman on a motorcycle




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Bicycle riders' protest




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Park. People sitting on benches marked N.W.S. watching a game of croque; thick, lush line of trees with abundant Spanish moss, hex blocks, bicycle




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Park. Street, streetlight, dense trees, grass, benches, sign "bicycle riding prohibited in the park.", small building, many people standing and walking




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Ohio parade float, cars, bicyclist in front of Ponce de Leon Hotel, fish market; spectators include people watching from hotel balcony




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Queen of Hearts parade float at Vinoy Hotel, with people in costume and on bicycles, including children




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Girl on decorated tricycle next to doll carriage with sign, "St. Pete Future Housewife."; taken at the Vinoy Hotel




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Three different types of transportation; Looking down brick street lined with trees; concrete curb, trees planted in grassy strip between road and sidewalk. bicycle parked on its side halfway down the street, horse-drawn cart and car side by side at far e




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1911 St. Petersburg High School (5th Street North between 1st and 2nd Avenues) with man standing in front doorway, several bicycles




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St. Petersburg Yacht Club (porte cochere, porch chairs, bicycle, Spa in background)




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Alexander Hotel, 500 block of Central Avenue seen from street, including bicyclist, benches, and cars, plus Sanitary Dry Cleaning Plant, and the Paul Reese Sign Store




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Floronton Hotel with cars, people, and bicyclist




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Ponce de Leon Hotel and cars, man walking, benches, bicycle, market, Café a la Carte, smokestack




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Lake surrounded by man on bicycle, houses, car, gazebo, grass




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Pier with powerlines, people, shelter at end with a shed on each side, cars, bicycles, boats in water at side




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Tampa Bay with various boats-mostly sailboats-and many spectators lining the shore, one with bicycle




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Five Wagners sitting on a bench in yard, Betty on a tricycle




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Five Wagners sitting on bench in yard, Betty on a tricycle




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Five Wagners sitting on bench in yard, Betty on a tricycle holding a doll




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Bud riding tricycle in grass with Uppy the puppy




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Betty wearing sweater and minidress, riding large tricycle in grass




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Betty wearing sweater and minidress, riding large tricycle in grass with Irma and Uppy the puppy




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Bud wearing long-sleeved shirt and knickers, sitting on too-large bicycle outside house




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The bicycle trail, Palm Beach, Fla




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Automobile Road and bicycle trail, Palm Beach




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Extensions of quandles and cocycle knot invariants




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Weblogs and the technology lifecycle




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Recycled materials relational database




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Helping break the cycle of school violence and aggression




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Occupational exposure to ultrafine particles and polycyclic aromatic hydrocarbons from candle emissions




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Chemical Investigation of two Antarctic Invertebrates, Synoicum adareanum (Chordata: Ascidiaceae; Enterogona; Polyclinidae) and Austrodoris kergulenensis (Molusca; Gastropoda; Nudibranchia; Dorididae)




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Simulations for thermodynamic analyses of transcritical carbon dioxide refrigeration cycle and reheat dehumidification air conditioning cycle




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Stabilization of marginal soils using recycled materials




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Polynomial quandle cocycles, their knot invariants and applications




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Bcl-2 related ovarian killer, Bok, is cell cycle regulated and sensitizes to stress-induced apoptosis




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Analysis of E2F1 target genes involved in cell cycle and apoptosis