Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper

George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01031K, Paper

Xinwan Zhao, Minjun Lei, Guangbo Liu, Zhiliang Jin, Noritatsu Tsubaki
A fundamental strategy for enhancing the performance of photocatalytic water-splitting catalysts is to facilitate the efficient migration of photogenerated charge carriers to establish a heterojunction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01029A, Paper

Haiting Ye, Takuma Sato, Taishi Nakanishi, Shigetomo Ito, Shigenobu Umemiya, Masahiro Terada
Chiral phosphoric acid catalysts were screened rationally and efficiently through the theoretical prediction model of the kinetic resolution of racemic γ-hydroxybutyrate without performing an exhaustive search for plausible lactonisation pathways.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01132E, Paper

Zaili Xiong, Jijun Guo, Yuwen Deng, Meirong Zeng, Zhandong Wang, Zhongyue Zhou, Wenhao Yuan, Fei Qi
This study investigates the oxidative coupling of methane (OCM) using a Li/MgO catalyst in a packed bed reactor.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00825A, Paper

Kanchan Sharma, Rajesh K. Yadav, Rajesh Kumar Verma, Satyam Singh, Shaifali Mishra, Rehana Shahin, Atul Pratap Singh, Chandani Singh, Navneet Kumar Gupta, Jin-Ook Baeg, Hwanhui Yun, Hyeongjoong Kim
Incorporating defects through intrinsic defect engineering has emerged as a versatile strategy for finely tuning key properties of materials, particularly the redox capacity. Defects are fundamentally important in enhancement of...
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Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper

Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO₂ into cyclic carbonates from flue gas under atmospheric pressure.
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Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper

Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO₂ reduction, resulting in the dynamic evolution of i-CuO_x species. The in situ formed i-CuO_x plays decisive roles in promoting C–C coupling.
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Catal. Sci. Technol., 2024, 14,6331-6337
DOI: 10.1039/D4CY01046A, Paper

Ling Ding, Lou Gao, Di Pan, Ke Du, Jiayu Yu, Wanyi Li, Yahong Zhang, Yi Tang
Efficiently reduce the formation of meso-lactide from racemic lactic acid by utilizing H-Beta zeolite shape selectivity towards lactic acid dimers.
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper

Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O₂ is reported.
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Catal. Sci. Technol., 2024, 14,6180-6185
DOI: 10.1039/D4CY01117A, Communication

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Ren-Rui Xu, Chang-Sheng Kuai, Xiao-Feng Wu
An efficient strategy for the synthesis of acrylamides via palladium-catalyzed carbonylation, using 1,2-dichloroethane and amines as starting materials has been developed.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper

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Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00775A, Paper

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Ettore Bianco, Fabrizio Sordello, Francesco Pellegrino, Valter Maurino
In hydrogen production through water splitting, two reactions are involved: Hydrogen Evolution Reaction (HER) and Oxygen Evolution Reaction (OER), both with efficiency issues. In previous works, our group demonstrated the...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper

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Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni₉₉Pt₁/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01035C, Paper

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Matthew E. Potter, Lucas Spiske, Philipp N. Plessow, Evangeline B. McShane, Marina Carravetta, Alice E. Oakley, Takudzwa Bere, James H. Carter, Bart D. Vandegehuchte, Kamila M. Kaźmierczak, Felix Studt, Robert Raja
Using a model microporous catalyst, the influence of acid site density and partial pressure is explored in alkane isomerisation. Combining with DFT calculations shows the role of olefins in this industrially important catalytic process.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01070A, Review Article

Deyu Chu, Jinjing Ma, Qishun Liu, Jie Fu, Heng Yin
Optimizing the production process of high value-added chemicals derived from renewable biomass holds immense promise for clean energy utilization and environmental sustainability.
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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper

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Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper

Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO₄ solution by electrochemical technology to catalyze the reduction of N₂ to NH₃. It was found that the applied magnetic field can significantly increase the current density.
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Catal. Sci. Technol., 2024, 14,6641-6650
DOI: 10.1039/D4CY00913D, Paper

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D. J. Ward, D. J. Saccomando, F. Vilela, G. Walker, S. M. Mansell
Flow chemistry helped optimise the conversion of a branched primary alcohol to an alkene. Mass balance was achieved through the elimination of by-products, including alkene oligomers, and the setup could be optimised to give up to 98% alkene product.
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Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper

Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO₂. The CO₂ conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper

Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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Catal. Sci. Technol., 2024, 14,6710-6719
DOI: 10.1039/D4CY00739E, Paper

Charlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann Pellegrin
A perylene-doped mesoporous silica material is used as a photocatalyst to produce H₂O₂ from aerated polluted water samples under light soaking.
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Catal. Sci. Technol., 2024, 14,6496-6502
DOI: 10.1039/D4CY00869C, Communication

Elena Gkantzou, Theofilia Koulopoulou, Hannah Brass, David Schönauer, Anton Glieder, Selin Kara
In the context of empowering biocatalysis, an easy-to-develop, reproducible, and easy-to-scale biocatalytic system is demonstrated as a microfluidic screening platform.
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Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper

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Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper

Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper

Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO₂ mitigation through conversion into useful chemicals.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper

Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
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Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper

Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Nanoscale, 2024, 16,20194-20201
DOI: 10.1039/D4NR03435J, Paper

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Lukas Schubert, Chiara Nenninger, Maximilian Nöth, Thomke Belthle, Robert Dirk de Lange, Andrij Pich, Ulrich Schwaneberg, Dominik Wöll
The distribution and local catalytic activity of Cytochrome P450 enzymes immobilized in microgels by electrostatic interaction has been determined with a combination of in situ super-resolution fluorescence microscopy experiments.
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Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper

H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
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Nanoscale, 2024, 16,20228-20234
DOI: 10.1039/D4NR03320E, Paper

Dongjie Zuo, Huifang Guo, Qinghua Xu, Ayisha He, Zilin Li, Simin Li, Hui Shen
The first gold–copper alloy cluster protected by both NHC and alkyne ligands was reported. The cluster displays interesting mechanochromic properties, highlighting the bright future of NHC-functionalized metal nanoclusters in materials science.
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Nanoscale, 2024, 16,20100-20117
DOI: 10.1039/D4NR03750B, Paper

Quanle Zou, Bochao Xu, Weizhi Wang, Yulin Hu, Ting Liu, Qingsong Li, Tengfei Ma, Haolong Zheng, Zixuan Huo
The SiO₂ nanofluids enhance coal wettability by promoting hydrogen bond formation, increasing hydrophilicity and water absorption. This weakens coal cohesion, causing softening.
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Nanoscale, 2024, 16,20118-20130
DOI: 10.1039/D4NR02887B, Paper

Hyeju Han, Bongkyun Kang, Shazid Md. Sharker, Tabassum Binte Kashem, Yuejin Kim, Jeehee Lee, Minok Park, Eunjeong Kim, YunJae Jung, Jinkyu Lim, Seungwon Ryu, Kyueui Lee
The combination of PDA NPs and 1,4-DPCA leads to a synergistic effect that enhances bone tissue regeneration in vivo.
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Nanoscale, 2024, 16,20089-20099
DOI: 10.1039/D4NR03278K, Paper

Xinyue Dou, Sariah Saalah, Chel-Ken Chiam, Jianping Xie, Coswald Stephen Sipaut
An Au nanocluster (NC)-based photodynamic antibacterial is designed by conjugating arginine on the surface of Au₂₂ NCs, achieving healing of bacteria-infected wounds via producing reactive oxygen species (ROS) and reactive nitrogen species (RNS).
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Nanoscale, 2024, 16,19936-19937
DOI: 10.1039/D4NR90169J, Editorial

Li Zhang, Martin Pumera, Samuel Sánchez, Xing Ma
Li Zhang, Martin Pumera, Samuel Sánchez and Xing Ma introduce the Nanoscale and Journal of Materials Chemistry B cross-journal themed collection on micro- and nano-motors.
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Nanoscale, 2024, 16,20354-20355
DOI: 10.1039/D4NR90194K, Correction

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Ziwei Li, Fan Yang, Di Wu, Yanhong Liu, Yang Gao, Haichen Lian, Hongxin Zhang, Zhibin Yin, Aiguo Wu, Leyong Zeng
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03871A, Paper

Gai-li Feng, Wei Zhou, Jinping Qiao, Guang-Jian Liu, Guo-Wen Xing
Photodynamic therapy (PDT) and chemodynamic therapy (CDT) are both promising cancer treatments to inhibit tumor cells by generating highly cytotoxic reactive oxygen species (ROS). Herein, we report a novel tumor...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03140G, Paper

Himangshu Baishya, Mayur Jagdishbhai Patel, Ramkrishna Das Adhikari, Deepak Yadav, Parameswar Krishnan Iyer
The interaction between CO and Pb²⁺ regulated grain growth, enhanced crystallinity that effectively passivated non-radiative recombination centres and CF₃ group stabilizes the perovskite structure by interacting with FA and Pb cationic defects.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04011B, Communication

Kentaro Tashiro
Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the emergence of macroscopic chiral symmetry breaking in the gelation of Fmoc amino acids.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02458C, Paper

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Ruoyu Wu, Peng Han, Tobias Dittmann, Fu-He Wang, Yan Zhang, Gabriel Bester
We use a computational method based on ab initio (constrained) density functional theory to obtain the photoluminescence spectrum of graphene quantum dots with up to 240 carbon atoms, including the...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03225J, Communication

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Yidong Yu, Theresa Vogel, Sina Hirsch, Jürgen Groll, Krystyna Albrecht, Andreas Beilhack
Application of anionic liposomes co-loaded with amphotericin B and siRNA demonstrates a temporary antifungal effect lasting 3–4 days, highlighting their therapeutic potential.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03545C, Paper

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Lauri Palmolahti, Harri Ali-Löytty, Markku Hannula, Tuomas Tinus, Kalle Lehtola, Antti Tukiainen, Jarno Reuna, Mika Valden
Amorphous TiO₂ has insufficient chemical stability that can be enhanced with annealing induced crystallization. However, the crystalline structure is already predetermined by the defect composition of the amorphous phase. In...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02845G, Paper

Na Zhou, Yanning Wang, Jiao Wang, Panchao Zhao, Hang Zhang
Exploiting efficient and inexpensive electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of great significance for the rapid development of renewable energy technologies.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02778G, Paper

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Masahiro Shibuta, Tsutomu Ohta, Toshiaki Kamoshida, Kana Yamagiwa, Hironori Tsunoyama, Tomoya Inoue, Tsugunosuke Masubuchi, Atsushi Nakajima
An alkaline-like Ta-encapsulating Si₁₆ superatom film was fabricated on a C₆₀ substrate. Charge transfer between Ta@Si₁₆ and C₆₀ lowers the work function. In the multilayer film, the central Ta atom's positive charge is compensated by the Si₁₆ cage.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04138K, Paper

Arushi Arora, Anima Mahajan, Nausad Khan, Santanu Ghosh, Menaka Jha
Design of a new process for the fabrication of FeS–Bi₂S₃ anisotropic nanostructure for field emission application.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03470H, Paper

Ding Nie, Hangyu Zhong, Hongli Hu, Zhenhua Luo, Boxing Zhang
Phenolic and carbon aerogels have important applications for thermal insulation and ablative resistance materials in aerospace areas. However, their antioxidant ability in long-term and high-temperature aerobic environments is facing serious...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02854F, Paper

Jiamin Liang, Yuxin Song, Huan Xing, Liang Ma, Fengxia Wang, Mingfang Zhang, Hongli Zhang, Gang Zou, Guang Yang
A electrochemical sensor for the chiral recognition of Trp based on chiral polyaniline (D-PANI) and β-CD-MOF was designed. It displayed higher affinity of L-Trp, and the oxidation peak current ratio (IL/ID) of DPV could be reached at 2.26.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03616F, Paper

Sanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha Khare
The photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03704A, Paper

Mohamed Aimene Benariba, Kanza Hannachi, Sha Zhu, Yuting Zhang, Xiaoli Wang, Nandi Zhou
This research reveals a significant correlation between PMVs and their associated miRNA. Additionally, the liposome-based assay demonstrates enhanced sensitivity with calcium-induced platelet activation.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03431G, Paper

Suman Yadav, Sarvesh Kumar Pandey, Shikha Awasthi
Polyvinyl alcohol (PVA) is a well-known cost-effective synthetic polymer that offers a variety of applications including medical, aerospace, automotive, and construction industries. However, weak bonding with low mechanical and tribological...
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