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This Strategy is the Key to Scaling Your Business — and Reducing Costs Along the Way

Scaling a business meaningfully and sustainably can be challenging and requires more than ambition. Offshore staffing enables the flexibility and efficiency needed to thrive in today's fast-paced market.




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Apple now lets app developers apply to be featured on the App Store

App developers now have a new way to promote their app launches, updates, and other new features on Apple’s App Store. First announced at the company’s Worldwide Developers Conference in June, Apple this week introduced a “Featuring Nominations” option in App Store Connect, which is the service developers use to submit their apps, games, and […]

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Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit

Commerzbank analizează opțiunea de a achiziționa o bancă germană de dimensiuni medii ca parte a strategiei de a evita o posibilă preluare de către UniCredit, potrivit Reuters. Planurile sunt într-o etapă incipientă, iar posibilele ținte ar putea include Hamburg Commercial Bank sau Oldenburgische Landesbank. Potrivit surselor Reuters, Commerzbank încearcă să conceapă un plan de apărare, ...

The post Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit appeared first on Forbes Romania.




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Chennai Rains: IMD predicts heavy showers for 2 days in Tamil Nadu; Are schools, colleges closed today?

The city experienced heavy rainfall on Wednesday night, and the IMD bulletin indicates that several isolated areas of the capital are expected to see heavy downpours on Thursday.




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Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00233D, Research Article
Fan Zhu, Zhi Qiao, Na He, Chunxiao Nong, Qiping He, Meilan Xi, Xizhong Song, Jun Lin, Jingbo Chen, Yi Jin
A general protocol for the hydroazolylation of alkenes with N-hydroxyl azoles is reported. These reactions proceed via a phosphoranyl radical, followed by radical coupling of the resulting azole radical to the alkene radical.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00140K, Research Article
Qun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin Zhang
Here, an unprecedented one-step modular construction of C2-symmetric N-PACs through  reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be  converted into  a powerful organic photocatalyst.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates: access to bridged eight-membered oxygen heterocycles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00329B, Research Article
Huawei Lin, Biming Mao, Bing Han, Jiayi Luo, Yanqing Ge, Xuerui Zhang, Chang Wang, Hongchao Guo, Chunhao Yuan
A novel palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates has been developed for the synthesis of bridged eight-membered oxygen heterocycles in good yields and with excellent stereoselectivities.
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Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00148F, Research Article
Dong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei Xu
The challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.
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Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00312H, Research Article
Fang-Fang Xu, Zhong-Lei Ruan, Pei-Qiang Huang
We report a highly efficient, versatile, and chemoselective method for the catalytic reduction of sulfoxides to sulfides under mild conditions.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00305E, Research Article
Chen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong Ma
Herein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Nickel metallaphotoredox-catalyzed C–O bond activation/Csp2–Csp3 coupling enabled by phosphine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00310A, Research Article
Jiaxi Fang, Ziheng Jian, Huan Liu, Yuting Wang, Xianbo Yu, Zehuai Mou, Huifei Wang
A novel and general nickel/photoredox dual catalysis platform for benzyl alcohol C–O bond activation/Csp2–Csp3 cross coupling of benzothiazolyl bromide and free alcohol, enabled by the catalytic generation of an alkyl radical, is reported.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis

Org. Chem. Front., 2024, 11,2344-2350
DOI: 10.1039/D3QO01955A, Research Article
Linge Huai, Li Zhang, Zhentao Wang, Yewen Fang
N → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Deoxygenation of N-heterocyclic N-oxides using isopropanol as a recyclable reductant

Org. Chem. Front., 2024, 11,2249-2268
DOI: 10.1039/D4QO00208C, Research Article
Ho Kyeong Ryu, Yun Do Song, Jun Hee Lee
An organic photoredox-based recyclable strategy that facilitates the chemoselective deoxygenation of various functionalised N-heterocyclic N-oxides is presented.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iridium-catalyzed reductive γ-lactonization of ortho-acylbenzoic acids in water: sustainable access to phthalides

Org. Chem. Front., 2024, 11,2220-2230
DOI: 10.1039/D3QO02019C, Research Article
Yang Chen, Jingyu Zhang, Hongguang Du, Renshi Luo, Jiaxi Xu, Zhanhui Yang
Iridium-catalyzed reductive γ-lactonization of ortho-acylbenzoic acids in water provides a practical and sustainable route to phthalides.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis

Org. Chem. Front., 2024, 11,2269-2276
DOI: 10.1039/D4QO00073K, Research Article
Yujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang Lu
Two major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nickel/photoredox-catalyzed carbonylative transformations of α-phosphorus-, α-sulfur-, and α-boron-substituted alkyl halides

Org. Chem. Front., 2024, 11,2297-2305
DOI: 10.1039/D4QO00167B, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Le-Cheng Wang, Xiao-Feng Wu
A novel dual nickel/photoredox catalyzed direct amino- and alkoxycarbonylation of α-heteroatom substituted organohalides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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NHC and photoredox catalysis dual-catalyzed 1,4-mono-/di-fluoromethylative acylation of 1,3-enynes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00372A, Research Article
Jiuli Xia, Ruiyang Ma, Lihong Wang, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC and photocatalysis dual-catalyzed mono/difluoromethylative acylation of 1,3-enynes was realized, providing fluormethyl-substituted allenyl ketones. SO2 might play a critical role in achieving high reactivity and selectivity.
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Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00317A, Research Article
Guohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin Yin
Amine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Efficient Fully Textured Perovskite Silicon Tandems with Thermally Evaporated Hole Transporting Materials

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03899A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bhushan Kore, Oussama Er-raji, Oliver Fischer, Adrian Callies, Oliver Schultz-Wittmann, Patricia Samia Cerian Schulze, Martin Bivour, Stefaan De Wolf, Stefan W Glunz, Juliane Borchert
Fully textured perovskite silicon tandem solar cells effectively minimize the reflection losses and are compatible with industrial silicon production lines. To facilitate scalability and industrial deployment of perovskite silicon tandems...
The content of this RSS Feed (c) The Royal Society of Chemistry




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MRPL honoured for excellence in AI-driven process efficiency

The award was presented at the 27th Energy Technology Meet in Bengaluru.




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Bangladesh includes 1,000 threatened species in 'Red List of Plants'




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Modi honoured Marathi by giving it classical language status, Amit Shah




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Electrochemical nitrate reduction for ammonia production: amorphous or crystalline oxidized copper catalyst?

J. Mater. Chem. A, 2024, 12,8689-8693
DOI: 10.1039/D3TA07506K, Communication
Quanxiao Peng, Dandan Xing, Liuqi Dong, Yuhan Fu, Jixue Lu, Xiaoyu Wang, Changhong Wang, Chunxian Guo
An amorphous oxidized copper (a-O–Cu) is designed to investigate for electrochemical nitrate reduction to ammonia. It is found that a-O–Cu has high capability for water dissociation and amorphous structure-enabled high catalytic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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From scrap metal to highly efficient electrodes: harnessing the nanotextured surface of swarf for effective utilisation of Pt and Co for hydrogen production

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00711E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Madasamy Thangamuthu, Emerson C. Kohlrausch, Ming Li, Alistair Speidel, Adam T. Clare, Richard Plummer, Paul Geary, James W. Murray, Andrei N. Khlobystov, Jesum Alves Fernandes
Atomically deposited Pt and Co on nano-grooves result in active and stable electrocatalysts for hydrogen evolution and oxygen evolution reactions.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Deciphering the role of 2D graphene oxide nanofillers in polymer membranes for vanadium redox flow batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00001C, Review Article
Sadhasivam Thangarasu, Shalu, Gowthami Palanisamy, Subramani Sadhasivam, Karuppaiah Selvakumar, Krishna Rao Eswar Neerugatti, Tae Hwan Oh
This comprehensive review article explains the influence of various GO and GO-polymer membrane modifications for VRFB, which range from cation and anion exchange to amphoteric and zwitterionic membranes.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Dioxygen atom co-doping g-C3N4 for boosted photoreduction activity of CO2 and mechanistic investigation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00156G, Paper
Zhang Jiang, Mingnv Guo, Zhongqing Yang, Ruiming Fang, Ziqi Wang, Jingyu Ran
Visible-light photocatalytic reduction of carbon dioxide with the help of photocatalysts has become an important means to mitigate the greenhouse effect.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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A bioinspired sulfur-surrounded iron catalyst for ammonia synthesis

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00710G, Paper
Na Zhang, Yubing Si, Qiang Fu, Xing Chen
A nitrogenase-inspired inorganic compound consisting of iron (Fe) and molybdenum disulfide (MoS2) is designed with a promising capability of N2 fixation using first principles.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal–support interaction triggered d–p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper
Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe2O3 catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica with promoted CO insertion and C–C coupling for higher alcohol synthesis from syngas

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01179A, Paper
Zhuoshi Li, Siqi Fan, Zhuang Zeng, Shaoxia Guo, Xiaofeng Pei, Shouying Huang, Yong Wang, Yue Wang, Xinbin Ma
Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica showed superior performance for HAS than catalysts with uncoated and amorphous supports.
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Development of diverse aluminium concentration gradient profiles in Ni-rich layered cathodes for enhanced electrochemical and thermal performances

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00433G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinwei Jiao, Junwei Yap, Junbin Choi, Mengyuan Chen, Devendrasinh Darbar, Gongshin Qi, Xiaosong Huang, Jung-Hyun Kim
Nickel (Ni)-rich cathodes with elemental concentration gradients within particles have attracted great interest due to their considerably enhanced interfacial stability and electrochemical performance for advanced Li-ion batteries.
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Reduction on Specific Lattice Planes for Metal-organic Frameworks/Poly-pyrrole Composites with Dilated Porosity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00766B, Paper
Wenxiu He, Xu Zhai, Zhipeng Qiao, Huan Chen, Weiliang Tian, Yu Fu, Junyi Chen
Owing to the microporosity, metal-organic frameworks (MOFs) have attracted great attention in various applications, whereas their potential in mass transfer and diffusion of larger molecules have been limited. To break...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Modulation of active metal species in MOF-derived catalysts for Efficient NO reduction by CO

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01075B, Paper
Ning-Rui Zhou, Zhen Yang, Ying Tang, Ming-Qi Zhang, Yun-Peng Zha, Min-Min Liu, Feng Yu, Jiang Liu
Transition metal oxides are usually used as one of the most excellent catalysts for NO selective catalytic reduction by CO (CO-SCR), but their catalytic activity is limited by the content...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Deciphering cycling voltage-dependent failures of O3-layered cathode for sodium ion battery

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07967H, Paper
Xuejiao Zhao, Lihan Zhang, Xiaoqi Wang, Jinhui Li, Lin Zhang, Di Liu, Rui Yang, Xu Jin, Manling Sui, Pengfei Yan
Interfacial degradations dominate the performance decay of O3-layered cathode during low-voltage cycling; high voltage cycling induced bulk failures cause rapid performance decay due to transition metal cation migration.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Regulating the local microenvironment on porous Cu nanosheets for enhancing electrocatalytic CO2 reduction selectivity to ethylene

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01198H, Paper
Dan Wang, Qingqing Song, Kaibin Li, Yuwei Zhou, Junjun Mao, Chenchen Zhang, Yang Lou, Chengsi Pan, Jiawei Zhang, Yongfa Zhu, Ying Zhang
Local microenvironments of the ECO2RR play an important role in tuning the adsorption energy of crucial intermediates, which helps enhance ECO2RR selectivity.
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Bio-inspired design of a self-supported bismuth microforest for high performance sodium storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00950A, Paper
Jia Bai, Yan Liu, Ben Pu, Qi Tang, Yongbin Wang, Ruihan Yuan, Jin Cui, Yi Yang, Xiaojia Zheng, Bin Zhou, Weiqing Yang
A self-supported bismuth microforest anode material, prepared by a simple, efficient and scalable in situ galvanic replacement approach, exhibits high performance for sodium-ion batteries.
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Insights into the Enhanced Cycling Stability of Cobalt-Free Single-Crystal Layered Oxide Cathodes at Elevated Voltage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA02135E, Paper
Tiancheng Liu, Ke Fan, Changsheng Chen, Mingxia Dong, Yanping Zhu, Gao Chen, Jiangtong Li, Zezhou Lin, Liuqing Li, Ye Zhu, Huangxu Li, Haitao Huang
Co-free single-crystal cathodes Li(NixMn1-x)O2 have been proposed as promising candidates due to remarkable thermal stability and low cost. Unfortunately, insufficient in-depth understanding on the failure mechanisms hinders the development of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly Boosted Energy Storage Performance of Few-Layered MoS2 Utilized by Improved Electrode Fabrication: Experimental and Theoretical Studies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01713G, Paper
Zeyad M. Abdulhamid, Abhishek C. Lokhande, Adewale Hammed Pasanaje, Daniel S Choi, Nirpendra Singh, Kyriaki Polychronopoulou, Dalaver H. Anjum
Few-layer two-dimensional (2D) molybdenum disulfide (MoS2) has great potential in designing high-performance supercapacitors due to its high theoretical specific capacity, tunable bandgap, and fascinating 2D layered structure. However, the lack...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Molecular-polaron-coupling-enhanced photocatalytic CO2 reduction on copper phthalocyanine/NiMgFe layered double hydroxide nanocomposites

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07538A, Paper
Yuexian Li, Wenli Su, Xiaoyan Wang, Jun Lu, Wenkai Zhang, Shuo Wei
We built CuPcS/NiMgFe-LDHs composites and probed the unique photogenerated-carrier transfer mechanism. A series of long-range Forster energy transfers prolonged the lifetime of photogenerated carriers to match the timescale of surface reaction.
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Machine Learning Enabled Exploration of Multicomponent Metal Oxides for Catalyzing Oxygen Reduction in Alkaline Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01884B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xue Jia, Hao Li
Low-cost metal oxides have emerged as promising candidates used as electrocatalysts for oxygen reduction reaction (ORR) due to their remarkable stability under oxidizing conditions, particularly in alkaline media. Recent studies...
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Nifty prediction today – November 13, 2024: Bearish. Go short now and on a rise

Nifty 50 November futures can fall to 23,400




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Bank Nifty Prediction today – November 13, 2024: Short when the support is breached

Bank Nifty futures is now testing the support at 51,000




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The Mushroom Color Atlas: An Interactive Web Site Lets You Explore the Incredible Spectrum of Colors Created from Fungi

Enter the Mushroom Color Atlas, and you can discover the “beautiful and subtle colors derived from dyeing with mushrooms.” Featuring 825 colors, each associated with different types of mushrooms, the interactive atlas lets you appreciate the broad spectrum of colors latent in the fungi kingdom. The shades, tints, and hues will surprise you. Julie Beeler, […]




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State Library Council Awards declared, M. Leelavathy wins I.V. Das award for overall contributions




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Youth injured in accident in Idukki




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New rest norms for pilots will reduce their salary, Air India tells DGCA

Meeting held as part of mediation ordered by Delhi High Court between pilots and airlines