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[ASAP] Rapid Route-Finding for Bifurcating Organic Reactions

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b13449




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Palladium supported on triazolyl-functionalized hypercrosslinked polymers as a recyclable catalyst for Suzuki–Miyaura coupling reactions

RSC Adv., 2020, 10,17123-17128
DOI: 10.1039/D0RA01190H, Paper
Open Access
Cijie Liu, Lijuan Zheng, Dexuan Xiang, Shasha Liu, Wei Xu, Qionglin Luo, You Shu, Yuejun Ouyang, Hongwei Lin
A novel hypercrosslinked polymer-palladium catalyst was prepared via external cross-linking reactions and applied in Suzuki–Miyaura reactions as a recyclable catalyst, resulting in TON numbers up to 1.66 × 104 and yields reaching 99%.
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Alkaline water-splitting reactions over Pd/Co-MOF-derived carbon obtained via microwave-assisted synthesis

RSC Adv., 2020, 10,17359-17368
DOI: 10.1039/D0RA02307H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Adewale K. Ipadeola, Kenneth I. Ozoemena
Palladium nanoparticles supported on MOF-derived carbon serve as an efficient bifunctional electrocatalyst for alkaline water-splitting reactions.
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1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01223H, Paper
Tomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh
1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...
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Simulations unveil Grignard reactions' complex mechanism

Detailed models highlight a key role for solvents




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New mapping method reveals reactions galore

System combines compounds in unfamiliar ways




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[ASAP] Design and Synthesis of Highly Performing Bifunctional Ni-NiO-MoNi Hybrid Catalysts for Enhanced Urea Oxidation and Hydrogen Evolution Reactions

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01637




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New insights into catalysis for Heck reactions with fine supported Pd particles

React. Chem. Eng., 2020, 5,921-934
DOI: 10.1039/C9RE00480G, Paper
Lin Huang, Zhan Wang, Jozel Tan
The catalytic activity over supported Pd particles is dependent on the concentration of soluble active Pd species. The correlation that the smaller the size of supported Pd particles, the higher the catalytic activity is confirmed.
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reactions

Multitask prediction of site selectivity in aromatic C–H functionalization reactions

React. Chem. Eng., 2020, 5,896-902
DOI: 10.1039/D0RE00071J, Paper
Open Access
Thomas J. Struble, Connor W. Coley, Klavs F. Jensen
Aromatic C–H functionalization reactions are an important part of the synthetic chemistry toolbox.
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reactions

Correction: Efficacy of proprietary Lactobacillus casei for anti-tuberculosis associated gastrointestinal adverse reactions in adult patients: a randomized, open-label, dose–response trial

Food Funct., 2020, 11,3751-3751
DOI: 10.1039/D0FO90017F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Song Lin, Shanliang Zhao, Jiahong Liu, Jianwen Zhang, Chao Zhang, Haibo Hao, Yuxia Sun, Jing Cai, Yang Yang, Yan Ma, Yuanyuan Li, Jinyu Wang, Aiguo Ma
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Upscaling Photoredox Cross-Coupling Reactions in Batch Using Immersion-Well Reactors

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00070




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Reactions to natural and man-made radioactive threat




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Effects of trait anxiety and cognitive appraisals on emotional reactions to psychological and physical stressors




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Multi-component Reactions in Molecular Diversity


 
While very useful for studying syntheses of molecular diversity, multi-component reactions also offer rapid access to a variety of complex molecules that are relevant for biological applications. Multi-component Reactions in Molecular Diversity analyzes these reactions, whether they are realized by organometallic, ionic or even radical processes. It highlights popular methods based on monotype reactions

Read More...




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[ASAP] Fundamental Studies of the Singlet Oxygen Reactions with the Potent Marine Toxin Domoic Acid

Environmental Science & Technology
DOI: 10.1021/acs.est.9b07380




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Simple guidelines could make designing catalysts for electrochemical reactions easy

Theoretical model uses readily available data to predict catalysts for tackling energy challenges




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Single atoms catalyze Suzuki reactions

Flow chemistry process takes place on carbon nitride surface




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[ASAP] CO<sub>2</sub> (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases

Organometallics
DOI: 10.1021/acs.organomet.9b00838




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




reactions

Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

Green Chem., 2020, 22,2605-2612
DOI: 10.1039/D0GC00223B, Paper
Jikuan Qiu, Huiyong Wang, Yuling Zhao, Pengxin Guan, Zhiyong Li, Hucheng Zhang, Hongshuai Gao, Suojiang Zhang, Jianji Wang
A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.
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reactions

Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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reactions

Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00738B, Communication
Lu Yang, Jie-Ping Wan
Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis
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reactions

Chemistry of electrochemical oxidative reactions of sulfinate salts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01025A, Tutorial Review
Haibo Mei, Romana Pajkert, Li Wang, Ziyi Li, Gerd-Volker Röschenthaler, Jianlin Han
Recent advances in the oxidative reactions of sulfinate salts under electrochemical conditions, and the reaction mechanism are discussed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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reactions

Microwave-assisted aqueous carbon–carbon cross-coupling reactions of aryl chlorides catalysed by reduced graphene oxide supported palladium nanoparticles

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00833H, Paper
Qingxiao Zhang, Zhan Mao, Kaixuan Wang, Nam Thanh Son Phan, Fang Zhang
Microwave-assisted reduced graphene oxide supported palladium nanoparticles can efficiently promote aqueous Ullmann and Suzuki coupling reactions of aryl chlorides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Solvent-free ageing reactions of rare earth element oxides: From geomimetic synthesis of new metal-organic materials towards a simple, environmentally friendly separation of scandium

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00454E, Paper
Igor Huskic, Mihails Arhangelskis, Tomislav Friščić
The development of cleaner methodologies for the separation and processing of rare earth elements, including scandium and yttrium, is of high importance to materials science and industry. Here, we explore...
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