New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00361F, Paper

Guanglei Liu, Yutong Feng, Yifan Yang, Yuan Wang, Huixiang Liu, Can Li, Mingxin Ye, Jianfeng Shen
Construction of NiCo₂S_4−xP_x nanowire arrays for improved HER performances in both acidic and alkaline media.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05752F, Paper

Huamei Yang, Ziqin Chen, Kai Luo, Mengjun Yu, Yao Zhang
Surface chemical etching for the in situ growth of metal–organic materials and electrochemical reconstruction are expected to efficiently improve the catalytic performance of oxygen evolution reactions (OERs).
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00333K, Paper

Peng Liu, Jiajian Peng, Ying Bai, Jiayun Li
A series of siloxane-containing phosphine (oxide) ligands have been designed and synthesized.
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00112E, Paper

Debojyoti Bag, Sanghapal D. Sawant
Herein, we describe a highly diastereoselective approach for synthesizing polyfunctionalized spiroindolines from indolyl-ynones involving an ipso-iodocyclization/nucleophile addition cascade.
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00304G, Paper

Michela Eleuteri, Jenny Desantis, Gabriele Cruciani, Raimondo Germani, Laura Goracci
Selective degradation of disease-causing proteins using proteolysis targeting chimeras (PROTACs) has gained great attention, thanks to its several advantages over traditional therapeutic modalities.
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00406J, Review Article

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Jun Ohata
This review demonstrates advances in Friedel–Crafts alkylation and acylation reactions in a variety of biomolecular chemistry fields.
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Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00272E, Paper

Brenno A. D. Neto, Pedro Beck, Arthur Leitão, Yasmin Santana, Jose R. Correa, Carime Vitória da Silva Rodrigues, Daniel Machado, Guilherme Matos, Luciana Machado Ramos, Claudia Cristina Gatto, Carlos Kleber Z. Andrade, Sarah Caldas
This study critically reevaluates reported Biginelli-like reactions using a Kamlet-Abboud-Taft-based solvent effect model. Surprisingly, structural misassignments were discovered in certain multicomponent reactions, leading to the identification of pseudo three-component derivatives...
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Mater. Chem. Front., 2024, 8,3558-3568
DOI: 10.1039/D4QM00800F, Research Article

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Elisabetta Grazia Tomarchio, Chiara Zagni, Vincenzo Paratore, Guglielmo Guido Condorelli, Sabrina Carola Carroccio, Antonio Rescifina
A phenylalanine-based palladium catalyst was developed for the Suzuki–Miyaura reaction, preventing palladium leaching. It demonstrated high yield (up to 99%) in aqueous media and can be reused up to seven times, making it scalable for industrial use.
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Mater. Chem. Front., 2024, 8,3741-3746
DOI: 10.1039/D4QM00555D, Research Article

Jiejie Ping, Mei Wu, Manyu Liu, Yan Jiang, Wenhui Shang, Menggai Jiao, Jiahao Ruan, Nan Wang, Zhiyu Jia
Porphyrin-linked graphdiyne anchored with transition metals exhibits outstanding electrochemical performance, attributed to the modifications in the coordination environment.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper

Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al₂O₃-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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Chem. Soc. Rev., 2024, 53,10741-10760
DOI: 10.1039/D4CS00539B, Review Article

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Morgan Regnier, Clara Vega, Dimitris I. Ioannou, Timothy Noël
Utilizing electrons directly offers significant potential for advancing organic synthesis by facilitating novel reactivity and enhancing selectivity under mild conditions.
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Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00105B, Paper

Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode MUKAMA, Olivier Habimana, Paulin Manirakiza , Jean Claude Dushimimana , Jean Pierre Alpha Munyaruhengeri , Samia Khan, Elizabeth Lakin
The current study ascertained the influence an instructional module had on enhancing students’ understanding of chemical reactions and acid-base topics. The sample size for this study consisted of 197 students,...
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Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00200H, Communication

Vijay Kumar, Otavio Augusto Titton Dias, Abdelaziz Gouda, Ritu Malik, Mohini M. Sain
Lithium–sulfur batteries (LSBs) show promise for achieving a high energy density of 500 Wh/kg, despite challenges such as poor cycle life and low energy efficiency due to sluggish redox kinetics...
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Mater. Horiz., 2024, 11,1957-1963
DOI: 10.1039/D3MH01921G, Communication

Zhi-Qiang Wang, ChengHua Deng, Bo Li, Hai-Qiang Luo, Peng Hao, Xiao Liu, Jian-Gong Ma, Peng Cheng
One pot H-transfer-coupling–cyclization–CO₂ fixation tandem reactions to synthesize high value-added dihydrobenzofurans are realized through the hierarchically constructed Cu–Ag nanoalloy with a MOF cover as an efficient catalyst.
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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04925J, Edge Article

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Jia-Qi Tian, Nan-Nan Deng
A dynamic satellite–parent liposome network was developed to explore molecular transfer and quantitative microreactions through environmental stimuli, offering a platform to mimic multicellular systems in vitro.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01619J, Review Article

Wenli Tong, Jie-Ping Wan, Jianchao Liu
This review highlights the recent progress in palladium-catalyzed C-glycosylation reactions for the synthesis of C-glycosides.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article

Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01546K, Research Article

Yan Wang, Yi-Ge Li, Feijing Chen, Yan-Na Ma, Xuenian Chen
Herein, we systematically compared the reactivity of o-carborane and benzene toward different electrophiles and explained the results with the HSAB principle.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01703J, Review Article

Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
Recent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.
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Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article

Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh₃ provided o-aminophenyl diene while PCy₃ offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
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Org. Chem. Front., 2024, 11,6558-6572
DOI: 10.1039/D4QO01637H, Review Article

Jie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan He
This review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01794C, Research Article

Xiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan Yu
The mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.
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RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper

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Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper

Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper

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Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K₂O₂ units by adding oligodentate ether molecules.
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Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper

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Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined Pd^II complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02838D, Paper

Yiwen Guan, Xian Xu, Xin Xu
An FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier

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Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO₂⁻) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper

Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]⁺ species (R = CH₃, C₂H₃, C₂H₅, C₃H₇, or C₅H₆) can be generated by using preparative tandem mass spectrometry (PTMSⁿ) via ion-molecule reactions between [UH]⁺ and neutral nitriles.
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03160A, Paper

Tongtai Ji, Qingsong Tu, Yang Zhao, Dominik Wierzbicki, Vincent Plisson, Ying Wang, Jiwei Wang, Kenneth S. Burch, Yong Yang, Hongli Zhu
This study unveils the intrinsic three-step thermodynamic and the two-step kinetics-limited pathways in all-solid-state sodium–sulfur batteries, providing crucial insights into sulfur reaction mechanisms for high-performance energy storage solutions.
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React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication

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Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper

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Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper

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Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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Food Funct., 2024, 15,11252-11265
DOI: 10.1039/D4FO03851G, Paper

Xinzhang Chen, Shengjun Yang, Zhengtao Guo, Bailiang Li, Zhongjiang Wang, Lianzhou Jiang
Human milk oligosaccharides (HMOs) and the milk fat globule membrane (MFGM) represent novel treatments for cow's milk allergy (CMA).
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00907J, Review Article

Baghendra Singh, Neetu Verma
Anodic oxidation reactions have been assessed focusing on essential parameters for the substrate choice.
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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper

Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article

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Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04201H, Paper

Ruyi Liang, Yiyang Shen, Tanqing Long, Peilin Yang, Chuanrui Xu, Tongbo Wu, Mingxia Zhang
The toehold-mediated strand displacement reaction plays a crucial role in the functionality of DNA nanodevices. However, the reaction's velocity is heavily reliant on the length of the toehold region. A...
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