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HSAB theory guiding electrophilic substitution reactions of o-carborane

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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01546K, Research Article
Yan Wang, Yi-Ge Li, Feijing Chen, Yan-Na Ma, Xuenian Chen
Herein, we systematically compared the reactivity of o-carborane and benzene toward different electrophiles and explained the results with the HSAB principle.
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Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites

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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01767F, Research Article
Gui-Xiang Zhou, Cheng Hou
This study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.
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The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives

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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01703J, Review Article
Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
Recent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.
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Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

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Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
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Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction

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Org. Chem. Front., 2024, 11,6426-6436
DOI: 10.1039/D4QO01551G, Research Article
Mao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long Zhao
A cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.
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Nickel-catalysed enantioselective cross-electrophile coupling reaction with the retention of the β-fluorine atom

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Org. Chem. Front., 2024, 11,6459-6469
DOI: 10.1039/D4QO01555J, Research Article
Xin-Yi Shi, Xueyuan Yan, Xiaodong Tang, Shi-Jing Zhai, Genping Huang, Jun-An Ma, Fa-Guang Zhang
A nickel-catalysed enantioselective reductive cross-coupling reaction of a new monofluoromethyl building block with acid chlorides is developed to give chiral α-monofluoromethyl acyloin derivatives.
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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

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Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
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Transition-metal-catalyzed C–Ge coupling reactions

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Org. Chem. Front., 2024, 11,6558-6572
DOI: 10.1039/D4QO01637H, Review Article
Jie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan He
This review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.
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A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones

By pubs.rsc.org
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01388C, Research Article
Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations

By pubs.rsc.org
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Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01512F, Research Article
Rahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez Khan
A new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...
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Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions

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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01794C, Research Article
Xiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan Yu
The mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.
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Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

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RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
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Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions

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RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper
Open Access
Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

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RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
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Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
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Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

By pubs.rsc.org
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RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
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Developing Ni0.5Zn0.5Fe2O4 ferrite with controlled particle size and morphology through optimized processing conditions of low energy solid state reaction

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RSC Adv., 2024, 14,36264-36272
DOI: 10.1039/D4RA07076C, Paper
Open Access
Sarah Baayyad, Fatima-Zahra Semlali, El Kébir Hlil, Tarik Mahfoud, Hassan El Moussaoui, Mounir El Achaby
Soft magnetic materials, like Ni0.5Zn0.5Fe2O4, require high temperatures and regulated environments for their manufacture and processing, which can be highly energy intensive.
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Ancelotti calls for Real Madrid’s positive reaction after consecutive losses

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 19:00:36 +0530

Ancelotti's side sit second in the league standings with 24 points from 11 matches, nine points behind leaders Barcelona, who have played a game more


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Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR)

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02217C, Paper
Bijoy Ghosh, Sahtaz Ahmed, Ashwini K. Phukan
Comprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.
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Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions

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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper
Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02871F, Paper
Yuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing Li
The reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.
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Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production

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Dalton Trans., 2024, 53,17819-17828
DOI: 10.1039/D4DT01625D, Paper
Songhan Hu, Kai Wang, Xinxin Xu, Qiang Wang
Two Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.
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The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

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Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper
Open Access
Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
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Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02838D, Paper
Yiwen Guan, Xian Xu, Xin Xu
An FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Three-step thermodynamic vs. two-step kinetics-limited sulfur reactions in all-solid-state sodium batteries

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03160A, Paper
Tongtai Ji, Qingsong Tu, Yang Zhao, Dominik Wierzbicki, Vincent Plisson, Ying Wang, Jiwei Wang, Kenneth S. Burch, Yong Yang, Hongli Zhu
This study unveils the intrinsic three-step thermodynamic and the two-step kinetics-limited pathways in all-solid-state sodium–sulfur batteries, providing crucial insights into sulfur reaction mechanisms for high-performance energy storage solutions.
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New Editor-in-Chief for Reaction Chemistry & Engineering

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90011A, Editorial
Dionisios G. Vlachos, Maria Southall, Klavs F. Jensen
Executive Editor Maria Southall welcomes Dionisios Vlachos as the new Editor-in-Chief of Reaction Chemistry & Engineering and pays tribute to the leadership and many contributions of departing inaugural Editor-in-Chief Klavs Jensen.
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Encapsulation of TixFeyLamOz nanoparticles into NH2-MIL-125(Ti) to fabricate a promising photocatalyst for the C–N coupling reaction

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React. Chem. Eng., 2024, 9,849-860
DOI: 10.1039/D3RE00457K, Paper
Yahya Absalan, Mohammad Rafsanjani Dehghazi, Reza Samavati, Kambiz Souri, Mostafa Gholizadeh
An array of organic compounds and natural products can be synthesized through carbon–nitrogen coupling reactions.
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Digital Pareto-front mapping of homogeneous catalytic reactions

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React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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Thermokinetic analyses of metal-sensitive reactions in a ceramic flow calorimeter

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper
Open Access
Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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Enhancing mass transport to accelerate photoreactions and enable scale-up

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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Hydrothermal liquefaction of plastics: a survey of the effect of reaction conditions on the reaction efficiency

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D2RE00510G, Review Article
Open Access
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Matthijs Justin Boel, Hongqi Wang, Ahmad AL Farra, Laura Megido, José Manuel González-LaFuente, N. Raveendran Shiju
Plastic waste is a major global issue and hydrothermal liquefaction is a promising technique for the chemical recycling of waste plastics. This review summarises the effect of reaction conditions on the liquefaction efficiency.
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Correction: Applying quantum mechanics to deconvolute benchtop 1H NMR reaction data

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90015D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiayu Zhang, Tristan Maschmeyer, Ben Shapiro, Sunil Babu Paudel, Matthew C. Leclerc, Jason E. Hein
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Human milk oligosaccharides and milk fat globule membrane reduce allergic reactions in mice through the modulation of gut microbiota and metabolic functions

By pubs.rsc.org
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Food Funct., 2024, 15,11252-11265
DOI: 10.1039/D4FO03851G, Paper
Xinzhang Chen, Shengjun Yang, Zhengtao Guo, Bailiang Li, Zhongjiang Wang, Lianzhou Jiang
Human milk oligosaccharides (HMOs) and the milk fat globule membrane (MFGM) represent novel treatments for cow's milk allergy (CMA).
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Exploring anodic oxidation reactions in hybrid water electrolysis: special emphasis on substrate choice

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00907J, Review Article
Baghendra Singh, Neetu Verma
Anodic oxidation reactions have been assessed focusing on essential parameters for the substrate choice.
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Ultrasmall RuO2/CoFe2O4 nanoparticles with robust interfacial interactions for the enhanced acidic oxygen evolution reaction

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00719K, Paper
Open Access
Ming Wei, Liuhua Mu, Zhiwei Liu, Feng Gao, Guangjian Song, Qiankang Si, Mao Zhang, Fangfang Dai, Min Zhang, Rui Ding, Li Yang, Zhonggui Gao, Sanzhao Song
Ultrasmall RuO2/CoFe2O4 nanoparticles with strong interfacial interactions exhibit enhanced oxygen evolution reaction (OER) performance, driven by efficient charge transfer between RuO2 and CoFe2O4.
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Influence of redox treatments on the low-temperature water gas shift reaction over Pt/CeO2 catalysts

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Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper
Open Access
Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H2 reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO2 catalysts by increasing the number of active Pt0 NPs. A 12 h oxidative post-treatment at 500 °C which forms PtOx species easily activated also leads to improvement.
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Theoretical insights into Pt–Rh alloy nanoparticles: stability, elemental distribution, and catalytic mechanisms for NO + CO reactions

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper
Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Construction of a highly efficient MoS2-based composite electrocatalyst for the oxygen evolution reaction

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Catal. Sci. Technol., 2024, 14,6380-6392
DOI: 10.1039/D4CY00923A, Paper
Mengyan Huang, Bo Liu, Junwei Wu, Junfeng Gu, Yichen Zheng, Peiyan Ma, Bei Li, Zhengyi Fu
The carboxyl groups in CC-MoC@MoS2 play a similar role to the amino acid residues in PS II.
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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Heteroatom-doped carbon nanomaterials as potential heterogeneous Fenton reaction catalysts

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Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper
Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H2O2 dissociation on heteroatom-doped carbon nanomaterials.
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Enhancing light-driven photocatalytic reactions through solid solutions of bismuth oxyhalide/bismuth rich photocatalysts: a systematic review

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article
Open Access
Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Material design of biodegradable primary batteries: boosting operating voltage by substituting the hydrogen evolution reaction at the cathode

By pubs.rsc.org
Published On ::

Nanoscale, 2024, 16,20027-20036
DOI: 10.1039/D4NR03321C, Minireview
Shunsuke Yamada, Takashi Honda
This review highlights recent progress in increasing the operating voltage of biodegradable primary batteries by suppressing or substituting the hydrogen evolution reaction at the cathode with alternative redox reaction.
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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

By pubs.rsc.org
Published On ::

Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Improving Dynamic Control of Toehold-Mediated Strand Displacement Reactions through Phosphorothioate Modifications

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04201H, Paper
Ruyi Liang, Yiyang Shen, Tanqing Long, Peilin Yang, Chuanrui Xu, Tongbo Wu, Mingxia Zhang
The toehold-mediated strand displacement reaction plays a crucial role in the functionality of DNA nanodevices. However, the reaction's velocity is heavily reliant on the length of the toehold region. A...
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One-pot reaction for the preparation of diatom hemostatic particles with effective hemostasis and economic benefits

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, 12,1883-1897
DOI: 10.1039/D3BM01793A, Paper
Yunji Sun, Chang Su, Jinfeng Liu, Zheng He, Shengting Che, Qinglan Wan, Jingyu Cai, Hao Zhan, Chao Feng, Xiaojie Cheng, Feng Lin, Junqiang Wei, Xiguang Chen
Diatom hemostatic particles prepared by one-pot reaction have streamlined process and mass production potential, can significantly stop bleeding and reduce accidental deaths.
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Simple guidelines could make designing catalysts for electrochemical reactions easy

By cen.acs.org
Published On :: 04 May 2018 19:52:18 +0000

Theoretical model uses readily available data to predict catalysts for tackling energy challenges


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