reaction

Electrochemical and photochemical reaction of isatins: a decade update

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00202D, Review Article
Nandini M. Gotgi, J. Saurab Jain, Rita Pal, Debashis Ghosh
This review presents all the recent reports on electro- and photochemical reactions of isatins over the last decade.
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reaction

Friedel–Crafts reactions for biomolecular chemistry

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00406J, Review Article
Open Access
Jun Ohata
This review demonstrates advances in Friedel–Crafts alkylation and acylation reactions in a variety of biomolecular chemistry fields.
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reaction

Stereoselective Synthesis of gem-Dihalopiperidines via Halo-Aza-Prins Cyclization Reaction: Access to Piperidin-4-ones and Pyridines

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00338A, Paper
Anil Kumar Saikia, Surjya Kumar Bora, Subhamoy Biswas, Bipin Kumar Behera
An efficient methodology for the synthesis of 4,4-dihalopiperidine derivatives has been developed from N-(3-halobut-3-en-1-yl)-4-methylbenzenesulfonamide and aldehyde catalyzed by In(OTf)3 in excellent yields. The reaction involves an initial formation of six...
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Revisiting Biginelli-like Reactions: Solvent Effects, Mechanisms, Biological Applications and Correction of Several Literature Reports

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00272E, Paper
Brenno A. D. Neto, Pedro Beck, Arthur Leitão, Yasmin Santana, Jose R. Correa, Carime Vitória da Silva Rodrigues, Daniel Machado, Guilherme Matos, Luciana Machado Ramos, Claudia Cristina Gatto, Carlos Kleber Z. Andrade, Sarah Caldas
This study critically reevaluates reported Biginelli-like reactions using a Kamlet-Abboud-Taft-based solvent effect model. Surprisingly, structural misassignments were discovered in certain multicomponent reactions, leading to the identification of pseudo three-component derivatives...
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An FeCl3-catalyzed three-component reaction for the synthesis of β-(1,2,3-triazolyl)-ketones using DMF as a one-carbon source

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00207E, Communication
Ruilin Fang, Lei Zheng, Xuyang Chen, Can Wang, Yunfeng Chen
FeCl3-catalyzed oxidative condensation of NH-1,2,3-triazoles and aryl methyl ketones and DMF has been reported.
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reaction

Facile synthesis of tetrahydroquinoline containing dithiocarbamate derivatives via one-pot sequential multicomponent reaction

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00490F, Communication
SIDDHARTHA KUMAR SENAPATI, Anit Pal, Animesh Das
An efficient sequential multi-component method for the synthesis of tertrahydroquinoline containing dithiocarbamate has been developed. This reaction involved a boronic acid-catalyzed reduction of quinoline to tertrahydroquinoline, followed by nucleophilic addition...
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reaction

Regioselective synthesis of 4-arylamino-1,2-naphthoquinones in eutectogel as a confined reaction medium using LED light

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00140K, Communication
R. Vara Prasad, Yogendra Kumar, R. Arun Kumar, Tohira Banoo, Subbiah Nagarajan
The use of a simple carbohydrate-derived eutectogel facilitating a LED-light-induced regioselective synthesis of 4-arylamino-1,2-naphthoquinones in good yields is reported.
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reaction

Efficient synthesis of SCF3-containing 3-alkenylquinoxalinones via three-component radical cascade reaction

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00363B, Paper
Si-Yu Wang, Chu Liu, Wei Yang, Zhong-Ying Tian, Lin Yuan, Long-Yong Xie
A three-component cascade reaction of quinoxalinones, alkynes and AgSCF3 toward complete E-selective SCF3-containing 3-alkenylquinoxalinones was developed.
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reaction

Bio-based palladium catalyst in cryogel for cross-coupling reactions

Mater. Chem. Front., 2024, 8,3558-3568
DOI: 10.1039/D4QM00800F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Elisabetta Grazia Tomarchio, Chiara Zagni, Vincenzo Paratore, Guglielmo Guido Condorelli, Sabrina Carola Carroccio, Antonio Rescifina
A phenylalanine-based palladium catalyst was developed for the Suzuki–Miyaura reaction, preventing palladium leaching. It demonstrated high yield (up to 99%) in aqueous media and can be reused up to seven times, making it scalable for industrial use.
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Porphyrin-linked graphdiyne as a substrate for constructing single-atom catalysts with transition metals towards oxygen reduction reactions and oxygen evolution reactions

Mater. Chem. Front., 2024, 8,3741-3746
DOI: 10.1039/D4QM00555D, Research Article
Jiejie Ping, Mei Wu, Manyu Liu, Yan Jiang, Wenhui Shang, Menggai Jiao, Jiahao Ruan, Nan Wang, Zhiyu Jia
Porphyrin-linked graphdiyne anchored with transition metals exhibits outstanding electrochemical performance, attributed to the modifications in the coordination environment.
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reaction

Robust determination of low Ti contents in zircon using LA–ICP–MS/MS with NH3 reaction gas

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00304G, Paper
Junlong Niu, Shitou Wu, Yueheng Yang, Hao Wang, Chao Huang, Lei Xu, Liewen Xie
Compared with the single quadrupole (SQ) mode, Triple Quadrupole (TQ) method is more robust for determining low Ti contents in zircon at high spatial resolutions (laser spot size <20 μm), making it useful for the analysis of complex zircon grains.
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reaction

Reactions to the Real Estate Bill




reaction

Revealing a synergistic orbital coupling adsorption mechanism of the oxygen reduction reaction in dual-atom catalysts

J. Mater. Chem. A, 2024, 12,30676-30684
DOI: 10.1039/D4TA05099A, Paper
Yangfan Liu, Yejun Li, Xinghan Liu, Jinming Li, Gufei Zhang, Jun Gong, Yanbin Jiang, Zhou Li
A synergistic adsorption mechanism of the oxygen evolution reaction for the dual atom catalysts (DACs) was proposed, which dominates the adsorption strength of intermediate species, potential determining step, and catalytic activity of DACs.
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reaction

Exploring reaction mechanisms for CO2 reduction on carbides

J. Mater. Chem. A, 2024, 12,30340-30350
DOI: 10.1039/D4TA05592F, Paper
Naveed Ashraf, Atef Iqbal, Younes Abghoui
The electrocatalytic conversion of carbon dioxide (CO2) into valuable fuels offers immense promise in pursuing sustainable energy solutions.
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reaction

Tracking the active phase and reaction pathway of the OER mediated by an MnMoO4 microrod electro(pre)-catalyst

J. Mater. Chem. A, 2024, 12,30810-30820
DOI: 10.1039/D4TA05985A, Paper
Anubha Rajput, Ankita Kumari, Hirak Kumar Basak, Dibyajyoti Ghosh, Biswarup Chakraborty
MnMoO4 is a barely explored material for the electrocatalytic oxygen evolution reaction (OER) and in situ tracking of the reactive intermediates and final active species during the OER in an alkaline pH lacks a sequential study.
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reaction

Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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reaction

Oxygen-defective ruthenium oxide as an efficient and durable electrocatalyst for acidic oxygen evolution reaction

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06592A, Paper
Jingwei Wang, Lejuan Cai, Zhipeng Yu, Hao Tan, Xinyi Xiang, Kaiyang Xu, Yang Chao, Sitaramanjaneya Mouli Thalluri, Fei Lin, Haoliang Huang, Chenyue Zhang, Yang Zhao, Wenlong Wang, Lifeng Liu
Proton exchange membrane water electrolysis (PEMWE) is considered a promising technology for green hydrogen production in combination with renewable energy. However, the high cost and particularly the scarcity of iridium...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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reaction

Regulating oxygen redox reactions in lithium-rich materials via an Al2O3-doped ZnO layer for enhanced stability and performance

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper
Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al2O3-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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reaction

Ternary NiFeCo-Glycerolate Catalysts: Rational Design for Improved Oxygen Evolution Reaction Efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06455K, Paper
Irlan Santos Lima, Josué M. Gonçalves, Lúcio Angnes
Catalysts capable of overcoming the bottleneck of water splitting, known as the oxygen evolution reaction (OER), are indispensable to the expansion of renewable energy systems. Thus, we report the synthesis...
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reaction

Enhancing electrochemical reactions in organic synthesis: the impact of flow chemistry

Chem. Soc. Rev., 2024, 53,10741-10760
DOI: 10.1039/D4CS00539B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Morgan Regnier, Clara Vega, Dimitris I. Ioannou, Timothy Noël
Utilizing electrons directly offers significant potential for advancing organic synthesis by facilitating novel reactivity and enhancing selectivity under mild conditions.
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reaction

Electrodegradation of nitrogenous pollutants in sewage: from reaction fundamentals to energy valorization applications

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00517A, Review Article
Ming-Lei Sun, Hao-Yu Wang, Yi Feng, Jin-Tao Ren, Lei Wang, Zhong-Yong Yuan
This review provides a comprehensive insight into the electrodegradation processes of nitrogenous pollutants in sewage, highlighting the reaction mechanisms, theoretical descriptors, catalyst design, and energy valorization strategies.
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reaction

Contribution of an instructional module, incorporating PhET simulations, to Rwanda students’ knowledge of chemical reactions and acids and bases through Social Interaction.

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00105B, Paper
Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode MUKAMA, Olivier Habimana, Paulin Manirakiza , Jean Claude Dushimimana , Jean Pierre Alpha Munyaruhengeri , Samia Khan, Elizabeth Lakin
The current study ascertained the influence an instructional module had on enhancing students’ understanding of chemical reactions and acid-base topics. The sample size for this study consisted of 197 students,...
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reaction

Elucidating the impact of oxygen functional groups on the catalytic activity of M–N4–C catalysts for the oxygen reduction reaction: a density functional theory and machine learning approach

Mater. Horiz., 2024, 11,1719-1731
DOI: 10.1039/D3MH02115G, Communication
Liang Xie, Wei Zhou, Yuming Huang, Zhibin Qu, Longhao Li, Chaowei Yang, Yani Ding, Junfeng Li, Xiaoxiao Meng, Fei Sun, Jihui Gao, Guangbo Zhao, Yukun Qin
While current experimental and computational studies often concentrate on introducing external structures or idealized MN4 models, we emphasize the often-overlooked impact of inherent OGs within the carbon structure of MN4 materials, presenting a new perspective on their catalytic activity origin.
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Advancing Lithium-Sulfur Battery Efficiency: Utilizing a 2D/2D g-C3N4@MXene Heterostructure to Enhance Sulfur Evolution Reactions and Regulate Polysulfides in Lean Electrolyte Conditions

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00200H, Communication
Vijay Kumar, Otavio Augusto Titton Dias, Abdelaziz Gouda, Ritu Malik, Mohini M. Sain
Lithium–sulfur batteries (LSBs) show promise for achieving a high energy density of 500 Wh/kg, despite challenges such as poor cycle life and low energy efficiency due to sluggish redox kinetics...
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reaction

Photochemical engineering unsaturated Pt islands on supported Pd nanocrystals for a robust pH-universal hydrogen evolution reaction

Mater. Horiz., 2024, 11,1964-1974
DOI: 10.1039/D3MH02041J, Communication
Yidan Liu, Nuttapon Yodsin, Ting Li, Haocheng Wu, Rongrong Jia, Liyi Shi, Zhuangchai Lai, Supawadee Namuangruk, Lei Huang
Novel core–shell Pd7@Ptx heterostructured nanocrystals with Pt-islands shell of unsaturated coordination edges could be directly photodeposited on a reduced graphene oxide support as a highly efficient HER electrocatalyst in a wide pH range.
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Hierarchical surface-modification of nano-Cu toward one pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions

Mater. Horiz., 2024, 11,1957-1963
DOI: 10.1039/D3MH01921G, Communication
Zhi-Qiang Wang, ChengHua Deng, Bo Li, Hai-Qiang Luo, Peng Hao, Xiao Liu, Jian-Gong Ma, Peng Cheng
One pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions to synthesize high value-added dihydrobenzofurans are realized through the hierarchically constructed Cu–Ag nanoalloy with a MOF cover as an efficient catalyst.
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reaction

Atomic-scale Ru anchored on chromium-shavings as a precursor for a pH-universal hydrogen evolution reaction electrocatalyst

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01951A, Communication
Qingxin Han, Qiangqiang Lu, Xuechuan Wang, Chao Wei, Xiaoyu Guan, Luming Chen, Xiao Wang, Ji Li
Chrome shavings produce electrocatalysts with atomically dispersed Ru sites. The CN/Cr2O3/Ru-1 catalyst has excellent HER catalytic performance under the synergistic effect of RuN4 and Cr2O3.
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reaction

Market Reactions to Quest for Decentralization and Independence: Evidence from Catalonia [electronic journal].




reaction

Feverish Stock Price Reactions to COVID-19 [electronic journal].




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Cryptocurrency market reactions to regulatory news [electronic journal].




reaction

Harnessing nanoscale spatial effects in inner-modified zeolitic imidazolate framework-8 for enhanced Knoevenagel condensation reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02190D, Research Article
Semi Kim, Seojeong Woo, Cheongwon Bae, Yuri Jeon, Yeeun Seong, Song Li, Juyeong Kim
Precise carving of ZIF nanocrystals generates heterogeneous internal mesoporosity, providing effective mass transport and uncoordinated active sites for enhanced heterogeneous catalysis.
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reaction

Recent progress on the photocatalytic hydrogen evolution reaction over a metal sulfide cocatalyst-mediated carbon nitride system

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00255E, Review Article
Xunhuai Huang, Junpeng Song, Guanyu Wu, Zhihuan Miao, Yanhua Song, Zhao Mo
Modification strategy and synthesis method of a metal sulfide-mediated carbon nitride photocatalytic H2 production system.
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reaction

An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00343H, Research Article
Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
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reaction

Integrating multiple regulatory strategies: phase, morphology and interface engineering to construct a hierarchical Ni2P–MoS2/rGO heterostructure catalyst for efficient oxygen reduction reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00262H, Research Article
Xinyi Wang, Jing Jin, Zeyuan Gao, Li Hou, Xiwen Tao, Jing Wang, Yueqi Zhao, Faming Gao
Two-dimensional (2D) molybdenum disulfide (MoS2) with a large surface area and unique electronic properties has emerged as a promising noble metal-free catalyst for electrochemical energy storage/conversion applications.
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reaction

Deciphering the active species and reaction mechanism in water oxidation catalyzed by a copper complex with redox-active ligands

Inorg. Chem. Front., 2024, 11,2365-2372
DOI: 10.1039/D4QI00163J, Research Article
Qing Fan, Cong Yang, Mengdi Li, Chen Wang, Guixia Wang, Xiangfei Kong, Qiping Zhu
This theoretical study unveils active species and the reaction mechanism in electrochemical water oxidation catalyzed by a copper complex with redox-active ligands.
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reaction

Ultrathin 2D–2D NiFe LDH/MOF heterojunction nanosheets: an efficient oxygen evolution reaction catalyst for water oxidation

Inorg. Chem. Front., 2024, 11,2489-2497
DOI: 10.1039/D4QI00090K, Research Article
Haoran Yin, Shibiao Su, Di Yao, Lixia Wang, Xinqiang Liu, Tayirjan Taylor Isimjan, Xiulin Yang, Dandan Cai
An ultrathin NiFe LDH/MOF catalyst is grown on carbon paper by an in situ self-dissociation–assembly strategy. Studies reveal that the strong electronic interaction between Fe and Ni species with rich active sites results in good OER and OWS performance.
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reaction

Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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reaction

Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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reaction

Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction

Chem. Sci., 2024, 15,18161-18169
DOI: 10.1039/D4SC04318A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan Li
A sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.
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Automated electrosynthesis reaction mining with multimodal large language models (MLLMs)

Chem. Sci., 2024, 15,17881-17891
DOI: 10.1039/D4SC04630G, Edge Article
Open Access
Shi Xuan Leong, Sergio Pablo-García, Zijian Zhang, Alán Aspuru-Guzik
Leveraging multimodal large language models (MLLMs) to process multimodal data inputs and complex inter-modality data dependencies for automated (electro)chemical data mining from scientific literature.
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Enhancing hydrogen evolution reaction activity through defects and strain engineering in monolayer MoS2

Chem. Sci., 2024, 15,18127-18134
DOI: 10.1039/D4SC04874A, Edge Article
Open Access
Renjith Nadarajan, Sraboni Dey, Arijit Kayal, Joy Mitra, Manikoth M. Shaijumon
The synergistic creation of vacancy defects, along with strain-induced active sites is shown to enhance hydrogen evolution reaction (HER) performance of CVD-grown monolayer MoS2.
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Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC90219J, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang Xu
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reaction

Dynamic satellite–parent liposome networks for quantitative microreactions

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04925J, Edge Article
Open Access
Jia-Qi Tian, Nan-Nan Deng
A dynamic satellite–parent liposome network was developed to explore molecular transfer and quantitative microreactions through environmental stimuli, offering a platform to mimic multicellular systems in vitro.
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reaction

Surface charge-induced electrospray for high-throughput analysis of complex samples and electrochemical reaction intermediates using mass spectrometry

Anal. Methods, 2024, 16,2002-2008
DOI: 10.1039/D4AY00276H, Communication
Yajie Huang, Yajun Zheng, Qianqian Zuo, Zhiming Zhang, Lixuan Zhu, Yun Li, Zhiping Zhang
A novel surface charge induced electrospray ionization is proposed due to its features of no contact between sample solution and metal electrode, fast analytical process (less than 40 s), and high analytical sensitivity.
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reaction

A highly sensitive and selective fluorescent biosensor for breast cancer derived exosomes using click reaction of azide–CD63 aptamer and alkyne-polymer dots

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00146J, Paper
Dumei Ma, Yiting Luo, Xiaoya Zhang, Zehu Xie, Yinghua Yan, Chuan-Fan Ding
A fluorescence method based on Cu-triggered click reaction of azide modified CD63 aptamer and alkyne capped Pdots was developed for breast cancer derived exosome detection.
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reaction

A reaction based carbazole–indolium conjugate probe for the selective detection of environmentally toxic ions

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00301B, Paper
Jayasudha Palanisamy, Mansour K. Gatasheh, Ashraf Atef Hatamleh
Carbazole–indolium based colorimetric probe was designed for detecting cyanide ions in various water samples. An outstanding response was shown by paper test strips prepared using the probe for the easy detection of cyanide in real time.
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reaction

A colorimetric tandem combination of CRISPR/Cas12a with dual functional hybridization chain reaction for ultra-sensitive detection of mycobacterium bovis

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D3AY02200E, Paper
Qiong Liu, Mei Yang, He Zhang, Wenjie Ma, Xin Fu, Huiqing Li, Sainan Gao
Tuberculosis caused by Mycobacterium bovis poses a global infectious threat to humans and animals. Therefore, there is an urgent need to develop a sensitive, precise, and easy-to-readout strategy. Here, a...
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reaction

Synthesis of C-glycosides enabled by palladium-catalyzed glycosylation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01619J, Review Article
Wenli Tong, Jie-Ping Wan, Jianchao Liu
This review highlights the recent progress in palladium-catalyzed C-glycosylation reactions for the synthesis of C-glycosides.
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reaction

Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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