polymer

A pillar[5]arene-based three-component supramolecular copolymer for the fluorescence detection of spermine

Org. Chem. Front., 2024, 11,6293-6303
DOI: 10.1039/D4QO01470G, Research Article
Open Access
Martina Mazzaferro, Daniele Crisafulli, Francesca Mancuso, Marco Milone, Fausto Puntoriero, Anna Irto, Salvatore Patanè, Valentina Greco, Alessandro Giuffrida, Ilenia Pisagatti, Anna Notti, Melchiorre F. Parisi, Giuseppe Gattuso
A supramolecular copolymer, composed of a bis-pillar[5]arene diacid and complementary alkylidene- and perylene-bisimide-bis-imidazole comonomers, acts as an OFF/ON luminescent sensor for spermine.
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

Correction: Sustainable polymeric adsorbents for adsorption-based water remediation and pathogen deactivation: a review

RSC Adv., 2024, 14,35104-35104
DOI: 10.1039/D4RA90129K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huda Alkhaldi, Sarah Alharthi, Salha Alharthi, Hind A. AlGhamdi, Yasmeen M. AlZahrani, Safwat A. Mahmoud, Lamiaa Galal Amin, Nora Hamad Al-Shaalan, Waleed E. Boraie, Mohamed S. Attia, Samera Ali Al-Gahtany, Nadiah Aldaleeli, Mohamed Mohamady Ghobashy, A. I. Sharshir, Mohamed Madani, Reem Darwesh, Sana F. Abaza
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

High-performance, high energy density symmetric supercapacitors based on δ-MnO2 nanoflower electrodes incorporated with an ion-conducting polymer

RSC Adv., 2024, 14,35657-35670
DOI: 10.1039/D4RA05670A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shrishti Sharma, Gurpreet Kaur, Bhargab Sharma, Buddu Nagasiva Saiteja, Anshuman Dalvi
The present work investigates liquid-based and liquid-free supercapacitors assembled using δ-MnO2-nanoflower-based electrodes.
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polymer

Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
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polymer

Tailoring dual cross-linked polymer-ionic liquid composites by blending co-crystallizable polymers for stretchable electronics

RSC Adv., 2024, 14,36022-36030
DOI: 10.1039/D4RA05968A, Paper
Open Access
Minjun Kim, Moonsung Park, Hobin Seon, Sohyun Choi, Hee Joong Kim, Sangwon Kim
A dual cross-linked polymer-ionic liquid composite exhibits self-healing capabilities and is ideal for wearable strain sensor applications.
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polymer

Applications and interventions of polymers and nanomaterials in alveolar bone regeneration and tooth dentistry

RSC Adv., 2024, 14,36226-36245
DOI: 10.1039/D4RA06092J, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Prashish Sharma, Sushmita Saurav, Zeba Tabassum, Bhawana Sood, Anil Kumar, Tabarak Malik, Anand Mohan, Madhuri Girdhar
Inflammatory diseases exert a significant influence on the periodontium, serving as a primary contributor to the development of periodontitis and alveolar bone loss.
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polymer

Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02603A, Paper
Takeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa Mehrkhodavandi
Alkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.
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polymer

Switchable, chiral aluminium catalysts for ring opening polymerisations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02831G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntosh
A switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.
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polymer

Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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polymer

Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets

Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830
DOI: 10.1039/D4EW00538D, Paper
Jun Li, Salma Tabassum, Hüseyin Altundag
Denitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.
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polymer

Polyphosphazene-based hyper crosslinked polymers for efficient uranium ion removal from nuclear wastewater

Environ. Sci.: Water Res. Technol., 2024, 10,2961-2980
DOI: 10.1039/D4EW00614C, Paper
Rimsha Khalid, Isham Areej, Faiza Ashraf, Saqlain Raza, Amin Abid, Tayyab Ahsan, Bien Tan
This study focuses on the removal of uranium ions from nuclear wastewater by fabricating inorganic–organic hybrid cyclic and linear polyphosphazene based polymers.
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polymer

Fe3+ and H2O2 assisted dopamine rapid polymerization on melamine foam to activate PMS for organic pollutant degradation

Environ. Sci.: Water Res. Technol., 2024, 10,2698-2708
DOI: 10.1039/D4EW00596A, Paper
Haoxiang Yan, Jianzheng Zhen, Yuyuan Yao
A bulk sponge catalytic material was prepared by rapid polymerization of DA and utilized for PMS activation to degrade BPA. The coexistence of HCO3 enhanced 1O2 generation, accelerating BPA degradation.
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

A fluoride gradient, Zn-salt-rich hydrophobic interphase formed by a zincophilic, hydrophobic, anion-philic polymer “skin” for an anode-free solid Zn battery

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE01978D, Paper
Xinpeng Han, Jinpeng Han, Kang Ma, Jiaqi Wen, Lianpeng Li, Daliang Han, Jie Sun
A Zn2+·OC group-derived contact ion pair (CIP)/aggregate (AGG)-rich electrolyte is fabricated to generate a fluoride gradient, Zn-salt-rich hydrophobic solid electrolyte interface (SEI) layer with ultrahigh mechanical properties.
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polymer

Flexible spacer-block multi-component copolymerized donors enable resilient organic solar cells with over 40% crack-onset strain

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04208E, Paper
Congqi Lin, Zhenyu Chen, Ruixiang Peng, Wei Song, Jiangwei Gao, Xueliang Yu, Tingting Feng, Yongqi Bai, Ziyi Ge
A series of novel block donors were synthesized, achieving excellent PCE of 19.57% in rigid OSCs and 18.03% in f-OSCs, along with an outstanding crack-onset strain value of 40.29%.
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polymer

Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

Naphtho[1,2-c:5,6-c']bis([1,2,3]thiadiazole) enables the design of efficient halogen-free polymer donors and fabrication of organic solar cells with >19% efficiency

Energy Environ. Sci., 2024, 17,8593-8608
DOI: 10.1039/D4EE02414A, Paper
Tao Jia, Yongmin Luo, Yulong Hai, Tao Lin, Xudong Qin, Ruijie Ma, Kezhou Fan, Aleksandr A. Sergeev, Top Archie Dela Peña, Yao Li, Mingjie Li, Kam Sing Wong, Gang Li, Jiaying Wu, Shengjian Liu, Fei Huang
Fusion and isomerization strategies are used to develop an electron-withdrawing motif naphtho[1,2-d:5,6-d']bis([1,2,3]thiadiazole) (iNT) and a halogen-free polymer donor achieving an efficiency of 19.1%.
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polymer

Polymer electrolytes with high cation transport number for rechargeable Li–metal batteries: current status and future direction

Energy Environ. Sci., 2024, 17,8457-8481
DOI: 10.1039/D4EE03097D, Review Article
Xinyuan Shan, Zhaowei Song, Hang Ding, Lengwan Li, Yuhang Tian, Alexei P. Sokolov, Ming Tian, Kang Xu, Peng-Fei Cao
The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.
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polymer

Self-healing polymer dielectric exhibiting ultrahigh capacitive energy storage performance at 250 °C

Energy Environ. Sci., 2024, 17,8866-8873
DOI: 10.1039/D4EE03705G, Paper
Open Access
Wenhan Xu, Fei Yang, Guodong Zhao, Shixian Zhang, Guanchun Rui, Muchen Zhao, Lingling Liu, Long-Qing Chen, Qing Wang
The Anderson localization effect has been exploited in the design of high-temperature dielectric polymers, resulting in reduced conduction loss and outstanding capacitive energy storage performance over a wide temperature range up to 250 °C.
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polymer

Towards efficient and stable organic solar cells: fixing the morphology problem in block copolymer active layers with synergistic strategies supported by interpretable machine learning

Energy Environ. Sci., 2024, 17,8954-8965
DOI: 10.1039/D4EE03168G, Paper
Yu Cui, Qunping Fan, Hao Feng, Tao Li, Dmitry Yu. Paraschuk, Wei Ma, Han Yan
Interpretable machine learning identifies the causal structure–property relationships and key control factors in block copolymer organic solar cells with excellent power conversion efficiency and thermal stability.
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polymer

Advancing high-temperature electrostatic energy storage via linker engineering of metal–organic frameworks in polymer nanocomposites

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04085F, Paper
Zongliang Xie, Zhiyuan Huang, He Li, Tianlei Xu, Haoyu Zhao, Yunfei Wang, Pang Xi, Zhiqiang Cao, Virginia Altoe, Liana M Klivansky, Zaiyu Wang, Steven Shelton, Shiqi Lai, Peng Liu, Chenhui Zhu, Michael D. Connolly, Corie Y. Ralston, Xiaodan Gu, Zongren Peng, Jian Zhang, Yi Liu
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

Salt Dissociation and Localized High-concentration Solvation by Interface of Fluorinated Gel and Polymer Solid Electrolyte

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04078C, Paper
Dechao Zhang, Yuxuan Liu, Dedi Li, Shimei Li, Qi Xiong, Zhaodong Huang, Shixun Wang, Hu Hong, Jiaxiong Zhu, Haiming Lyu, Chunyi Zhi
Low salt dissociation and unstable [Li(N, N-dimethylformamide (DMF))x]+ solvent structure in poly(vinylidene fluoride) (PVDF)-based solid polymer electrolyte (SPE) remarkably restricts the high throughput ion transport and interfacial stability. Here, we...
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

Multi-omics analysis reveals that agaro-oligosaccharides with different degrees of polymerization alleviate colitis in mice by regulating intestinal flora and arginine synthesis

Food Funct., 2024, 15,10628-10643
DOI: 10.1039/D4FO03650F, Paper
Long Yuan, Chunhui Liu, Bolun Li, Sai Wang, Jianan Sun, Xiangzhao Mao
Inflammatory bowel disease (IBD) is a common chronic disease with a complex etiology, characterized by body weight loss, intestinal barrier damage, and an imbalance of intestinal flora, posing a significant threat to people's health.
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polymer

1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment

Catal. Sci. Technol., 2024, 14,6573-6583
DOI: 10.1039/D4CY00969J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

Correction: 1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment

Catal. Sci. Technol., 2024, 14,6720-6720
DOI: 10.1039/D4CY90084G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

Preceramic polymer hybridized phenolic aerogels and the derived ZrC/SiC/C ceramic aerogels with ultrafine nanocrystallines

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03470H, Paper
Ding Nie, Hangyu Zhong, Hongli Hu, Zhenhua Luo, Boxing Zhang
Phenolic and carbon aerogels have important applications for thermal insulation and ablative resistance materials in aerospace areas. However, their antioxidant ability in long-term and high-temperature aerobic environments is facing serious...
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polymer

Particle Surface Engineering at Nano-Micro Scale Interfaces of Metal-Nonmetal Bonded Polymeric Coatings: Experimental and In-Silico Evaluations

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03431G, Paper
Suman Yadav, Sarvesh Kumar Pandey, Shikha Awasthi
Polyvinyl alcohol (PVA) is a well-known cost-effective synthetic polymer that offers a variety of applications including medical, aerospace, automotive, and construction industries. However, weak bonding with low mechanical and tribological...
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polymer

Effect of number ratio and size ratio on the formation of binary superlattices assembled by two-sized polymer-tethered spherical nanoparticles

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04032E, Communication
Open Access
Jinlan Li, Xin Yu, Jianing Zhang, Jing Jin, Yanxiong Pan, Xiangling Ji, Wei Jiang
Binary superlattices (BNSLs) with unique configurations are of great interest, attributing to the interaction between two kinds of nanoparticles, providing potential applications in sensing, electronic and optical fields. Here, polystyrene...
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polymer

Ultra-efficient delivery of CRISPR/Cas9 using ionic liquid conjugated polymers for genome editing-based tumor therapy

Biomater. Sci., 2024, 12,1716-1725
DOI: 10.1039/D3BM01981K, Paper
Zhongming Huang, Tongren Yang, Jie Yu, Yijian Gao, Yuhua Weng, Yuanyu Huang, Shengliang Li
Through molecular screening, ionic liquid-conjugated polymers (IL-CPs) are developed for highly efficient delivery of CRISPR/Cas9 system, which demonstrated high-performance genome editing-based tumor therapy.
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polymer

A highly tuneable inverse emulsion polymerization for the synthesis of stimuli-responsive nanoparticles for biomedical applications

Biomater. Sci., 2024, 12,1707-1715
DOI: 10.1039/D3BM01765F, Paper
Andrew C. Murphy, Heidi F. Oldenkamp, Nicholas A. Peppas
This article demonstrates an inverse emulsion scheme to polymerize a variety of ionizable and non-ionizable monomers to form stimuli-responsive nanoparticles with potential applications in biomaterials science.
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polymer

N-Halaminated spermidine-containing polymeric coating enables titanium to achieve dual functions of antibacterial and osseointegration

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00061G, Paper
Hang Ren, Peng Wang, Hanwen Huang, Junshen Huang, Yuheng Lu, Yanfeng Wu, Zhongyu Xie, Youchen Tang, Zhaopeng Cai, Huiyong Shen
Modified Ti with a porous N-halaminated spermidine-containing polymeric coating is constructed, and it has both excellent antibacterial and osteogenic abilities to enhance osseointegration, making it potentially applicable in orthopedics.
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polymer

A mitochondria-targeting heptamethine cyanine-chlorambucil formulated polymeric nanoparticle to potentiate native tumor chemotherapeutic efficacy

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00003J, Paper
Jing Liu, Jie Zhang, Yongteng Zhang, Wei Wei, Meixiao Zhan, Zhiren Zhang, Bing Liu, Xianglong Hu, Weiling He
Facile conjugation of chlorambucil with IR775 chloride can afford IR775-Cbl with mitochondria-targeting potency for tumor cells, exhibiting distinct “1 + 1 > 2” tumor inhibition.
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polymer

Comparison study of surface-initiated hydrogel coatings with distinct side-chains for improving biocompatibility of polymeric heart valves

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00158C, Paper
Yiduo Chen, Yirong Guo, Xinyi Li, Yanchen Chen, Jiarong Wang, Honglin Qian, Jing Wang, Youxiang Wang, Xinyang Hu, Jian'an Wang, Jian Ji
Three surface-initiated hydrogel coatings (pMPC, pAMPS, pHEMA) are constructed on polymeric heart valves. The zwitterionic pMPC coating displays optimal performances, including durable anti-coagulation, anti-inflammation, and anti-calcification.
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polymer

Recent advances in shape memory polymeric nanocomposites for biomedical applications and beyond

Biomater. Sci., 2024, 12,2033-2040
DOI: 10.1039/D4BM00004H, Review Article
Yifan Zheng, Yudi Du, Ling Chen, Wei Mao, Yuan Pu, Steven Wang, Dan Wang
Shape memory polymers (SMPs), which initiate shape transformation in response to environmental stimuli, have attracted significant attention in both academic research and technological innovation.
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polymer

Optimization of lipid assisted polymeric nanoparticles for siRNA delivery and cancer immunotherapy

Biomater. Sci., 2024, 12,2057-2066
DOI: 10.1039/D3BM02071A, Paper
Song Lin, Houjin Jing, Xiaojiao Du, Xianzhu Yang, Jun Wang
A siRNA delivery system was developed using clinically approved mPEG-b-PLGA, cationic lipid and ionizable lipid for siRNA delivery and cancer immunotherapy.
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polymer

Lipid sulfoxide polymers as potential inhalable drug delivery platforms with differential albumin binding affinity

Biomater. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D3BM02020G, Paper
Gayathri Ediriweera, Neville Butcher, Ashok Kothapalli, Jiacheng Zhao, Joanne Therese Blanchfield, Christopher N. Subasic, James Lynden Grace, Changkui Fu, Xiao Tan, John F. Quinn, David Ascher, Michael R Whittaker, Andrew Whittaker, Lisa Kaminskas
Inhalable nanomedicines are increasingly being developed to optimise the pharmaceutical treatment of respiratory diseases. Large lipid-based nanosystems at the forefront of the inhalable nanomedicines development pipeline, though, have a number...
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polymer

Polymers and composites made incredibly cheaply

Frontal polymerization approach reduces energy use significantly




polymer

DuPont sets new plant for fluoropolymer




polymer

Polymer solar cell hopes to claim new record

Engineering two organic molecules for better compatibility boosts the conversion efficiency of polymer solar cells to 14.2%




polymer

Division of Polymer Chemistry seeks nominations for awards




polymer

Polymer strips off-taste from wine

Magnetic property enables easy separation of sorption medium




polymer

Red blood cells catalyze polymerization

Iron from hemoglobin initiates radical reaction




polymer

Easy-to-make polymer stretches, sticks, self-heals

Material’s features attributed to bonds that readily break and re-form




polymer

Biodegradable polymers: from synthesis methods to applications of lignin-graft-polyester

Green Chem., 2024, 26,10774-10803
DOI: 10.1039/D4GC03558E, Tutorial Review
Open Access
Sundol Kim, Hoyong Chung
Biodegradable lignin-based grafted polyesters have wide range of applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




polymer

A sequential flow process of CO2 capture and conversion using cost-effective porous organic polymers

Green Chem., 2024, 26,10960-10968
DOI: 10.1039/D4GC03494E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhongqi Wu, Zhong Li, Lei Hu, Samson Afewerki, Maria Strømme, Qian-Feng Zhang, Chao Xu
A sequential flow process utilizing cost-effective porous organic materials to capture CO2 and directly convert it into fine chemicals has been achieved, which could improve the practical applicability of CO2 capture and utilization technologies.
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polymer

Advancing green chemistry in environmental monitoring: the role of electropolymerized molecularly imprinted polymer-based electrochemical sensors

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03250K, Tutorial Review
Christopher Mwanza, Wei-Zhi Zhang, Kalulu Mulenga, Shou-Nian Ding
Molecularly imprinted polymers (MIPs) are synthetic materials designed to mimic the natural “lock and key” mechanism observed in biomolecular systems, such as the interactions between antibodies and antigens.
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polymer

Continuous-flow Synthesis of Cyclic Carbonates with Polymer-supported Imidazolium-based Ionic Liquid (Im-PSIL) Catalysts

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04499A, Communication
Open Access
Zhibo Yu, Haruro Ishitani, Shu Kobayashi
Carbon dioxide (CO2), a major greenhouse gas emitted through human activities, represents a valuable carbon source for chemical production. However, maximizing its efficiency requires novel methods for CO2 conversion that...
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polymer

Three distinct glycosylation pathways are involved in the decoration of Lactococcus lactis cell wall glycopolymers [Microbiology]

Extracytoplasmic sugar decoration of glycopolymer components of the bacterial cell wall contributes to their structural diversity. Typically, the molecular mechanism that underpins such a decoration process involves a three-component glycosylation system (TGS) represented by an undecaprenyl-phosphate (Und-P) sugar-activating glycosyltransferase (Und-P GT), a flippase, and a polytopic glycosyltransferase (PolM GT) dedicated to attaching sugar residues to a specific glycopolymer. Here, using bioinformatic analyses, CRISPR-assisted recombineering, structural analysis of cell wall–associated polysaccharides (CWPS) through MALDI-TOF MS and methylation analysis, we report on three such systems in the bacterium Lactococcus lactis. On the basis of sequence similarities, we first identified three gene pairs, csdAB, csdCD, and csdEF, each encoding an Und-P GT and a PolM GT, as potential TGS component candidates. Our experimental results show that csdAB and csdCD are involved in Glc side-chain addition on the CWPS components rhamnan and polysaccharide pellicle (PSP), respectively, whereas csdEF plays a role in galactosylation of lipoteichoic acid (LTA). We also identified a potential flippase encoded in the L. lactis genome (llnz_02975, cflA) and confirmed that it participates in the glycosylation of the three cell wall glycopolymers rhamnan, PSP, and LTA, thus indicating that its function is shared by the three TGSs. Finally, we observed that glucosylation of both rhamnan and PSP can increase resistance to bacteriophage predation and that LTA galactosylation alters L. lactis resistance to bacteriocin.




polymer

ವಿಶಾಖಪಟ್ಟಣದ LG Polymers ಕಂಪೆನಿ ಬಗ್ಗೆ ನಿಮಗೆಷ್ಟು ಗೊತ್ತು?

ವಿಶಾಖಪಟ್ಟಣದಲ್ಲಿ ಗುರುವಾರದ ಅನಿಲ ಸೋರಿಕೆ ಘಟನೆಯು ಕನಿಷ್ಠ ಎಂಟು ಮಂದಿಯ ಪ್ರಾಣ ತೆಗೆದಿದೆ. ನೂರಾರು ಮಂದಿ ಅಸ್ವಸ್ಥರಾಗಿದ್ದಾರೆ. ಈ ಘಟನೆಯ ಮೂಲ ಇರುವುದು ಎಲ್.ಜಿ. ಪಾಲಿಮರ್ಸ್ ಒಡೆತನದ ಕಾರ್ಖಾನೆಯಲ್ಲಿ. ಪ್ಲಾಸ್ಟಿಕ್ ರಿಸಿನ್ ಮತ್ತು ಸಿಂಥೆಟಿಕ್ ಫೈಬರ್ ಉತ್ಪಾದನೆ ಮಾಡುವ ಕೈಗಾರಿಕೆಯ ಒಂದು ಭಾಗವಷ್ಟೇ ಈ ಘಟಕ. ಇನ್ನು ಇದರ ಮಾಲೀಕತ್ವ ಯಾರದು ಅಂತ ನೋಡಿದರೆ, ದಕ್ಷಿಣ ಕೊರಿಯಾದ




polymer

Vizag gas leak: LG Polymers issues official statement, says doing our best to help victims

On May 7, 11 persons were killed while over 1,000 were hospitalised due to gas leakage from LG Polymers chemical plant at RR Venkatapuram in Andhra Pradesh's Visakhapatnam.




polymer

Vizag gas leak: NGT notice to LG Polymers, others; directs company to deposit Rs 50 cr