At the start of National Crime Victims’ Rights Week, the Department of Justice today announced that on April 20, the Madoff Victim Fund (MVF) began its fifth distribution of approximately $378.5 million in funds forfeited to the U.S. Government in connection with the Bernard L. Madoff Investment Securities LLC (BLMIS) fraud scheme, bringing the total distributed to over $2.7 billion to nearly 38,000 victims worldwide.

Bank Hapoalim B.M. (BHBM), an Israeli bank with international operations, and its wholly owned subsidiary, Hapoalim (Switzerland) Ltd. (BHS), have agreed to forfeit $20,733,322 and pay a fine of $9,329,995 to resolve an investigation into their involvement in a money laundering conspiracy that fueled an international soccer bribery scheme.

The Department of Justice has reached a settlement of its civil forfeiture cases against assets acquired by Khadem al-Qubaisi using funds allegedly misappropriated from 1Malaysia Development Berhad (1MDB), Malaysia’s investment development fund, and laundered through financial institutions in several jurisdictions, including the United States, Switzerland, Singapore and Luxembourg.

A Las Vegas resident was sentenced to 65 months in prison today for his role in a stolen identity tax fraud, announced Principal Deputy Assistant Attorney General Richard E. Zuckerman of the Justice Department’s Tax Division and U.S. Attorney Nicholas A. Trutanich for the District of Nevada.

Take a listen to Jonathan Murray on WBAL News Now from Monday.

Financial Analyst Jonathan Murray describes what happened on what was a roller coaster of a day on the stock market.

Top trainer Mike de Kock has warned of a “grim reality” featuring “loss of jobs and euthanasia” of significant parts of the horse population if the South African racing shutdown continues. On Tuesday, the South African government blocked plans for a resumption when it refused to allow the sport to take place under Lockdown Level […]

The post Trainer Mike de Kock Warns Of Mass Job Loss, Euthanasias In South Africa If Racing Shutdown Continues appeared first on Horse Racing News | Paulick Report.

The OHDSI study-a-thon group has a pre-print An international characterisation of patients hospitalised with COVID-19 and a comparison with those previously hospitalised with influenza. What is encouraging with this one over yesterday’s study, is multiple data sources and almost too many co-authors to count (take that Nature’s editors). So an opportunity to see the variation […]

https://www.nps.gov/grca/learn/news/news_2009-11-12_phase_i.htm

On Saturday, May 19, 2012 – Armed Forces Day – the National Park Service will begin issuing an annual pass offering free entrance to all 397 national parks for active duty military members and their dependents. https://www.nps.gov/grca/learn/news/2012-05-16_military.htm

Rather than opting for the costly and complex process of using stem cells to cure age-related macular degeneration, scientists used skin cells.

The post Irreversible No Longer: Blind Mice See Again Thanks To New Method of Synthesizing Lost Cells appeared first on Good News Network.

Banksy droped off an art piece that is inspiring the world with its superhero nurse theme, in gratitude to NHS Southampton General Hospital in England.

The post Banksy Drops Off Superhero Nurse Artwork at Hospital in UK With a Thank You Note appeared first on Good News Network.

Blackrock, the world’s largest asset management company has pledged to invest its trillions of dollars in capital to maintaining the health of the planet.

The post Trillions of Dollars Now Being Leveraged to Protect the Earth, Thanks to World’s Largest Asset Manager appeared first on Good News Network.

Rally your troops to get virtual to bring new creative ideas to your radio stations. Get on ZOOM and have a brainstorming session with your creative teams and clients. Time to squeeze new … more

Statement Highlights: Geriatric conditions such as frailty, cognitive impairment, taking multiple medications and having multiple medical conditions complicate care for older people with acute cardiovascular diseases. Most research on how to treat...

DALLAS, April 2, 2020 – The American Heart Association — the world’s leading voluntary organization dedicated to a world of longer, healthier lives — announced today more than $14 million in scientific research grants are being awarded to four...

Today, more than patient advocacy, medical and public health organizations sent a letter to senior Trump Administration officials, appealing to the Administration to take immediate action to alleviate the critical shortage across the nation ventilators...

Not many of the present readers might know me very well, and that in part, is the reason that I have made the decision to transfer WLTC to more willing and presently capable hands. I am a stranger on my blog and the time has come for me to make sure that this blog, its contents and its knowledge are archived and preserved and maybe rejuvenated at a later time. I delved into blogging tools back in 2004 when I started my Masters degree in CS. I wanted some code to mess around with in my free time and everyone was talking about blogging. I looked into a variety of tools, built a small Linux server for myself at home, and installed a few of the tools that were freely available at that time. I had a heck of a time getting a hold of MT (Moveable Type, the most well-known name) and […]

Lately, The hype of GDPR was on high around May 25, 2018 but due to its complication and in depth detail, it was not easy for everyone to understand and get prepare for this new policy for European countries. In very simple words, GDPR stands for General...

The post Better Late Than Never To Make Your WordPress GDPR Compliant – 21 Plugins You Might Need To Know appeared first on SmashingApps.com.

A look at how to describe clinical recovery time and factors that might impact recovery after a sports-related mild traumatic brain injury (SR-mTBI; concussion).

When the world seemingly changed overnight due to COVID-19, it was surreal. Maybe your surroundings looked exactly the same. Your to-do list contained the same projects. Even if things were...

The post Reasons to Be Thankful: Bright Spots for Web Designers appeared first on Speckyboy Design Magazine.

Editor’s note: The Gazette sports staff has compiled lists of its top 15 favorite sports movies. Each day, a different staffer will share some insight into one of their favorites. Some of them...

Gazette awards more than $60,000 in marketing grants The Gazette has awarded more than $60,000 in grants to help local businesses market themselves during the coronavirus pandemic, and there’s...

Right now, there are so many things that are hard to believe. It’s hard to believe we’re in the midst of a global pandemic. It’s hard to believe how much things have changed how incredibly quickly. It’s hard to believe I’ve only been the Iowa Department of Human Services director for six months. What is not hard to believe is how our team at DHS has stepped up during this public health emergency. In my short time in the great state of Iowa, I have seen our team do incredible things. In honor of Public Service Recognition Week, I want to take a moment to talk about #TeamDHS and their unwavering dedication to those we serve.

The DHS mission is to help Iowans achieve healthy, safe, stable, and self-sufficient lives through the programs and services we provide. To accomplish this mission in typical times, our team wakes up every day to do difficult work. Our front-line staff often work holidays, evenings and weekends, sacrificing time with their own families to serve others. Our team members hear difficult stories, make tough decisions and assist families when they are at their most vulnerable. Their jobs are tough under normal circumstances — navigating a global pandemic has challenged everything we do, but the work has not stopped, because the work cannot stop. Iowans need us now more than ever.

COVID-19 impacts the way social workers support families. It impacts the way facilities support and protect the individuals we serve. It impacts the mental health of countless Iowans. It impacts the needs of Medicaid members and Iowans receiving other assistance.

As an agency impacted from top to bottom, I’m proud to share our collective response effort. The Medicaid and Adult, Children and Family Services (ACFS) teams kicked into high gear and set forth waivers that will truly help those most in need; ensuring access to medical care, food and economic assistance. Our income maintenance workers stand ready to assist those families who have questions or find themselves now in need of supports.

DHS went from an agency with no telecommute policy, to deploying more than 2,000 people to work from home. Our IT team stepped in to help disassemble and lift computers for those team members who couldn’t. Our fiscal team shifted paper approval processes to electronic streamlined processes to assist our new telecommute capabilities and continues to source supplies to meet our entire system’s personal protective equipment (PPE) need. We’ve even been able to help some of our partners out in the community obtain PPE. And many, many team members have stepped into new roles when asked because there was a need.

If this isn’t teamwork, I don’t know what is.

Many of our staff continue their work on the front line every day, despite these uncertain and unprecedented times. I know for many of them it is challenging, and our work and our lives are changing in ways we would never have imagined just weeks ago. We know there is more to come, and our response effort must pivot on a dime. So, to my team, thank you for stepping up and leaning in. And to my fellow Iowans, I ask you join me in thanking them, and all of our public servants and essential workforce during Public Service Recognition Week.

Public Service Recognition Week (PSRW) is May 3-9, celebrated the first week of May since 1985 (beginning on the first Sunday of the month) to honor the men and women who serve our nation as federal, state, county and local government employees.

We’re asking individuals whose lives have been positively impacted by one of our team members, to reach out to them directly with an email or video message to thank them. Whether it’s a case worker, social worker, income maintenance worker or direct care staff, now more than ever they deserve to hear how they’re improving the lives of Iowans.

We’re hoping we can count on you to get the word out and support our public servants. Notes directly to DHS team members are a really impactful way to personally show gratitude. This week we’ll also be encouraging people to thank those in public service using the hashtags #PSRW and #TeamDHS. Stay tuned to our social media to see how you can help celebrate our public servants.

The bravery, grace, and sacrifice our team shows every day is what true public service looks like. From one very proud DHS team member to her more than 4,100 colleagues — thank you. Public service is indeed a noble calling.

Kelly Garcia is the director of the Iowa Department of Human Services.

Gazette awards more than $60,000 in marketing grants

The Gazette has awarded more than $60,000 in grants to help local businesses market themselves during the coronavirus pandemic, and there’s more help available.

“We awarded $50,000 in the first 10 days,” said Kelly Homewood, Director of Operations at The Gazette. “That tells us the need is real. The help necessary. We’re a locally owned business too, and in Iowa we lift each other up in challenging times.”

The grant program, which launched April 17, awarded $50,393 to more than 60 businesses in the first 10 days. To date, almost $68,000 has been awarded to 75 businesses.

“The Gazette’s Matching Program is a true testament to their commitment to our community and their small business advertisers,” said Annie Hills, marketing manager at Destinations Unlimited. “As a local small business, this program will be a huge benefit to our agency in such an unprecedented time so that we can continue to connect with our clients.”

The program allocates up to $100,000 in matching advertising dollars to assist local businesses that apply. There’s still approximately $32,000 in matching grants still available to award by July 31. Businesses can apply online at www.thegazette.com/marketinggrant.

The Federal Emergency Management Agency (FEMA) has obligated $78 million to the state of Iowa to help reimburse eligible expenses for emergency protective measures that the state has incurred as a result of its response to COVID-19.

The grant funds, awarded by FEMA’s Public Assistance (PA) Grant Program, were made available Thursday. FEMA has provided nearly $150 million to date in support of the state’s COVID-19 efforts.

The money reimburses 75 percent of projected eligible costs associated with buying essential Personal Protective Equipment (PPE), and medical supplies and equipment during the months of May and June 2020.

This obligation also includes: $19.5 million in contract services for TestIowa, $35,000 in contract services associated with overseas PPE purchases and $13.7 million for additional medical supplies and equipment for the month of April. All figures represent the 75 percent federal share. The 25 percent is paid by the grant recipient.

Iowa Gov. Kim Reynolds issued a new proclamation allowing campgrounds in the state of Iowa to open.

The proclamation states:

“Any public or private campground may reopen provided that the campground implements reasonable measures under the circumstances of each campground to ensure social distancing, increased hygiene practices, and other public health measures to reduce the risk of transmission of COVID-19 consistent with guidance issued by the Iowa Department of Public Health (5/6/20).”

Linn County Conservation has continued to seek guidance from local and state health officials and are announcing that campgrounds will open Friday with certain restrictions and limitations.

At 5 a.m. on May 8, Buffalo Creek Park, Morgan Creek Park, Pinicon Ridge Park and Squaw Creek Park campgrounds will open to campers in self-contained units. This also includes primitive (non-electric) camping areas at Matsell Bridge Natural Area (including Mount Hope) and Wakpicada Natural Area.

Campers may camp only with a self-contained camping unit that has a functioning restroom, as showerhouses with flushable restrooms will remain closed. Self-contained is defined as a tent or pop-up camper with a portable toilet or an RV or camping trailer with a functioning, self-contained bathroom.

Occupants are limited to six or less per camp site (unless household is more than six). No visitors are allowed. Campground showerhouses with restrooms will remain closed.

Reserving campsites is not allowed as campgrounds continue to be first-come, first-served. The exception to this is Squaw Creek Park A-Loop which normally accepts online reservations at LinnCountyParks.com, starting Friday at 1 p.m.

Linn County Conservation’s lodges, shelters, cabins and group camps remain closed.

Hy-Vee Inc., announced Friday that it is now offering a two-hour express pickup option as part of its Hy-Vee Aisles Online grocery ordering service, allowing customers to pay a fee to pick up their order faster.

Customers will see a “Get It Faster” option on Aisles Online time slots where the two-hour pickup option is available. A limited number of two-hour pickup orders will be available for $9.95, from 8 a.m. until 8 p.m. daily, at all Hy-Vee store locations offering Aisles Online services.

The lights on Alliant Energy’s Cedar Rapids Tower will change colors to recognize area high schools and honor the Class of 2020.

“In this time of uncertainty, it’s important to remember that brighter days are up ahead,”

said Linda Mattes, Vice President of IT and Customer Operations. “Changing the lights on our tower is our way of celebrating this important milestone in the lives of these students and their families.”

Each Cedar Rapids-area high school’s colors will be on display. The schedule:

May 21 — Washington High School — Red and blue

May 22 — Jefferson High School — Blue and white

May 23 — Kennedy High School — Green and gold

May 24 — Linn-Mar High School — Red and black

May 25 — Marion High School — Crimson and gold

May 26 — Prairie High School — Orange and black

May 27 — Xavier High School — Navy and silver

May 28 — Metro High School — Purple and black

MusicIC Festival cancels June in-person programming

What was planned to be the 10th annual MusicIC Festival has been canceled. Programming planned for June 18-20 will be pushed to summer 2021.

The festival, presented by the Iowa City UNESCO City of Literature, will offer alternate programming. In place of the in-person performances this year, the festival will offer video performances from musicians to be highlighted in the 2021 season.

Details about these video performances will be forthcoming.

Due to the ongoing social distancing guidelines and additional precautions taking place to help slow and reduce the spread of COVID-19, the Linn County Fair Association is canceling the grounds and grandstand entertainment for the 2020 Linn County Fair, scheduled for June 24-28.

The Linn County Fair Association, in partnership with the Iowa State University Extension and Outreach of Linn County and Linn County 4-H, still plan on providing opportunities to 4-Her’s, FFA members, and youth of Linn County to showcase their talents and accomplishments at this year’s fair.

Details regarding the 4-H/FFA exhibits and events are still being finalized and Linn County 4-H plans to email details to 4-H/FFA members in mid-May.

To encourage safe and responsible social distancing practices during the COVID-19 pandemic, Cedar Rapids’ Bike to Work Week activities — traditionally held in May — will be postponed and are tentatively scheduled for September 21-27.

This will include events such as the Mayor’s bike ride and proclamation, pit stops, group rides, and wrap-up party.

Von Maur announced it will reopen stores in Cedar Rapids, Coralville and Cedar Falls using reduced hours and safety measures starting Friday.

The reduced hours will be from 11 a.m. to 7 p.m. Monday through Saturday and 12 p.m. to 6 p.m. on Sundays.

Von Maur said it will be implementing daily employee health screenings, social distancing measures, contactless payments, curbside service options and sanitizing and cleaning procedures in common areas and after each customer transaction. Its aforementioned stores are at Lindale Plaza, Iowa River Landing and College Square Mall.

Online Czech language lessons offered

The National Czech & Slovak Museum & Library recently partnered with Anna Cooková, an instructor with CzechTalk, to offer online Czech language and culture lessons.

Beginner’s Czech Language & Culture I begins on Thursday, June 4. Each class will be held from 8 to 9:30 p.m. every Thursday from June 4 through August 6. During the 15 hours of instruction over 10 weeks, participants will learned to read, write, and speak in Czech.

The cost is $210 for NCSML members, $235 for non-members. This fee includes all course materials. The class size is limited to 20 students, so interested individuals are encouraged to register early to secure a spot.

Contact Cooková for a registration form at annacookova@gmail.com or 715-651-7044.

Thanks for all the positive support and reception to my Lightroom presets so far, especially to those who pulled the trigger and became my first customers! I’d love to hear your feedback once you try them out!
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Still time to enter the giveaway or to take advantage of the 50% sale! See my last post for full details and the link in my profile. ❤️ (at Toronto, Ontario)

Merry Xmas everyone! It’s giveaway time! ????????
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Thank you to all those who participated in my preset giveaway this week! The support makes all the hard work and extra effort worth it!
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Without further ado, the randomly drawn winners of my custom Lightroom presets are @l9lee @rchellau @bokeh.jay! Congrats and check your DMs soon for details! ????
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You still have until tomorrow to grab my presets (which this shot was edited with) for 50% off! They’ll be going back to regular price after so don’t miss out! ???? (at Toronto, Ontario)

"This study challenges current perceptions that most people with a sports-related mTBI recover within 10 to 14 days," said lead author Dr. Stephen Kara, from Axis Sports Medicine in Auckland, New Zealand.

For many veterans’ spouses, we’ve watched our partners struggle not only with post-traumatic stress disorder (PTSD) but with other mental health conditions, as well. Around 80 percent of people with PTSD wrestle with at least one other co-occurring mental health condition in their lifetime.What many people don’t see is the impact PTSD and comorbidity have on vets’ spouses.

For many veterans’ spouses, we’ve watched our partners struggle not only with post-traumatic stress disorder (PTSD) but with other mental health conditions, as well. Around 80 percent of people with PTSD wrestle with at least one other co-occurring mental health condition in their lifetime.What many people don’t see is the impact PTSD and comorbidity have on vets’ spouses.

On this week's episode, we were joined by Stray From the Path guitarist Tom Williams. We talk about band's recently...

The post METAL INJECTION LIVECAST #541 - Thank You For Your Cervix with STRAY FROM THE PATH's Tom Williams appeared first on Metal Injection.

Adam thanks you — his blog viewers and supporters — and encourages you to continue the discussion and awareness raising about TBI and PTSD; the battle does not stop here.

For many veterans’ spouses, we’ve watched our partners struggle not only with post-traumatic stress disorder (PTSD) but with other mental health conditions, as well. Around 80 percent of people with PTSD wrestle with at least one other co-occurring mental health condition in their lifetime.What many people don’t see is the impact PTSD and comorbidity have on vets’ spouses.

More than 1,000 workers at the Tyson Foods plant in Waterloo have tested positive for the coronavirus, a county public health leader said Thursday -- more than double the number Gov. Kim Reynolds had said were infected the day before.

Bob Duncan talks about what happened to his son when he returned to college and to his midterm exams only 24 hours after his concussion.

By The Office of Energy Efficiency & Renewable Energy Within 25 years, the United States could produce enough biomass to support a bioeconomy, including renewable aquatic and terrestrial biomass resources that could be used for energy and to develop products … Continue reading →

Node.js 14 is available now. We wanted to get more context and details about the state of Node, and why developers should care about Node.js 14. We talked with Bethany Griggs, Node.js Technical Steering Committee member and Open-source Engineer at IBM, to find out more. 

Bethany has been a Node Core Collaborator for over two years. She contributes to the open-source Node.js runtime and is a member of the Node.js Release Working Group where she is involved with auditing commits for the long-term support (LTS) release lines and the creation of releases. 

The apps and devices you use are conducting surveillance with your every move Sure, you lock your home, and you probably don't share your deepest secrets with random strangers.…

March is obviously going to be the busiest month for any purveyor of traditional Irish music, and with St. Patrick's Day right around the corner, Spokane's Floating Crowbar has multiple gigs crowding the week's calendar.…

Methods and related systems efficiently and effectively recover a significant amount of valuable, useable oil from byproducts formed during a dry milling process used for producing ethanol. The method may include forming a concentrate from the byproduct and recovering oil from the concentrate. The step of forming the concentrate may comprise evaporating the byproduct using a multi-stage evaporator, as well as recovering the oil before the final stage of the evaporator. Further, the step of recovering oil from the concentrate may comprise using a centrifuge and, in particular, a disk stack centrifuge. Other aspects include related methods and subsystems for recovering oil.

The invention relates to radiation curable coating systems on the basis of aqueous polyurethane dispersions, to a method for the production thereof, to the use of the coating systems as paints and/or adhesives, and to objects and substrates provided with said paints and/or adhesives.

A primer solution for enhanced adhesion to a rigid substrate for aviation and aerospace applications includes an aminosilane-capped polyurethane prepolymer and a first solvent. The first solvent reacts with or modifies the surface of the rigid substrate, enabling the primer solution including the aminosilane-capped polyurethane prepolymer to become a part of the surface of the rigid substrate.

The present invention relates to a process to make alpha olefins comprising: dehydrating ethanol to recover an ethylene stream,introducing said ethylene stream into an oligomerization zone containing an oligomerization catalyst and into contact with said oligomerization catalyst,operating said oligomerization zone at conditions effective to produce an effluent consisting essentially of 1-butene, 1-hexene, optionally heavier alpha olefins and unconverted ethylene if any,introducing the above effluent into a fractionation zone to recover a stream consisting essentially of 1-butene, a stream consisting essentially of 1-hexene, optionally a stream consisting essentially of heavier alpha olefins and an optional ethylene stream. In an advantageous embodiment the 1-hexene or at least one heavier alpha olefins, if any, are isomerized to an internal olefin and subsequently transformed by metathesis with the aid of additional ethylene into different alpha-olefins with even or odd number of carbons. By way of example 1-hexene is isomerized into 2-hexene and by methathesis with ethylene converted to 1-pentene and propylene.In another embodiment the oligomerization zone is only a dimerization zone and butene is produced. 1-butene is isomerized to 2-butene and sent to a methathesis zone in the presence of ethylene to be converted to propylene. In said embodiment the dehydration catalyst is selected in the group consisting of a crystalline silicate having a ratio Si/Al of at least about 100, a dealuminated crystalline silicate, and a phosphorus modified zeolite.

Hydroswellable, absorbable and non-absorbable, aliphatic, segmented polyurethanes and polyurethane-urea capable of swelling in the biological environment with associated increase in volume of at least 3 percent have more than one type of segments, including those derived from polyethylene glycol and the molecular chains are structurally tailored to allow the use of corresponding formulations and medical devices as carriers for bioactive agents, rheological modifiers of cyanoacrylate-based tissue adhesives, as protective devices for repairing defective or diseased components of articulating joints and their cartilage, and scaffolds for cartilage tissue engineering.

The present invention aims in a method wherein tetrachloroethylene (PCE) is reacted with HF in a gas phase in the presence of a catalyst to obtain pentafluoroethane (HFC-125), to reduce production of undesirable by-products and maintain a catalytic activity at a high level over a long period of time while achieving a high conversion ratio of PCE and suppressing deterioration of the catalyst. In a method for producing pentafluoroethane wherein tetrachloroethylene is reacted with HF in a gas phase in the presence of a catalyst to obtain pentafluoroethane, characterized in that chromium oxyfluoride is disposed in a reactor as the catalyst, and oxygen is fed into the reactor together with tetrachloroethylene and HF, at a amount of 0.4-1.8% by mole with respect to tetrachloroethylene.

The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used.

The present invention relates to a process for separating chlorinated methanes utilizing a dividing wall column. Processes and manufacturing assemblies for generating chlorinated methanes are also provided, as are processes for producing products utilizing the chlorinated methanes produced and/or separated utilizing the present process(es) and/or assemblies.

To provide a method for efficiently separating 2,3,3,3-tetrafluoropropene (HFO-1234yf) and chloromethane (R40) from a composition comprising HFO-1234yf and R40. An azeotrope-like composition comprising from 58 to 78 mol % of HFO-1234yf and from 22 to 42 mol % of R40, and a method for producing HFO-1234yf, which comprises steps of distilling an initial mixture containing HFO-1234yf in a content exceeding 63 mol % in the total amount of HFO-1234yf and R40, thereby to separate the initial mixture into a first fraction in which the content of HFO-1234yf in the total amount of HFO-1234yf and R40 is lower than the content of HFO-1234yf in the total amount of HFO-1234yf and R40 in the initial mixture, and a second fraction in which the content of HFO-1234yf in the total amount of HFO-1234yf and R40 is higher than the content of HFO-1234yf in the total amount of HFO-1234yf and R40 in the initial mixture, and then obtaining HFO-1234yf having a reduced R40 concentration, from the second fraction.

The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides routes for HCFO-1233zd from inexpensive and commercially available trifluoromethane (HFC-23).