x PIX: NZ players melt under Mumbai's scorching sun By www.rediff.com Published On :: Fri, 01 Nov 2024 14:21:15 +0530 New Zealand's cricketers are facing a tough test of endurance in the third Test against India in Mumbai on Friday. Full Article
x PIX: India's top order collapse again; NZ in control By www.rediff.com Published On :: Fri, 01 Nov 2024 18:16:16 +0530 IMAGES from the Day 1 of the third Test played between India and New Zealand at the Wankhede Stadium in Mumbai on Friday Full Article
x IPL: Punjab Kings expected to break the bank for Pant By www.rediff.com Published On :: Fri, 01 Nov 2024 19:43:16 +0530 RCB might show interest in KL Rahul. Full Article
x PIX: Gill, spinners give India upper hand on Day 2 By www.rediff.com Published On :: Sat, 02 Nov 2024 18:02:32 +0530 Spinners Ravindra Jadeja and Ravichandran Ashwin chipped away at the wickets to leave New Zealand reeling on 171/9 in their second innings at stumps on Day 2. Full Article
x PIX: New Zealand crumble but match evenly poised By www.rediff.com Published On :: Sat, 02 Nov 2024 18:09:56 +0530 Images from Day 2 of the 3rd Test played between India and New Zealand, in Mumbai, on Saturday. Full Article
x PIX: New Zealand humble India for historic sweep! By www.rediff.com Published On :: Sun, 03 Nov 2024 15:05:01 +0530 New Zealand beat India by 25 runs in Mumbai to complete an unprecedented 3-0 series sweep in India. Full Article
x 1st T20 PIX: Samson slams century as India maul SA By www.rediff.com Published On :: Sat, 09 Nov 2024 01:13:21 +0530 Sanju Samson became the first Indian to hit two consecutive hundreds in T20 Internationals to power the visitors to a thumping 60-run victory against South Africa. Full Article
x 2nd T20 PIX: Buttler smashes England to thumping win! By www.rediff.com Published On :: Mon, 11 Nov 2024 08:57:04 +0530 England skipper Jos Buttler hammered a superb 83 off 45 balls to steer his side to a seven-wicket victory in the second Twenty20 international against West Indies. Full Article
x Diagnostic protocols, more research needed to combat H. pylori challenge in India: experts By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:08:47 +0530 The bacterial infection, which often begins in childhood, is almost 10 times more prevalent than diabetes in the country and is a major cause of chronic gastritis, peptic ulcers and even stomach cancer, according to doctors Full Article Hyderabad
x Citing ‘exigency’, T.N. Health Dept posts 51 PGs to peri-urban, rural government medical colleges By www.thehindu.com Published On :: Fri, 08 Nov 2024 20:23:34 +0530 Official sources and a number of senior doctors confirmed that these deputation/postings were made to address specific manpower shortages in medical colleges in Nagapattinam, Tiruvallur and Tiruvarur Full Article Tamil Nadu
x Shift in Hindi cinema’s portrayal of doctors reflects society’s evolving perception: Expert By www.thehindu.com Published On :: Sat, 09 Nov 2024 18:59:37 +0530 Full Article Hyderabad
x Fight over including carbon border tax in agenda delays climate talks on day one By www.thehindu.com Published On :: Tue, 12 Nov 2024 12:02:46 +0530 Agenda disputes are common at UN climate conferences but this one is especially significant as countries have limited time to agree on a new climate finance goal. Full Article Environment
x Clamp it! VS Code extension By css-tricks.com Published On :: Wed, 23 Oct 2024 13:15:20 +0000 There’s a lot of math behind fluid typography. CSS does make the math a lot easier these days, but even if you’re comfortable with that, writing the full declaration can be verbose and tough to remember. I know I often … Clamp it! VS Code extension originally published on CSS-Tricks, which is part of the DigitalOcean family. You should get the newsletter. Full Article Links clamp typography
x You can use text-wrap: balance; on icons By css-tricks.com Published On :: Thu, 24 Oct 2024 14:05:56 +0000 The CSS text-wrap property is (rightfully) widely assumed to be used strictly for text elements. But Terrence Eden posted an article on his blog that shows how it can also be used to balance the way other types of elements wrap, including icons. You can use text-wrap: balance; on icons originally published on CSS-Tricks, which is part of the DigitalOcean family. You should get the newsletter. Full Article Links typography
x Tim Brown: Flexible Typesetting is now yours, for free By css-tricks.com Published On :: Mon, 11 Nov 2024 14:03:37 +0000 Another title from A Book Apart has been re-released for free. The latest? Tim Brown's Flexible Typesetting. I may not be the utmost expert on typography and its best practices but I do remember reading this book (it's still on the shelf next to me!) thinking maybe, just maybe, I might be able to hold a conversation about it with Robin when I finished it. Tim Brown: Flexible Typesetting is now yours, for free originally published on CSS-Tricks, which is part of the DigitalOcean family. You should get the newsletter. Full Article Links book typography
x FACTBOX-Who are the candidates running in the US presidential election? By www.thehindubusinessline.com Published On :: Tue, 01 Oct 2024 09:56:12 +0530 The upcoming elections in the United States on November 5 have the world on the edge of their seats as they heat up, here is a brief overview of who they are Full Article World
x Vice President Harris is in ‘excellent health,’ physician says By www.thehindubusinessline.com Published On :: Sat, 12 Oct 2024 18:59:36 +0530 Her most recent physical exam in April was “unremarkable,” Simmons added Full Article World
x Trump talks Xi, tariffs and aliens in freewheeling Joe Rogan podcast By www.thehindubusinessline.com Published On :: Sat, 26 Oct 2024 11:06:50 +0530 The conversation stretched long enough that Trump ended up hours late for a rally in swing-state Michigan, where hundreds of supporters trickled out of the venue as temperatures dropped while waiting for him to arrive Full Article World
x European banks to extend dealing with Indian clearing firms By www.thehindubusinessline.com Published On :: Mon, 28 Oct 2024 15:39:05 +0530 Europe’s authorities set the deadline last year after their request for co-supervision of European trades settled through Indian clearing houses was denied by the Reserve Bank of India Full Article Money & Banking
x Indian, Chinese troops exchange sweets at several border points on Diwali By www.thehindubusinessline.com Published On :: Thu, 31 Oct 2024 14:33:40 +0530 The ties between the two Asian giants had nosedived following the clash Full Article World
x Trump expands lead, Republican Party captures Senate as Harris path narrows By www.thehindubusinessline.com Published On :: Wed, 06 Nov 2024 12:08:41 +0530 Trump wins both North Carolina and Georgia, while holding a more tentative advantage across Wisconsin, Michigan, Pennsylvania and Arizona Full Article News
x Write Alt Text Like You’re Talking To A Friend By cloudfour.com Published On :: Mon, 22 Apr 2024 15:30:00 +0000 “There was this dog wearing safety glasses, surrounded by chemistry equipment, saying ‘I have no idea what I’m doing.’” Full Article Accessibility batman heists race
x Real Madrid beats Alaves 3-2 in La Liga as Kylian Mbappé extends scoring streak By www.thehindu.com Published On :: Wed, 25 Sep 2024 13:15:46 +0530 Kylian Mbappé asked to be substituted in the 80th minute because of a muscle injury, according to Madrid coach Carlo Ancelotti, who said it was not serious. Full Article Football
x No extra pressure on in-form Barcola, says PSG manager Enrique By www.thehindu.com Published On :: Sun, 03 Nov 2024 09:34:23 +0530 The Spaniard said he was relying on all his players when asked about French forward Randal Kolo Muani, who has been linked with a move away from the reigning Ligue 1 champions Full Article Football
x RBI’s gold holdings now exceed India’s annual demand for the precious metals By www.thehindubusinessline.com Published On :: Thu, 23 May 2024 20:30:39 +0530 Central bank embarks on gold buying spree, adds 25 tonnes to forex reserves Full Article Gold & Silver
x Tamil Nadu’s mineral exploration projects for gold, rare-earth elements approved By www.thehindubusinessline.com Published On :: Fri, 21 Jun 2024 18:57:39 +0530 The state has seen an increase in mineral revenue, with plans to explore new deposits through agencies like the Geological Survey of India. Full Article Gold & Silver
x The purity paradox: Why gold’s fineness matters in your investment By www.thehindubusinessline.com Published On :: Sat, 27 Jul 2024 11:00:00 +0530 The precious metal’s brilliance lies not just in its physical form, but also in its adaptability to diverse investment strategies Full Article Gold & Silver
x Govt to decide on Sovereign Gold Bond issuance for next fiscal By www.thehindubusinessline.com Published On :: Thu, 01 Aug 2024 20:49:03 +0530 No plan to stop the issuance of Sovereign Green Bonds, says a Senior official Full Article Economy
x Gold prices may correct by 5-7% before the next leg up: Motilal Oswal By www.thehindubusinessline.com Published On :: Sat, 05 Oct 2024 11:17:10 +0530 Gold demand in India has remained robust, particularly following an initial surge after the import duty cut Full Article Gold & Silver
x Silver poised to outperform gold, expected to hit ₹1.25 lakh/kg in 12-15 months: MOFSL By www.thehindubusinessline.com Published On :: Sun, 27 Oct 2024 13:15:23 +0530 Silver has shown impressive growth in 2024, recording gains of over 40 per cent year-to-date and surpassing the ₹1,00,000 mark domestically Full Article Gold & Silver
x Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Recent advances in discrete Cu complexes for enhanced chemodynamic therapy By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02380C, FrontierZhao-Guo Hong, Liangliang Zhang, Hong Liang, Fu-Ping HuangSince the concept of metal ion stimulation-mediated chemodynamic therapy was proposed by Bu and Shi 's group in 2016, increasing attention has been directed toward fabricate efficient, safe and stable...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450 By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02197E, PaperVandana Kardam, Vaibhav Bhatt, Kshatresh DubeyArylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02496F, PaperSergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena ShubinaOctahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Rhenium(I) and technetium(I) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02714K, PaperAna Cristina Resende Gonçalves, Silvia Helena Libardi, Júlio Cesar Borges, Ronaldo Junio de Oliveira, Carla Gotzmann, Olivier Blacque, Sergio Albuquerque, Carla Duque Lopes, Roger Alberto, Pedro Ivo da Silva MaiaThe diagnosis and treatment of Chagas disease (CD) in the chronic phase remains a challenge. With that in mind, a potential theranostic device based on the trypanocidal agent known as...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02690J, CommunicationAlexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di SunFirst metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02469A, PaperZhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei QinHeteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02603A, PaperTakeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa MehrkhodavandiAlkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Exploring the versatility of MoSe2/WS2 heterostructures By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02075H, PaperTuan V. Vu, Dat D. Vo, Cuong Q. Nguyen, Nguyen N. Hieu, Huynh V. Phuc, Chuong V. NguyenTwo-dimensional materials and their combined heterostructures have paved the way for numerous next-generation electronic and optoelectronic applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Oxaphosphiranes: isolable phosphorus-containing epoxide rings By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02915A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer StreubelA new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x What is the key factor affecting the cathodoluminescence intensity of europium complexes? By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02501F, CommunicationRongdeng Lu, Tinghui Huang, Alexander Goloveshkin, Dmitry Kopytov, Kseniya Orekhova, Ivan Khanbekov, Valentina V. UtochnikovaCathodoluminescence of lanthanide coordination compounds correlates with PLQY/τ in the saturation regime and with PLQY when saturation is not reached. Understanding this, a brightly cathodoluminescent europium complex was obtained.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02650K, CommunicationKatherine Merkel, Alyssa V. B. Santos, Scott SimpsonDFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02848A, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi ShimojimaWell-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01765J, PaperRomain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim StorrThe synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02645D, PaperKetan Maru, Sarita Kalla, Ritambhara JangirThe study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02958E, PaperJanak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika KhullarThe development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02901A, PaperMaxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia SpitsynaThe hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02396J, PaperChuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo PengZinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x A ratiometric luminescence thermometer based on lanthanide encapsulated complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02639J, PaperAribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju LaishramThis paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02721C, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias WesterhausenThe diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
