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Effects of oxide platforms on the dynamics and reduction characteristics of hydrogen spillover

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03093A, Paper
Kazuki Shun, Akihito Fujimoto, Kohsuke Mori, Hiromi Yamashita
The interparticle hydrogen spillover can be facilitated over TiO2 and WO3 as a consequence of the interfacial diffusion of H+ and e− pairs, while the e− diffusion coupled with H+ is inhibited on MgO and CeO2.
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A hydrogen passivation strategy for the electrocatalytic chlorine evolution reaction on metal–organic frameworks: a theoretical insight

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03153A, Paper
Jiake Fan, Lei Yang, Hui Li, Zijian Sun, Mengyun Mei, Weihua Zhu
The chlorine evolution reaction (CER) is a crucial solution for treating chlorine-containing wastewater, a type of wastewater generated during the chemical production process.
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Intermolecular Hydrogen Bonding Delineates Stability of Non-canonical Adenine Base Pairs: A First-Principles Study

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP02875A, Paper
Nicholas Adu-Effah, Nabanita Saikia
Non-canonical nucleobase pairs differ from canonical Watson-Crick (WC) pairs in their hydrogen bonding patterns. This study uses density functional theory with empirical dispersion correction to examine the stability and electronic...
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Recent progress and prospects of dimer and multimer acceptors for efficient and stable polymer solar cells

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00895A, Review Article
Open Access
Jin-Woo Lee, Jin Su Park, Hyesu Jeon, Seungjin Lee, Dahyun Jeong, Changyeon Lee, Yun-Hi Kim, Bumjoon J. Kim
This review summarizes the recent progress, key design principles and prospects of dimer and multimer acceptors for developing polymer solar cells (PSCs) with high efficiency and long-term stability.
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Peptide hydrogen-bonded organic frameworks

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Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review
Open Access
Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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Progress and perspectives on iron-based electrode materials for alkali metal-ion batteries: a critical review

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Chem. Soc. Rev., 2024, 53,4154-4229
DOI: 10.1039/D3CS00819C, Review Article
Junzhe Li, Chao Wang, Rui Wang, Chaofeng Zhang, Guanjie Li, Kenneth Davey, Shilin Zhang, Zaiping Guo
This review critically evaluates recent advances in iron-based electrode materials and applications in alkali metal ion batteries, covering chemical synthesis, structural design, and modification strategies, with insights into future directions.
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The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Like Dravid, I want to coach juniors before gradual progression, says P.R. Sreejesh

By www.thehindu.com
Published On :: Tue, 13 Aug 2024 22:34:52 +0530

If he decides to take up coaching, Sreejesh is clear in his mind how to go about in the new role.


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Programmed to paint / written and illustrated by Mauricio Abril

By darius.uleth.ca
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Abril, Mauricio, author, illustrator


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Inclusive program: Leaving no child behind in software skills

By www.thehindubusinessline.com
Published On :: Sun, 21 Apr 2024 21:36:00 +0530

Hyderabad start-up’s tactile cardboard kit introduces visually challenged students to joys of coding 


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Direct alkene functionalization via photocatalytic hydrogen atom transfer from C(sp3)–H compounds: a route to pharmaceutically important molecules

By pubs.rsc.org
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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05026F, Highlight
Hangqian Fan, Yuxin Fang, Jingbo Yu
Direct functionalization of alkenes with C(sp3)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.
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Fabrication of gelatin hydrogels using pre-coordinated lanthanide complexes via imine crosslinking

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication
Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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Nitrogen-doped graphene quantum dot-intensified tungsten oxide nanosheets as a SERS substrate for antibiotics detection

By pubs.rsc.org
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Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication
Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO3 NSs) were fabricated as SERS substrates.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

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Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Enhanced glucose-responsivity of PBA–diol hydrogel networks by reducing crosslink affinity

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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00106K, Paper
Open Access
Sijie Xian, Yuanhui Xiang, Svenja Deichmann, Matthew J. Webber
New diol chemistries are explored for insulin delivery from glucose-responsive hydrogels comprised of dynamic-covalent crosslinking interactions between phenylboronic acids and diols.
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Selective mineralization at hydrogel interface induced by fusion between peptide hydrogels

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Mol. Syst. Des. Eng., 2024, 9,1107-1115
DOI: 10.1039/D4ME00112E, Paper
Yongbaek Kim, Hiroto Isobe, Keishi Nishio, Kazuki Murai
Biomineralization has garnered attention not only for its fundamental role in understanding the mechanisms of biomineral formation but also as a method for fabricating next-generation functional materials.
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Dual responsive fluorescence switching of organohydrogel towards base/acid

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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00067F, Communication
Manish Kumar Dixit, Moupia Mukherjee, Bharat Kumar Sahu, Abul Kalam, Mrigendra Dubey
Herein, we report a dual acid/base responsive fluorescent and simultaneous reversible phase transformative organohydrogel (OHG).
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Ultrafine VN quantum dots modified with a nitrogen-doped reduced graphene oxide anode material for enhanced rate capability and lifespan of lithium-ion batteries

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00502C, Paper
Dong Wang, Zihan Guo, Zhiwei Wang, Yanfang Gao
The excellent electrochemistry performance is attributed to vanadium nitride quantum dots (VNQDs) offering large capacity and nitrogen-doped reduced graphene oxide (NrGO) acting as a conductive network and buffer skeleton.
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Ni–Co alloys via controlled pyrolysis of NiCo–MOF as heterogeneous hydrogenation catalysts

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00664J, Paper
Lidan Deng, Xingwang Liu, Chong Chen, Lu Wang, Fan Liu, Jie Zhang
The pyrolysis in H2 at lower temperatures can obtain MNP/MOF with more complete MOFs structure and dispersed Ni–Co alloy nanoparticles, which display significantly better activity for the hydrogenation of toluene to methylcyclohexane.
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From byproducts to NLO-active dyes: catalyst-free transfer hydrogenation in the modular synthesis of merocyanines

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00820K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Zou, Yi Pan, Di Zhang, Jie Zhang, Weilong Chen, Hongyan Sun, Kai-Chung Lau, Jingdong Luo
Direct transfer hydrogenation from a strong electron donor to highly polarizable hemicyanines was discovered in the synthesis of push–pull chromophores. The reaction mechanism and experimental results were elucidated using DFT calculations.
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Research progress of Co-based spinel oxide materials for direct methanol fuel cells

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New J. Chem., 2024, 48,7148-7167
DOI: 10.1039/D3NJ05431D, Paper
Zhiyang Zhong, Qinghui Zhang, Yingying Zhu, Bingyu Chen, Siyan Xu, Tianyu Shen, Aijuan Xie, Shiping Luo
With decades of research, both the synthesis and applications of spinels have achieved greatly increased development. The preparation, regulation strategies, and their application in MOR of Co based spinels are reviewed in this paper.
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Preparation of hydrogels with self-reinforced mechanical properties using ball-milled microcrystalline cellulose and regenerated cellulose from deep eutectic solvent

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New J. Chem., 2024, 48,7405-7412
DOI: 10.1039/D4NJ00622D, Paper
Yi Zhang, Yingming Zhu, Kejing Wu, Yingying Liu, Houfang Lu, Bin Liang
Choline chloride–lactic acid deep eutectic solvent assisted by ball milling effectively dissolved microcrystalline cellulose. Regenerated cellulose was used to prepare novel cellulose hydrogel with self-reinforced mechanical properties.
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Design and synthesis of few-layer molybdenum oxide selenide encapsulated in a 3D interconnected nitrogen-doped carbon anode toward high-performance sodium storage

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New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper
Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO3–MoSe2 encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
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Hydrogen-bonded organic frameworks with extended conjugate systems for boosted photocatalytic degradation

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New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper
Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
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Construction of NiCo2S4−xPx nanowire arrays for efficient hydrogen evolution reactions in both acidic and alkaline media

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00361F, Paper
Guanglei Liu, Yutong Feng, Yifan Yang, Yuan Wang, Huixiang Liu, Can Li, Mingxin Ye, Jianfeng Shen
Construction of NiCo2S4−xPx nanowire arrays for improved HER performances in both acidic and alkaline media.
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1-Butyl-3-methylimidazolium hydrogen sulfate-induced structure modification and reconstruction of nickel foams for oxygen evolution reactions

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05752F, Paper
Huamei Yang, Ziqin Chen, Kai Luo, Mengjun Yu, Yao Zhang
Surface chemical etching for the in situ growth of metal–organic materials and electrochemical reconstruction are expected to efficiently improve the catalytic performance of oxygen evolution reactions (OERs).
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A robust dual-network hydrogel electrolyte coupled with a porous carbon material for flexible quasi-solid-state zinc ion hybrid supercapacitors

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00310A, Paper
Chenchen Ji, Xinhong Lin, Yang Hong, Junfeng Liu, Aoteng Liu, Yijia Yao, Sicheng Liu, Hongyu Mi
A hydrogel electrolyte was designed by constructing a multi-crosslinked network. The quasi-solid-state ZHSC based on the hydrogel electrolyte and HSSPC delivers a high specific capacity, high energy/power densities, and good cycle stability.
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Electrodeposited Ni-Fe alloy a cost-effective material for harnessing hydrogen via oxygen evolution and urea oxidation reaction

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00797B, Paper
Venkatachalam Ananth, Venkatesan Senthilnathan, Murugan Veerapandian, Neelamegam Rajasekaran
Electrochemical energy conversion for hydrogen production is a crucial method to address global energy demand. Here, a cost-effective approach for the preparation of transition metal-based alloy electrode through electrodeposition with...
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Effect of Functionalized Multiwalled Carbon Nanotubes on Mechanical, Swelling and Viscoelastic Properties on Gum ghatti-cl-poly(NIPAm) Hydrogels

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01677G, Paper
Pragnesh N Dave, Pradip Macwan
The present work involves the Gum ghatti-cl-poly(NIPAm)/-o-MWCNT (GGNIPACNT) hydrogels via free radical polymerization technique. The synthesized hydrogels were characterized by FTIR analysis which suggested the successful binding of -o-MWCNT in...
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Self-Sacrificial templated-directed synthesis of ultrathin 0D/2D FeNi3-NC/NiFeOx Schottky junction as hydrogen evolution reaction electrode for alkaline seawater electrolysis

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01321B, Paper
Zili Xu, Yuankang Bao, Xun Xu, Ping Li, Hao Zhang, Deliang Li, Shuwang Duo
Seawater, a plentiful natural resource, is promising for hydrogen production compared to traditional electrocatalytic methods based on high-purity freshwater. This strategy shift addresses the challenge of limited freshwater resources and...
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Estrogenic activity of plastic nanoparticle mixtures under in vitro settings

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00883E, Paper
Lucija Božičević, Korinna Altmann, Jana Hildebrandt, Xenia Knigge, Valerije Vrček, Nikolina Peranić, Nikolina Kalčec, Ivana Vinković Vrček
This study provides science-based evidence on endocrine disrupting effects of polyethylene, polystyrene and polypropylene nanoparticles and their mixtures indicating the importance of hazard assessment of aggregate exposure to nanoplastics.
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Carbon dot-embedded hydrogels promote maize germination and growth under drought stress

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00070F, Paper
Yuying Ren, Xiaona Li, Bingxu Cheng, Le Yue, Xuesong Cao, Chuanxi Wang, Zhenyu Wang
Tannic acid derived carbon dot (TACD)-embedded gelatin hydrogels (GTACDs) were formed by hydrogen bonding and electrostatic interactions, which as seed coating were applied to drought soil to enhance crop drought resistance and growth.
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Preparation of UV-responsive hydrogels based on nanocellulose and their utilization in fungicide delivery

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Environ. Sci.: Nano, 2024, 11,1442-1451
DOI: 10.1039/D3EN00910F, Paper
Chaoqun You, Xinyue Ji, Hanchen Lin, Ning Ma, Wei Wei, Lingfeng Long, Like Ning, Fei Wang
A stimuli-responsive hydrogel for fungicide delivery based on UV-sensitive molecular (AZO)-conjunct CNCs is successfully prepared.
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Core–shell magnetic zinc-based molecularly imprinted polymer: a robust heterogeneous catalytic nanoreactor toward the CO2 fixation reaction

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Environ. Sci.: Nano, 2024, 11,1622-1635
DOI: 10.1039/D3EN00554B, Paper
Tahereh Nasiriani, Neda Adabi Nigjeh, Ahmad Shaabani
This study deals with the synthesis of a core–shell magnetic zinc-based molecularly imprinted polymer (M-Zn-MIP) as a robust heterogeneous catalytic nanoreactor. The catalytic activity of the M-Zn-MIP was explored in the CO2 fixation reaction.
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Functionalized molybdenum disulfide (MoS2) monolayer as an efficient nanosensor towards toxic nitrogen containing gases

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Environ. Sci.: Nano, 2024, 11,1740-1754
DOI: 10.1039/D4EN00072B, Paper
Wadha Alfalasi, Tanveer Hussain, Nacir Tit
Selective detection of toxic nitrogen-containing gases (e.g. NO and NO2) is achieved when special transition metal (TM) atoms are selected in doping molybdenum disulfide (MoS2) monolayer. The change of magnetic state is the secret of that selectivity.
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Rational construction of micro-plate-like iron oxide/aluminium oxide-fabricated screen-printed carbon electrode for the electrochemical detection of the antiandrogen drug

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1521-1532
DOI: 10.1039/D3EN00808H, Paper
Sivakumar Musuvadhi Babulal, Nandini Nataraj, Tse-Wei Chen, Shen Ming Chen, Bih-Show Lou, Arshad Mehmood Abbasi, Amal M. Al-Mohaimeed, Mohamed Soliman Elshikh, Jaysan Yu
An improved electrochemical sensing platform with a vital strategy for NTM antiandrogen drug detection in real environmental and biofluid samples.
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Incisive analysis of hydrogen-bonded supramolecular architectures in designer polycyclitols: observation of some interesting self-assembly patterns

By pubs.rsc.org
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CrystEngComm, 2024, 26,1952-1961
DOI: 10.1039/D4CE00010B, Paper
Showkat Rashid, Ahmad Husain, Bilal A. Bhat, Goverdhan Mehta
This article examines C–H⋯O and O–H⋯O hydrogen-bonded patterns in polyoxygenated decalins, showcasing varied supramolecular architectures influenced by oxyfunctionalisation and surrogate carbonate groups.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

By pubs.rsc.org
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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
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Highly efficient and durable P, Ru–CeO2 self-supporting electrodes toward industrial-level hydrogen production

By pubs.rsc.org
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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00143E, Paper
Wenguang Ma, Xiaodong Yang, Yanru Xu, Cuncheng Li, Yiqiang Sun, Qi Shen, Zhixin Sun
The electrolysis of seawater has become a preferred method for hydrogen production since the current shortage of freshwater resources, offering an effective strategy to address the energy crisis.
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A highly stable hydrogen-bonded organic framework for hydrogen storage

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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A perturbational approach for approximating heterogeneous agent models [electronic resource] / Anmol Bhandari, Thomas Bourany, David Evans, Mikhail Golosov

By darius.uleth.ca
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Cambridge, MA. : National Bureau of Economic Research, 2023


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Clean facts about green hydrogen versus blue hydrogen

By www.thehindubusinessline.com
Published On :: Sun, 24 Dec 2023 16:31:54 +0530

Suitability of blue or green hydrogen as a future fuel is premised on how much water is consumed for their production


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Anatomy of a landfill remediation in progress  

By www.thehindubusinessline.com
Published On :: Sun, 18 Aug 2024 22:00:00 +0530

A visit to a dumpsite in Chennai illustrates the solution to the pile up of legacy waste across the country 


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Indian scientists develop method to create hydrogels to boost drug delivery

By www.newkerala.com
Published On :: Tue, 29 Oct 2024 22:12:02 +0530


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Gujarat DDU-GKY Program: Over 30,000 rural youth trained, 450 receive job appointment letters

By www.newkerala.com
Published On :: Fri, 25 Oct 2024 00:18:03 +0530


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Progress targets $1 billion revenue with acquisition; expands Bangalore team

By www.thehindubusinessline.com
Published On :: Mon, 04 Nov 2024 18:56:03 +0530

The ShareFile business the company is acquiring generates approximately $240 million in revenue


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Copper catalyzed dehydrogenative cyclization, alkenylation towards dihydroquinolinones

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Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00134F, Paper
Pari Keerthana, Fazlur-Rahman Nawaz Khan
An efficient copper-catalysized one-pot sequential synthesis of alkenylated quinolinyldihydroquinolinones is reported utilizing ketones, 1,3-cyclohexanediones, and benzyl alcohols via dehydrogenative cyclisation, followed by alkenylation. This highly straightforward method provides a mild...
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