magnetic

Magnetic colloidal single particles and dumbbells on a tilted washboard moir'e pattern in a precessing external field

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM01183J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Farzaneh Farrokhzad, Nico C. X. Stuhlmüller, Piotr Kuswik, Maciej Urbaniak, Feliks Stobiecki, Sapida Akhundzada, Arno Ehresmann, Daniel de las Heras, Thomas M. Fischer
We measure the dynamical behavior of colloidal singlets and dumbbells on an inclined magnetic moir'e pattern, subject to a precessing external homogeneous magnetic field. At low external field strength single...
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magnetic

Magnetic appeal

A.S.R. Murthy’s magnets from across the world are more than just souvenirs. They are a mine of information




magnetic

Anomalous magnetic behaviour induced by a structural phase transition with anisotropic thermal expansion in a spirodiradical

Org. Chem. Front., 2024, 11,6495-6502
DOI: 10.1039/D4QO01098A, Research Article
Open Access
Takuya Kanetomo, Daigo Matsunaga, Shinichi Ogawa, Masaya Enomoto
A Ge-centred spirodiradical exhibited anomalous magnetic behaviour, influenced by two key structural factors: negative thermal expansion and a structural phase transition.
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magnetic

Electromagnetic wave effects on Mn-doped superparamagnetic iron oxide nanofluids: applications in enhanced oil recovery

RSC Adv., 2024, 14,35671-35678
DOI: 10.1039/D4RA04500A, Paper
Open Access
Mohamad Amin Bin Hamid, Beh Hoe Guan, Chan Kar Tim, Hassan Soleimani
This study reveals that both direct current (DC) and alternating current (AC) electromagnetic fields can effectively reduce the interfacial tension (IFT) of Mn-doped Fe3O4 nanofluids, with AC fields showing more predictable and pronounced effects.
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magnetic

Stability and magnetic properties of transition metal (V, Cr, Mn, and Fe) doped cobalt oxide clusters: a density functional theory investigation

RSC Adv., 2024, 14,36031-36039
DOI: 10.1039/D4RA05482B, Paper
Open Access
Nguyen Thi Mai, Tran Dang Thanh, Do Hung Manh, Nguyen Thi Ngoc Anh, Ngo Thi Lan, Phung Thi Thu, Nguyen Thanh Tung
Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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magnetic

Effect of magnetic field on the rate performance of a Fe2O3/LiFePO4 composite cathode for Li-ion batteries

RSC Adv., 2024, 14,36005-36015
DOI: 10.1039/D4RA06707J, Paper
Open Access
Emmanuel Iheonu Nduka, Nazgul Assan, Mukagali Yegamkulov, Aliya Mukanova, Zhumabay Bakenov
Application of magnetic field upon drying of LiFePO4 cathode enhances its electrochemical performance. It is further enhanced with Fe2O3 nanoparticle additives, thereby reducing polarization and improving conductivity and lithium-ion diffusion.
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magnetic

Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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magnetic

Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
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magnetic

The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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magnetic

Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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magnetic

Scientists uncover a magnetic misunderstanding about Uranus

Much of what we know is based on Voyager 2’s flyby of Uranus in 1986, but now it seems the probe visited at a time of unusual conditions




magnetic

In situ preparation and performance of iron-based electro-magnetic synergistic electrochemical nitrogen fixation catalysts

Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper
Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO4 solution by electrochemical technology to catalyze the reduction of N2 to NH3. It was found that the applied magnetic field can significantly increase the current density.
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magnetic

Size effect on the structural and magnetic phase transformations of iron nanoparticles

Nanoscale, 2024, 16,20304-20311
DOI: 10.1039/D4NR02488E, Paper
Alexis Front, Georg Daniel Förster, Chu Chun Fu, Cyrille Barreteau, Hakim Amara
(a) Magnetic (top) and structural (bottom) phase transformation of an iron nanoparticle. (b) Size dependence on magnetic and structural transition temperatures on iron nanoparticles.
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magnetic

Metamagnetic transition and meta-stable magnetic state in Co-doped Fe3GaTe2

Nanoscale, 2024, 16,20252-20259
DOI: 10.1039/D4NR02622E, Paper
Hyo-Bin Ahn, Hyunjong Lim, Jaegu Song, Jisung Lee, Seung-Young Park, Minwoong Joe, Chang-Jong Kang, Kyoung-Whan Kim, Tae-Eon Park, Tuson Park, Changgu Lee
The phase diagram and MH curves of the metamagnetic regime of (Fe1−xCox)3GaTe2 with x = 0.19–0.26 at various temperatures were studied.
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magnetic

Magnetic dimeric metal–porphyrin rings mechanically bonded around carbon nanotubes: the role of nanotube defects modulating magnetic properties

Nanoscale, 2024, 16,20342-20353
DOI: 10.1039/D4NR02984D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rocío Sánchez-de-Armas, Nicolás Montenegro-Pohlhammer, Emilio M. Pérez, Enrique Burzurí, Carmen J. Calzado
A DFT study of mechanically bonded magnetic Co2+ and Cu2+ dimeric metal–porphyrin rings around carbon nanotubes (mMINTs) points to defcts in the NT as responsible for the different dimer–nanotube interactions and the loss of the Co2+ EPR signal.
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magnetic

Retraction: Enhanced activity of vancomycin by encapsulation in hybrid magnetic nanoparticles conjugated to a cell-penetrating peptide

Nanoscale, 2024, 16,20356-20356
DOI: 10.1039/D4NR90195A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wenjie Zhang, Reza Taheri-Ledari, Zoleikha Hajizadeh, Ehsan Zolfaghari, Mohammad Reza Ahghari, Ali Maleki, Michael R. Hamblin, Ye Tian
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magnetic

Current progress and frontiers in three-dimensional macroporous carbon-based aerogels for electromagnetic wave absorption: a review

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03738C, Review Article
Han Ding, Bo Hu, Yu Wang, Yunchen Du
This article provides a timely review on the construction of three-dimensional macroporous carbon-based aerogels and their application in the field of electromagnetic absorption.
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magnetic

Expression of concern: Iron oxide magnetic nanoparticles with versatile surface functions based on dopamine anchors

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR90209B, Expression of Concern
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mykola Mazur, Alexandre Barras, Victor Kuncser, Andrei Galatanu, Vladimir Zaitzev, Kostiantyn V. Turcheniuk, Patrice Woisel, Joel Lyskawa, William Laure, Aloysius Siriwardena, Rabah Boukherroub, Sabine Szunerits
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magnetic

Ultrasmall catechol-PEG-anchored ferrite nanoparticles for highly sensitive magnetic resonance angiography

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D3BM02074F, Paper
Yanzhi Dong, Jiaojiao Wang, Ting Zhou, Jinbing Pan, Xu Wang, Shao-Kai Sun
We developed ultrasmall catechol-PEG-anchored ferrite nanoparticles for highly sensitive MRA. The probe enables the diagnosis of carotid artery stenosis and subsequent evaluation of reperfusion through a single injection.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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magnetic

Microsoft unveils open-source multi-agent AI system Magnetic-One

The system works with a lead agent called the Orchestrator which then directs the other four agents to solve tasks




magnetic

Magnetic fields could fish out enantiomers

Spin-state effect could lead to new way to run chiral separations on racemic mixtures




magnetic

Shrinking magnetic sectors

Analytical chemists are bringing these old-school mass analyzers into the high-tech, miniature realm




magnetic

Re: Prognosis of unrecognised myocardial infarction determined by electrocardiography or cardiac magnetic resonance imaging: systematic review and meta-analysis





magnetic

Description of the American electro magnetic telegraph: now in operation between the cities of Washington and Baltimore: illustrated by fourteen wood engravings / by Alfred Vail

Archives, Room Use Only - TK5123.V35 1845




magnetic

The life of Samuel F.B. Morse, LL. D.: inventor of the electro-magnetic recording telegraph / by Samuel Irenæus Prime

Archives, Room Use Only - TK5243.M7 P75 1875




magnetic

Decision of Hon. Philip F. Thomas, commissioner of patents, on the application of Samuel F.B. Morse, for an extension of his patent for a new and useful improvement in electro-magnetic telegraphs: patented April 11, 1846: patent extended for seven years f

Archives, Room Use Only - KF228.M674 U55 1860




magnetic

Description of the American electro magnetic telegraph: now in operation between the cities of Washington and Baltimore: illustrated by fourteen wood engravings / by Alfred Vail

Archives, Room Use Only - TK5123.V35 1847




magnetic

Extracts from the Proceedings of the Board of Regents of the Smithsonian Institution, in relation to the electro-magnetic telegraph.

Archives, Room Use Only - TK5118.H5 S66 1858




magnetic

The secret corresponding vocabulary: adapted for use to Morse's electro-magnetic telegraph, and also in conducting written correspondence, transmitted by the mails, or otherwise / by Francis O.J. Smith, Esq

Archives, Room Use Only - HE7673.S65 1845




magnetic

On the application of the principle of the galvanic multiplier to electro-magnetic apparatus: and also to the development of great magnetic power in soft iron with a small galvanic element / by Prof. Joseph Henry ..

Archives, Room Use Only - QC611.H46 1831











magnetic

Crystal structure and magnetic properties of bis­[butyl­tris­(1H-pyrazol-1-yl)borato]iron(II)

The asymmetric unit of the title compound, [Fe(C13H18BN6)2], contains two half independent complex mol­ecules. In each complex, the FeII atom is located on an inversion center and is surrounded by two scorpionate ligand butyl­tris­(1H-pyrazol-1-yl)borate mol­ecules that coordinate to the iron(II) ion through the N atoms of the pyrazole groups. The two independent complex mol­ecules differ essentially in the conformation of the butyl substituents. In the crystal, the complex mol­ecules are linked by a series of C—H⋯π inter­actions, which generate a supra­molecular three-dimensional structure. At 120 K, the average Fe—N bond distance is 1.969 Å, indicating the low-spin state of the iron(II) atom, which does not change upon heating, as demonstrated by high-temperature magnetic susceptibility measurements.




magnetic

X-ray magnetic diffraction under high pressure

Advances in both non-resonant and resonant X-ray magnetic diffraction since the 1980s have provided researchers with a powerful tool for exploring the spin, orbital and ion degrees of freedom in magnetic solids, as well as parsing their interplay. Here, we discuss key issues for performing X-ray magnetic diffraction on single-crystal samples under high pressure (above 40 GPa) and at cryogenic temperatures (4 K). We present case studies of both non-resonant and resonant X-ray magnetic diffraction under pressure for a spin-flip transition in an incommensurate spin-density-wave material and a continuous quantum phase transition of a commensurate all-in–all-out antiferromagnet. Both cases use diamond-anvil-cell technologies at third-generation synchrotron radiation sources. In addition to the exploration of the athermal emergence and evolution of antiferromagnetism discussed here, these techniques can be applied to the study of the pressure evolution of weak charge order such as charge-density waves, antiferro-type orbital order, the charge anisotropic tensor susceptibility and charge superlattices associated with either primary spin order or softened phonons.




magnetic

Magnetic field-induced magnetostructural transition and huge tensile superelasticity in an oligocrystalline Ni–Cu–Co–Mn–In microwire

Meta-magnetic shape-memory alloys combine ferroelastic order with ferromagnetic order and exhibit attractive multifunctional properties, but they are extremely brittle, showing hardly any tensile deformability, which impedes their practical application. Here, for the first time, an Ni–Cu–Co–Mn–In microwire has been developed that simultaneously exhibits a magnetic field-induced first-order meta-magnetic phase transition and huge tensile superelasticity. A temperature-dependent in situ synchrotron high-energy X-ray diffraction investigation reveals that the martensite of this Ni43.7Cu1.5Co5.1Mn36.7In13 microwire shows a monoclinic six-layered modulated structure and the austenite shows a cubic structure. This microwire exhibits an oligocrystalline structure with bamboo grains, which remarkably reduces the strain incompatibility during deformation and martensitic transformation. As a result, huge tensile superelasticity with a recoverable strain of 13% is achieved in the microwire. This huge tensile superelasticity is in agreement with our theoretical calculations based on the crystal structure and lattice correspondence of austenite and martensite and the crystallographic orientation of the grains. Owing to the large magnetization difference between austenite and martensite, a pronounced magnetic field-induced magnetostructural transition is achieved in the microwire, which could give rise to a variety of magnetically driven functional properties. For example, a large magnetocaloric effect with an isothermal entropy change of 12.7 J kg−1 K−1 (under 5 T) is obtained. The realization of magnetic-field- and tensile-stress-induced structural transformations in the microwire may pave the way for exploiting the multifunctional properties under the coupling of magnetic field and stress for applications in miniature multifunctional devices.




magnetic

Spin resolved electron density study of YTiO3 in its ferromagnetic phase: signature of orbital ordering

The present work reports on the charge and spin density modelling of YTiO3 in its ferromagnetic state (TC = 27 K). Accurate polarized neutron diffraction and high-resolution X-ray diffraction (XRD) experiments were carried out on a single crystal at the ORPHÉE reactor (LLB) and SPRING8 synchrotron source. The experimental data are modelled by the spin resolved pseudo-atomic multipolar model (Deutsch et al., 2012). The refinement strategy is discussed and the result of this electron density modelling is compared with that from XRD measured at 100 K and with density functional theory calculations. The results show that the spin and charge densities around the Ti atom have lobes directed away from the O atoms, confirming the filling of the t2g orbitals of the Ti atom. The dxy orbital is less populated than dxz and dyz, which is a sign of a partial lift of degeneracy of the t2g orbitals. This study confirms the orbital ordering at low temperature (20 K), which is already present in the paramagnetic state above the ferromagnetic transition (100 K).




magnetic

Crystallographic insights into diamond-shaped 7M martensite in Ni–Mn–Ga ferromagnetic shape-memory alloys

For Heusler-type Ni–Mn–Ga ferromagnetic shape-memory alloys, the configuration of the martensite variants is a decisive factor in achieving a large magnetic shape-memory effect through field-induced variant reorientation. Based upon the spatially resolved electron backscatter diffraction technique, the microstructural evolution associated with the martensitic transformation from austenite to seven-layered modulated (7M) martensite was investigated on a polycrystalline Ni53Mn22Ga25 alloy. It was clearly shown that grain interior nucleation led to the formation of diamond-shaped 7M martensite within the parent austenite matrix. This diamond microstructure underwent further growth through an isotropic expansion with the coordinated outward movement of four side habit planes, followed by an anisotropic elongation with the forward extension of a type-I twin pair. A two-step growth model is proposed to describe the specific morphology and crystallography of 7M martensite. In addition, the habit planes were revealed to possess a stepped structure, with the {1 0 1}A plane as the terrace and the {0 1 0}A plane as the step. The characteristic combination of martensite variants and the underlying mechanism of self-accommodation in the martensitic transformation have been analysed in terms of the minimum total transformation strain, where the deformation gradient matrix was constructed according to the experimentally determined orientation relationship between the two phases. The present results may deepen the understanding of special martensite microstructures during the martensitic transformation in ferromagnetic shape-memory alloys.




magnetic

Synthesis, structure, magnetic and half-metallic properties of Co2−xRuxMnSi (x = 0, 0.25, 0.5, 0.75, 1) compounds

A series of Co2−xRuxMnSi (x = 0, 0.25, 0.5, 0.75, 1) Heusler compounds were successfully synthesized. The heat-treatment conditions were crucial to make the materials form a single phase with a Heusler structure. With increasing Ru content, the half-metallic gap, lattice parameters and magnetization are continuously adjustable in a wide range. The Co2−xRuxMnSi (x = 0, 0.25) compounds are rigorous half-metals and show a T3 dependence of resistance at low temperature. The Co2−xRuxMnSi (x = 0.5, 0.75, 1) Heusler compounds are the nearly half-metallic materials and show a semiconductive dependence of resistance at low temperature. The experimental magnetization is consistent with that in theory and follows the Slater–Pauling rule. The Curie temperature is higher than 750 K for all Co2−xRuxMnSi Heusler compounds.




magnetic

Magnetic Guinier law

Small-angle scattering of X-rays and neutrons is a routine method for the determination of nanoparticle sizes. The so-called Guinier law represents the low-q approximation for the small-angle scattering curve from an assembly of particles. The Guinier law has originally been derived for nonmagnetic particle-matrix-type systems and it is successfully employed for the estimation of particle sizes in various scientific domains (e.g. soft-matter physics, biology, colloidal chemistry, materials science). An important prerequisite for it to apply is the presence of a discontinuous interface separating particles and matrix. Here, the Guinier law is introduced for the case of magnetic small-angle neutron scattering and its applicability is experimentally demonstrated for the example of nanocrystalline cobalt. It is well known that the magnetic microstructure of nanocrystalline ferromagnets is highly nonuniform on the nanometre length scale and characterized by a spectrum of continuously varying long-wavelength magnetization fluctuations, i.e. these systems do not manifest sharp interfaces in their magnetization profile. The magnetic Guinier radius depends on the applied magnetic field, on the magnetic interactions (exchange, magnetostatics) and on the magnetic anisotropy-field radius, which characterizes the size over which the magnetic anisotropy field is coherently aligned into the same direction. In contrast to the nonmagnetic conventional Guinier law, the magnetic version can be applied to fully dense random-anisotropy-type ferromagnets.




magnetic

Coronal mass ejection from July 12 solar flare headed toward Earth; minor geomagnetic storm activity predicted

A July 12 news alert from NASA indicates a X1.4 class solar flare erupted from the center of the Sun, peaking July 12 at 12:52 P.M.

The post Coronal mass ejection from July 12 solar flare headed toward Earth; minor geomagnetic storm activity predicted appeared first on Smithsonian Insider.





magnetic

As Stars Form, Magnetic Fields Influence Regions Big and Small

Stars form when gravity pulls together material within giant clouds of gas and dust. But gravity isn’t the only force at work. Both turbulence and […]

The post As Stars Form, Magnetic Fields Influence Regions Big and Small appeared first on Smithsonian Insider.




magnetic

Event Horizon Telescope Reveals Magnetic Fields at Milky Way’s Central Black Hole

Most people think of black holes as giant vacuum cleaners sucking in everything that gets too close. But the supermassive black holes at the centers […]

The post Event Horizon Telescope Reveals Magnetic Fields at Milky Way’s Central Black Hole appeared first on Smithsonian Insider.




magnetic

3D simulations reveals why the Sun flips its magnetic field every 11 years

Using new numerical simulations and observations, scientists may now be able to explain why the Sun’s magnetic field reverses every eleven years. This significant discovery […]

The post 3D simulations reveals why the Sun flips its magnetic field every 11 years appeared first on Smithsonian Insider.



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