Ready for a literary trip that messes with your head? These six books will leave you wondering what just happened.

A representational image of a voter casting their ballot voter on June 30, 2024. — Reuters

A town in Saskatchewan, Canada is facing a issue in the run-up to its November mayor election and that is no one is running for the position.

Mayor of Kyle, George Williams is...

Posts circulating on social media claim that politician and lawyer Aitzaz Ahsan has accused two senior Supreme Court judges, Justice Mansoor Ali Shah and Justice Munib Akhtar, of facilitating a political party.

The claim is false.

On October 23, a user on X posted a...

Sean "Diddy" Combs' shocking motive behind dating Jennifer Lopez unveiled

Diddy’s motive behind dating Jennifer Lopez in the past has just been unveiled.

In a throwback interview with Essence in 2007, the music mogul, who is currently being held at a detention centre in...

Privacy: Our analog parents had the right to meet whomever they liked, wherever they liked, and discuss whatever they liked, without the government knowing. Our digital children have lost this, just because they use more modern items.

For a lot of our digital children’s activities, there’s no such thing as privacy anymore, as they naturally take place on the net. For people born 1980 and later, it doesn’t make sense to talk of “offline” or “online” activities. What older people see as “people spending time with their phone or computer”, younger see as socializing using their phone or computer.

This is an important distinction that the older generation tends to not understand.

Perhaps this is best illustrated with an anecdote from the previous generation again: The parents of our parents complained that our parents were talking with the phone, and not to another person using the phone. What our parents saw as socializing (using an old analog landline phone), their parents in turn saw as obsession with a device. There’s nothing new under the sun.

(Note: when I say “digital children” here, I am not referring to children as in young people below majority age; I am referring to the next generation of fully capable adult professionals.)

This digital socializing, however, can be limited, it can be… permissioned. As in, requiring somebody’s permission to socialize in the way you and your friends want, or even to socialize at all. The network effects are strong and create centralizing pressure toward a few platforms where everybody hang out, and as these are private services, they get to set any terms and conditions they like for people assembling and socializing – for the billions of people assembling and socializing there.

Just as one example to illustrate this: Facebook is using American values for socializing, not universal values. Being super-against anything even slightly naked while being comparatively accepting of hate speech is not something inherently global; it is strictly American. If Facebook had been developed in France or Germany instead of the US, any and all nudity would be welcomed as art and free-body culture (Freikörperkultur) and a completely legitimate way of socializing, but the slightest genocide questioning would lead to an insta-kickban and reporting to authorities for criminal prosecution.

Therefore, just using the dominant Facebook as an example, any non-American way of socializing is effectively banned worldwide, and it’s likely that people developing and working with Facebook aren’t even aware of this. But the Freedom of Assembly hasn’t just been limited in the online sphere, but also in the classic analog offline world where our analog parents used to hang out (and still do).

Since people’s locations are tracked, as we saw in the previous post, it is possible to match locations between individuals and figure out who was talking to whom, as well as when and where this happened, even if they were only talking face to face. As I’m looking out my window from the office writing this piece, it just so happens that I’m looking at the old Stasi headquarters across from Alexanderplatz in former East Berlin. It was a little bit like Hotel California; people who checked in there tended to never leave. Stasi also tracked who was talking to whom, but required a ton of people to perform this task manually, just in order to walk behind other people and photograph whom they were talking to — and therefore, there was an economic limit to how many people could be tracked like this at any one time before the national economy couldn’t sustain more surveillance. Today, that limit is completely gone, and everybody is tracked all the time.

Do you really have Freedom of Assembly, when the fact that you’ve associated with a person — indeed, maybe just spent time in their physical proximity — can be held against you?

I’m going to illustrate this with an example. In a major leak recently, it doesn’t matter which one, a distant colleague of mine happened to celebrate a big event with a huge party in near physical proximity to where the documents were being copied at the same time, completely unaware and by sheer coincidence. Months later, this colleague was part of journalistically vetting those leaked documents and verifying their veracity, while at this time still unaware of the source and that they had held a big party very close to the origin of the documents.

The government was very aware of the physical proximity of the leak combined with this person’s journalistic access to the documents, though, and issued not one but two arrest-on-sight warrants for this distant colleague based on that coincidence. They are now living in exile outside of Sweden, and don’t expect to be able to return home anytime soon.

Privacy, including Privacy of Location, remains your own responsibility.

"Deep inside, all candidates think about winning and losing -- but the latter is suppressed. This unleashes a lot of energy. It's also the time where candidates stop sleeping and campaign day and night. It's another way of dealing with the fear of losing that you don't want to leave any stone unturned," campaign consultant Louis Perron said in a written statement shared with Inside the Beltway.

A friend sent me a note on social media last Wednesday morning: "Well, he did it!"

Many voters are wondering which of the presidential candidates would empty their pockets more.

IOC presidential candidate Juan Antonio Samaranch Jr. has urged European lawmakers to regard investing in sport as a public health policy in his first keynote speech of a six-month Olympic leadership campaign.

Crochet, 25, was one of the top starting pitchers in the American League last season, posting a 3.58 ERA.

The post Red Sox viewed as a top candidate to land Garrett Crochet by pair of insiders appeared first on Boston.com.

The more romantically inclined might describe Nantucket’s signature hue as a “dusty rose” or a “sunset pink.” Candid folks may note the passing resemblance to a bad sunburn.

The post How did ‘Nantucket red’ become an island tradition? appeared first on Boston.com.

Test your knowledge of cider doughnut secrets, Pink House problems, and Jaylen Brown’s brainstorm in this week’s news quiz.

The post Did you follow the local news this week? Take our Greater Boston news quiz. appeared first on Boston.com.

Music has an undeniable influence on us as humans. Some songs make us sad; others make us happy; others we associate with memories—good or bad. ... Read more

The post How Did Grunge Music Affect Society? appeared first on CMUSE.

There's so much history to be discovered right in the heart of Boston.

The post 5 things you didn’t know about the Boston Public Library appeared first on Boston.com.

For a millennial couple buying their first home, on an island in the Puget Sound, the cost of humanely resolving the bat problem was more than they expected.

The post They thought they found their dream home — so did thousands of bats appeared first on Boston.com.

Test your knowledge of Trump trolling, atypical temps, and a radio reversal in this week’s news quiz.

The post Did you follow the local news this week? Take our Greater Boston news quiz. appeared first on Boston.com.

Sex therapists — including the one in today’s episode of the Love Letters podcast — say that a lot of people don’t really understand the range of the work.

The post I didn’t know enough about sex therapy, either appeared first on Boston.com.

For some people, running a marathon changes everything — including how you are as a partner.

The post How did a marathon change your romantic relationship? appeared first on Boston.com.

"I just felt like I didn’t fit into the situation."

The post Former Pro Bowler explains why he ‘didn’t like’ playing for the Patriots  appeared first on Boston.com.

"I had to go down with the ship, buddy."

The post Julian Edelman explains why he didn’t join Tom Brady, Rob Gronkowski on Buccaneers  appeared first on Boston.com.

Dustin and James answer YOUR most pressing questions. On this episode we cover everything from distractions to multiple services, being the authority to playing at the back of the church. You won’t want to miss these tips on living a better church life!

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The racial justice charity accepts the wording and statistics used in posts about the Chris Kaba case ‘were not as carefully expressed as they should have been’

Are we willing to reject the broken ‘as is’ and push towards a more radical new way of learning and working together?

Washington — The Senate on Sept. 29 confirmed the nominations of Mary Lu Jordan and Timothy Baker to serve as members of the Federal Mine Safety and Health Review Commission.

Madison, WI — A federal grand jury has indicted Didion Milling and six of its current and former employees on nine charges, including two willful violations of OSHA standards.

Cambridge, MA — The median time from a worker’s injury to “first medical service” was either unchanged or shorter early in the COVID-19 pandemic relative to prior years, a new report shows.

In a few weeks, we will begin publishing predictions for 2025. Prior to sharing our outlook for the year ahead, we wanted to review the predictions we made for 2024 to determine what we got right and what might not have fully taken shape.

Prior to sharing our outlook for 2025, we wanted to review the predictions we made for 2024 to determine what we got right and what might not have fully taken shape. Here, we've collected capsule information for each section of our 2024 Predictions, in areas such as sustainability, foodservice and global flavors. Within each capsule, you will find our 2024 predictions and assessments of their accuracy.

I’m a pretty proud Daddy today… I just heard my daughter Alyssa rock her interview on Focus on the Family yesterday (we record these things months prior, so I had forgot how good she was- truly amazing). You can catch the whole thing on YouTube HERE: I think my favorite part was how courageous she …

Continue reading "Did you see us on Focus?"

The post Did you see us on Focus? appeared first on Jonathan's Blog From The Source.

by Wm. Steven Humphrey

If you’re reading this, you probably know the value of the Mercury’s news reporting, arts and culture coverage, event calendar, and the bevy of events we host throughout the year. The work we do helps our city shine, but we can’t do it without your support. If you believe Portland benefits from smart, local journalism and arts coverage, please consider making a small monthly contribution, because without you, there is no us. Thanks for your support!

GOOD MORNING, PORTLAND! ????

Hmmm... let's check the calendar to see if anything interesting is happening this week, and... OH WOW, THE ELECTION IS TOMORROW. If you haven't filled out your ballot yet, allow us to help! Check out the Mercury's Election Issue (in more than 500 spots around town) which comes complete with all our endorsements AND our handy-dandy voter cheat sheet! And despite what some people might say, voting is actually a lot easier than you might think. Now let's think a little about today's NEWS.

IN LOCAL NEWS:

• Let's start with the disappointing Oregonian headline of the day:

Oh, hello... unless I overslept again and missed it, THE ELECTION HASN'T HAPPENED YET, AND THEREFORE HAS NOT BEEN "UPENDED" BY ANYTHING. Despite the inference behind this very poorly worded headline, ranked-choice voting is actually super easy, and having a "sprawling" candidate field simply means that we finally have a far more diverse group of people (not just moneyed white dudes bought and paid for by local business interests) running for office. THAT IS A VERY GOOD THING. So allow me to rewrite this headline: "Ranked-choice voting, healthy and diverse candidate field is great for Portland City Council races and democracy in general." Oh, and you are WELCOME.

Filling out your ballot this weekend? GOOD! Need help? Voila, here's your 100% accurate Mercury Endorsement Cheat Sheet to help you fill out your ballot lickety-split!https://t.co/kKi0W0Yfmd

— Portland Mercury ???? (@portlandmercury) November 2, 2024

• As we know, Portland's attempts to construct and carry out good environmental policies has been hampered by our current city council (who, again, was bought and paid for by local business interests ????). However, that could very well change with a more progressive, people-oriented council, and a significant number of current candidates are promising to change this narrative if they are elected to office on Tuesday. Find out more with this interesting report from our Taylor Griggs.

• A suspect has been arrested in the Halloween shooting at a Vancouver mall which left one person dead and two injured. Vancouver resident Travis L. Ward was taken into custody by police and members of the city's SWAT team after receiving tips from Facebook users. The shooting was allegedly a targeted attack, and the suspect—who was reportedly dressed in black and wearing a clown mask—is scheduled to appear in court today.

When Skye Baskin died, it was initially portrayed as a failure of the Oregon State Hospital. New records reviewed by OPB indicate serious failures in the Douglas County Jail preceded his death.

Jail health care remains terrible in Oregon. https://t.co/Jwm2Z1Ziik

— Ryan Haas (@ryanjhaas) November 4, 2024

• One of Oregon's conservation greats, Bob Sallinger, has died suddenly at the age of 57. Known for leading such longtime environmental groups as Willamette Riverkeeper and Bird Conservation Oregon (BCO), Sallinger was a beloved figure who, according to the board of BCO, "was a pioneer in highlighting the importance of preserving and restoring wildlife habitat in urban areas, and a key player in efforts to conserve iconic Oregon landscapes, including the Elliott Forest, Malheur National Wildlife Refuge, and the Klamath Basin." He will be missed.

Looking for fun on election night? Join your friends at Mississippi Studios for the Mercury's official election night watch party—hosted by the hilarious Alex Falcone and Shain Brenden! (And what? IT'S FREE!)https://t.co/OXyBltoyPr

— Portland Mercury ???? (@portlandmercury) November 3, 2024

IN NATIONAL/WORLD NEWS:

• Since that's all anyone can think about at the moment, here's your ELECTION EVE HEADLINE ROUNDUP: "Harris and Trump head to key battleground states for final campaign sprint." "GOP primed to back Trump if he contests election." (And he will.) "North Carolina sees turnout record with more than 4.2M ballots cast at early in-person voting sites." "Trump doesn't rule out banning vaccines if he becomes president." "Pollster Behind Shock Iowa Poll Hits Back at Trump’s Attacks." "Trump says he doesn’t mind someone shooting at journalists at rally." "Ad showing women hiding their vote from their husbands sparks conservative anger." (Hee-hee-hee!)

Univision poll: Latino voters

Harris 64%
Trump 30%

69% said the Puerto Rico garbage remark was "more racist than humorous."

Oct. 29-Nov. 3, MOE +/-5%

— Kyle Griffin (@kylegriffin1) November 4, 2024

This is NORTH CAROLINA the morning before the election. Donald Trump is on stage in 90 mins time at this 7,600 seater stadium and there are NO huge crowds outside and people are still walking in. I have never seen this at a Trump rally in a red state. pic.twitter.com/AXYFP3n7m0

— Phil Lavelle ????????/???? (@phillavelle) November 4, 2024

• The tech union for the New York Times—which helps handle such critical things as, say... oh, I don't know... election coverage—is going on strike today after management (who have reportedly known about this strike deadline for months) failed to come to an agreement with workers.

• A cyclone in the Caribbean is showing signs of developing into (yet another) hurricane this week as storm prepares to cross over Cuba and into the Gulf of Mexico.

I do believe that, despite this, she will win https://t.co/cOU7ZeWAKa

— Chase Mitchell (@ChaseMit) November 3, 2024

• RIP to one of the music industry's most prolific giants, Quincy Jones (who produced the best-selling album of all time, Michael Jackson's Thriller, as well as countless other memorable songs and movie scores) who has died at the age of 91.

• And finally... you and this goat paper towel dispenser share something in common a day before the election:

@henajahan_ #goat ♬ original sound - HenAJaHan_

by Elinor Jones

What's happening Trash Pandas? Welcome back to the Trash Report. I am Elinor Jones and I am not doing well! Lucky for us, things have been shitty often enough and recently enough that we can disassociate and do our silly little activities. How fortunate we are to live in times that challenge us! JK! I hate it!!

Well my friends, I guess we didn't coconut hard enough, because Donald Trump is headed back to the White House. A lot of people will have a lot of thoughtful breakdowns in the coming weeks and months about what went wrong, but it seems pretty obvious to me that we live in a country that hates women—Black women especially—and they like Trump. It sucks, but usually the simplest explanation is the correct one. Ad buys in Pennsylvania or door knocking in Michigan wouldn't have changed the fact that people hate women and like Trump, and even if they didn't totally love Trump, they were at least more comfortable with him in power than with a woman. Democrats spent a billion dollars to try to educate voters on why Trump is bad, but it didn't work; people know he's bad, they just don't care, or they like that part about him. They like how Trump talks more than they like the way Democrats talk, especially Democrats who are women. This handwringing about like "oh, if only people understood the real issues" and like: no. We're past that. Issues don't matter. Not only do people not care, but it also makes Democrats even less likable when we're trying to scold them over to our side. During one of my spirals I realized how weird it is that there isn't even a phrase like "owning the libs" for chuds? Like, us bullying them into silence or an embarrassing hissy fit isn't even on the damn table. Why is that? What are we doing? In hindsight the best messaging of the entire campaign was when everybody laughed at J.D. Vance for fucking a couch; if we could have had more like that in play instead of Liz fucking Cheney reminding us that Kamala Harris is pro-military and celebrities who will never worry about money insisting that Biden's economy is good, actually, we probably could have could probably have gotten some people (who voted only off vibes) to like ours better, although probably not enough to convince people not to hate women. As you can tell, I am very, very angry! Most of it is directed at Joe Biden. He should have run in 2016, he should not have run in 2020, he shouldn't have attempted a reelection campaign this year, and then he should have dropped out faster when the writing was on the wall after the debate in June. End rant. (For now. There's still a lot of juice in this tank, and it's gonna be a loooong four years.)

Trump promised RFK Jr a role overseeing health in his new administration, and the first order of business floated is removing fluoride from our nation's drinking water. This captured headlines for its absurdity. "Why in the world would we not take such an easy and impactful action to help everybody, but especially poor children, have healthier teeth? What anti-science freakshows would take issue with fluoride in the water?" "Wow, yeah, totally," said the city of Portland as we pulled our shirt collars up around our faces and sought an immediate exit from the conversation. Being part of a Venn diagram where one circle is RFK Jr. and the other circle is Portland and the middle part is "fluoride = bad" is not a good look for us.

In other news, fans allege that someone attending a recent Sabrina Carpenter concert squatted and peed in the middle of the pit before the show started. Knowing that Carpenter had just played in Portland, when I saw the headline about someone being gross at a show, I immediately assumed that it happened here. I was wrong—it was San Francisco—but that is the kind of national news I'd like our city to make and not "RFK Jr approves of Portland's municipal health initiatives." Let's go back to "Portland Sucks." Nationally, it's an easier place for us to be.

The thing that might divide my family this Thanksgiving is not politics—we are all aligned there, thank God—but whether we should first see Moana 2 or Wicked. We are leaning Moana 2, mostly because this Disney sequel is shockingly not the one unleashing inescapable product tie-ins everywhere I look. Speaking of which, the folks at Mattel did so by putting a link to a porn site on the packaging for some Glinda and Elphaba dolls and had to apologize and issue a recall. LOL. I can imagine the exhausted and overworked marketing associate who's trying to stave off sleep by occasionally watching some adult content and deliriously copy-pasting the wrong link. Look, you mass produce 10,000 different green and pink items, you're bound to screw up something.  

In other Wicked news, director Jon Chu missed the LA premiere because his wife went into labor and gave birth to a baby girl. The baby is the couple's fifth; a full three of those five children were born during the development and filming of Wicked. His wife may have told him she was proud of him, but her body was clearly saying "no sir, we are not doing that anymore." And she feels like five kids is plenty, but knows that Wicked 2 is only a year away and is debating whether a sixth baby could keep that press buzz out of their family life.

Grammy nominations came out last week, and women came out on top. Imagine if Kamala Harris won the White House during the same week that Beyoncé became the most nominated artist in Grammy history? We could have been so happy, and so annoying. Etsy would have gotten absolutely filthy with throw pillow bearing feminist catchphrases. This column would have been damn near unreadable, even more so than usual. The gods took a look at us American women as our souls threatened to leave our bodies with how badly we (at least most of us) needed a win, and said "they simply cannot have both things" and went with Grammys instead of the presidency, which isn't the direction I would have gone, but I am not a god. Yet.

A passenger got video of a raccoon falling out of the ceiling at La Guardia airport in New York City. La Guardia had just been named America's Best Airport, taking the coveted spot that PDX usually holds, and you know what? I agree. We simply need more raccoons. Trash Pandas: assemble.

Meanwhile down in South Carolina, 43 monkeys escaped a research facility and are currently on the loose. Authorities are advising residents to lock their windows, and I would definitely have a hard time doing that. I think they would like me. It's like how at Yellowstone they have to put up all the signs advising people not to approach bears. While I understand the reason for the signs, I also believe that I am a person who a bear would allow to pet it. I think monkeys would feel the same way. Any other indoor kids read Summer of the Monkeys? It's a book about a circus train that derailed and a bunch of monkeys got loose and they finally trusted one young man to return them to captivity. I think I could be that young man. Call me, South Carolina. 

I'm gonna be honest, Trash Pandas: I could keep writing this column all night. I didn't want to start working on it, but as I've been writing, and reflecting, and trying to put words to all the big things I feel, I have to admit that Doing Something does feel better than doing nothing, even though doing nothing is so tempting. We may not have fluoridated water, and we may not be pissing on the floors at arena concerts (yet), but we have each other, and I'm very grateful for that.

Togetherly,

In this week's episode we get into the primary free-for-all, from three towns that all want to be the first to vote first in the nation; to the dozens of lesser-known names on the primary ballot and what exactly they're doing there. #Politics #2016

The uber-viral children's song "Baby Shark" landed in the top 40 of the Billboard charts this week, years after it debuted on YouTube.

Andy Warhol transcended a photographer's copyright by transforming a picture of a vulnerable and uncomfortable Prince into an artwork that made the singer an "iconic, larger-than-life figure," a judge ruled Monday.

DFL Rep. Brad Tabke leads GOP challenger Aaron Paul by just 14 votes out of about 22,000 cast. That's one more vote than his lead was earlier in the week.

Sen. Tina Smith and her Republican challenger Jason Lewis sparred over the coronavirus response, public safety, climate change and immigration Friday during a debate on MPR News. 

The front-runners in Minnesota’s 1st and 3rd Congressional Districts took part in telephone debates on Politics Friday.

"God in Eternity and Time" has been well received by all segments of the Evangelical community, and its irenic spirit has been much appreciated, drawing accolades from across the Evangelical theological spectrum.

Source: REX/Shutterstock Boris Yeltsin lied when he said that he had been looking for a successor in the person of Vladimir Putin for a long time, historian Andrei Fursov told Pravda.Ru.Declassified transcripts of Bill Clinton's phone conversations with Boris Yeltsin in 1999 show that the late Russian president says that it took him long to find the man who would be in charge of Russia in 2000. "I came across him eventually, this is Putin. You will work with him," Yeltsin told Clinton promising that Putin would continue his line of Russia's democratic development and expand Russias contacts. Historian and political scientist Andrei Fursov noted in an interview with Pravda.Ru that Boris Yeltsin was reporting his decisions and ideas to Bill Clinton. "He informed his boss about his choice. It brings up the memory of Yeltsin's call to George H. Bush after the decision to disintegrate the Soviet Union. Bush was the first man whom Yeltsin called. Gorbachev was hurt by that. In another episode, Yeltsin tried to assure US Congress that communism would never be back on the Russian territory. This transcript is another evidence to prove the fact that Russia used to be a semi-colony during Yeltsin's presidency," the expert said. "I think that Yeltsin lied when he said that he had been searching for a successor for a long time. From what I know about the events of the late 1990s, Yeltsin did not intend to quit his job, but there were several aspects that forced American masters to put pressure on him. First, there was a conspiracy in the army led by Rokhlin to remove Yeltsin from power. Rokhlin's murder ruined the plan, and people in Yeltsin's team realised that there was serious discontent brewing in the army. "Secondly, not long before that, the parliament had nearly impeached Yeltsin. In addition, Russia suffered a default in 1998. Those three events drew the line under Yeltsin's rule, and he had to quickly search for a successor. Apparently, he counted on Stepashin at first, but then it turned out that the latter was ready to compromise with the Primakov-Luzhkov team, so a need in another candidate arose. "Today, the Russian leadership should give a moral assessment to Yeltsin's rule. In today's Russia, many tend to despise Gorbachev a lot, but they dislike Yeltsin to a lesser degree. Yeltsin was a product of Gorbachev's rule. Yeltsin was working within the corridor of opportunities set by Gorbachev. Gorbachev is still alive, and the man who destroyed the USSR should be held accountable for that. At the same time, I understand that Putin does not want to criticise Yeltsin because it was Yeltsin who made Putin his successor," the expert told Pravda.Ru. 

On January 11, 2023, Army General Valery Gerasimov was appointed Commander of the Russian grouping of troops in the zone of the special military operation in Ukraine. Gerasimov thus replaced General Sergei Surovikin, who became his deputy. Gerasimov has an extensive experience of army service. He fought Chechen militants at the head of the army, organised Russia's special operation in Syria, and chaired the General Staff of the Russian Armed Forces in November 2012. Valery Gerasimov was born on September 8, 1955 in Kazan, into a working class family. In 1977 he graduated from the Kazan Higher Tank Command School named after the Presidium of the Supreme Council of the Tatar Autonomous Soviet Socialist Republic (currently the Kazan Higher Tank Command Red Banner School). In 1987, he graduated with honours from the Military Academy of Armoured Forces named after Marshal of the Soviet Union Malinovsky. In 1997 — from the Military Academy of the General Staff of the Armed Forces of the Russian Federation.

Friedrich Merz, candidate for Chancellor of Germany from the Christian Democratic Union (CDU), said that he would be ready to issue Russia a 24-hour ultimatum. He also said that he could talk to the Russian President Vladimir Putin. "If there is a reason for this and an agreement is reached among European and transatlantic partners, then, of course, yes, I will call him," Friedrich Merz said. According to Merz, he will demand hostilities in Ukraine to end. Moscow will be given 24 hours to do this. If the ultimatum is not fulfilled, Merz will transfer Taurus cruise missiles to Kyiv and lift the ban on long-range strikes deep into Russian territory.

Did you feel the earth move? Mini-earthquake recorded on Shropshire/Staffordshire border  Express & Star

The title compound, C17H17BN3I, is a type of di­aza­borinane featuring substitution at the 1, 2, and 3 positions of the nitro­gen–boron six-membered heterocycle. The organic mol­ecule has a planar structure, the dihedral angle between the pyridyl ring and the fused ring system being 3.46 (4)°. In the crystal, mol­ecules are stacked in a head-to-tail manner. The iodide ion makes close contacts with three organic mol­ecules and supports the alternating stack.

The cation of the title hydrated salt, C17H17BN3+·I−·H2O, is a di­aza­borinane featuring substitution at the 1, 2, and 3 positions in the nitro­gen–boron six-membered heterocycle. The cation is approximately planar with a dihedral angle between the pyridyl ring and the di­aza­borinane ring system of 5.40 (5)°. In the crystal, the cations stack along [100] in an alternating head-to-tail manner, while the iodide ion and water mol­ecule form one-dimensional hydrogen-bonded chains beside the cation stack. The cation stacks and I−–water chains are crosslinked by N—H⋯I and N—H⋯O hydrogen bonds.

By studying the structures of (μ-1,4,10,13-tetra­thia-7,16-di­aza­cyclo­octa­deca­ne)bis[iodidopalladium(II)] diiodide penta­(diiodine), [Pd2I2(C12H26N2S4)](I)2·5I2 or [Pd2I2([18]aneN2S4)](I)2·(I2)5, and 4,7,13,16,21,24-hexa­oxa-1,10-diazo­niabi­cyclo­[8.8.8]hexa­cosane triiodide iodide hemi­penta­(diiodine) di­chloro­methane mono­solvate, C18H38N2O62+·I3−·I−·2.5I2·CH2Cl2 or [H2([2.2.2]cryptand)](I3)(I)(I2)2.5·CH2Cl2, we confirm the structural variety of extended polyiodides achievable upon changing the shape, charge and dimensions of the cation template, by altering the synthetic strategy adopted and/or the experimental conditions. Although it is still often difficult to characterize discrete [I2m+n]n− polyiodides higher than I3− on the basis of structural parameters, such as I—I bond distances, FT–Raman spectroscopy appears to identify them as aggregates of I2, I− and (symmetric or slightly asymmetric) I3− building blocks linked by I⋯I inter­actions of varying strengths. However, because FT–Raman spectroscopy carries no information about the topological features of extended polyiodides, the two techniques should therefore be applied in combination to enhance the analysis of this kind of compounds.

The structures of 16 phosphane chalcogenide complexes of gold(I) halides, with the general formula R13-nR2nPEAuX (R1 = t-butyl; R2 = isopropyl; n = 0 to 3; E = S or Se; X = Cl, Br or I), are presented. The eight possible chlorido derivatives are: 1a, n = 3, E = S; 2a, n = 2, E = S; 3a, n = 1, E = S; 4a, n = 0, E = S; 5a, n = 3, E = Se; 6a, n = 2, E = Se; 7a, n = 1, E = Se; and 8a, n = 0, E = Se, and the corresponding bromido derivatives are 1b–8b in the same order. However, 2a and 2b were badly disordered and 8a was not obtained. The iodido derivatives are 2c, 6c and 7c (numbered as for the series a and b). All structures are solvent-free and all have Z' = 1 except for 6b and 6c (Z' = 2). All mol­ecules show the expected linear geometry at gold and approximately tetra­hedral angles P—E—Au. The presence of bulky ligands forces some short intra­molecular contacts, in particular H⋯Au and H⋯E. The Au—E bond lengths have a slight but consistent tendency to be longer when trans to a softer X ligand, and vice versa. The five compounds 1a, 5a, 6a, 1b and 5b form an isotypic set, despite the different alkyl groups in 6a. Compounds 3a/3b, 4b/8b and 6b/6c form isotypic pairs. The crystal packing can be analysed in terms of various types of secondary inter­actions, of which the most frequent are `weak' hydrogen bonds from methine hydrogen atoms to the halogenido ligands. For the structure type 1a, H⋯X and H⋯E contacts combine to form a layer structure. For 3a/3b, the packing is almost featureless, but can be described in terms of a double-layer structure involving borderline H⋯Cl/Br and H⋯S contacts. In 4a and 4b/8b, which lack methine groups, Cmeth­yl—H⋯X contacts combine to form layer structures. In 7a/7b, short C—H⋯X inter­actions form chains of mol­ecules that are further linked by association of short Au⋯Se contacts to form a layer structure. The packing of compound 6b/6c can conveniently be analysed for each independent mol­ecule separately, because they occupy different regions of the cell. Mol­ecule 1 forms chains in which the mol­ecules are linked by a Cmethine⋯Au contact. The mol­ecules 2 associate via a short Se⋯Se contact and a short H⋯X contact to form a layer structure. The packing of compound 2c can be described in terms of two short Cmethine—H⋯I contacts, which combine to form a corrugated ribbon structure. Compound 7c is the only compound in this paper to feature Au⋯Au contacts, which lead to twofold-symmetric dimers. Apart from this, the packing is almost featureless, consisting of layers with only translation symmetry except for two very borderline Au⋯H contacts.

4,4'-(Disulfanedi­yl)dipyridinium chloride triiodide, C10H10N2S22+·Cl−·I3−, (1) was synthesized by reaction of 4,4'-di­pyridyl­disulfide with ICl in a 1:1 molar ratio in di­chloro­methane solution. The structural characterization of 1 by SC-XRD analysis was supported by elemental analysis, FT–IR, and FT–Raman spectroscopic measurements.

The reaction of cadmium iodide with 3-amino­pyrazole (3-apz) in ethano­lic solution leads to tautomerization of the ligand and the formation of crystals of the title compound, catena-poly[[di­iodido­cadmium(II)]-bis­(μ-3-amino-1H-pyrazole)-κ2N2:N3;κ2N3:N2], [CdI2(C3H5N3)2]n or [CdI2(3-apz)2]n. Its asymmetric unit consists of a half of a Cd2+ cation, an iodide anion and a 3-apz mol­ecule. The Cd2+ cations are coordinated by two iodide anions and two 3-apz ligands, generating trans-CdN4I2 octa­hedra, which are linked into chains by pairs of the bridging ligands. In the crystal, the ligand mol­ecules and iodide anions of neighboring chains are linked through inter­chain hydrogen bonds into a di-periodic network. The inter­molecular contacts were qu­anti­fied using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative qu­anti­tative contributions of the weak inter­molecular contacts.

The title organic–inorganic hybrid salt, C2H7IN+·I−, is isotypic with its bromine analog, C2H7BrN+·Br− [Semenikhin et al. (2024). Acta Cryst. E80, 738–741]. Its asymmetric unit consists of one 2-iodo­ethyl­ammonium cation and one iodide anion. The NH3+ group of the organic cation forms weak hydrogen bonds with four neighboring iodide anions, leading to the formation of supra­molecular layers propagating parallel to the bc plane. Hirshfeld surface analysis reveals that the most important contribution to the crystal packing is from N—H⋯I inter­actions (63.8%). The crystal under investigation was twinned by a 180° rotation around [001].

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