Faraday Discuss., 2024, 253,289-313
DOI: 10.1039/D4FD90035A, Discussion

Andrew P. Abbott, Rob Atkin, Duncan W. Bruce, Paola Carbone, Giacomo Damilano, Robert A. W. Dryfe, Jean-Francois Dufrêche, Karen J. Edler, Y. K. Catherine Fung, Kateryna Goloviznina, Margarida Costa Gomes, Alexis Grimaud, Timothy S. Groves, Jennifer M. Hartley, John D. Holbrey, Christian Holm, Pierre Illien, Roland Kjellander, Alexei Kornyshev, Kevin R. J. Lovelock, Daniel M. Markiewitz, Joshua Maurer, Shurui Miao, Naoya Nishi, Beatriz Rocha de Moraes, Bernhard Roling, Benjamin Rotenberg, Joshua Sangoro, Nicolas Schaeffer, Monika Schönhoff, David J. Sconyers, John M. Slattery, Małgorzata Swadźba-Kwaśny, Adriaan van den Bruinhorst, Tom Welton
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02023E, Research Article

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Roberto Paciotti, Davide Corinti, Cecilia Coletti, Nazzareno Re, Giel Berden, Jos Oomens, Simonetta Fornarini, Maria Elisa Crestoni
The [(Et₃P)AuCys]⁺ and [(Et₃P)AuSec]⁺ ions and their deamination products were characterized using IRMPD spectroscopy backed by DFT calculations finding differences in binding motifs and reactivity.
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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article

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Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Inorg. Chem. Front., 2024, 11,8139-8145
DOI: 10.1039/D4QI02061H, Research Article

Nan Li, Lujiao Mao, Yuting Fu, Haoran Wang, Yuchang Shen, Xuemei Zhou, Qipeng Li, Jinjie Qian
This study demonstrates a new approach for Ru-anchoring CoOF-1-derived porous Ru-Co₃O₄ nanomaterials with high activity and durability, showcasing great potential in the field of practical energy storage and conversion.
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Inorg. Chem. Front., 2024, 11,8147-8147
DOI: 10.1039/D4QI90073A, Correction

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Maddalena Paolillo, Giarita Ferraro, Irene Cipollone, Eugenio Garribba, Maria Monti, Antonello Merlino
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Lab Chip, 2024, 24,2176-2192
DOI: 10.1039/D3LC00912B, Paper

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Priscilla Delgado, C. Alessandra Luna, Anjana Dissanayaka, Oluwamayokun Oshinowo, Jesse J. Waggoner, Sara Schley, Todd Fernandez, David R. Myers
This activity enables students to construct geometrically complex microfluidics at their desk with no specialized equipment. It can be easily transported, and helped students significantly improve their understanding of miniaturization science.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00931A, Perspective

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Fu Der Chen, Ankita Sharma, David A. Roszko, Tianyuan Xue, Xin Mu, Xianshu Luo, Hongyao Chua, Patrick Guo-Qiang Lo, Wesley D. Sacher, Joyce K. S. Poon
We explore the development of multifunctional nanophotonic neural probes, integrating microelectrodes, optical emitters, and microfluidic channels for multimodal brain mapping.
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RSC Adv., 2024, 14,12147-12157
DOI: 10.1039/D4RA01483A, Paper

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Pham Hai Yen, Bui Huu Tai, Dan Thi Thuy Hang, Le Doan Tung Lam, Duong Thi Dung, Do Thi Trang, Duong Thi Hai Yen, Nguyen Huy Hoang, Phan Thi Thanh Huong, Nguyen Viet Dung, Ngo Anh Bang, Nguyen Duc Duy, Phan Van Kiem
Seven new oleanane saponins were discovered from Dendrobium officinale. These saponins containing 29-noroleana-12,20(30)-dien-28-oic acid framework, caffeoyl, and coumaroyl moieties potentially inhibited α-glucosidase and α-amylase activities.
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RSC Adv., 2024, 14,12303-12312
DOI: 10.1039/D3RA08750F, Paper

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Chenyang Xue, Xinmiao Xu, Han Lyu, Yunfeng Li, Yangang Ren, Jinhe Wang, Yujing Mu, Abdelwahid Mellouki, Zongzheng Yang
The relative position of two CC on the acyclic dienes could determine its reactivity. The number and type of alkyl group and the number of addition sites on diene could also strongly affect its reactivity toward OH radical.
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RSC Adv., 2024, 14,12883-12887
DOI: 10.1039/D4RA02616K, Paper

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Zheng-Ying Wang, Shi-Zheng Liu, Cong Guo, Yi-Zheng Cheng, Qiang Li, Jianmin Dou, Dacheng Li
Nickel-catalyzed cross-electrophile coupling of cyclopropyl ketones and alkyl chlorides. High reactivity and selectivity can be achieved with sodium iodide as a cocatalyst that generates a low concentration of alkyl iodide via halide exchange.
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RSC Adv., 2024, 14,13062-13082
DOI: 10.1039/D3RA08574K, Paper

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Sathish Thanigachalam, Madhvesh Pathak
Five new homoleptic derivatives of titanium(IV) have been developed and characterized by physicochemical techniques.
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RSC Adv., 2024, 14,13129-13141
DOI: 10.1039/D4RA01683A, Paper

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Marcin Cybulski, Magdalena Zaremba-Czogalla, Bartosz Trzaskowski, Marek Kubiszewski, Joanna Tobiasz, Anna Jaromin, Piotr Krzeczyński, Jerzy Gubernator, Olga Michalak
New conjugates 1–6 containing 5-dFCR and selected hydroxycinnamic acids were synthesized and tested in vitro against pancreatic cancer (PDAC) lines. The ADME properties and molecular docking to CES2 or human albumin were discussed.
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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00185G, Communication

Pricilla Matseketsa, Donovan Mafukidze, Lahiru Pothupitiya, Udo P. Otuonye, Yasemin Çimen Mutlu, Boris B. Averkiev, Tendai Gadzikwa
The reactivity of hydroxyl-bearing MOF linkers with isocyanates is influenced by their mutual confinement with amine-bearing linkers within the pores of the framework.
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J. Mater. Chem. B, 2024, 12,11156-11164
DOI: 10.1039/D4TB01521E, Paper

Sandra Mena-Gutiérrez, Ekain Maiza-Razkin, Jon Pascual-Colino, Marcos J. Araúzo-Bravo, Garikoitz Beobide, Oscar Castillo, Ainara Castellanos-Rubio, Daniela Gerovska, Antonio Luque, Sonia Pérez-Yáñez
Supramolecular metal-organic porous materials as drug delivery systems, modulation of the release kinetics using cholesterol as pore blocking agent and its impact on colorectal cancer cell cultures: cytotoxicity and RNA-seq transcriptomics studies.
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Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01227E, Paper

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Amanda D. French, Kirby P. Hobbs, Richard M Cox, Isaac J. Arnquist
Interference removal in inductively coupled plasma tandem mass spectrometry (ICP-MS/MS) is strongly dependent on the gas selected for use within the collision/reaction cell.
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Phys. Chem. Chem. Phys., 2024, 26,27245-27247
DOI: 10.1039/D4CP90153C, Editorial

Adam A. L. Michalchuk, Francesco Delogu
This themed collection includes a collection of articles on the fundamental basis of mechanochemical reactivity.
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Phys. Chem. Chem. Phys., 2024, 26,27371-27381
DOI: 10.1039/D4CP03102D, Paper

Zidi Zhu, Daoming Huan, Jingchao Yuan, Dan Zhang, Aijun Li, Jiujun Zhang
This study constructs a multiphysics model that successfully replicates experimental results, introducing an improved Thiele modulus to enhance the prediction of catalytic activity in hierarchical nanostructured SOFC electrodes.
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03779K, Paper

Jiaxiang Wu, Erjun Kan, Cheng Zhan
Promising ORR/OER single atom catalysts have been designed in the form of TM–N₂X via DFT simulation.
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03237C, Paper

Amin Kiani, Wentong Zhou, Lawrence M. Wolf
The development and application of intermolecular interaction potential maps to rationalize a range of interactions at the DFT level using suitable probes is described.
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04919E, Communication

Shuran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guangjuan Xu, Wei Xie, Na Xu, Yanhong Xu, Yaqian Lan
UiO-66-NH2 with different aggregation morphology are prepared to verify the morphology of photocatalysts could influence the charge transfer. Among them, UiO-66-NH2 with the poor aggregation exhibits superior performances over CO2...
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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication

Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)₂ at 23 °C.
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00808A, Paper

Tetsuo Umegaki, Takeru Nakamura, Yoshiyuki Kojima
This work investigated influence of ammonia addition in the immersion process of active species on dispersion and activity of copper supported porous hollow silica-alumina spheres catalysts for decomposition of nitrous...
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00209A, Paper

Vu Ngoc Toan, Nguyen Dinh Thanh, Do Son Hai, Nguyen Minh Tri
A series of thioureas 7a-k containing pyrimidine and D-glucose moiety have been synthesized through the reaction between substituted 2-aminopyrimidines 3a-k and tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate 6. The yields achieved were 55‒77%. The...
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New J. Chem., 2024, 48,7334-7339
DOI: 10.1039/D4NJ00883A, Paper

Min Zhang, Yanhong Dong, Qingshuang Li, Xiaoyan Li, Hongjian Sun
Three silyl [PSiP] pincer cobalt(II) chlorides [(2-Ph₂PC₆H₄)₂MeSiCo(Cl)(PMe₃)] (1), [(2-ⁱPr₂PC₆H₄)₂MeSiCo(Cl)(PMe₃)] (2) and [(2-Ph₂PC₆H₄)₂MeSiCo(Cl)(LSi:)] (LSi: = {PhC(N^tBu)₂}SiCl) (3) were used as catalysts for dinitrogen silylation was studied.
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New J. Chem., 2024, 48,7244-7255
DOI: 10.1039/D4NJ01100G, Paper

Jesús A. Lara-Cerón, Roberto Flores-Moreno, José A. Flores-Ramos, Gururaj K. Jayaprakash
Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors.
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New J. Chem., 2024, 48,7070-7080
DOI: 10.1039/D4NJ00704B, Paper

Muthukumaran Sangamithirai, Venkatachalam Ashok, Arunagiri Gayathri, Murugan Vijayarangan, Jayaraman Jayabharathi
Citrus sap-stabilized RCoFe nanoplatelets were synthesized by simple co-precipitation, and are highly efficient and stable electrocatalysts for solar cell water splitting (1.56 V).
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New J. Chem., 2024, 48,7134-7147
DOI: 10.1039/D4NJ00430B, Paper

Iveta S. Turomsha, Maxim Y. Gvozdev, Nikolai P. Osipovich, Viktoryia A. Staravoitava, Dmitriy I. Shiman, Natalia V. Loginova
Phenolic Schiff bases and their Cu(II) complexes have been synthesized and characterized by physicochemical methods. The complexes exhibit low cell toxicity and high antioxidant and antibacterial activity, as evidenced by molecular docking studies.
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New J. Chem., 2024, 48,7197-7204
DOI: 10.1039/D4NJ00509K, Paper

Han Zhang, Xiaodan Qi, Zhifei Wang, Lihua Jin, Yehua Shen
An Fe and N co-decorated biomass-derived porous carbon framework with boosted oxidase-like activity was prepared and applied to sensitive hydroquinone detection.
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00801D, Paper

Yan Yin, Wenhui Song, Yinhu Ai, Weiying Lin
Evaluation of the antiepileptic activity of hesperidin via near-infrared fluorescence imaging based on viscosity.
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper

Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00563E, Paper

Sravanthi Baddepuri, G. Rama Krishna, Jyothi Kumari, Sriram Dharmarajan, Srinivas Basavoju
The aim of the study is to develop the synthesis of a novel series of potent anti-tubercular (anti-TB) activity of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidine derivatives via an efficient green approach achieved by...
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00978E, Paper

Lian Zhang, Xiaona Li, Le Yue, Xuesong Cao, Bingxu Cheng, Chuanxi Wang, Zhenyu Wang
Herein, the effect of selenium engineered nanomaterials (Se ENMs) on soybean photosynthesis and fatty-acid synthesis by regulating ferredoxin (Fd) and iron–sulfur (Fe/S) protein synthesis and acetyl CoA carboxylase (ACC) activity was explored.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00883E, Paper

Lucija Božičević, Korinna Altmann, Jana Hildebrandt, Xenia Knigge, Valerije Vrček, Nikolina Peranić, Nikolina Kalčec, Ivana Vinković Vrček
This study provides science-based evidence on endocrine disrupting effects of polyethylene, polystyrene and polypropylene nanoparticles and their mixtures indicating the importance of hazard assessment of aggregate exposure to nanoplastics.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00839H, Paper

S. Aisvarya, M. Kalyanasundaram, M. Kannan, P. Arunkumar, S. Preetha, K. Elango, K. Govindaraju
Utilizing environmentally friendly nanomaterials to address insect pests and promote plant growth is imperative.
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper

Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
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Environ. Sci.: Nano, 2024, 11,1412-1416
DOI: 10.1039/D3EN00884C, Communication

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Christopher J. Thompson, Sebastian T. Mergelsberg, Bavan P. Rajan, Paul F. Martin, Sebastien N. Kerisit, John S. Loring
Temperature modulation was demonstrated as a novel way to control water partitioning during the reaction of silicate minerals with water-saturated supercritical carbon dioxide.
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CrystEngComm, 2024, 26,2103-2111
DOI: 10.1039/D4CE00171K, Paper

Zikun Yang, Jingxuan Zheng, Mengge Shi, Zhao Wang
Single-atom Au₁/TiO₂-DBD catalysts were synthesised using DBD plasma and glow plasma, and the synergistic effect of single-atom Au and oxygen vacancies improved the degradation performance.
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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper

Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00333K, Paper

Peng Liu, Jiajian Peng, Ying Bai, Jiayun Li
A series of siloxane-containing phosphine (oxide) ligands have been designed and synthesized.
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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00256C, Paper

Min Zhang, Liang Shi, Li Chen, Zhengyu Liu, Ting Zhao, Chunyin Zhu, Liuqing Yang
A total of 27 novel spirooxindoles were synthesized through a water mediated three-component reaction of isatin, 4-aminocoumarin, and 1,3-cyclodicarbonyl compounds. Several compounds showed excellent antifungal activity against Physalospora piricola.
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Org. Biomol. Chem., 2024, 22,3009-3018
DOI: 10.1039/D4OB00211C, Paper

Yu-Ke Cen, Lin Zhang, Yue Jiang, Xiang-Fu Meng, Yuan Li, Chao Xiang, Ya-Ping Xue, Yu-Guo Zheng
A single-point mutation of 7α-HSDH achieved the highest activity and synergistically improved substrate tolerance, thermal stability, cofactor affinity, and conversion rate.
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Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00822G, Research Article

Muhammad Faisal Iqbal, Mengjiao Li, Tao Xu, Junchao Lou, Weitao Wang, Jing Zhang, Enlai Hu, Pan Xu
Owing to its greater specific surface area and electrical conductivity, mesoporous nature and leaf-like structure, Fe@ZIF-67-2 showed an overpotential of 45 mV and a Tafel slope of 32 mV dec⁻¹ along with a TOF of 129.35 ms⁻¹ in 1 M KOH.
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Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM90073A, Correction

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Jia Wang, Wenling Zhang, Ting Wu, Haisi Wu, Yuan Zhang, Siwan Wang, You Ji, Hui Jiang, Ziting Zhang, Chunming Tang, Qiyun Tang, Xiaolin Li, Huae Xu
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA05885B, Paper

Cláudia de Lourenço, Ana Beatriz Sorana de Araujo, Leonardo Hideki Hasimoto, Isaque A.A. Feitosa, Matheus Felipe Fagundes das Neves, Jefferson Bettini, Tarcísio Micheli Perfecto, Tulio C. R. Rocha, Thiago J.A. Mori, Edson R. Leite, Murilo Santhiago
Introducing surface defects on molybdenum disulfide (MoS₂) crystals plays a crucial role in enhancing the electrocatalytic activity toward the hydrogen evolution reaction (HER). Despite the remarkable progress in this area,...
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J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper

Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06655C, Paper

Yaroslav Zhigalenok, Saken Abdimomyn, Mikhail Levi, Netanel Shpigel, Margarita Ryabicheva, Maxim Lepikhin, Alina Galeyeva, Fyodor Malchik
Aqueous electrolytes offer enhanced safety and environmental friendliness for next-generation energy storage systems, but their application is limited by a narrow electrochemical stability window. This study provides a comprehensive analysis...
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper

Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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