ter Identification and quantification of local antiaromaticity in polycyclic aromatic hydrocarbons (PAHs) based on the magnetic criterion By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, 22,3035-3044DOI: 10.1039/D4OB00114A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Erich Kleinpeter, Andreas KochThe ring current effect of entirely and partly (anti)aromatic PCHs are calculated and employed to visualize, qualify and quantify existing (anti)aromaticity, especially to decide unequivocally between PAHs and PAAHs.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Stereoselective synthesis of (R)- and (S)-1,2-diazetidine-3-carboxylic acid derivatives for peptidomimetics By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, 22,2974-2977DOI: 10.1039/D4OB00278D, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew Nutter, Henry Stone, Michael Shipman, Stefan RoesnerStereoselective synthesis of both enantiomers of orthogonally protected 1,2-diazetidine-3-carboxylic acid (aAze) from homochiral glycidol and its application in peptidomimetics.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Additive-free oxychlorination of unsaturated C–C bonds with tert-butyl hypochlorite and water By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, 22,3080-3085DOI: 10.1039/D4OB00003J, PaperDuyi Shen, Chaoyue Sun, Yun Han, Zhen Luo, Ting Ren, Qin Zhang, Wenting Huang, Jianru Xie, Ying Jia, Mianran ChaoA facile oxychlorination of various alkynes and alkenes with tBuOCl as an alternative chlorine source and H2O as a green oxygen source.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Photochromism of phenazine-2,3-diol derivatives through excited state intermolecular proton transfer based on keto–enol tautomerization By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00387J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kazuki Ohira, Kumpei Kozuka, Naoki Kaneda, Masahiro Yamamoto, Keiichi Imato, Yousuke OoyamaIt was found that phenazine-2,3-diol derivatives exhibit photochromism through excited state intermolecular proton transfer (ESInterPT) processes based on keto–enol tautomerization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Nickel-catalysed regio- and stereoselective hydrocyanation of alkynoates and its mechanistic insights proposed by DFT calculations By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00380B, CommunicationShigeru Arai, Koichi Nakazawa, Xiao-Fei Yang, Masaya Nakajima, Shinji Harada, Atsushi NishidaThis work discloses the origin of regio- and stereoselectivity of hydrocyanation of alkynoates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Revisiting Biginelli-like Reactions: Solvent Effects, Mechanisms, Biological Applications and Correction of Several Literature Reports By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00272E, PaperBrenno A. D. Neto, Pedro Beck, Arthur Leitão, Yasmin Santana, Jose R. Correa, Carime Vitória da Silva Rodrigues, Daniel Machado, Guilherme Matos, Luciana Machado Ramos, Claudia Cristina Gatto, Carlos Kleber Z. Andrade, Sarah CaldasThis study critically reevaluates reported Biginelli-like reactions using a Kamlet-Abboud-Taft-based solvent effect model. Surprisingly, structural misassignments were discovered in certain multicomponent reactions, leading to the identification of pseudo three-component derivatives...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Recent developments in the enzymatic modifications of steroid scaffolds By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00327F, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Huibin Wang, Ikuro AbeThis review highlights the recent advancements in the enzymatic modifications of steroid scaffolds, emphasizing enzymatic hydroxylation, ketoreduction, dehydrogenation, enzymatic cascade reactions, and other modifications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Synthesis of Deuteriodifluoromethylthiolated Isocoumarins-1- imines and Isocoumarins Enabled by Multi-Component Reagents System (MCRS) By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00328D, CommunicationXuemin Li, Haofeng Shi, Jiaxin He, Jialiang Wu, Fengxia Sun, Yunfei DuThe combining use of BnSCF2D, mCPBA and Tf2O serves as an efficient multi-component reagents system (MCRS) for the synthesis of deuteriodifluoromethylthiolated isocoumarins-1-imines/isocoumarins via intramolecular cyclization/ deuteriodifluoromethylthiolation of 2-alkynylbenzamide/2-alkynylbenzoates. The approach...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Measuring local pH at interfaces from molecular tumbling: A concept for designing EPR-active pH-sensitive labels and probes By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00167B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Maxim A. Voinov, Nicholas Nunn, Roshan Rana, Atli Davidsson, Alex I. Smirnov, Tatyana I. SmirnovaEPR-based local pH measurements based on changes in rotational dynamics of spin-bearing molecules upon protonation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter A Highly Diastereoselective One-Pot Ugi/Radical Spirocyclization/Aza-Michael Addition Sequence By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00610K, CommunicationChandra Volla, Salman Khan, Abhradeep Chatterjee, Akshay Murali NairWe hereby report a highly diastereoselective synthesis of chalcogenated azaspirotricycles via a one-pot Ugi/spirocyclization/ aza-Michael addition sequence. The reaction proceeded via a key visible light mediated spirocyclization step under mild,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Wanted: A booster dose for airlines By www.thehindubusinessline.com Published On :: Sun, 27 Jun 2021 12:55:40 +0530 As vaccination numbers increase, airlines and the government look for the middle path to revive the beleagured travel sector Full Article Flight Plan
ter Travel now, pay later By www.thehindubusinessline.com Published On :: Sun, 10 Jul 2022 16:50:00 +0530 Revenge travel has led to an increase in ‘buy now, pay later’ aggregators Full Article Flight Plan
ter Google to develop AI that takes over computers: Report By www.thehindu.com Published On :: Mon, 28 Oct 2024 09:20:28 +0530 Google is developing AI technology that takes over a web browser to complete tasks such as research and shopping, The Information reported Full Article Technology
ter Amazon's improving retail sales boost third-quarter profit, revenue beats estimates By www.thehindu.com Published On :: Fri, 01 Nov 2024 10:16:16 +0530 Like its tech peers, Amazon said it expected higher capital expenditures for the foreseeable future to help develop artificial intelligence software Full Article Technology
ter Indonesia bans sales of Google phones days after blocking Apple's iPhone 16 By www.thehindu.com Published On :: Fri, 01 Nov 2024 13:36:42 +0530 Indonesia said it has banned sales of smartphones made by Alphabet's Google due to rules requiring the use of locally manufactured components Full Article Technology
ter Transformation Stories #4 A New Podcast Interview With Me (Rob Larsen) By htmlcssjavascript.com Published On :: Wed, 28 Feb 2024 18:33:05 +0000 Check out yours truly on an episode of Atlas Systems’ Transformation Stories. A hands-on leader and change-maker with 20 years of experience, Rob Larsen remains at the forefront of software-led innovation – in financial services and the larger enterprise world. In this all-new conversation with Atlas Systems, Larsen offers insights into finding the right pace […] Full Article CSS HTML Web
ter Will not allow dilution of AIIMS brand: Union Health Minister J. P. Nadda By www.thehindu.com Published On :: Mon, 21 Oct 2024 15:33:33 +0530 The Health Minister said no compromises will be made in faculty recruitments or standards of teaching at any of the new AIIMS institutes being set up across the country Full Article Health
ter Dietary restriction or good genes: new study tries to unpack which has greater impact on lifespan By www.thehindu.com Published On :: Mon, 21 Oct 2024 16:50:20 +0530 If we know that genetics and lifestyle affect how long you live, which one is more important? And how do they interact? Full Article Health
ter Should men be allowed into operation theatres when their wives are having a baby? Doctors weigh in after YouTuber’s video sparks controversy By www.thehindu.com Published On :: Tue, 22 Oct 2024 21:52:17 +0530 YouTuber Irfan recently posted a video on social media that showed him cutting the umbilical cord of his newborn, in the operation theatre of a private hospital in Chennai; consent of the medical personnel involved to being videoed was another aspect doctors say needs discussion Full Article Health
ter Air pollution: Centre warns of the rising ill-effects of deteriorating air quality By www.thehindu.com Published On :: Fri, 25 Oct 2024 15:41:18 +0530 In a letter to States and UTs, the Director General of Health Services Atul Goel has said to discourage stubble and waste burning, and spread awareness among people about reducing firecrackers during festivities Full Article Health
ter Polio in Pakistan: Another vaccination campaign begins after worrying surge By www.thehindu.com Published On :: Mon, 28 Oct 2024 13:27:32 +0530 Pakistan regularly launches such campaigns, but violence targeting the health workers and police assigned to escort them is common Full Article World
ter What is stereotactic radiation therapy for prostate cancer? How does it compare to other treatments? By www.thehindu.com Published On :: Mon, 28 Oct 2024 17:06:09 +0530 Stereotactic radiotherapy uses high doses of radiation to target and kill cancer cells; it uses newer machines that can deliver very focused radiation beams Full Article Health
ter ICMR invites expression of interest from firms for making anaemia detection device By www.thehindu.com Published On :: Wed, 30 Oct 2024 19:45:56 +0530 The council wants to expand the effective screening network of anaemia among different age populations across India Full Article India
ter Tiruchi man with mpox symptoms: Sample has returned negative, says Tamil Nadu Health Minister By www.thehindu.com Published On :: Sat, 02 Nov 2024 20:57:07 +0530 The man, who had returned from Sharjah on October 31, was found to have fever during screening on arriving at the Tiruchi airport. Full Article Health
ter National Task Force files interim report on safety measures for hospital staff By www.thehindu.com Published On :: Thu, 07 Nov 2024 15:18:08 +0530 NTF report has suggested short term, medium, and long term measures to protect doctors and medical staff in their workplaces. Full Article India
ter 'Once in a blue moon you get a lottery like Animal' By www.rediff.com Published On :: Thu, 11 Jan 2024 10:04:01 +0530 'It has never happened that all Top 5 songs on Spotify are from one film. On the Ormax list, the Top 9 are from Animal.''The music is good, sure. But everything has taken off with Animal the film.' Full Article
ter Meet Fighter's Evil Villain! By www.rediff.com Published On :: Tue, 06 Feb 2024 12:05:17 +0530 'Coming out of a burning building with a machine gun in your hand, that is badass because you don't get to do that in real life.' Full Article
ter 'They'd say act like your sister!' By www.rediff.com Published On :: Tue, 16 Apr 2024 14:40:08 +0530 'Padmini and I are very different people.''Our acting styles are very different. She's from a different era.' Full Article Tejaswini Kolhapure Scoop Yes Papa Bollywood actor Tejaswini Kolhapure Interview Shraddha Kapoor Padmini Kolhapure
ter EXCLUSIVE! The Payal Kapadia Interview By www.rediff.com Published On :: Mon, 27 May 2024 11:22:33 +0530 'Hope is about being more accepting of each other, the kind of solidarity and friendship that even our families may not be able to give.' Full Article
ter 'At Times, Life Has Better Plans For You' By www.rediff.com Published On :: Thu, 22 Aug 2024 11:34:01 +0530 'You have to keep working hard.''The universe sees that in you and the higher power puts those opportunities in your way.' Full Article Dhairya Karwa Gyaarah Gyaarah Umesh Bist Karan Johar Guneet Monga Dhairya Karwa Interview Bollywood Actor Rediff Interview
ter The Man Behind Bollywood's Blockbuster Horror Films By www.rediff.com Published On :: Wed, 18 Sep 2024 10:07:38 +0530 'People worship Krishna. People don't worship Ved Vyas, who wrote the Mahabharata.''It's a cultural thing because we don't see the heroes behind the screen, we see the heroes who are in front of the screen.' Full Article
ter THE MUST READ REKHA INTERVIEW! By www.rediff.com Published On :: Mon, 07 Oct 2024 12:39:11 +0530 'At one time, I felt being a mother was the ultimate experience, a woman was not complete without it.''Now I feel it's not the be all and end all. Motherhood is a part of a jigsaw puzzle; life is the real big picture.' Full Article Rekha Amitabh Bachchan Amitji IMAGE James Dean Mumtaz Dinesh Raheja Ram Ram Yashji God Silsila Nani Umrao Jaan Madam Hollywood Chopra
ter 60fps scrolling using pointer-events: none By www.thecssninja.com Published On :: Mon, 25 Nov 2013 10:30:36 +0000 Paul Lewis did an interesting article a while back about avoiding unnecessary paints through disabling hover effects as the user scrolls, which is a great approach. The down side being managing all your hover states through a parent class. UPDATE: I’ve done a follow up article which demonstrates a more robust technique. .hover .element:hover { … Continue reading "60fps scrolling using pointer-events: none" Full Article css javascript
ter How I built my earthin24 twitter bot By www.thecssninja.com Published On :: Sat, 26 Aug 2017 05:43:36 +0000 At work my team have recently taken over a golang app. To learn a new language I like to build something that keeps my interest and by the nature of exploring something of interest you tend to cover way more surface area of a language this way. 🌏 12pm 25th August – 12pm 26th August … Continue reading "How I built my earthin24 twitter bot" Full Article golang hacking
ter OnePlus 13 launched with Snapdragon 8 Gen 4 SoC: Price details, battery and other specifications By www.dnaindia.com Published On :: Fri, 01 Nov 2024 07:10:00 GMT While the OnePlus 13 has only been revealed in China so far, speculations are that it will arrive on the global market in the coming months. In India, the phone is expected to be launched in January 2025. Full Article Technology
ter 25 Billion Kilometers and Broken Voice: The Voyager 1 Saga By www.dnaindia.com Published On :: Fri, 01 Nov 2024 08:25:00 GMT NASA's Voyager 1 Faces Technical Glitch in Deep Space, says Girish Linganna Full Article Technology Science
ter ‘Dance matters most’ By www.thehindu.com Published On :: Fri, 29 Jul 2016 16:28:49 +0530 Actress and up-and-coming dancer Mahalakshmi S. performs in the city today Full Article Metroplus
ter Tribute to the master By www.thehindu.com Published On :: Thu, 01 Sep 2016 23:00:22 +0530 The recent two-day dance festival organised by Debdhara brought an eclectic mix of Odissi and Kathak recitals on stage. Full Article Friday Review
ter Master flautist at work By www.thehindu.com Published On :: Sun, 04 Sep 2016 14:16:32 +0530 Celebrating the myriad forms of Lord Krishna Full Article Metroplus
ter It doesn’t come on a platter By www.thehindu.com Published On :: Thu, 27 Oct 2016 13:02:03 +0530 Manju Barggavee talks about the challenges Kuchipudi faces today and how to overcome them. Full Article Friday Review
ter Moving like a master By www.thehindu.com Published On :: Thu, 27 Oct 2016 13:36:46 +0530 Kuchipudi dancer Avijit Das shone in parts during his performance in New Delhi. Full Article Friday Review
ter Celebrating an alternate style of Odissi By www.thehindu.com Published On :: Thu, 03 Nov 2016 16:18:31 +0530 A dance festival-symposium paid tribute to Guru Debaprasad Das who believed that Odissi originated from the tribal and folk traditions. Full Article Friday Review
ter Kanak Rele was a doyenne of Mohiniyattam who redefined and reinterpreted the traditional dance form of Kerala By www.thehindu.com Published On :: Thu, 23 Feb 2023 15:45:43 +0530 In her passing, Mohiniyattam has lost a crusader who widened its repertoire and gave it a new aesthetics rooted in Kerala Full Article Dance
ter Apprenticeships can make India’s youth matter By www.thehindubusinessline.com Published On :: Tue, 03 Feb 2015 21:52:46 +0530 With a target of skilling 500 million people by 2022, apprenticeship will be the key to increasing the employability of youth Full Article New Manager
ter Why marketers need that tech edge By www.thehindubusinessline.com Published On :: Tue, 28 Apr 2015 22:12:18 +0530 Integration of technology and marketing changes the role of marketers Full Article New Manager
ter Data on how smartphones driving enterprise mobility in India By www.thehindubusinessline.com Published On :: Thu, 27 Aug 2015 19:05:50 +0530 Full Article New Manager
ter When disaster strikes By www.thehindubusinessline.com Published On :: Fri, 29 Jan 2016 19:12:21 +0530 An effective business continuity plan is key to disaster-proofing your business Full Article New Manager
ter Fostering positive workplace communication By www.thehindubusinessline.com Published On :: Tue, 15 Mar 2016 12:26:34 +0530 At the core of positive workplace communications is the management of employee relationships. Full Article New Manager
ter Collaborating on a new charter By www.thehindubusinessline.com Published On :: Fri, 28 Aug 2020 17:44:28 +0530 The pandemic has brought into focus the role of the Chief People Officer, who has to handle unprecedented circumstances that are not covered in the rule book Full Article New Manager
ter Bitter truths in Maharashtra’s sugar fields By www.thehindu.com Published On :: Mon, 31 Jul 2023 00:08:00 +0530 The Maharashtra government must create a favourable legal environment that protects the rights of and ensures the safety of seasonal migrant workers in the sugar industry Full Article Comment