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Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00097H, Review Article
Matthew J. Evans, Cameron Jones
This review summarises advances in the chemistry of low-oxidation state and hydrido group 2 metal complexes, focussing on their use for the reductive activation of feed-stock gaseous small molecules, and their subsequent transformation into value added products.
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Visible photons as ideal reagents for the activation of coloured organic compounds

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01129A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lorenzo Di Terlizzi, Luca Nicchio, Stefano Protti, Maurizio Fagnoni
In search for the perfect wave(length). This review is dedicated to recent efforts in the development of visible light driven photochemical strategies occurring in coloured organic compounds.
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Protein misfolding and amyloid nucleation through liquid–liquid phase separation

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01065A, Review Article
Semanti Mukherjee, Manisha Poudyal, Kritika Dave, Pradeep Kadu, Samir K. Maji
Protein misfolding and amyloid aggregation, linked to neurodegenerative diseases, can result from liquid–liquid phase separation (LLPS) and a subsequent liquid-to-solid transition. This represents LLPS as a generic mechanism in amyloid nucleation.
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Bridging the gap between academic research and industrial development in advanced all-solid-state lithium–sulfur batteries

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00439B, Review Article
Jieun Lee, Chen Zhao, Changhong Wang, Anna Chen, Xueliang Sun, Khalil Amine, Gui-Liang Xu
This review builds upon the fundamentals and substantial progress achieved, aiming to inspire the battery community to advance all-solid-state lithium–sulfur batteries toward practical applications and accelerate the industrialization process.
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Gel polymer electrolytes for rechargeable batteries toward wide-temperature applications

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00551H, Review Article
Open Access
Xiaoyan Zhou, Yifang Zhou, Le Yu, Luhe Qi, Kyeong-Seok Oh, Pei Hu, Sang-Young Lee, Chaoji Chen
Design principles, engineering strategies, challenges, and opportunities of gel polymer electrolytes for rechargeable batteries toward wide-temperature applications are thoroughly reviewed.
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Engineered two-dimensional nanomaterials based diagnostics integrated with internet of medical things (IoMT) for COVID-19

Chem. Soc. Rev., 2024, 53,3774-3828
DOI: 10.1039/D3CS00719G, Review Article
Mohd. Abubakar Sadique, Shalu Yadav, Raju Khan, Avanish K. Srivastava
Engineered 2D nanomaterials-based smartphone-assisted detection approaches integrated with IoMT, focusing on reliable, sensitive, and rapid diagnostics for COVID-19.
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Peptide hydrogen-bonded organic frameworks

Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review
Open Access
Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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Peptide-based self-assembled monolayers (SAMs): what peptides can do for SAMs and vice versa

Chem. Soc. Rev., 2024, 53,3714-3773
DOI: 10.1039/D3CS00921A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Carlos Redondo-Gómez, Paula Parreira, M. Cristina L. Martins, Helena S. Azevedo
Self-assembled monolayers (SAMs) based on peptides represent a reproducible platform for screening and studying peptide functions and facilitating their translation into multidisciplinary applications.
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Squaramide-based receptors in anion supramolecular chemistry: insights into anion binding, sensing, transport and extraction

Chem. Soc. Rev., 2024, 53,3952-3975
DOI: 10.1039/D3CS01165H, Review Article
Open Access
Giacomo Picci, Riccardo Montis, Vito Lippolis, Claudia Caltagirone
Squaramides are a class of extremely versatile receptors for anion recognition, sensing, transport and extraction.
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Routes to high-performance layered oxide cathodes for sodium-ion batteries

Chem. Soc. Rev., 2024, 53,4230-4301
DOI: 10.1039/D3CS00929G, Review Article
Jingqiang Wang, Yan-Fang Zhu, Yu Su, Jun-Xu Guo, Shuangqiang Chen, Hua-Kun Liu, Shi-Xue Dou, Shu-Lei Chou, Yao Xiao
Various optimization strategies are reviewed and summarized to formulate design principles for layered oxide cathodes for sodium-ion batteries.
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The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Kush Maini buoyant after maiden Formula One test for Alpine




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Red Bull braces for its most formidable challenge yet

Led by the irresistible Verstappen, the outfit, over the last three years, has ended Mercedes’ dominance. But amidst an upheaval among its personnel, exits of key strategists, an underperforming driver and increasing competition, Red Bull has its back to the wall. As the F1 circus regroups at Zandvoort on Sunday, can the reigning champion handle the tricky transition phase that has tripped many a successful sporting franchise?




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Sarthak Chavan clinches maiden National crown




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Paris Olympics 2024: I watch clips of my goals to boost confidence ahead of debut, says Sukhjeet Singh

Sukhjeet Singh is one of the five debutants — Sanjay, Abhishek, Rajkumar Pal, and Jarmanpreet Singh — who have joined the 11 members of Tokyo Olympic bronze medalist team for the Paris Games.




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Sreejesh’s father swells with pride watching his last hurrah ending in Olympic glory

At that time, it cost around ₹10,000, which was a big sum for an ordinary farmer like me. But I did what I had to and bought him the kit, says P.V. Raveendran, father of goalkeeper and two-time Olympic medallist P.R. Sreejesh




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Amit Rohidas on red-card incident: I am indebted to teammates for not once letting me feel ostracized

Rohidas was penalised in the 17th minute of the quarterfinals for a swinging stick that inadvertently struck British forward Will Calnan in the face.




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Like Dravid, I want to coach juniors before gradual progression, says P.R. Sreejesh

If he decides to take up coaching, Sreejesh is clear in his mind how to go about in the new role.




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Watch: PR Sreejesh: Like Rahul Dravid, I wanted to start coaching juniors




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Tayyab Ikram set to be FIH president for another term




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Third Reich Player's Guide is Shipping Now!

The title's a handful, but it's loaded with good stuff: the Third Reich/Great Pacific War Player's Guide is on our shelves once again, and that means you can buy it right now and we'll send it to you right away!




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Cambridge exam results out




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A lesson in hidden agendas

The assault on the Right to Education Act and government schools is motivated. It is definitely not in the interest of India’s children, especially those from less privileged households




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Noida government school students “in the dark” for months

Several schools in Gautam Budh Nagar without electricity since April as Education Department failed to clear dues




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Staff shortage affects Kendriya Vidyalayas

Lack of career advancement, transfer policy leave principals bitter, as teaching vacancies climb to 12,044




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Eklavya Model Residential Schools face teacher shortage

The Tribal Affairs Ministry works towards centralising administration and doing away with state-level societies  




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Astronomy for curious kids : an illustrated introduction to the Solar System, our galaxy, space travel--and more! / [Giles Sparrow ; illustrated by Nik Neves]

Sparrow, Giles, 1970- author




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Engineering for curious kids : an illustrated introduction to building machines and amazing structures! / [author: Chris Oxlade ; illustrator: Alex Foster]

Oxlade, Chris, author




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Hello fungi : a little guide to nature / Nina Chakrabarti

Chakrabarti, Nina, author, illustrator




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See the dog : three stories about a cat / David LaRochelle ; illustrated by Mike Wohnoutka

LaRochelle, David, author




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But I live : three stories of child survivors of the Holocaust / Miriam Libicki and David Schaffer, Gilad Seliktar and Nico and Rolf Kamp, Barbara Yelin and Emmie Arbel ; editor: Charlotte Schallié




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Mythical monsters of Greenland : a survival guide / by Maria Bach Kreutzmann ; illustrated by Maria Bach Kreutzmann and Coco Apunnguaq Lynge

Kreutzmann, Maria Bach, author




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Wrong side of the court / H.N. Khan

Khan, H. N., author




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When the world didn't end : poems / Caroline Kaufman ; illustrations by Yelena Bryksenkova

Kaufman, Caroline, author




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Poems to fall in love with / chosen and illustrated by Chris Riddell




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All about insects : an illustrated guide to bugs and creepy-crawlies / [author: Polly Cheeseman ; illustrator: Iris Deppe]

Cheeseman, Polly, author




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Evidence! : how Dr. John Snow solved the mystery of cholera / Deborah Hopkinson ; illustrated by Nik Henderson

Hopkinson, Deborah, author




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Exoplanets : a guide to the worlds outside our solar system / Wendy Bjazevich ; art by David Miles

Bjazevich, Wendy, author




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Extreme weather for kids : lessons and activities all about hurricanes, tornadoes, blizzards, and more! / Matthew Cappucci ; illustrated by Stephanie Hathaway

Cappucci, Matthew, author




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Wildfire : inside the inferno / by Jaclyn Jaycox

Jaycox, Jaclyn, 1983- author




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Fireside Ventures aims to birth Indian mega-brands

Why VC firm Fireside Ventures believes it can build multimillion-dollar consumer brands in India without burning capital




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These ‘docs’ keep solar assets fit as a fiddle

Chennai start-up’s drone-based imaging service helps build, maintain defect-free solar plants




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A budget that chose to be on the side of the angels

Why the nixing of angel tax can prove a game changer for job creation in India




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A ‘PA on steroids’ for the richie-rich

Concierge service startup Indulge Global sells convenience to Indians who crave the luxe life




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Bond investment 101: Create a login ID

Higher interest. Bond investment platforms buzz with users drawn by the user-friendly interface, zero cost, jargon-free guidance




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Coaching future Olympians with AI-aided computer vision

Why Bengaluru startup Game Theory believes technology offers our best shot at sporting glory




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Loss of fluorine during crosslinking by the biarylitide P450Blt proceeds due to restricted peptide orientation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication
Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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Mild boroxazolidone formation and dissociation: Application toward target identification of bioactive molecules

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05370B, Communication
Toya Tabei, Kyoko Nagasawa-Goto, Yohei Saito
We successfully found that boroxazolidone can dissociate under aqueous conditions, which were applicable to a solution containing proteins. The immobilization of a newly synthesized diarylborinic acid on beads enabled the...
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Yolk-shelled MoS2/C@Void@C@MoS2 nanospheres as a stable and high-rate anode in sodium/potassium ion batteries

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05088F, Communication
Mang Niu, Zongfan Zhu, Zhenkai Mou, Wenpei Kang
Yolk-shelled MoS2/C@Void@C@MoS2 exhibits superior high-rate sodium/potassium sodium storage capability, owing to the large inner void and ingenious shell.
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Extended polyene formation by a cryptic iterative polyketide synthase from Rhodococcus

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04963B, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Panward Prasongpholchai, Sam Tucker, Charles Burgess, Robert Jenkins, Ina Wilkening, Christophe Corre, Lijiang Song, Manuela Tosin
Investigations of the workings of a newly identified iterative polyketide synthase from Rhodococcus erythropolis PR4 reveal its ability to synthesise extended polyenes.
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