The title compound, [Mn(S4)(C8H20N4)], was accidentally obtained by the hydro­thermal reaction of Mn(ClO4)2·6H2O, cyclen (cyclen = 1,4,7,10-tetra­aza­cyclo­dodeca­ne) and Na3SbS4·9H2O in water at 413 K, indicating that polysulfide anions might represent inter­mediates in the synthesis of thio­metallate compounds using Na3SbS4·9H2O as a reactant. X-ray powder diffraction proves that the sample is slightly contaminated with NaSb(OH)6 and an unknown crystalline phase. The crystal investigated was twinned with a twofold rotation axis as the twin element, and therefore a twin refinement using data in HKLF-5 format was performed. The asymmetric unit of the title compound consists of one MnII cation, one [S4]2− anion and one cyclen ligand in general positions. The MnII cation is sixfold coordinated by two cis-S atoms of the [S4]2− anions, as well as four N atoms of the cyclen ligand within an irregular coordination. The complexes are linked via pairs of N—H⋯S hydrogen bonds into chains, which are further linked into layers by additional N—H⋯S hydrogen bonding. These layers are connected into a three-dimensional network by inter­molecular N—H⋯S and C—H⋯S hydrogen bonding. It is noted that only one similar complex with MnII is reported in the literature.

The title compound, [Mn(C3H7NO)4(H2O)2][Cu5(C7H4NO3)4]·C3H7NO or cis-[Mn(H2O)2(DMF)4]{Cu[12-MCCu(II)N(shi)-4]}·DMF, where MC is metallacrown, shi3− is salicyl­hydroximate, and DMF is N,N-di­methyl­formamide, crystallizes in the monoclinic space group P21/n. Two crystallographically independent metallacrown anions are present in the structure, and both anions exhibit minor main mol­ecule disorder by an approximate (non-crystallographic) 180° rotation with occupancy ratios of 0.9010 (9) to 0.0990 (9) for one anion and 0.9497 (8) to 0.0503 (8) for the other. Each penta­copper(II) metallacrown contains four CuII ions in the MC ring and a CuII ion captured in the central cavity. Each CuII ion is four-coordinate with a square-planar geometry. The anionic {Cu[12-MCCu(II)N(shi)-4]}2− is charged-balanced by the presence of a cis-[Mn(H2O)2(DMF)4]2+ cation located in the lattice. In addition, the octa­hedral MnII counter-cation is hydrogen bonded to both MC anions via the coordinated water mol­ecules of the MnII ion. The water mol­ecules form hydrogen bonds with the phenolate and carbonyl oxygen atoms of the shi3− ligands of the MCs.

It’s not an exaggeration to say Hedrick was ecstatic when she peered into her inverted phase contrast microscope and found "Amphisolenia quadrispina" floating in her sample. “For 20 years I’ve been hoping to see something like this,” she says.

The post From the Bay of Bengal, a dinoflagellate makes its way to the Smithsonian appeared first on Smithsonian Insider.

“We are working as hard as we can to find and identify frogs before the disease reaches them, and to learn more about a disease that has the power to ravage an entire group of organisms,” said Roberto Ibanez, research scientist at STRI and local director of the Panama Amphibian Rescue and Conservation Project.

The post Two new frog species discovered in Panama’s fungal war zone appeared first on Smithsonian Insider.

A description and photos of the green-headed tanager (Tangara seledon), a bird native to east-central South America, can be found in the Species of the […]

The post Green-headed Tanager (Tangara seledon) of east-central South America appeared first on Smithsonian Insider.

A new study has revealed information about the way tungara frogs in the tropical rain forest hear, sort, and process sounds which is very similar to the way humans do. The knowledge could be applicable to communication disorders associated with hearing loss and attention deficits or difficulties.

The post Research on tungara frogs may be applicable to hearing loss/attention deficits in humans appeared first on Smithsonian Insider.

Scientists have discovered an incredible story of fungal fidelity among certain species of ants.

The post Fungal fidelity: some ants have been eating the same meal for 5 million years! appeared first on Smithsonian Insider.

In theory, crabs of the species Planes major should stay true to their mates for life. Heterosexual pairs of these small crustaceans live on loggerhead […]

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Ana Loncar, Sergio A. Rincon, Manuel Lera Ramirez, Anne Paoletti, and Phong T. Tran

To segregate the chromosomes faithfully during cell division, cells assemble a spindle that captures the kinetochores and pulls them towards opposite poles. Proper spindle function requires correct interplay between microtubule motors and non-motor proteins. Defects in spindle assembly or changes in spindle dynamics are associated with diseases like cancer or developmental disorders. Here we compared mitotic and meiotic spindles in fission yeast. We show that even though mitotic and meiotic spindles undergo the typical three phases of spindle elongation, they have distinct features. We found that the relative concentration of kinesin-14 Pkl1 is decreased in meiosis I compared to mitosis, while the concentration of kinesin-5 Cut7 remains constant. We identified the second kinesin-14 Klp2 and microtubule dynamics as factors necessary for proper meiotic spindle assembly. This work defines differences between mitotic and meiotic spindles in fission yeast, and provides prospect for future comparative studies.

A robotic male frog attracts a female tungara frog in a sound chamber at the Smithsonian Tropical Research Institute, Gamboa, Panama, in the summer 2013. […]

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What’s an Asian small-clawed otter’s favorite enrichment toy? Anything it can get its paws on! This species’ dexterous, partially-webbed digits are adept at feeling for […]

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High schools that successfully engage students in learning have many things in common.

The National Academies of Sciences, Engineering, and Medicine are launching the “New Voices in Sciences, Engineering, and Medicine” initiative to identify outstanding early-career science, engineering, and medicine (SEM) leaders.

For some patients, the ability to participate in a clinical trial from the comfort of one’s home is becoming a reality.

Healthy People 2030 (HP2030) – which will set national objectives for improving the health of all Americans from 2020 to 2030 – should include in its Leading Health Indicators (LHIs) voting as a measure of civic engagement, the health effects of climate change, and indicators of racial and ethnic residential segregation, says a new report from the National Academies of Sciences, Engineering, and Medicine.

A new study has investigated the effects of set-aside management —when fields are taken out of agricultural production — on common invertebrate decomposers in soil. The diversity of woodlice species was higher in set-aside fields compared to neighbouring wheat fields and this effect increased in older set-asides. This study highlights the importance of set-aside areas as habitats for soil invertebrates, which are important for soil health.

A review of the community-led research programme Open Air Laboratories (OPAL) – a UK national programme that brings scientists and communities together to investigate environmental issues – concludes that it benefits both science and the public. The public’s involvement not only raises their awareness of their relationship with the environment, but also contributes to securing a sustainable future.

There is greater potential for non-governmental organisations (NGOs) to influence the environmental responsibilities of small and medium enterprises (SMEs), suggests new research in Hungary. The study says that environmental policymakers should consider how they could enhance SME-NGO relations.

Recent research from China suggests that partially converting both natural gas and coal into 'syngas' fuel for power generation can generate around 6 per cent more electricity than competing 'conventional' gasification methods. The savings arise from more efficient use of the chemical energy in gas and coal which is lost in a conventional burner.

Ensuring successful public engagement in policy can be difficult. Four key challenges – communicating complexity, providing balanced information, creating space for deliberation and accessing broader values – are highlighted by a new study. Its authors show how they dealt with these challenges in a UK programme, designed to gather public views on the future of national energy policy.

In theory, payment for environmental services (PES) is a market mechanism but, in practice, it depends on intervention from the state or community. This is the conclusion of a new review of case studies that indicates that PES relies on public bodies and communities to act as intermediaries in the trading of services.

Individuals and groups of individuals have been influential in changing the Tisza River water policy in Hungary, according to a new study. A shift away from engineering solutions towards sustainable flood management was achieved through new policy ideas being recognised by civil servants at the national level and a regional coalition championing the ideas at the local level.

A pilot cloud-based learning platform that brings together multiple datasets, models and visualisation tools has been developed with the engagement of numerous stakeholders throughout the design process. This tool could lead to informed decisions about flood risk at the local level. These types of tools and frameworks are effective ways of facilitating better decision making.

Online retailers such as Myntra and Tjori have their consumer engagement teams working on to engage their customers till the time the lockdown eases.

Bengaluru police has opened an account on short video-making platform TikTok to reach out to the people in an engaging and entertaining manner, an official said on Friday.

Rajasthan to create a common data and analytics platform for all government departments across the State to collate and utilize data more effectively and efficiently, improving the delivery of citizen services with the help of Teradata solutions.

The platform enables enterprises to reduce Video KYC completion drop-offs by 20% and reduce the cost of operations by up to 90%

Robert Bosch Engineering and Business Solutions (RBEI) launched Internet of Things (IoT) garage in Electronic City, Bengaluru, to offer enterprises a full stack IoT implementation capability.

In theory, payment for environmental services (PES) is a market mechanism but, in practice, it depends on intervention from the state or community. This is the conclusion of a new review of case studies that indicates that PES relies on public bodies and communities to act as intermediaries in the trading of services.

Setting aside agricultural land remains an important method of promoting biodiversity in Central Europe, according to new Hungarian research. Results have indicated that, compared to winter cereal fields, set-aside land has greater plant and insect diversity. This supports the continuing use of set-aside policy in Central and Eastern Europe.

Scientists have called for tighter biosecurity measures to reduce the growing threat to biodiversity, food security and ecosystems from fungal infections. Their study reveals that fungal disease outbreaks are on the rise around the world, and will cause further damage unless urgent steps are taken to restrict their unintentional spread through international trade and transport.

Social scientists have been advising on environmental issues for decades, but their contributions to policy remain unclear. This study analysed how social scientists interact with policymakers and provides recommendations for future engagement.

A new study has investigated the effects of set-aside management —when fields are taken out of agricultural production — on common invertebrate decomposers in soil. The diversity of woodlice species was higher in set-aside fields compared to neighbouring wheat fields and this effect increased in older set-asides. This study highlights the importance of set-aside areas as habitats for soil invertebrates, which are important for soil health.

Bangladesh’s economy is heavily dependent on ship recycling. However, the shipbreaking industry is polluting the Bay of Bengal, an area of high biodiversity. This study measured trace metals in sediments around the area, concluding that heavy metal pollution is at an alarming stage and an urgent threat to marine life.

Azole fungicides are active ingredients in a range of pharmaceutical and personal care products, and are also used in agriculture. This study reviewed the sources, presence and risks of these compounds in the environment, finding evidence of toxic effects on aquatic organisms. The researchers provide directions for future research and warn caution should be exercised until more toxicity data becomes available.

Danish researchers have recently revealed that crop harvesting can release high levels of Alternaria fungal spores, affecting air quality locally and, occasionally, over long distances. The fungus is known to trigger human allergic reactions, and the study calls for improved monitoring and forecasting of airborne fungal spores.

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A study of families in Singapore with terminally ill children found that parents tend to defer discussing their psychological pain with their spouses to protect them from emotional distress. The study, conducted by psychologists at NTU through interviews, revealed the parents’ preference to support each other in pragmatic and solution-oriented ways such as discussing treatment options, arranging care plans and sharing caregiving responsibilities....

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The rejuvenated Yunnan Garden, a sprawling open space of greenery, waterscapes and heritage landmarks, will officially open at Nanyang Technological University, Singapore (NTU Singapore) on 13 February 2020. The 9-hectare heritage precinct – bigger than 12 soccer fields – preserves the Garden’s legacy while enriching it as an educational and recreation hub, making it a go-to place not just for the NTU community, but also for the residents who live in the wider Jurong neighbourhood....

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Professor Su Guaning, President Emeritus of Nanyang Technological University, Singapore (NTU Singapore), has been elected to the United States' National Academy of Engineering (NAE)....

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