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Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02469A, Paper
Zhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei Qin
Heteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.
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Oxaphosphiranes: isolable phosphorus-containing epoxide rings

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02915A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer Streubel
A new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.
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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02703E, Paper
Vilakkathala U. Krishnapriya, Cherumuttathu H. Suresh
Dinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.
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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper
Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).
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Boozers beware: Maharashtra orders sophisticated surveillance of 'watering holes'




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Fear or knowledge the impact of graphic cigarette warnings on tobacco product choices [electronic resource] / Donald S. Kenkel, Alan D. Mathios, Grace N. Phillips, Revathy Suryanarayana, Hua Wang, Sen Zeng

Cambridge, MA. : National Bureau of Economic Research, 2023




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Philippine dictator set to be buried at heroes' cemetery

"There will be no state funeral. It will be very simple, the body will be carried on a hearse then brought to his tomb," Mr. Albayalde said.




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‘There’s no pure European culture,’ says Josephine Quinn, author of How the World Made the West

In an ambitious narrative on history, Josephine Quinn argues that the West is a product of links with a much larger network of societies




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A fluoride gradient, Zn-salt-rich hydrophobic interphase formed by a zincophilic, hydrophobic, anion-philic polymer “skin” for an anode-free solid Zn battery

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE01978D, Paper
Xinpeng Han, Jinpeng Han, Kang Ma, Jiaqi Wen, Lianpeng Li, Daliang Han, Jie Sun
A Zn2+·OC group-derived contact ion pair (CIP)/aggregate (AGG)-rich electrolyte is fabricated to generate a fluoride gradient, Zn-salt-rich hydrophobic solid electrolyte interface (SEI) layer with ultrahigh mechanical properties.
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Interplay of intercalation dynamics and lithium plating in monolithic and architectured graphite anodes during fast charging

Energy Environ. Sci., 2024, 17,8702-8721
DOI: 10.1039/D4EE02211D, Paper
Open Access
Aleksandar S. Mijailovic, Seth Waag-Swift, Guanyi Wang, Bingyao Zhou, Mei Luo, Wenquan Lu, Qingliu Wu, Brian W. Sheldon
Fast charging of high-capacity anodes is challenging due to lithium plating reactions, which lead to poor cycling performance and safety concerns.
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Co3O4 supported by ultrathin-layered graphitic carbon nitride for efficient electrocatalytic evolution of oxygen

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00020J, Paper
Ruixue Luo, Xi Li, Youping Guo, Renchun Fu
An efficient OER. Co3O4@g-C3N4 using layered g-C3N4-loaded Co3O4 was significantly higher than that using g-C3N4 or Co3O4.
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Green synthesis of surfactant-free mesoporous silica with strong hydrophilicity via metal salt modifications for moisture adsorption

React. Chem. Eng., 2024, 9,816-824
DOI: 10.1039/D3RE00513E, Paper
Pariyawalee Sangteantong, Kunpirom Chainarong, Waleeporn Donphai, Metta Chareonpanich
In this work, the green synthesis of mesoporous silica (MPS) was carried out using low-cost sodium silicate as a precursor.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correlation between vitamin D metabolic pathway-related gene polymorphisms and cardiovascular disease

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03234A, Review Article
Jiao Pang, Chunshuo Yang, Jiaqi Liu, Zhilin Wang, Xueshu Tao, Zhipeng Cao
Polymorphisms in key genes in the vitamin D metabolic pathway affect susceptibility to cardiovascular disease (CVD) and play potential roles in the pathogenesis of CVD.
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Philip's Review

Philip's is a light-hearted film you can enjoy with your family and safely recommend to your friends, endorses Divya Nair.




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Phir Aayi Hasseen Dillruba Review

Taapsee, Vikrant, Sunny are a fine fit on their own as well as around each other and prove themselves to be well equipped to survive the air of double dealing. What's missing is sizzle, feels Sukanya Verma..




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Micrographia: Hooke’s monumental masterpiece

A great book written and illustrated by English polymath Robert Hooke, Micrographia appeared in bookshops in January 1665. The advance copy of this book, which details Hooke’s exploration into many things small, far, and sometimes elusive, is believed to have been shown to the Royal Society on November 3, 1664. A.S.Ganesh tries to hook you onto Hooke’s story…  




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Person-centered politics [electronic resource] : a personalist approach to political philosophy / Eamonn Gerard O'Higgins ; foreword by Rocco Buttiglione.

Lanham : Hamilton Books, an imprint of Rowman & Littlefield, [2024]




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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Broadening the substrate range of serine palmitoyltransferase by protein engineering and applications to 3-keto-dihydrosphingosine analogs

Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper
Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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An eco-friendly polycaprolactone/graphite composite as a robust freestanding electrode platform for supercapacitive energy storage

Nanoscale, 2024, 16,20155-20167
DOI: 10.1039/D4NR03113J, Paper
Rajeev Gupta, Monika Singhal
A novel eco-friendly composite electrode/current collector made from polycaprolactone and graphite filler offers bulk conductivity, is freestanding, cost-effective, and shows supercapacitive energy storage potential with electrodeposited polyaniline.
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Conduction band photonic trapping via band gap reversal of brookite quantum dots using controlled graphitization for tuning a multi-exciton photoswitchable high-performance semiconductor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03616F, Paper
Sanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha Khare
The photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...
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Exploring Graphene's Impact on Graphite/PANI Matrix Composites: High-Press Fabrication and Enhanced Thermal-Electrical Properties

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03171G, Paper
Murat OZLEK, Merve Sehnaz Akbulut, Engin Burgaz
This study investigates the effects of graphene content and applied press on electrical and thermal conductivities of graphite/polyaniline (GP) and graphite/graphene/polyaniline (GGP) composites which were produced by using direct mixing...
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Trap & kill: a neutrophil-extracellular-trap mimic nanoparticle for anti-bacterial therapy

Biomater. Sci., 2024, 12,1841-1846
DOI: 10.1039/D4BM00145A, Paper
Jingtao Zheng, Lei Rong, Yao Lu, Jing Chen, Kai Hua, Yongzhong Du, Qiang Zhang, Weishuo Li
A neutrophil-extracellular-trap mimic nanoparticle effectively eliminates bacteria in a trap & kill manner.
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Retraction: Strontium-doped gelatin scaffolds promote M2 macrophage switch and angiogenesis through modulating the polarization of neutrophils

Biomater. Sci., 2024, 12,2167-2167
DOI: 10.1039/D4BM90023E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tao Li, Hongtao He, Zezheng Yang, Junjie Wang, Yuxin Zhang, Guangxu He, Jun Huang, Deye Song, Jiangdong Ni, Xiaojun Zhou, Junfeng Zhu, Muliang Ding
The content of this RSS Feed (c) The Royal Society of Chemistry




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OPPO Find X7 Ultra review: A photographic powerhouse 

With Hasselblad-approved imaging prowess, this starrer on this phone is its quad-camera setup




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Lenovo Tab Plus review. An audiophile’s tablet 

If watching movies, listening to music and catching up on social media are your primary needs, then the Lenovo Tab Plus is definitely worth considering




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Miracles de Nostre Dame / collected by Jean Mielot secretary to Philip the Good, Duke of Burgundy ; reproduced in facsimile from Douce Manuscript 374 in the Bodleian Library for John Malcolm of Poltalloch ; with text, introduction, and annotated analysis

Westminster : Nichols and Sons, 25 Parliament Street, MDCCCLXXXV [1885]




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Papers of the Edinburgh Bibliographical Society : 1890-95.

Edinburgh : Printed for the Society, MDCCCXCVI [1896]




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Le Psautier de Genève : 1562-1865 : images commentées et essai de bibliographie.

Genève : Bibliothèque publique et universitaire, 1986.




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Biblia. Concordantiae in eadem, ex tum Veteri, tum Nouo Testamento, sacrisq[ue] canonibus: necnon & ex uiginti Iosephi De antiquitatibus, & Bello Iudaico libris excerptae. Annotationes ex sacris scriptoribus sumptae, & suis quaeq[ue] locis, &a

Lugduni : apud Hugonem à Porta, M. D. X L VI. [1546]




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Designers Abraham and Thakore bring their black and white design philosophy to Hyderabad

Slow, responsible and fashion that lasts seasons are beliefs that A&T hold dear




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Periodic graphics: Soap versus body wash

Chemical educator and Compound Interest blogger Andy Brunning explains the similarities and differences between the two bath products




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Periodic Graphics: The chemistry of slime

Chemical educator and Compound Interest blogger Andy Brunning wrings all the molecular details out of the popular goo




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Errors in C&EN graphic reveal widespread misconceptions about slime chemistry

Multiple sources, including journal articles and chemical catalogs, get the borate bonding and reactivity wrong




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Periodic Graphics: Lava and volcanic gases

Chemical educator and Compound Interest blogger Andy Brunning probes the molecular makeup of the molten rock and gases spewed by volcanoes




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Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04450A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tribani Boruah, Ren Ishizeki, Alberto Roldan, Rebecca L. Melen, Thomas Wirth
A robust flow electrochemical method for P–N and P–O oxidative coupling under mild conditions has been developed. Cyclic voltammetry (CV) was employed to investigate the redox behaviour of reactants.
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In silico modeling enables greener analytical and preparative chromatographic methods

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04300F, Paper
Troy T. Handlovic, Daipayan Roy, Muhammad Qamar Farooq, Gabriel Mazzi Leme, Kevin Crossley, Imad A. Haidar Ahmad
Environmental impact of chromatographic separation at both analytical and preparative scale can be significantly reduced using In Silico Modeling.
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IPL 2022 - SRH vs MI | Sunrisers have an uphill task to qualify

Mumbai will look to play spoilsport



  • Indian Premier League

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NBA: Philadelphia 76ers centre Joel Embiid to miss out on $1 million for shoving reporter





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After Jio deals, RIL valued higher than BP, Sinopec, Shell, ConocoPhillips, Vodafone, Tesco

The investor confidence shot up in RIL because of the back-to-back strategic investments in its telecom subsidiary in the last three weeks




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My First Million: Cecile Reinaud, founder of Seraphine

The maternity wear boutique is a favourite of Royals and celebrities




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Jamie Laing seen in London with girlfriend Sophie Habboo after couple fled to isolate in Cotswolds 

Jamie Laing has appeared to flout lockdown rules after he returned to London with his girlfriend Sophie Habboo. The Made in Chelsea couple had left the capital to isolate in the Cotswolds.




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From Anushka Sharma To Sophie Choudry, The Divas Who Wore Heavy Costumes And Jewellery

While the script, directing, editing, and other technical aspects can make or break a film, more than often costumes also indirectly affect the film. Since costumes define a character, costumes become an essential part of the film. For instance, Sanjay




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The man in song: a discographic biography of Johnny Cash / John M. Alexander

Lewis Library - ML420.C265 A74 2018