ea Donald Trump Hires Elon Musk and Vivek Ramaswamy to Bring 'Drastic Change' to the U.S. Government — And Gives Them a 2 Year Deadline By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 16:05:00 GMT Musk and Ramaswamy have to find ways to cut down on government spending and overall bureaucracy. Full Article false
ea 10 Negotiation Strategies Strong Leaders Use to Get Results By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 17:30:00 GMT Effective negotiation for business leaders requires clear goals, understanding the other party's needs and utilizing strategies like preparation, flexible options, active listening and knowing when to stand firm or concede to build mutually beneficial relationships. Full Article false
ea This Is How Much You Need to Earn to Buy a House in the U.S., According to a New Report By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 21:54:59 GMT Plus, if you are in the market, these metro areas were found to be the least and most affordable to buy in. Full Article false
ea Over a Million People Have Recently Joined Bluesky, the Ad-Free X Alternative and Threads Competitor By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 22:04:00 GMT Bluesky has been seeing noticeable growth since the election, though its user numbers are nowhere close to Meta's X competitor, Threads. Full Article false
ea Don Lemon officially leaves Elon Musk’s X By techcrunch.com Published On :: Wed, 13 Nov 2024 21:14:19 +0000 Former CNN anchor Don Lemon said on Wednesday he is leaving Elon Musk’s X, a decision made less than a year after X announced that “The Don Lemon Show” would appear on the social media platform three times a week. That deal was canceled before it was ever signed, and Lemon sued Musk and X […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Media & Entertainment TC Elon Musk social media Twitter
ea Apple now lets app developers apply to be featured on the App Store By techcrunch.com Published On :: Wed, 13 Nov 2024 16:09:17 +0000 App developers now have a new way to promote their app launches, updates, and other new features on Apple’s App Store. First announced at the company’s Worldwide Developers Conference in June, Apple this week introduced a “Featuring Nominations” option in App Store Connect, which is the service developers use to submit their apps, games, and […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Apps app store Apple developers Marketing
ea Spotify teases a ‘super premium’ tier for superfans and upcoming video expansion in Q3 earnings call By techcrunch.com Published On :: Wed, 13 Nov 2024 18:12:39 +0000 Spotify CEO Daniel Ek has once again teased the company’s long-delayed HiFi or “super premium” tier, a higher-qualify subscription offering the streaming service first announced in 2021 and then failed to roll out. In the company’s third-quarter earnings call with investors on Wednesday, the exec suggested that such a product was still on the way, […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Apps Media & Entertainment hifi Premium Spotify streaming service subscriptions super fan apps Video
ea Modi-Mundipharma Pvt. Ltd. & Anr. vs Win Health Pharma Through Its ... on 13 November, 2024 By indiankanoon.org Published On :: 13.11.2024 MINI PUSHKARNA, J: I.A. No. 4172/2023 (Application under Section 124 of the Trademarks Act, 1999 read with Section 151 CPC seeking permission to challenge the validity of the defendants' trademark registrations) 1. The present application has been filed by the plaintiffs under Section 124 of the Trade Marks Act, 1999 read with Section 151 Code of Civil Procedure, 1908 ("CPC") seeking permission to challenge the validity of the defendant‟s trademark registrations. Full Article
ea Zydus Healthcare Limited & Ors. vs Alder Biochem Private Limited on 13 November, 2024 By indiankanoon.org Published On :: 13.11.2024 MINI PUSHKARNA, J: I.A. 14145/2023 (Application under Order XXXIX Rules 1 & 2 read with Section 151 CPC, 1908) 1. The present application has been filed on behalf of the plaintiffs under Order XXXIX Rules 1 and 2 of Code of Civil Procedure, 1908 ("CPC") seeking interim injunction for restraining the defendant from manufacturing, selling, offering for sale, advertising and/or promoting by using the mark/ trade name „ALDER BIOCHEM‟ and any other mark/ trade name/ label/ device that contains the trademark BIOCHEM. Full Article
ea Jinneng Clean Energy Technology Ltd vs Sunedison Energy Holding (Singapore) ... on 2 September, 2024 By indiankanoon.org Published On :: The above Original Petition has been filed by the successful Award Holder under Chapter I Part II of the Arbitration and Conciliation Act, 1996 to recognize the Final Award dated 22.02.2021 and the addendum to the Final Award dated 08.03.2021. ______________ Page No 3 of 184 https://www.mhc.tn.gov.in/judis Arb.O.P.(Com.Div.)No.186 of 2023 2. The respective legal contentions of the Petitioner (the claimant) and the Award Debtor Respondent No.2 (the Engineering Company) and the Award Debtor Respondent No.3 (the Project Company) shall be adverted after narrating the facts of the case. I propose to narrate the facts in two parts. Full Article
ea Ifgl Refractories Limited vs Guntur- Appeal on 13 November, 2024 By indiankanoon.org Published On :: . 96. It would be evident from the above discussion that the claims for refund under the said two enactments constitute an independent regimen. Every decision favourable to an assessee/manufacturer, whether on the question of classification, valuation or any other issue, does not automatically entail refund. Section 11B of the Central Excises and Salt Act and Section 27 of the Contract Act, whether before or after 1991 amendment - as interpreted by us herein - make every refund claim subject to proof of not passing-on the burden of duty to others. Even if a suit is filed, the very same condition operates. Similarly, the High Court while examining its jurisdiction under Article 226 - and this Court while acting under Article 32 - would insist upon the said condition being satisfied before ordering refund. Unless the claimant for refund establishes that he has not passed on the burden of duty to another, he would not be entitled to refund, whatever be the proceedings and whichever be the forum. Section 11B/Section 27 are constitutionally valid, as explained by us hereinbefore. They have to be applied and followed implicitly wherever they are applicable. Full Article
ea Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 By www.forbes.ro Published On :: Wed, 13 Nov 2024 10:40:58 +0000 Bogdan Naumovici, om de publicitate, își lansează lungmetrajul de debut pe 28 ianuarie 2025. Comedia „Țăndări”, distribuită de Forum Film, are în distribuție actori precum Alin Florea, Constantin Florescu, Cristian Bota, Nicodim Ungureanu, Cătălin Neamțu, Carmen Tănase, Dan Badea, Alex Conovaru, Sergiu Costache, Robert Tudor, Andreea Samson, și Gabriel Spahiu. De la spoturi publicitare pentru ... The post Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 appeared first on Forbes Romania. Full Article Afaceri Media şi entertainment Bogdan Naumovici lungmetraj publicitate Țăndări
ea Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:08:08 +0000 Commerzbank analizează opțiunea de a achiziționa o bancă germană de dimensiuni medii ca parte a strategiei de a evita o posibilă preluare de către UniCredit, potrivit Reuters. Planurile sunt într-o etapă incipientă, iar posibilele ținte ar putea include Hamburg Commercial Bank sau Oldenburgische Landesbank. Potrivit surselor Reuters, Commerzbank încearcă să conceapă un plan de apărare, ... The post Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
ea Eurostat: România a fost al șaptelea producător agricol din UE în 2023 By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:14:46 +0000 Valoarea producţiei agricole a blocului comunitar a scăzut cu 1,5% în 2023, comparativ cu 2022, până la 537,1 miliarde de euro, însă România se numără printre ţările UE a căror valoare a producţiei agricole a crescut de la un an la altul, arată datele publicate miercuri de Eurostat. Scăderea uşoară din 2023 vine după o ... The post Eurostat: România a fost al șaptelea producător agricol din UE în 2023 appeared first on Forbes Romania. Full Article Actualitate Eurostat producator agricol Romania UE
ea Trump îl nominalizează pe veteranul și prezentatorul Fox News, Pete Hegseth, pentru funcția de secretar al apărării By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:24:11 +0000 Președintele ales Donald Trump a surprins observatorii politici marți seară prin nominalizarea prezentatorului Fox News, Pete Hegseth, pentru funcția de secretar al apărării. „Pete și-a petrecut întreaga viață ca un războinic pentru trupele noastre și pentru țară,” a declarat Trump într-un comunicat. „Pete este dur, inteligent și un adevărat susținător al politicii America First. Cu ... The post Trump îl nominalizează pe veteranul și prezentatorul Fox News, Pete Hegseth, pentru funcția de secretar al apărării appeared first on Forbes Romania. Full Article Actualitate Afaceri
ea Din lumea orologerilor independenți By www.forbes.ro Published On :: Wed, 13 Nov 2024 14:10:52 +0000 Lumea companiilor independente constituie adevăratul laborator creativ al industriei orologere. Mediul acesta divers și discret al micilor Case guvernat de talentul și experiența maeștrilor și de capriciile colecționarilor se dovedește deosebit de efervescent. Vă prezint de această dată trei mărci noi care intră pe această piață selectă, semnalându-și prezența prin lansarea unor modele remarcabile. Guebly. ... The post Din lumea orologerilor independenți appeared first on Forbes Romania. Full Article Actualitate
ea Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională By www.forbes.ro Published On :: Wed, 13 Nov 2024 15:06:09 +0000 Pehart Grup, una dintre cele mai mari companii producătoare de hârtie tissue din Sud-Estul Europei, celebrează tradițiile românești prin cea de-a doua ediție a campaniei naționale Pufina Tradiții Românești. După ce anul trecut, de 1 Decembrie, producătorul a dat startul campaniei naționale Pufina Tradiții Românești, anul acesta, la debutul lui noiembrie a lansat cea de-a ... The post Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională appeared first on Forbes Romania. Full Article Actualitate Pehart Grup producator de hartie Pufina traditii romanesti
ea Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” By www.forbes.ro Published On :: Wed, 13 Nov 2024 21:44:31 +0000 Moov Leasing, un start-up românesc lansat de Bogdan Speteanu și Mircea Dihel, propune o schimbare radicală în leasingul auto, transformând experiența de utilizare a unei mașini într-una simplă și accesibilă, la fel ca utilizarea unui telefon mobil. După 20 de ani de experiență la BCR, timp în care a ocupat mai multe funcții de conducere, printre care și ... The post Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” appeared first on Forbes Romania. Full Article Emisiuni Online | Proiecte Forbes Bogdan Speteanu Moov Leasing
ea ADM Naveen Babu Death: 'എനിക്ക് രണ്ട് ഒപ്പുണ്ട്'; നവീൻ ബാബുവിനെതിരെ പരാതി നൽകിയത് താനാണെന്ന് ഉറപ്പിച്ച് പ്രശാന്ത് By zeenews.india.com Published On :: Wed, 13 Nov 2024 15:06:38 +0530 ADM Naveen Babu Death: എഡിഎം നവീൻ ബാബുവിന്റെ മരണത്തിൽ ആദ്യമായാണ് അന്വേഷണസംഘം പ്രശാന്തിന്റെ മൊഴി എടുത്തത്. Full Article
ea Real Estate Scam: ഭൂമി വാങ്ങിത്തരാമെന്ന് പറഞ്ഞ് കോടികൾ തട്ടിയ പ്രതി അറസ്റ്റിൽ By zeenews.india.com Published On :: Thu, 14 Nov 2024 07:06:18 +0530 Land Scam Case: അടുത്ത കാലങ്ങളില് സാമ്പത്തികമായി പെട്ടന്ന് അഭിവൃദ്ധി പ്രാപിച്ച ബ്രോക്കര്മാരും പോലീസ് നിരീക്ഷണത്തിലാണ്. Full Article
ea Bigg Boss OTT-fame Bhojpuri actress Akshara Singh receives extortion threat By www.dnaindia.com Published On :: Thu, 14 Nov 2024 03:11:00 GMT Bhojpuri actress Akshara Singh receives extortion threat, investigation underway. Full Article Entertainment
ea Chennai Rains: IMD predicts heavy showers for 2 days in Tamil Nadu; Are schools, colleges closed today? By www.dnaindia.com Published On :: Thu, 14 Nov 2024 02:35:00 GMT The city experienced heavy rainfall on Wednesday night, and the IMD bulletin indicates that several isolated areas of the capital are expected to see heavy downpours on Thursday. Full Article India
ea A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00244J, Research ArticleHui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping XuAn efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea A Pd(II)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00344F, Research ArticlePratiksha Bhorali, Deep J. Kalita, Babulal Das, Sanjib GogoiThe first denitrative Pd(II)-catalyzed alkyne annulation reaction is reported for the synthesis of cyclopenta[b]chromanes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Organocatalyzed double dearomatization reaction of non-functionalized phenols and propargylic alcohols: the important regulating effect of steric hindrance By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00103F, Research ArticleXihong Liu, Boyan Zhu, Panpan Zhou, Jingying Zhang, Anqi Chu, Rui WangSteric hindrance-regulated double dearomatization reaction of non-functionalized phenols and propargylic alcohols for the efficient synthesis of polycyclic diketones is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00374H, Research ArticleYongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua LiuCyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00148F, Research ArticleDong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei XuThe challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00396A, Review ArticleDong-Sheng Yang, Xiang-Long Chen, An-Xin WuThe synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00265B, Research ArticleShuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping HuiAn efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00311J, Research ArticlePei-Ting Li, Zi-Fa Shi, Wei YuTwo triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Visible-light-mediated catalyst-free synthesis of trifluoromethyl(spiro)-epoxides bearing contiguous quaternary centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00184B, Research ArticleJingchuan Lin, Yu Zhang, Jinxin Wang, Xinyu Han, Shenglan Zhu, Tong Li, Yanping Zhu, Wei-Dong ZhangHerein, we describe a non-covalent complex-mediated epoxidation strategy that can yield highly selective central spiro-epoxides by irradiation with visible light without the need for catalyst addition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Sulfamide instead of urea in Biginelli reaction: from black box to reality By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2155-2160DOI: 10.1039/D3QO01926H, Research ArticleAlexander Yu. Lyapunov, Andriy V. Tarnovskiy, Sergey Yu. Boron, Eduard B. Rusanov, Galyna P. Grabchuk, Dmytro M. Volochnyuk, Serhiy V. RyabukhinThe scope and limitations of the classical Biginelli reaction have been expanded to principally novel substrates: sulfamide and its monosubstituted analogues.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2344-2350DOI: 10.1039/D3QO01955A, Research ArticleLinge Huai, Li Zhang, Zhentao Wang, Yewen FangN → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2277-2282DOI: 10.1039/D3QO01999C, Research ArticleYan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang MoWe describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Synthesis of benzothiophenes via sulfonium-[3,3]-rearrangement of aryl sulfoxides with allenenitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2208-2214DOI: 10.1039/D4QO00121D, Research ArticleLei Zhang, Kun Wan, Huanhuan Wang, Mengyao Wang, Ao Cui, Xin Huang, Bo PengA facile synthesis of benzothiophenes from readily available aryl sulfoxides and allenenitriles has been established through sulfonium-rearrangement triggered cyclization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2178-2181DOI: 10.1039/D4QO00269E, Research ArticleVojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, Guy BertrandChiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from L-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Visible light/copper catalysis enabled Heck-like coupling between alkenes and cyclic sulfonium salts via selective C–S bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2195-2200DOI: 10.1039/D3QO02009F, Research ArticleXianqin Liu, Xufeng Li, Linyuan Wang, Yongjia Shi, Jian Lv, Daoshan YangA Heck-like coupling of cyclic sulfonium salts with alkenes via selective C–S bond cleavage using a copper complex as a photosensitizer through a visible-light-driven redox-neutral process has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2231-2240DOI: 10.1039/D4QO00177J, Research ArticleRomain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas PoissonHerein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2241-2248DOI: 10.1039/D4QO00136B, Research ArticleXinyu Wang, Zhaobin WangWe present an approach involving Fe-catalyzed B–H and Si–H insertion of gem-dichloroalkanes. In contrast to previous strategies, our method uses gem-dihaloalkanes as non-stabilized carbene precursors and operates through a radical reaction pathway.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea A dearomatization–rearomatization strategy for construction of 4H-quinolizin-4-ones via C–H bond functionalization of pyridines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2319-2325DOI: 10.1039/D3QO01990J, Research ArticleDong Qiu, Yijin SuHerein, the synthesis of 4H-quinolizin-4-ones from N-(2-methoxy-2-oxoethyl) pyridinium salts and alkenes through dearomative cycloaddition and rearomative ring expansion has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Selective deletion of one carbon atom from C60 through benzylamine mediated reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00449C, Research ArticleYaqiong Wang, Yiran Wu, Yuming Yu, Jie Su, Yi Qiu, Liangbing GanBenzylamine selectively adds to one of the two carbonyl groups on the 9-membered orifice to form an N,O-aminal moiety. Subsequent oxidation and hydrogen atom transfer lead to a decarboxylation process and formation of a nor [59]fullerene derivative.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00351A, Research ArticleFei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng ZhuLovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Visible-light Induced [1, 3]-Brook Rearrangements of α-Ketoacylsilanes and Its Subsequent Trapping in a Tandem Annulation with 1, 3, 5-Triazinanes and Azomethine Imines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00463A, Research ArticleZhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng YuAn unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Base- and metal-free visible-light driven site-selective α-C(sp3)–H functionalization reaction of glycine derivatives with hydroxamic acid derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00425F, Research ArticleShiyun He, Hongying Fan, Xue Zhang, Meiling Ye, Jian Chen, Jinyu Hou, Tianle Huang, Li Guo, Guanghui Lv, Yong WuA visible-light-mediated radical–radical cross-coupling reaction between hydroxamic acid and N-phenyl glycine derivatives under base and metal free conditions is reported. A series of unnatural amino acids and peptides were obtained in good to excellent yields with good chemo-selectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00317A, Research ArticleGuohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin YinAmine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Regioselective Oxidative Cleavage of Conjugated Dienes to Access α,β–Unsaturated Nitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D3QO02101G, Research ArticleYuqing Fu, Yijia Leng, Haotong Bai, Jiaxi Xu, Ning ChenA highly regioselective oxidative cleavage method has been developed for the synthesis of α,β-unsaturated nitriles from unsymmetric conjugated dienes. This transformation selectively cleaved the terminal C=C double bond, providing moderate...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Substituent-controlled divergent cyclization reactions of benzo[c][1,2]dithiol-3-ones and hexahydro-1,3,5-triazines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00356J, Research ArticleBohao Zhang, Sifan He, Na Dong, Antong Zhu, Haojie Duan, Dunjia Wang, Yao ZhouAn unprecedented metal-free divergent cyclization reaction of benzo[c][1,2]dithiol-3-ones with hexahydro-1,3,5-triazines to assemble six- and eight-membered N-containing heterocycles has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00412D, Research ArticleChengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling SongA deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00481G, Research ArticleJia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin LiaoThree typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Thiourea as a precatalyst for the electron donor–acceptor complex photoactivation platform of oxime esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00424H, Research ArticleHaichen Mao, Yuting Zhang, Hengrong Cao, Qianqian Shi, Yu Lan, Junbiao Chang, Bo ZhuA novel electron donor–acceptor (EDA) complex catalysis strategy has been developed using thiourea as a precatalyst under blue LED irradiation. Using 2–5 mol% of thiourea, various nitrogen-containing compounds were successfully synthesized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
