This copepod Aleutha potter,officially named and described in 2007, is found in Potter Cove, King George Island, Antarctica. Copepod (Kope = Greek for “oar” Podos = […]

The post World of Copepods appeared first on Smithsonian Insider.

Scientists at the University of Arizona and in California have completed the most challenging large astronomical mirror ever made.

The post First of seven mirrors completed for Giant Magellan Telescope appeared first on Smithsonian Insider.

This simulated image shows the Giant Magellan Telescope in operation in Chile while deploying lasers for its adaptive-optics system. The GMT is scheduled to begin […]

The post Giant Magellan Telescope appeared first on Smithsonian Insider.

Recent spectroscopic analysis of macaroni penguin (Eudyptes chrysolophus) crest feathers and king penguin (Aptenodytes patagonicus) neck feathers have shown they contain a yellow pigment that […]

The post Yellow pigment in penguin feathers is chemically distinct, spectroscopic studies reveal appeared first on Smithsonian Insider.

NASA’s Interface Region Imaging Spectrograph (IRIS) spacecraft launched at 10:27 p.m. EDT Wednesday, June 26 from Vandenberg Air Force Base, Calif. Its primary goal is […]

The post NASA launches IRIS carrying Smithsonian-built telescope appeared first on Smithsonian Insider.

An 880-pound asteroid moving at 38,000 miles per hour hit the moon last September with a blast equivalent to 15 tons of TNT. While errant […]

The post Give us the telescopes and we’ll find the asteroid mines! appeared first on Smithsonian Insider.

A research team from the Smithsonian and Arizona State University have developed a new, non-destructive method using spectroscopic analysis to help unravel the complex chemistry […]

The post Feathers yield mysteries of pigment chemistry to spectroscopic analysis appeared first on Smithsonian Insider.

From bizarre bugs to penis spines on bats, our world is infinitely expanded when we look down the microscope! Check out the stories behind these […]

The post What is that?! Five Amazing Microscopic Images appeared first on Smithsonian Insider.

Astronomers have measured the passing of a super-Earth in front of a bright, nearby Sun-like star using a ground-based telescope for the first time. The […]

The post A first: Ground-based telescope detects super-earth transit appeared first on Smithsonian Insider.

  In the store-rooms of the National Museum of American History curators recently discovered a small microscope made around 1750 by John Cuff (1708-1772), a […]

The post The oldest microscope in the museum appeared first on Smithsonian Insider.

The center of our Milky Way galaxy is a mysterious place. Not only is it thousands of light-years away, it’s also cloaked in so much […]

The post RADIO TELESCOPES COULD SPOT STARS HIDDEN IN THE GALACTIC CENTER appeared first on Smithsonian Insider.

Most people think of black holes as giant vacuum cleaners sucking in everything that gets too close. But the supermassive black holes at the centers […]

The post Event Horizon Telescope Reveals Magnetic Fields at Milky Way’s Central Black Hole appeared first on Smithsonian Insider.

The world’s most indestructible species, the tardigrade, an eight-legged micro-animal, also known as the water bear, will survive until the Sun dies, according to a […]

The post Study determines microscopic water bears will be Earth’s last survivors appeared first on Smithsonian Insider.

The Giant Magellan Telescope Organization (GMTO) today announced that it has initiated the casting of the fifth of seven mirrors that will form the heart of […]

The post Fifth mirror cast for Giant Magellan Telescope appeared first on Smithsonian Insider.

In the past 50 years, the amount of water in the open ocean with zero oxygen has increased more than fourfold. In coastal water bodies, […]

The post Earth’s oceans are losing their breath. Here’s the global scope appeared first on Smithsonian Insider.

Very early on, cockroach moms found out maternal care gave their offspring a better chance at survival. The cockroach parenting method—which includes feeding, guarding and […]

The post Helicopter cockroach moms have protected their young for millions of years appeared first on Smithsonian Insider.

Mycoplasma hyopneumoniae is a prokaryotic pathogen that colonizes the respiratory ciliated epithelial cells in swine. Infected animals suffer respiratory lesions, causing major economic losses in the porcine industry. Characterization of the immunodominant membrane-associated proteins from M. hyopneumoniae may be instrumental in the development of new therapeutic approaches. Here, the crystal structure of P46, one of the main surface-antigen proteins, from M. hyopneumoniae is presented and shows N- and C-terminal α/β domains connected by a hinge. The structures solved in this work include a ligand-free open form of P46 (3.1 Å resolution) and two ligand-bound structures of P46 with maltose (2.5 Å resolution) and xylose (3.5 Å resolution) in open and closed conformations, respectively. The ligand-binding site is buried in the cleft between the domains at the hinge region. The two domains of P46 can rotate with respect to each other, giving open or closed alternative conformations. In agreement with this structural information, sequence analyses show similarities to substrate-binding members of the ABC transporter superfamily, with P46 facing the extracellular side as a functional subunit. In the structure with xylose, P46 was also bound to a high-affinity (Kd = 29 nM) Fab fragment from a monoclonal antibody, allowing the characterization of a structural epitope in P46 that exclusively involves residues from the C-terminal domain. The Fab structure in the complex with P46 shows only small conformational rearrangements in the six complementarity-determining regions (CDRs) with respect to the unbound Fab (the structure of which is also determined in this work at 1.95 Å resolution). The structural information that is now available should contribute to a better understanding of sugar nutrient intake by M. hyopneumoniae. This information will also allow the design of protocols and strategies for the generation of new vaccines against this important swine pathogen.

The use of strongly bent crystals in spectrometers for pulses of a hard X-ray free-electron laser is explored theoretically. Diffraction is calculated in both dynamical and kinematical theories. It is shown that diffraction can be treated kinematically when the bending radius is small compared with the critical radius given by the ratio of the Bragg-case extinction length for the actual reflection to the Darwin width of this reflection. As a result, the spectral resolution is limited by the crystal thickness, rather than the extinction length, and can become better than the resolution of a planar dynamically diffracting crystal. As an example, it is demonstrated that spectra of the 12 keV pulses can be resolved in the 440 reflection from a 20 µm-thick diamond crystal bent to a radius of 10 cm.

A mysterious nocturnal animal was leaving its tracks on the delicate mirrors of the telescopes at the Smithsonian's Whipple Observatory in Arizona. With a little ingenuity and a live trap, the mystery was solved. The visitor proved to be a ringtail cat, a member of the raccoon family.

The post Astronomers solve mystery of dusty foot trails crossing telescope mirrors appeared first on Smithsonian Insider.

The new copper(II) complex [CuLCl2]2, where L is a product of Schiff base condensation between methyl­amine and 2-pyridine­carbaldehyde, is built of discrete centrosymmetric dimers.

The title complex, Cu(L)2 or [Cu(C15HF10O2)2], comprising one copper ion and two fully fluorinated ligands (L−), was crystallized with 3,4-ethyl­ene­dioxy­thio­phene (EDOT, C6H6O2S) as a guest mol­ecule to give in a di­chloro­methane solution a unique co-crystal, Cu(L)2·3C6H6O2S.

The new copper(II) complex, namely, di-μ-chlorido-bis{chlorido[methyl(pyridin-2-ylmethylidene)amine-κ2N,N']copper(II)}, [Cu2Cl4(C7H8N2)2], (I), with the ligand 2-pyridylmethyl-N-methylimine (L, a product of Schiff base condensation between methylamine and 2-pyridinecarbaldehyde) is built of discrete centrosymmetric dimers. The coordination about the CuII ion can be described as distorted square pyramidal. The base of the pyramid consists of two nitrogen atoms from the bidentate chelate L [Cu—N = 2.0241 (9), 2.0374 (8) Å] and two chlorine atoms [Cu—Cl = 2.2500 (3), 2.2835 (3) Å]. The apical position is occupied by another Cl atom with the apical bond being significantly elongated at 2.6112 (3) Å. The trans angles of the base are 155.16 (3) and 173.79 (2)°. The Cu...Cu separation in the dimer is 3.4346 (3) Å. In the crystal structure, the loosely packed dimers are arranged in stacks propagating along the a axis. The X-band polycrystalline 77 K EPR spectrum of (I) demonstrates a typical axial pattern characteristic of mononuclear CuII complexes. Compound (I) is redox active and shows a cyclic voltammetric response with E1/2 = −0.037 V versus silver–silver chloride electrode (SSCE) assignable to the reduction peak of CuII/CuI in methanol as solvent.

Experimental electron-density studies based on high-resolution diffraction experiments allow halogen bonds between heavy halogens to be classified. The topological properties of the electron density in Cl⋯Cl contacts vary smoothly as a function of the inter­action distance. The situation is less straightforward for halogen bonds between iodine and small electronegative nucleophiles, such as nitro­gen or oxygen, where the electron density in the bond critical point does not simply increase for shorter distances. The number of successful charge–density studies involving iodine is small, but at least individual examples for three cases have been observed. (a) Very short halogen bonds between electron-rich nucleophiles and heavy halogen atoms resemble three-centre–four-electron bonds, with a rather symmetric heavy halogen and without an appreciable σ hole. (b) For a narrow inter­mediate range of halogen bonds, the asymmetric electronic situation for the heavy halogen with a pronounced σ hole leads to rather low electron density in the (3,−1) critical point of the halogen bond; the properties of this bond critical point cannot fully describe the nature of the associated inter­action. (c) For longer and presumably weaker contacts, the electron density in the halogen bond critical point is only to a minor extent reduced by the presence of the σ hole and hence may be higher than in the aforementioned case. In addition to the electron density and its derived properties, the halogen–carbon bond distance opposite to the σ hole and the Raman frequency for the associated vibration emerge as alternative criteria to gauge the halogen-bond strength. We find exceptionally long C—I distances for tetra­fluoro­diiodo­benzene molecules in cocrystals with short halogen bonds and a significant red shift for their Raman vibrations.

An efficient synthesis of 1-aryl­isochromeno[3,4-d][1,2,3]triazol-5(1H)-ones, involving the diazo­tization of 3-amino-4-aryl­amino-1H-isochromen-1-ones in weakly acidic solution, has been developed and the spectroscopic characterization and crystal structures of four examples are reported. The mol­ecules of 1-phenyl­isochromeno[3,4-d][1,2,3]triazol-5(1H)-one, C15H9N3O2, (I), are linked into sheets by a combination of C—H⋯N and C—H⋯O hydrogen bonds, while the structures of 1-(2-methyl­phen­yl)isochromeno[3,4-d][1,2,3]triazol-5(1H)-one, C16H11N3O2, (II), and 1-(3-chloro­phen­yl)isochromeno[3,4-d][1,2,3]triazol-5(1H)-one, C15H8ClN3O2, (III), each contain just one hydrogen bond which links the mol­ecules into simple chains, which are further linked into sheets by π-stacking inter­actions in (II) but not in (III). In the structure of 1-(4-chloro­phen­yl)isochromeno[3,4-d][1,2,3]triazol-5(1H)-one, (IV), isomeric with (III), a combination of C—H⋯O and C—H⋯π(arene) hydrogen bonds links the mol­ecules into sheets. When com­pound (II) was exposed to a strong acid in methanol, qu­anti­tative conversion occurred to give the ring-opened transesterification product methyl 2-[4-hy­droxy-1-(2-methyl­phen­yl)-1H-1,2,3-triazol-5-yl]benzoate, C17H15N3O3, (V), where the mol­ecules are linked by paired O—H⋯O hydrogen bonds to form centrosymmetric dimers.

An operationally simple and time-efficient approach has been developed for the synthesis of racemic N-substituted 3-(2-aryl-2-oxoeth­yl)-3-hy­droxy­indolin-2-ones by a piperidine-catalysed aldol reaction between aryl methyl ketones and N-alkyl­isatins. These aldol products were used successfully as strategic inter­mediates for the preparation of N-substituted (E)-3-(2-hetaryl-2-oxo­ethyl­idene)indolin-2-ones by a stereoselective dehydration reaction under acidic conditions. The products have all been fully characterized by 1H and 13C NMR spectroscopy, by mass spectrometry and, for a representative selection, by crystal structure analysis. In each of (RS)-1-benzyl-3-hy­droxy-3-[2-(4-meth­oxy­phen­yl)-2-oxoeth­yl]indolin-2-one, C24H21NO4, (Ic), and (RS)-1-benzyl-3-{2-[4-(di­methyl­amino)­phen­yl]-2-oxoeth­yl}-3-hy­droxy­indolin-2-one, C25H24N2O3, (Id), inversion-related pairs of mol­ecules are linked by O—H⋯O hydrogen bonds to form R22(10) rings, which are further linked into chains of rings by a combination of C—H⋯O and C—H⋯π(arene) hydrogen bonds in (Ic) and by C—H⋯π(arene) hydrogen bonds in (Id). The mol­ecules of (RS)-1-benzyl-3-hy­droxy-3-[2-oxo-2-(pyridin-4-yl)eth­yl]indolin-2-one, C22H18N2O3, (Ie), are linked into a three-dimensional framework structure by a combination of O—H⋯N, C—H⋯O and C—H⋯π(arene) hydrogen bonds. (RS)-3-[2-(Benzo[d][1,3]dioxol-5-yl)-2-oxoeth­yl]-1-benzyl-3-hy­droxy­indolin-2-one, C24H19NO5, (If), crystallizes with Z' = 2 in the space group Poverline{1} and the mol­ecules are linked into com­plex sheets by a combination of O—H⋯O, C—H⋯O and C—H⋯π(arene) hydro­gen bonds. In each of (E)-1-benzyl-3-[2-(4-fluoro­phen­yl)-2-oxo­ethyl­idene]indolin-2-one, C23H16FNO2, (IIa), and (E)-1-benzyl-3-[2-oxo-2-(thiophen-2-yl)ethylidene]indolin-2-one, C21H15NO2S, (IIg), the mol­ecules are linked into simple chains by a single C—H⋯O hydrogen bond, while those of (E)-1-benzyl-3-[2-oxo-2-(pyridin-4-yl)ethyl­idene]indolin-2-one, C22H16N2O2, (IIe), are linked by three C—H⋯O hydrogen bonds to form sheets which are further linked into a three-dimensional structure by C—H⋯π(arene) hydrogen bonds. There are no hydrogen bonds in the structures of either (E)-1-benzyl-3-[2-(4-meth­oxy­phen­yl)-2-oxo­ethyl­idene]indolin-2-one, C24H19NO3, (IIc), or (E)-1-benzyl-5-chloro-3-[2-(4-chloro­phen­yl)-2-oxo­ethyl­idene]indolin-2-one, C23H15Cl2NO2, (IIh), but the mol­ecules of (IIh) are linked into chains of π-stacked dimers by a combination of C—Cl⋯π(arene) and aromatic π–π stacking inter­actions.

The federal government should not increase the maximum level of copper allowed in drinking water, because higher levels could lead to liver poisoning in infants and children with certain genetic disorders.

The opportunities surrounding a potential district-scale prospect are outlined by Hannan Metals CEO Michael Hudson in conversation with Maurice Jackson of Proven and Probable.

New research has compared the environmental impact of four alternative methods of water supply in Copenhagen. Results indicated that rain and stormwater harvesting is the most environmentally sound approach, whilst desalination currently has a large environmental impact, mainly due to electricity use. However, if freshwater extraction is included as an impact, the environmental credibility of desalination is improved.

For more than 120 years the Venus Table of the Dresden Codex -- an ancient Mayan book containing astronomical data -- has been of great interest to scholars around the world. The accuracy of its observations, especially the calculation of a kind of 'leap year' in the Mayan Calendar, was deemed an impressive curiosity used primarily for astrology.

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Acute exacerbations of chronic obstructive pulmonary disease, or COPD, are associated with significant long-term lung function loss, according to research published online, ahead of print in the American Thoracic Society's American Journal of Respiratory and Critical Care Medicine.

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There is greater potential for non-governmental organisations (NGOs) to influence the environmental responsibilities of small and medium enterprises (SMEs), suggests new research in Hungary. The study says that environmental policymakers should consider how they could enhance SME-NGO relations.

Following extreme weather events, many countries are unable to afford the costs of providing relief to communities and repairing infrastructure, a new study suggests. The researchers estimate that providing relief on a global scale for events which recur every 10 to 50 years would cost US$3.3 billion (€2.37 billion) annually.

Global demand for copper could increase by up to 341% by 2050, and energy use is likely to increase with it — rising to a possible 2.4% of global energy demand in 2050, according to new research. Policy actions to avoid such drastic changes could include improving copper recycling and using renewable technologies.

The German Renewable Energy Sources Act was introduced in 2001 to encourage an increase in renewable energy supply. Since then, supply has increased from 7% (in 2001) to 37% (in 2017. Wind energy is an important part of Germany’s renewable energy production — but deploying sufficient turbines to achieve the climate goals requires a large amount of raw materials, many of which are metals in limited supply. This study found copper and dysprosium to be the most critical of these metals, as they could face future bottlenecks and are essential elements in present and future turbine design.

Phosphate is added to domestic drinking water to reduce lead levels in the UK, to help meet EU Drinking Water Directive standards. New research has now found that phosphate can also reduce the amount of copper in domestic sewage by more than a third. This method could help Member States meet forthcoming “safe” levels for water discharged to the environment, under forthcoming EU Water Framework Directive (WFD) proposals.

A new study of European river restoration projects has indicated that their impact on the physical characteristics of rivers depends on the region, river type and restoration approach. However, regardless of the river, region or approach, impacts on the biodiversity of riverbed species is limited. Larger scale projects could be more effective.

How can ecotourism be managed so that tourists' visits are compatible with the protection of species and their habitats? In a new study, researchers developed a tool to calculate the trade-off between tourism and the protection of an endangered bird in an Austrian national park, in order to optimise conservation and visitor management.

Copper (Cu) is frequently used in agricultural practices, particularly in fungicides, used extensively in the management of permanent crops, such as vineyards, olive groves, and fruit orchards — all crops of significant economic importance to the EU. An investigation into the factors influencing Cu distribution in the topsoils of 25 EU Member States has identified that, in conjunction with other factors such as topsoil properties, land cover, and climate, such agricultural management practices play a role in influencing Cu concentration. The analysis used 21 682 soil samples from the EU-funded Land Use and Coverage Area frame Survey (LUCAS)¹ and found that vineyards, olive groves, and orchards had the highest mean soil Cu concentrations of all land use categories. The findings highlight the major impact of land use and agricultural practices on soil Cu concentrations and emphasise a need for more sustainable land management practices.

A technique called reflectance spectroscopy is the subject of a new literature review focusing on the use of this tool to study the effects of air pollution on vegetation. In particular, the researchers suggest that the technique could be more widely applied in the Mediterranean region, to study the effects of climate change and air pollution, which will be detrimental to crop growth as well as other vegetation. It could also be used as a more general biomonitoring technique for assessing pollutant levels in the environment.

Researchers have assessed the phyto-toxic effects of copper nanoparticles on vegetables grown within urban gardens, comparing increasing doses of these nanoparticles to simulate potential aerial deposition to extreme pollution of CuO-NP in a range of increasing exposure periods. Lettuce and cabbage absorbed high amounts of copper nanoparticles, after 15 days of exposure, which interfered with photosynthesis, respiration and also reduced growth. Under the specific exposure conditions of the study the researchers indicate that metal nanoparticles could lead to potential health risks to humans from the contamination of crops from pollution.

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The post Oz Minerals study confirms West Musgrave copper potential appeared first on The Lead SA.

Join Copper House on Saturday, November 2, for a colourful celebration at their Day of the Dead Party.

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NTU Singapore has unveiled its COVID-19 Relief Package comprising three new coordinated measures to assist students facing hardship due to the pandemic....