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24 hours in Copenhagen

Another short trip report. Just an overnight in Copenhagen to go see a ballet and a little of the city. Since this is on SAS it now fulfills the flight requirements for the status match from BA, and I am now SkyTeam Elite Plus until November 2026....




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Extensive Drill Program Aims to Unlock New Copper and Molybdenum Zones in Southern Colombia

Libero Copper and Gold Corp. (LBC:TSX.V; LBCMF:OTCQB) announced the progress and objectives of its 14,000-metre exploration program at the Mocoa porphyry copper-molybdenum project in southern Colombia. Read more to discover how this ambitious program targets high-grade copper and molybdenum zones.




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COP29 participants endorse new rules on global carbon markets

The COP29 Summit in Baku has approved the key rules that would govern trade in carbon credits. A UN-backed global carbon market is likely to begin next year or so. Despite the BASIC grouping’s demand that discussions on ‘climate change-related, trade-restrictive unilateral measures’ like Europe's CBAM should be included in the main agenda, it was decided that CBAM would be discussed informally.




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Copy of IWMW 2008 Ning social network produced

Following changes to the terms and conditions of the Ning social networking service a copy of the IWMW 2008 Ning social network has been taken. [16 August 2008]




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USAF Eyes $100,000 Per Copy Munitions

The U.S. Air Force’s inventory of high-end munitions is sufficient, as the service moves to field lower-cost, $100,000 models in the coming years to bolster capacity to deter China and […]




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The TRUMP EFFECT: Argentina suddenly withdraws negotiators from Cop29 summit after just 3 days!

Argentina’s negotiating team were ordered home. The country’s president Javier Milei has previously said that the climate crisis is a “socialist lie”. “We have instructions from the ministry of foreign affairs to no longer participate,” the country’s top environmental official said,

France’s ecology minister, Agnes Pannier-Runacher, announced she was cancelling her trip to Baku to take part in the Cop29 talks. 

On Wednesday, representatives from Milei’s government were ordered to leave the Azerbaijani capital. Speaking to the Guardian, Argentina’s undersecretary for the environment, Ana Lamas – the country’s most senior representative on the climate and nature after Milei dissolved the environment ministry – confirmed the decision, which was first reported by Climatica.

“It’s true. We have instructions from the ministry of foreign affairs to no longer participate. That’s all I can tell you,” she said. Lamas said the decision applied only to Cop29, when asked if Argentina was planning to leave the Paris agreement.

There is widespread concern about the future of the climate accord after the election in the US of Donald Trump, who has pledged to exit the agreement for the second time.




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Day 2 of COP29: Azerbaijan Pres says fossil fuels a ‘Gift from God’, UN parades world leaders

https://www.cfact.org/2024/11/13/day-2-azerbaijan-president-says-fossil-fuels-a-gift-from-god-un-parades-world-leaders/ By Craig Rucker Day two of the UN Conference of the Parties meeting (COP 29) in Baku, Azerbaijan, saw numerous heads of state roll into town to pay homage to he global warming cause. In all, some 100 world leaders were represented, with many ushered into the main plenary stage to deliver short testimonials on how […]




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TRUMP EFFECT: New York Times columnist: ‘Climate Change Is Losing Its Grip on Our Politics’ – Trump’s election ‘looks like a black dawn to climate activists’ – ‘Governments have retreated’ from climate ‘promises’ as world leaders skip COP29

https://www.nytimes.com/2024/11/13/opinion/climate-change-politics-trump-cop29.html By David Wallace-Wells When the COP29 climate conference comes to an end next week, it will have concluded without an appearance by President Biden. This is not because Donald Trump just won the election, supplanting the outgoing American head of state on the world stage. The president-elect isn’t attending, either. Neither is Vice President […]




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Solidigm's Monster 122-Terabyte SSD Is Here For Copious Data Center Storage

You remember yesterday, when we wrote about Micron's new 6550 ION SSD and how it wasn't exactly the biggest SSD we'd seen? Well, that was yesterday. Today, Solidigm is announcing a new model in the D5-P5336 SSD family with a whopping 122.88 terabytes of storage in a single drive, finally topping the Nimbus Exadrive. Micron still holds the




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Webb telescope sees world that could reek of burnt matches and rotten eggs

With the help of the James Webb Space Telescope, astronomers have discovered an exoplanet with a sulfur-rich atmosphere, a hint of volcanic activity.




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Horóscopo de hoy jueves 14 de noviembre de 2024

 Leer




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COP 29, Day 3: Small islands reaffirm commitments, and Climate Action Commissioner EU's leadership

COP 29, Day 3: Small islands reaffirm commitments, and Climate Action Commissioner EU's leadership




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New Product Spotlight: Aeriz, Copperstate Farms revisit the old while exploring the new

Award-winning cannabis cultivator Aeriz has debuted a carefully crafted lineup of four new cannabis strains…



  • News & Opinion/Cannabis

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Grizzled cop says he's retiring soon, dies - first use of trope?

So I was watching a movie that's close to 40 years old that featured not only the "I'm too old for this shit!" line but also the trope where there's a cop announcing he's due to retire in a few days who more or less immediately gets killed. What is the earliest appearance of this trope? (This will by its nature be a spoilery thread. Since I'm looking for examples that are 40+ years old, I don't think that should be an issue for most people, but if you're some kind of anti-spoiler monastic even on movies old nearly enough to retire from the police force themselves, feel free to opt out.)

The movie I was watching was To Live and Die in LA, by the way.

I'm fully expecting someone who frequents those movie trope pages to have a handy link for this, but I'm also figuring some example by example sorting may be in order.

I figure there were probably antecedents to this trope, like maybe WWII movies where a guy's stint is up the next day, then he gets killed by a sniper or what have you. I'm interested to hear about those too, but I'd also like to know where it started with cop movies, what some classic examples are (Lethal Weapon springs to mind), and even if it's appeared much since it's 1980's heyday.




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France furious as Azerbaijan leader accuses it of colonial ‘crimes’ at COP29

President Ilham Aliyev, who is hosting the COP29 UN climate talks, drew loud applause from delegates of some Pacific island nations after a combative speech targeting France's handling of its overseas territories.




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French boycott of COP29 lays bare widening divides at UN climate summit

Azerbaijan’s President Ilham Aliyev lashes out at Emmanuel Macron and steps up defence of oil and gas as regional countries dominate guest list




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BHP set to detail copper growth plans on Chile roadshow, analysts say

In This Article: By Melanie Burton MELBOURNE (Reuters) - BHP Group is likely to flesh out plans next week to spend at least $7 billion over the coming years to recover more metal from the world's biggest copper mine, Escondida in Chile, investors and analysts said on Thursday. The world's biggest…




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Aaron Copland (1900)

Famously public-spirited and generous, Copland came to be unofficially regarded as the US's national composer. Although his earliest works show European influences, the American character of the greater part of his compositions is evident in his use of jazz and American folk tunes. He is best known for his three ballets based on American folk material: Billy the Kid, Rodeo, and Appalachian Spring, for which he won the Pulitzer Prize. For what films did Copland compose music? Discuss




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Polymarket's CEO Shayne Coplan responds after FBI raid

The FBI conducted a raid at Polymarket CEO Shayne Coplan's home Wednesday morning, a company spokesperson told BI.




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News24 | Development bank financing pledge gives COP29 summit early boost

COP29 negotiators welcomed a pledge by major development banks to lift funding to poor and middle-income countries struggling with global warming as an early boost to the two-week summit.




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Fake Cop Gets Caught Pretending To Be A Cop In Front Of A Real Cop




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70-Year-Old Man Thrown Ground During Traffic Stop: Cops




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See Rare First-Edition Copies of Jane Austen's Novels at the Cottage Where She Wrote and Revised Them

A new exhibition at the author's home in Chawton, which has never previously displayed all six first-edition books together, is part of preparations for the author's 250th birthday celebrations




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Explained: What's Climate Finance And Why Countries Are Fighting Over It At COP29

Countries are negotiating a higher target for payments starting next year, but some have been reluctant to confirm its size until it is clear which countries will contribute.




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UN Climate Draft Shows Deep Divide On Funding For Poorer Nations At COP29

A fresh draft of a UN climate deal released Wednesday offers wide-ranging options to raise funding for poorer countries, signalling that tough negotiations remain at the COP29 talks in Baku.




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Navy takes delivery of three Augusta helicopters

The Nigerian Navy has taken delivery of three Agusta Westland 109 Trekker helicopters. The helicopters, which were purchased by the Ministry of Defence, were handed over to the Navy on November 12, 2024. A statement on Wednesday by the Director of Naval Information, Commodore A. Adams-Aliu, said the ministry handed over the helicopters to the


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Development bank financing pledge gives COP29 summit early boost

BAKU, Azerbaijan — COP29 negotiators welcomed as an early boost to the two-week summit a pledge by major development banks to lift funding to poor and middle-income countries struggling with global warming. A group of lenders, including the World Bank, announced a joint goal on Tuesday of increasing this finance to $120 billion by 2030, a roughly 60% increase on the amount in 2023. "I think it's a very good sign," Irish Climate Minister Eamon Ryan told Reuters on Wednesday. "It's very helpful. But that on its own won't be enough," Ryan said, adding countries and companies must also contribute. The chief aim of the conference in Azerbaijan is to secure a wide-ranging international climate financing agreement that ensures up to trillions of dollars for climate projects. Developing countries are hoping for big commitments from rich, industrialized countries that are the biggest historical contributors to global warming, and some of which are also huge producers of fossil fuels. "Developed countries have not only neglected their historical duty to reduce emissions, they are doubling down on fossil-fuel-driven growth," said climate activist Harjeet Singh. Wealthy countries pledged in 2009 to contribute $100 billion a year to help developing nations transition to clean energy and adapt to the conditions of a warming world. But those payments were only fully met in 2022 and the pledge expires this year. With 2024 on track to be the hottest year on record, scientists say global warming and its impacts are unfolding faster than expected. Climate-fueled wildfires forced evacuations in California and triggered air quality warnings in New York. In Spain, survivors are coming to terms with the worst floods in the country's modern history. Albania's Prime Minister Edi Rama said he was concerned that the international process to address global warming, now decades old, was not moving swiftly enough. "This seems exactly like what happens in the real world everyday," he told the conference. "Life goes on with its old habits, and our speeches, filled with good words about fighting climate change, change nothing," Rama added.




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COP29 Facing Challenges Including Climate Denier Trump




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Horoscope 14th November, 2024: Check astrological prediction for Virgo, Sagittarius and other signs - The Indian Express

  1. Horoscope 14th November, 2024: Check astrological prediction for Virgo, Sagittarius and other signs  The Indian Express
  2. Horoscope Today: November 14, 2024  VOGUE India
  3. Love and Relationship Horoscope for November 14, 2024  Hindustan Times
  4. Horoscope Today, November 14, 2024: Read your today's astrological predictions  The Times of India
  5. Aries Daily Horoscope Today (Mar 21 – April 19), November 14, 2024: Relationships will be comfortable!  India Today





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COP29 to Feature Thematic Day on Climate Change and Tourism for the First Time

For the first time, the UN Climate Change conference of the parties will welcome Tourism Ministers, placing the sector firmly within the COP29 Action Agenda and providing a high-level platform for dialogue – at the initiative and joint leadership of the State Tourism Agency of the Republic of Azerbaijan and the World Tourism Organization (UN Tourism).





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Horoscope Today LIVE Updates on November 14, 2024 : Love and Relationship Horoscope for November 14, 2024 - Hindustan Times

  1. Horoscope Today LIVE Updates on November 14, 2024 : Love and Relationship Horoscope for November 14, 2024  Hindustan Times
  2. Horoscope Today: November 14, 2024  VOGUE India
  3. Love and Relationship Horoscope for November 14, 2024  Hindustan Times
  4. Horoscope Today, November 14, 2024: Read your today's astrological predictions  The Times of India
  5. Aries Daily Horoscope Today (Mar 21 – April 19), November 14, 2024: Relationships will be comfortable!  India Today





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Visible light/copper catalysis enabled Heck-like coupling between alkenes and cyclic sulfonium salts via selective C–S bond cleavage

Org. Chem. Front., 2024, 11,2195-2200
DOI: 10.1039/D3QO02009F, Research Article
Xianqin Liu, Xufeng Li, Linyuan Wang, Yongjia Shi, Jian Lv, Daoshan Yang
A Heck-like coupling of cyclic sulfonium salts with alkenes via selective C–S bond cleavage using a copper complex as a photosensitizer through a visible-light-driven redox-neutral process has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Copper-catalyzed oxidative sulfenylation and alkylation of indolin-2-ones for direct construction of sulfur-substituted quaternary carbons

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00491D, Research Article
Yun-Hao Zhang, Yi-Nuo Wang, Zi-Yu Liu, Si-Han Zheng, Guang-Lin Li, Dexin Feng, Da-Zhen Xu
A rapid and green one-pot access to S-substituted quaternary carbon centers from commercially available feedstock chemicals has been established, providing complex molecules with high chemoselectivity by the use of air as the terminal oxidant.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00481G, Research Article
Jia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin Liao
Three typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical nitrate reduction for ammonia production: amorphous or crystalline oxidized copper catalyst?

J. Mater. Chem. A, 2024, 12,8689-8693
DOI: 10.1039/D3TA07506K, Communication
Quanxiao Peng, Dandan Xing, Liuqi Dong, Yuhan Fu, Jixue Lu, Xiaoyu Wang, Changhong Wang, Chunxian Guo
An amorphous oxidized copper (a-O–Cu) is designed to investigate for electrochemical nitrate reduction to ammonia. It is found that a-O–Cu has high capability for water dissociation and amorphous structure-enabled high catalytic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Symmetry-induced Modulation of Proton Conductivity in Y-doped Ba(Zr,Ce)O3: Insights from Raman Spectroscopy

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00415A, Paper
Yiming Yang, Jiachen Lu, Xinyu Zhang, Yanuo Shi, Peng Du, Xiao Ling, Nan Yang, Qianli Chen
Y-doped Ba(Zr,Ce)O3 (BZCY) proton conducting ceramics have attracted extensive attention for their promising applications as electrolytes for intermediate-temperature proton ceramic electrochemical cells. The proton conductivity of BZCY is governed by...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07218E, Paper
Yun-Dong Cao, Di Yin, Ming-Liang Wang, Hong Liu, Yi Feng, Lin-Lin Fan, Cai-Li Lv, Guang-Gang Gao
This work not only confirms the long-standing prediction that the Cu8 center can accommodate an oxygen atom but also demonstrates a novel central atom regulation strategy to obtain highly active copper clusters as photocatalysts.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Molecular-polaron-coupling-enhanced photocatalytic CO2 reduction on copper phthalocyanine/NiMgFe layered double hydroxide nanocomposites

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07538A, Paper
Yuexian Li, Wenli Su, Xiaoyan Wang, Jun Lu, Wenkai Zhang, Shuo Wei
We built CuPcS/NiMgFe-LDHs composites and probed the unique photogenerated-carrier transfer mechanism. A series of long-range Forster energy transfers prolonged the lifetime of photogenerated carriers to match the timescale of surface reaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
The content of this RSS Feed (c) The Royal Society of Chemistry




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India will continue to be vocal about climate finances at COP29




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$19 mn Loss & Damage funding pledged by Sweden at COP29, bringing total pledged funding to $720 mn




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Rajnath Singh stresses on adaptive defence to cope with Age of Grey Zone, hybrid warfare




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COP29: India, other developing countries demand fair climate finance commitments

India, LMDCs advocate for equitable climate finance at COP29, pushing for transparency, fairness, and flexibility in financial commitments




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Anticancer potential of copper(I) complexes based on isopropyl ester derivatives of bis(pyrazol-1-yl)acetate ligands

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00610K, Research Article
Open Access
Maura Pellei, Carlo Santini, Miriam Caviglia, Jo' Del Gobbo, Chiara Battocchio, Carlo Meneghini, Simone Amatori, Chiara Donati, Eleonora Zampieri, Valentina Gandin, Cristina Marzano
In this paper, the isopropyl ester derivatives LOiPr and L2OiPr of bis(pyrazol-1-yl)acetic acid and bis(3,5-dimethyl-pyrazol-1-yl)acetic acid were used as chelators for the preparation of the new Cu(I) phosphane complexes 1-4....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why are countries fighting over climate finance at COP29?

Here is what you need to know about the November 11-22 summit talks on finance.




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COP29: India, other developing countries demand fair climate finance commitments

India, LMDCs advocate for equitable climate finance at COP29, pushing for transparency, fairness, and flexibility in financial commitments