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Pistons' Tim Hardaway Jr leaves game in wheelchair after slamming head on court in scary scene

Detroit Pistons veteran guard Tim Hardaway Jr. was wheelchaired out of the game against the Miami Heat after multiple hits to the head, including slamming it on the court.



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FBI offering $25K reward for info leading to suspect wanted for ballot box fires in Oregon, Washington state

The FBI announced its offering a reward of up to $25,000 for information leading to the arrest of the suspect responsible for West Coast ballot box fires.



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N.S. Liberals allege voter bribery after PC candidate handed out $2 Tim Hortons gift cards

The Liberals want Susan Corkum-Greek removed from the ballot in the upcoming provincial election, but the Nova Scotia Supreme Court confirmed Wednesday it will not hear the case until after voting day on Nov. 26.



  • News/Canada/Nova Scotia

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Candyman, Transformers Actor Tony Todd Dies at 69

Voiced The Faillen in Transformers: Revenge of the Fallen, Dreadwing in Transformers Prime




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Dr. Stone: Science Future Anime's Teaser Reveals 2 New Cast Members

Kenji Nojima, Kōji Yusa join cast as Dr. Xeno, Stanley Snyder




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Want to Prevent Prostate Cancer Naturally? Try Button Mushroom Supplement

An investigational white button mushroom supplement shows promise in slowing and even preventing the spread of prostate cancer among men participating




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Want to Prevent Prostate Cancer Naturally? Try Button Mushroom Supplement

Food as Medicine to Fight Prostate Cancer: White button mushroom supplement can keep prostate cancer at bay.




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Lopesan Hotel Group and Stoneweg Hospitality join forces to acquire Hotel Miguel Angel in Madrid

Lopesan Hotel Group, the leading hotel company from the Canary Islands, in partnership with the investment firm Stoneweg Hospitality, has acquired the Hotel Miguel Angel, previously owned by General Mediterranean Holding S.A SPF, an iconic luxury hotel in the heart of Madrid’s Paseo de la Castellana.




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KE Hotels Expands UK Portfolio With Management of Three Hampton by Hilton Hotels

KE Hotels is pleased to announce the expansion of its UK portfolio with the addition of three Hampton by Hilton hotels under new Hotel Management Agreements (HMA) as of October 2024. The properties now under KE Hotels’ management are Hampton by Hilton Newcastle, Hampton by Hilton Birmingham Broad Street, and Hampton by Hilton Sheffield.




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Tharaldson Hospitality Management Celebrates Opening of Hampton Inn & Suites by Hilton Porter Ranch Los Angeles

Tharaldson Hospitality Management proudly announces the grand opening of their 88th hotel, the Hampton Inn & Suites by Hilton Porter Ranch Los Angeles. This milestone marks another significant achievement in THM’s continued expansion and commitment to delivering exceptional hospitality experiences. Located in the vibrant and rapidly growing area of Porter Ranch, CA, the new Hampton Inn & Suites by Hilton boasts 100 modern and beautifully designed guest rooms, providing visitors with the perfect blend of comfort and convenience. Guests can enjoy premium amenities, including complimentary breakfast, free Wi-Fi, a state-of-the-art fitness center, and a refreshing outdoor pool. The opening of this new hotel comes thanks to the hard work and dedication of the entire THM team, who have worked tirelessly to ensure a seamless and successful launch. THM extends sincere gratitude to every team member for their unwavering commitment and efforts. The Hampton Inn & Suites by Hilton Porter Ranch Lo...




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Sheraton Jumeirah Beach Resort Unveils a New Era of Modern Comfort with a Stunning Transformation

Sheraton Jumeirah Beach Resort is proud to announce its relaunch following an extensive revitalization, redefining the guest experience at this iconic destination. As the first hotel built in the Jumeirah Beach Residence (JBR) area, Sheraton Jumeirah Beach Resort has set the standard for excellence in hospitality for over two decades. This transformation ushers in a new era, blending modern design, amenities, and cutting-edge technology while preserving the resort’s rich history and cherished legacy. The reinvention of the Resort is driven by the vision of bringing people together through shared moments and spaces. The newly reimagined rooms and suites offer a sophisticated fusion of modern design and natural textures, with a color palette inspired by the serene beachfront setting. All rooms have been thoughtfully equipped to cater to the diverse needs of today’s travellers with the latest technologies, providing guests with a seamless blend of comfort and innovation. The bathrooms to...




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Bihar: PM Modi lays foundation stone of multiple projects including AIIMS in Darbhanga

Prime Minister Narendra Modi laid the foundation stone for multiple projects in Bihar, including an AIIMs in Darbhanga district.




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Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00374H, Research Article
Yongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua Liu
Cyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00148F, Research Article
Dong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei Xu
The challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.
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Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00396A, Review Article
Dong-Sheng Yang, Xiang-Long Chen, An-Xin Wu
The synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Metal-Free Cascade O-H Double Insertion Between I(III)/S(VI)-Ylides, Carboxylic Acids, and Alcohols: Modular Access to Unsymmetrical α,α-O,O-Substituted Ketones

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00453A, Research Article
Shang-Shi Zhang, Jiaohang Wei, Wen-Xuan Zou, Qiong Hu, Mei-Zhu Bao, Dan-Ting Shen, Lin Xiao, Jia-Lin Song, Xiang Liu
The synthesis of unsymmetrical α,α-O,O-substituted ketones via O-H double insertion is appealing but remains constrained due to the lack of compatible coupling partners or uncontrollable selectivity. Herein, we present a...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dynamic kinetic resolution of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed asymmetric hydrogenation

Org. Chem. Front., 2024, 11,2201-2207
DOI: 10.1039/D4QO00125G, Research Article
Pengtao Yang, Dingguo Song, Lingxin Chen, Xianghua Zhao, Yirui Chen, Feiyang Shen, Fei Ling, Weihui Zhong
Highly reactive and highly stereoselective asymmetric hydrogenation of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed dynamic kinetic resolution is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iridium-catalyzed reductive γ-lactonization of ortho-acylbenzoic acids in water: sustainable access to phthalides

Org. Chem. Front., 2024, 11,2220-2230
DOI: 10.1039/D3QO02019C, Research Article
Yang Chen, Jingyu Zhang, Hongguang Du, Renshi Luo, Jiaxi Xu, Zhanhui Yang
Iridium-catalyzed reductive γ-lactonization of ortho-acylbenzoic acids in water provides a practical and sustainable route to phthalides.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00351A, Research Article
Fei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng Zhu
Lovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00280F, Research Article
Hui Yin, Siqi Jian, Xiujuan Feng, Ming Bao, Xuan Zhang
A metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.
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A retro-Mannich mediated transformation of Morita–Baylis–Hillman ketones to saturated imidazo[1,2-a]pyridines

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00352G, Research Article
Sachin Sharma, Ajit Kumar Jha, Srinivasan Easwar
Two fruits felled with one stone! – a proof of mechanism and a synthetic method that delivers a privileged heterocyclic motif.
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Development of a photoenzymatic one-pot hybrid system for the direct synthesis of 3,3-disubstituted indole-2-ketones from N-methyl indoles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00371C, Research Article
Yao Yao, Yuan Yu, Ming-Liang Shi, Xin-Yue Fan, Ru-De Lin, Kun Li, Wen-Dian Li, Fei-Yan Tao, Na Wang
The effective combination of photocatalysis and enzyme catalysis has been widely utilized for the synthesis of high-value-added products.
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Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00317A, Research Article
Guohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin Yin
Amine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.
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NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00347K, Research Article
Zhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping Hui
A novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...
The content of this RSS Feed (c) The Royal Society of Chemistry




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[LINK] A new design for Mark Boulton

Words to tattoo on your knuckles:

Over the past couple of years, my blog hasn’t felt my own, to a degree. It’s felt like I’ve been writ­ing for an audi­ence, post­ing stuff for oth­ers rather than myself. That’s arse-backwards. A blog should be about per­sonal expres­sion. The moment you start think­ing, and writ­ing, to please oth­ers then it’s a bind; it feels less like a per­sonal exer­cise and more of a job.

A beautiful, thoughtful redesign from Mark Boulton (and a responsive one at that). Go go, read read.




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[LINK] Mark Boulton on “A Richer Canvas”

I won’t lie to you: I might’ve pounded the table emphatically a few times while reading Mark Boulton’s latest entry:

We can now design effective adaptive layouts that respond to their environment. If these layouts are based on a system that defines its ratios from the content, then there is connectedness on two levels: connectedness to the device, and connectedness to the content.

Mark’s thinking about flexible, content-driven grids has me damned excited about his upcoming talk at AEA Boston, and you know I’ll be flinging fistfuls of lucre at my laptop screen whenever his new book’s available to preorder.

The web really feels fun again.




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Superhydrophilic covalent organic frameworks accelerate photocatalytic production of hydrogen peroxide through proton channels

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01785D, Paper
Xiaojuan Bai, Linlong Guo, Tianqi Jia, Zhuofeng Hu
Superhydrophilic COFs with D–A structure accelerate photocatalytic synthesis of H2O2 using water as a proton supply reservoir.
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Prolonging exciton diffusion length via manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells over 19% efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00594E, Paper
Wang Ke, Fuwen Zhao, Yufan Zhu, Yi He, Zesheng Liu, Xiao Han, Qi Ai, Xingxing Shen, Bao Li, Jianqi Zhang, Yuze Lin, Chun-Ru Wang, Dan He
The limited exciton diffusion length (LD) of organic semiconductors constraints exciton dissociation in pseudo-planar heterojunction (PPHJ) organic solar cells (OSCs), which is deemed as the bottleneck issue hampering the further...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Symmetry-induced Modulation of Proton Conductivity in Y-doped Ba(Zr,Ce)O3: Insights from Raman Spectroscopy

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00415A, Paper
Yiming Yang, Jiachen Lu, Xinyu Zhang, Yanuo Shi, Peng Du, Xiao Ling, Nan Yang, Qianli Chen
Y-doped Ba(Zr,Ce)O3 (BZCY) proton conducting ceramics have attracted extensive attention for their promising applications as electrolytes for intermediate-temperature proton ceramic electrochemical cells. The proton conductivity of BZCY is governed by...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Melatonin treatment as an anti-aging therapy for UV-related degradation of perovskite solar cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01332H, Paper
Fei Liu, Agnes Valencia, Yuhua Zhu, Xiangyang Zhang, Weilu Li, Walid A. Daoud
With the ability to absorb UV light and scavenge radicals, the melatonin modified perovskite exhibits enhanced anti-aging and resistance to UV-related degradation.
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Highly selective and high-performance sulfonated poly(ether ether ketone)-based hybrid membrane enabled by complexed UiO-66-NH2 and sulfonated graphitic carbon nitride for vanadium flow battery

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00988F, Paper
Caiyuan Zhao, Haixia Wang, Lang Li, Liping Liu, Xinrui Cui, Haifeng Shi
A series of sulfonated poly(ether ether ketone) (SPEEK) hybrid membranes (SPEEK/NF) with a constant 1 wt% complexed nanofillers (NF) comprising of UiO-66-NH2 and sulfonated graphitic carbon nitride (s-g-C3N4) are prepared...
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A New 3D Scan, Created from 25,000 High-Resolution Images, Reveals the Remarkably Well-Preserved Wreck of Shackleton’s Endurance

Photos on this page courtesy of the Falklands Maritime Heritage  Few who hear the story of the Endurance could avoid reflecting on the aptness of the ship’s name. A year after setting out on the Imperial Trans-Antarctic Expedition in 1914, it got stuck in a mass of drifting ice off Antarctica. There it remained for ten months, […]




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Greaves Cotton Q2 net loss narrows to ₹14 crore




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CRICKET | Tanmay’s 15th Ranji Trophy ton powers Hyderabad to position of strength

The opener makes Andhra pay a heavy price for a dropped catch early in his innings; off-spinner Vijay the pick of the bowlers with his three wickets




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CCI starts buying cotton at minimum support price




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Tilak’s maiden ton, Abhishek’s 50 fire India to 219/6 against South Africa in 3rd T20I

Tilak Varma got ample backing from Abhishek Sharma who made a brisk 50 after SA skipper Aiden Markram invited the visitors to bat first.




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Shares plummet 11% post Greaves Cotton’s mixed Q2 results  

Greaves Cotton reported consolidated revenue of ₹705 crore for Q2 FY25, with standalone revenue growing by 2 per cent to ₹468 crore




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Binghamton University Expands Efforts to Protect Birds From Deadly Collisions

Glass windows are an invisible killer, resulting in billions of bird deaths in the U.S. each year. To prevent collisions on campus. Binghamton University, State University of New York has installed bird-safe windows.




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Pickin' Cotton

Pickin' Cotton by William Tolliver is a(n) Limited Edition. The Edition is Limited to 1000 S/N pcs




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Jammin Limited Edition Stone Lithograph

Jammin Limited Edition Stone Lithograph by William Tolliver is a(n) Limited Edition. The Edition is Limited to Limited Edition pcs




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Early Ordovician to Early Devonian tectonic development of the northern margin of Laurentia, Canadian Arctic Islands

Dewing, K; Hadlari, T; Pearson, D G; Matthews, W. Geological Society of America Bulletin 2019 p. 1-20, https://doi.org/10.1130/B35017.1
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20160081.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20160081.jpg" title="Geological Society of America Bulletin 2019 p. 1-20, https://doi.org/10.1130/B35017.1" height="150" border="1" /></a>




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Tectonic-paleogeographic implications of a detailed Cretaceous-Cenozoic exhumation history in the Richardson Anticlinorium, northern Yukon, documented by multi-kinetic apatite fission track modelling

Lane, L S; Issler, D R; O'Sullivan, P B. Geoconvention 2020 abstracts; 2020 p. 1-2
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20210002.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20210002.jpg" title="Geoconvention 2020 abstracts; 2020 p. 1-2" height="150" border="1" /></a>




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Field data, till composition, and ice-flow history, south Rae Craton, Northwest Territories: results from the GEM-2 South Rae project - Surficial Mapping activity

Campbell, J E; McCurdy, M W; Lauzon, G; Regis, D; Wygergangs, M. Geological Survey of Canada, Open File 8714, 2020, 40 pages, https://doi.org/10.4095/327218
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_327218.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_327218.jpg" title="Geological Survey of Canada, Open File 8714, 2020, 40 pages, https://doi.org/10.4095/327218" height="150" border="1" /></a>




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High-resolution correlation between contrasting early Tonian carbonate successions in NW Canada highlights pronounced global carbon isotope variations

Greenman, J W; Rainbird, R H; Turner, E C. Precambrian Research vol. 346, 105816, 2020 p. 1-17, https://doi.org/10.1016/j.precamres.2020.105816
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200113.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200113.jpg" title="Precambrian Research vol. 346, 105816, 2020 p. 1-17, https://doi.org/10.1016/j.precamres.2020.105816" height="150" border="1" /></a>




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Archean and Paleoproterozoic cratonic rocks of Baffin Island

Re-release; St-Onge, M R; Scott, D J; Rayner, N; Sanborn-Barrie, M; Skipton, D R; Saumur, B M; Wodicka, N; Weller, O M. Geological synthesis of Baffin Island (Nunavut) and the Labrador-Baffin Seaway; by Dafoe, L T (ed.); Bingham-Koslowski, N (ed.); Geological Survey of Canada, Bulletin 608, 2020 p. 25-53, https://doi.org/10.4095/321824
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_321824.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_321824.jpg" title="Geological synthesis of Baffin Island (Nunavut) and the Labrador-Baffin Seaway; by Dafoe, L T (ed.); Bingham-Koslowski, N (ed.); Geological Survey of Canada, Bulletin 608, 2020 p. 25-53, https://doi.org/10.4095/321824" height="150" border="1" /></a>




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Dinoflagellate cyst taxonomy of the Late Cretaceous Smoking Hills Formation (Horton-Anderson Plains, NWT)

Bringué, M; Fensome, R A; Galloway, J M. Geoconvention 2020 abstracts; 2020 p. 1-2
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20190494.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20190494.jpg" title="Geoconvention 2020 abstracts; 2020 p. 1-2" height="150" border="1" /></a>




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U-Pb zircon ages of plutonic rocks in the eastern Slave Craton and adjacent Thelon tectonic zone, Nunavut, determined by laser-ablation inductively coupled multi-collector mass spectrometry

Berman, R G; Camacho, A. Geological Survey of Canada, Open File 8703, 2020, 20 pages, https://doi.org/10.4095/321633
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/of8703.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/of8703.jpg" title="Geological Survey of Canada, Open File 8703, 2020, 20 pages, https://doi.org/10.4095/321633" height="150" border="1" /></a>




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The composite nature of pericratonic Yukon-Tanana Terrane and its distinction from parautochthonous North American rocks in west-central Yukon

Ryan, J J; Cleven, N R; Zagorevski, A; van Staal, C R; Parsons, A J; Joyce, N L; Kellett, D A. Geological Survey of Canada, Scientific Presentation 114, 2020, 1 sheet, https://doi.org/10.4095/321431
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/sp0114.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/sp0114.jpg" title="Geological Survey of Canada, Scientific Presentation 114, 2020, 1 sheet, https://doi.org/10.4095/321431" height="150" border="1" /></a>




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40Ar/39Ar hornblende and biotite cooling ages for metaplutonic rocks of the central Thelon Tectonic Zone, Nunavut

Camacho, A; Berman, R G; Sanborn-Barrie, M. Geological Survey of Canada, Open File 8625, 2020, 77 pages, https://doi.org/10.4095/315135
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/of8625.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/of8625.jpg" title="Geological Survey of Canada, Open File 8625, 2020, 77 pages, https://doi.org/10.4095/315135" height="150" border="1" /></a>




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Early Cambrian maximum depositional age for the upper Yelverton Formation, northern Ellesmere Island, Nunavut

Hadlari, T; Matthews, W A. Geological Survey of Canada, Open File 8820, 2021, 15 pages, https://doi.org/10.4095/328836
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_328836.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_328836.jpg" title="Geological Survey of Canada, Open File 8820, 2021, 15 pages, https://doi.org/10.4095/328836" height="150" border="1" /></a>