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Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05792A, Edge Article
Open Access
Jyoti Yadav, Sanjit Konar
Stimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential for functional devices. However, engineering complexes with controlled switchability remains challenging due to their sensitivity to lattice...
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India's climate policies expected to reduce CO2 emissions by around 4 billion tonnes by 2030: Report

The study by Delhi-based independent think tank Council on Energy, Environment and Water (CEEW) said policies for India's power, residential and transport sectors have already saved 440 million tonnes of carbon dioxide (MtCO2) between 2015 and 2020.




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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance

Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper
Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
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Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction

Dalton Trans., 2024, 53,17772-17776
DOI: 10.1039/D4DT02595D, Communication
Zaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi Yi
Neutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.
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An innovative CuxAg50−x/UiO66-NH2 photocatalyst prepared using a dual ship bottling strategy for photocatalytic CO2 reduction: controlled product selectivity and pathways

Energy Environ. Sci., 2024, 17,8228-8242
DOI: 10.1039/D4EE03103B, Paper
Lipeng Jiang, Dengqian Chen, Zhengkai Hao, Dongxue Cao, Runqiao Liu, Jingyu Cheng, Limei Chen, Xin Liu, Boyin Jia, Dongdong Liu
This study proposed a “dual ship bottling” strategy to synthesize CuxAg50−x/UiO66-NH2, achieving over 90% selectivity for reduced carbon products.
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Experimental study of CO2 capture from air via steam-assisted temperature-vacuum swing adsorption with a compact kg-scale pilot unit

React. Chem. Eng., 2024, 9,910-924
DOI: 10.1039/D3RE00460K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
H. M. Schellevis, D. W. F. Brilman
Reactor design and process performance evaluation.
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Immunomodulatory effects of supercritical CO2 extracted oils from Portulaca oleracea and Perilla frutescens (PPCE) in healthy individuals: a randomized double-blind clinical trial

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03361B, Paper
Su-Jin Jung, Hyang-Im Baek, Eun-Ock Park, Ki-Chan Ha, Deuk-Seon Park, Soo-Wan Chae, Seung-Ok Lee
This study evaluated the immune-boosting effects of Portulaca oleracea L. and Perilla frutescens var. japonica Hara extract oils (PPCE) in healthy individuals. PPCE improved NK cell activity and cytokine levels (IL-12, IFN-γ) without adverse effects, supporting immune enhancement.
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Solar-Driven Tripus Photocatalytic Action of Defective S-doped g-C3N4 for 1,4 NADH Regeneration and Simultaneous Benzylamine Conversion along with CO2 Fixation into HCOOH

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00825A, Paper
Kanchan Sharma, Rajesh K. Yadav, Rajesh Kumar Verma, Satyam Singh, Shaifali Mishra, Rehana Shahin, Atul Pratap Singh, Chandani Singh, Navneet Kumar Gupta, Jin-Ook Baeg, Hwanhui Yun, Hyeongjoong Kim
Incorporating defects through intrinsic defect engineering has emerged as a versatile strategy for finely tuning key properties of materials, particularly the redox capacity. Defects are fundamentally important in enhancement of...
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Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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First-principles investigation of an efficient non-noble single-atom catalyst Fe1/Ti2CO2 for formaldehyde oxidation

Catal. Sci. Technol., 2024, 14,6233-6246
DOI: 10.1039/D4CY00809J, Paper
Yongkang Zhang, Yuting Fu, Kaibin Su, Yuhang Wang, Fengping Wang
Indoor formaldehyde (HCHO) removal holds paramount significance for human health, particularly in mild conditions. Fe1/Ti2CO2 is an efficient catalyst that can remove indoor formaldehyde.
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Cycloaddition of CO2 with epoxides into cyclic carbonates catalyzed by a binary organocatalyst under mild conditions

Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper
Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO2 into cyclic carbonates from flue gas under atmospheric pressure.
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New insights into influences of initial oxidization states on dynamic reconstruction of Cu catalysts and C–C coupling in CO2 reduction

Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper
Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO2 reduction, resulting in the dynamic evolution of i-CuOx species. The in situ formed i-CuOx plays decisive roles in promoting C–C coupling.
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Ag co-catalyst prepared by ultrasonic reduction method for efficient photocatalytic conversion of CO2 with H2O using ZnTa2O6 photocatalyst

Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper
Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO2 with H2O—known as artificial photosynthesis—is important.
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Accelerated design of nickel-cobalt based catalysts for CO2 hydrogenation with human-in-the-loop active machine learning

Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO2 methanation and is extendable to other catalytic processes.
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Multiscale modelling of CO2 hydrogenation of TiO2-supported Ni8 clusters: on the influence of anatase and rutile polymorphs

Catal. Sci. Technol., 2024, 14,6393-6410
DOI: 10.1039/D4CY00586D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. Filot
The selection of TiO2 phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO2 hydrogenation to methane.
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Effect of metal loading sequences in CO2 methanation activity on samarium-doped ceria supported bimetallic catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper
Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Ag/Cu foam catalyst for selective reduction of CO2 to CH3OH at low potential

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01056F, Paper
Ruitao Nie, Xiaolong Deng, Haoyu Yang, Hongwei Chen, Jie Yang, Meiyi Lu, Keqi Peng, Xiaoyu Zhou, Yang Chen, Juan Xie, Hu Wang
Electrocatalytic selective reduction of CO2 to liquid phase products, particularly methanol, is a promising technique for CO2 utilization. However, the challenge is daunting because the reduction of carbon dioxide to...
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Innovations in nanocomposite photocatalysts for CO2 to CH3OH conversion

Catal. Sci. Technol., 2024, 14,6443-6465
DOI: 10.1039/D4CY00822G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shuang Deng, Nannan Wang, Yanqiu Zhu, Kunyapat Thummavichai
Nowadays, the excessive use of fossil fuels has led to a global energy shortage and exacerbated the greenhouse effect.
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Oxygen vacancy-dependent low-temperature performance of Ni/CeO2 in CO2 methanation

Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper
Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO2 methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
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Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst

Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance

Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper
Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Deciphering the role of chemisorbed CO in CO2 methanation: kinetic and mechanistic investigation over monometallic (Ru) and bimetallic (Ru–Ni) catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper
Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO2 mitigation through conversion into useful chemicals.
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HKUST-1 MOF Nanoparticles: Non-classical Crystallization Route in Supercritical CO2

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03070B, Communication
Ji Feng, Almond Lau, Igor V. Novosselov
Reducing MOF particles to the nanoscale size range is beneficial due to their increased surface-to-volume ratio, higher defects exposing metals and ligands, and short diffusion path. While great efforts have...
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Constructing Nickel Complex/Crystalline Carbon Nitride Hybrid with a Built-in Electric Field for Boosting CO2 Photoreduction

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03586K, Paper
Yanrui Li, Linda Wang, Bo Zhan, Liangqing Zhang, Xiaolin Zhu, Xiang Gao
Sluggish charge separation dynamics resulting from the amorphous structure and the lack of driving force for graphitic carbon nitride (GCN) limits its highly effective CO2 photoreduction performance. Herein, a built-in...
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One-pot synthesis of conjugated vinylene-extended viologen ionic radical polyacetylenes for visible light-promoted photocatalytic CO2 cycloaddition

Green Chem., 2024, 26,10876-10885
DOI: 10.1039/D4GC03683B, Paper
Yanan Chang, Shuo Wang, Juan Chen, Zixuan Xu, Qing Shi, Yunjie Mao, Yanli Gai, Zhouyang Long, Guojian Chen
In situ synthesis of a conjugated vinylene-extended viologen ionic radical polyacetylene (VIRP-2) for visible light-promoted photocatalytic CO2 cycloaddition under ambient conditions.
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A sequential flow process of CO2 capture and conversion using cost-effective porous organic polymers

Green Chem., 2024, 26,10960-10968
DOI: 10.1039/D4GC03494E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhongqi Wu, Zhong Li, Lei Hu, Samson Afewerki, Maria Strømme, Qian-Feng Zhang, Chao Xu
A sequential flow process utilizing cost-effective porous organic materials to capture CO2 and directly convert it into fine chemicals has been achieved, which could improve the practical applicability of CO2 capture and utilization technologies.
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Electroreductive deoxygenative carboxylation of alkyl oxalates with CO2

Green Chem., 2024, 26,10811-10817
DOI: 10.1039/D4GC03452J, Communication
Yong Yuan, Hangfei Jiang, Ya-Nan Zhang, Yuyan Tao, Xincong Liu, Congde Huo
An electroreductive deoxygenative carboxylation of alkyl oxalates with CO2 is demonstrated.
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CO2 catalyzed recycling of polyester and polycarbonate plastics

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04782F, Paper
Open Access
Qiao Zhang, Nan Wang, Chenyang Hu, Peng-Yuan Li, Fu-Quan Bai, Xuan Pang, Xuesi Chen, Xianhong Wang
CO2 was found to be an efficient catalyst for depolymerizing common waste polyesters and polycarbonates via alcoholysis, yielding valuable organic molecules. CO2 was considered a Lewis acid–base pair, activating both polymers and alcohol.
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Formaldehyde dehydrogenase SzFaldDH: an indispensable bridge for relaying CO2 bioactivation and conversion

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03745F, Communication
Boxia Guo, Xiuling Ji, Yaju Xue, Yuhong Huang
A novel formaldehyde dehydrogenase with outstanding reductive activity and kinetic properties was discovered for CO2 bioactivation and conversion.
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CO2 switchable solvents for sustainable dissolution, modification, and processing of cellulose materials: a critical review

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04032E, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peter McNeice, Ben L. Feringa
CO2 switchable solvents provide a convenient and environmental method to dissolve and process cellulose.
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Dy/Assistant Manager Marketing – Bhopal (OEM/Dealer Sales, 4 yrs exp, Welding Wires, PowerTools, CO2 )

Company: P & I Management Consultants
Experience: 3 to 4
location: India
Ref: 24341083
Summary: Job Description: JD for Dy/Assistant Manager-Bhopal a. Persons should belongs to MP (preferably Bhopal). As persons has to develop MP and Chhattisgarh customers. b. Should have Experience of 3 to 4 years of Welding Industry,....




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Carbon taxes and emissions trading are cheapest ways of reducing CO2, OECD says

Carbon taxes and emission trading systems are the most cost-effective means of reducing CO2 emissions, and should be at the centre of government efforts to tackle climate change,according to a new OECD study.




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Carbon taxes and emissions trading are cheapest ways of reducing CO2, OECD says

Carbon taxes and emission trading systems are the most cost-effective means of reducing CO2 emissions, and should be at the centre of government efforts to tackle climate change,according to a new OECD study.




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Carbon taxes and emissions trading are cheapest ways of reducing CO2, OECD says

Carbon taxes and emission trading systems are the most cost-effective means of reducing CO2 emissions, and should be at the centre of government efforts to tackle climate change,according to a new OECD study.




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The varied structures of cobalt(II)–pyridine (py)–sulfate: [Co(SO4)(py)4]n, [Co2(SO4)2(py)6]n, and [Co3(SO4)3(py)11]n

The solid-state structures of two cobalt–pyridine–sulfate compounds, namely catena-poly[[tetra­kis­(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O'], [Co(SO4)(C5H5N)4]n, (1), and catena-poly[[tetra­kis­(pyridine-κN)cobalt(II)]-μ-sulfato-κ3O:O',O''-[bis­(pyridine-κN)cobalt(II)]-μ-sulfato-κ3O,O':O'']n, [Co2(SO4)2(C5H5N)6]n, (2), are reported. Compound (1) displays a polymeric structure, with infinite chains of CoII cations adopting octa­hedral N4O2 coordination environments that involve four pyridine ligands and two bridging sulfate ions. Compound (2) is also polymeric with infinite chains of CoII cations. The first Co center has an octa­hedral N4O2 coordination environment that involves four pyridine ligands and two bridging sulfate ligands. The second Co center has an octa­hedral N2O4 coordination environment that involves two pyridine ligands and two bridging sulfate ions that chelate the Co atom. The structure of (2) was refined as a two-component inversion twin.




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Synthesis, structure, magnetic and half-metallic properties of Co2−xRuxMnSi (x = 0, 0.25, 0.5, 0.75, 1) compounds

A series of Co2−xRuxMnSi (x = 0, 0.25, 0.5, 0.75, 1) Heusler compounds were successfully synthesized. The heat-treatment conditions were crucial to make the materials form a single phase with a Heusler structure. With increasing Ru content, the half-metallic gap, lattice parameters and magnetization are continuously adjustable in a wide range. The Co2−xRuxMnSi (x = 0, 0.25) compounds are rigorous half-metals and show a T3 dependence of resistance at low temperature. The Co2−xRuxMnSi (x = 0.5, 0.75, 1) Heusler compounds are the nearly half-metallic materials and show a semiconductive dependence of resistance at low temperature. The experimental magnetization is consistent with that in theory and follows the Slater–Pauling rule. The Curie temperature is higher than 750 K for all Co2−xRuxMnSi Heusler compounds.




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What the Ancient CO2 Record May Mean for Future Climate Change

The last time Earth experienced both ice sheets and carbon dioxide levels within the range predicted for this century was a period of major sea […]

The post What the Ancient CO2 Record May Mean for Future Climate Change appeared first on Smithsonian Insider.




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Scientists find excess nitrogen favors plants that respond poorly to rising CO2

Two grass species that had been relatively rare in the plots, Spartina patens and Distichlis spicata, began to respond vigorously to the excess nitrogen. Eventually the grasses became much more abundant. Nitrogen ultimately changed the composition of the ecosystem as well as its capacity to store carbon.

The post Scientists find excess nitrogen favors plants that respond poorly to rising CO2 appeared first on Smithsonian Insider.




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High CO2 spurs wetlands to absorb more carbon

Under elevated carbon dioxide levels, wetland plants can absorb up to 32 percent more carbon than they do at current levels, according to a 19-year […]

The post High CO2 spurs wetlands to absorb more carbon appeared first on Smithsonian Insider.




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The strange, controversial way plants trap CO2

Plants are among the world’s best carbon sinks, but there’s a side to the plant-CO2 love affair that’s rarely discussed. When carbon dioxide rises, plants […]

The post The strange, controversial way plants trap CO2 appeared first on Smithsonian Insider.




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Discovery: Rising CO2 depletes pollen’s nutritional potency, bees suffer

Unless you’ve been living under a rock for the last few years, you’ve doubtless caught at least a passing reference to the plight of the […]

The post Discovery: Rising CO2 depletes pollen’s nutritional potency, bees suffer appeared first on Smithsonian Insider.




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Non-CO2 emissions should not be overlooked

A new study by European researchers highlights the important contribution of greenhouse gases (GHGs) other than carbon dioxide to climate change and suggests policy measures to help reduce their impact. The study provides improved estimates of the current GHG balance of Europe, taking nitrous oxide and methane into account.




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Urea fertilisation of the sea for CO2 removal: Issues for consideration

One method that has been proposed for removing carbon dioxide (CO2) from the atmosphere is to ‘fertilise’ the ocean to encourage phytoplankton (algae) blooms. A recent study has outlined the environmental, legal and social implications of large-scale fertilisation of the sea with urea in the Sulu Sea off the coast of the Philippines.




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Long-term consequences of storing captured CO2

A recent study has examined the implications of CO2 leaking from storage sites under a variety of scenarios over 100,000 years. The findings suggest that ocean storage of CO2 (prohibited in the EU) would lead to long-term warming of the atmosphere, higher sea levels and acidification and dead zones in the ocean. In contrast, geological storage with low-leakage rates (1 per cent per 1000 years) would lead to conditions similar to a low-emissions future. This implies that




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Innovative ways to reduce CO2 emissions from the cement industry

Technological advances in European cement production could reduce energy consumption by up to 10% and CO2 emissions by 4%, according to a new analysis. The research suggests that initial costs of some of the pending technological improvements could be recouped in as little as a year.




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High atmospheric CO2 levels stimulate GHG emissions from soil

Rising levels of atmospheric carbon dioxide (CO2) is likely to cause some soils to release large quantities of two potent greenhouse gases (GHGs), nitrous oxide and methane, according to a recent analysis. The results suggest that the contribution of soils and terrestrial ecosystems to slow climate change has been overestimated.




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Rising CO2’s impacts on marine ecosystems and the people that rely on them

The world’s ocean ecosystems will suffer warming, increased acidity, low oxygen and reduced primary food supply as a result of rising CO2 and this is likely to have dramatic environmental and social impacts, a new study concludes. It predicts that the most vulnerable low-income countries, where 870 million people are dependent on marine ecosystems, would be affected if CO2 emissions are not tackled.




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Deep-water fish remove over a million tonnes of CO2 in Irish-UK waters every year

Deep-water fish living along the Irish-UK continental slope remove more than a million tonnes of CO2 from the atmosphere each year, according to a recent study. Continental slope ecosystems play an important role in carbon sequestration, which should be considered before exploiting deep-water resources, say the researchers.