co2

Sulfonylcalix[4]arene-based Al4 clusters: three aluminum oxo clusters with different coordinated solvents for the CO2 cycloaddition reaction

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02096K, Research Article
Xiao-Jie Liu, Long-Xue Guo, Wei Xu, Ya-Wen Wang, Yuan-Hang Tian, Li-Xing Zhao, Xiao-Yu Li, Jin-Hua Li, Guo-Ming Wang
By using a macrocyclic H4BTC4A-SO2 ligand, we successfully synthesized three Al4 clusters with different solvents, which exhibit different potentials to expose metal active sites for the catalytic reaction. of cycloaddition of carbon dioxide.
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Scalable complete conversion of MgCo2O4 by mechanochemistry for high-performance supercapacitors

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Inorg. Chem. Front., 2024, 11,7886-7897
DOI: 10.1039/D4QI02020K, Research Article
Zhiyuan Liu, Qixuan Xiang, Hao Zhang, Xianglong Zhang, Huijun Tan, Yaping Zhao
Complete conversion of MgCo2O4 with excellent electrochemical performance has been successfully achieved.
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Copper-doped Bi2MoO6 with concurrent oxygen vacancies for enhanced CO2 photoreduction

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Inorg. Chem. Front., 2024, 11,8003-8015
DOI: 10.1039/D4QI02005G, Research Article
Jiawei Liu, Xin Liu, Chunhui Dai, Chao Zeng, Sajjad Ali, Mohamed Bououdina, Yushuai Jia
Bi2MoO6 catalysts doped by monovalence Cu with self-adapting O vacancies (Ov) are prepared. The optimal Bi2MoO6–10% Cu exhibits an outstanding CO evolution rate of 11.40 μmol g−1 h−1, about 6 times higher than that of Bi2MoO6 (1.94 μmol g−1 h−1).
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A non-equivalent Ni doped La-MOF for enhanced photocatalytic CO2 reduction through oxygen vacancy regulation and electronic structure optimization

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02143F, Research Article
Tongzheng Zhang, Zhaohui Huang, Guanshun Xie, Le Liao, Changqiang Yu, Xiuqiang Xie, Nan Zhang
La/Ni-MOF with oxygen vacancies and regulated electronic structures is prepared and exhibits enhanced visible-light photocatalytic activity for CO2-to-CO conversion.
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Enhancing CO2 electroreduction with decamethylcucurbit[5]uril-alkaline earth metal modified Pd nanoparticles

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02135E, Research Article
Tao Shao, Xianmeng Song, Zongnan Wei, Shuaibing Yang, Siying Zhang, Rong Cao, Minna Cao
Pd NP modification with Me10CB[5]–M capsules boosted CO2RR by enhancing CO2 adsorption, tuning Pd's electronic structure, and optimizing *COOH/*CO binding.
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Bifunctional catalysts for the coupling processes of CO2 capture and conversion: a minireview

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00334A, Minireview
Chengxiong Dang, Hao Yu
A bifunctional catalyst for integrated CO2 capture and utilization (ICCU).
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Evaluating metal-free quaternized boronate esters as efficient catalysts for the fixation of CO2 with epoxides to form cyclic carbonates under suitable conditions

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React. Chem. Eng., 2024, 9,2938-2953
DOI: 10.1039/D4RE00282B, Paper
Eyyup Yasar, Emine Aytar, Ahmet Kilic
The conversion of CO2 into high value-added chemicals is receiving increasing attention from the scientific community, commercial enterprises, and policymakers due to environmental problems like global warming.
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Two-temperature model of the non-thermal chemical dissociation of CO2

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00300D, Paper
Q. Shen, A. Pikalev, F. J. J. Peeters, J. Gans, M. C. M. van de Sanden
A two-temperature model with a vibrational temperature different from the gas temperature is presented for the decomposition of CO2.
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Unveiling the dynamic CO2 capture performance of MgO promoted with molten salts and CaCO3 via fixed bed reactor experiments

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00432A, Paper
Open Access
Theodoros Papalas, Andy N. Antzaras, Angeliki A. Lemonidou
MgO promoted with molten alkali salts and CaCO3 displayed efficient CO2 capture activity in a fixed bed reactor, attaining 75% CO2 removal at 275 °C and stable cyclic performance, with the promoters providing an alternative carbonation mechanism.
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CO2 hydrogenation to light olefins over Fe–Co/K–Al2O3 catalysts prepared via microwave calcination

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00428K, Paper
Nutkamaithorn Polsomboon, Thanapha Numpilai, Kulpavee Jitapunkul, Kajornsak Faungnawakij, Metta Chareonpanich, Xingda An, Le He, Günther Rupprechter, Thongthai Witoon
Microwave calcination optimizes the Fe–C/Fe3O4 ratio to 0.34, enhancing CO2 conversion and light olefin yield.
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Design and performance evaluation of low-volatility and low-viscosity absorbents for CO2 capture

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00379A, Paper
Ning Ma, Liu Yang, Zhenchang Fang, Kaijia Jiang, Xinling Li, Zhen Huang
This study synthesized a novel homogeneous non-aqueous absorbent and analyzed hydrogen bonds and viscosities, which were rarely studied before.
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A prediction model for CO2/CO adsorption performance on binary alloys based on machine learning

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RSC Adv., 2024, 14,12235-12246
DOI: 10.1039/D4RA00710G, Paper
Open Access
Xiaofeng Cao, Wenjia Luo, Huimin Liu
Machine-learning models were constructed to accurately predict CO2 and CO adsorption affinity on a wide range of binary alloying.
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Optimizing methanol synthesis from CO2 using graphene-based heterogeneous photocatalyst under RSM and ANN-driven parametric optimization for achieving better suitability

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RSC Adv., 2024, 14,12496-12512
DOI: 10.1039/D4RA00578C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ramesh Kumar, Jayato Nayak, Somnath Chowdhury, Sashikant Nayak, Shirsendu Banerjee, Bikram Basak, Masoom Raza Siddiqui, Moonis Ali Khan, Rishya Prava Chatterjee, Prashant Kumar Singh, WooJin Chung, Byong-Hun Jeon, Sankha Chakrabortty, Suraj K. Tripathy
Assessment of the performance of linear and nonlinear regression-based methods for estimating in situ catalytic CO2 transformations employing TiO2/Cu coupled with hydrogen exfoliation graphene (HEG) has been investigated.
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High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon

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RSC Adv., 2024, 14,13017-13026
DOI: 10.1039/D4RA01641F, Paper
Open Access
Shayan Gul, Fatima Nasim, Waheed Iqbal, Amir Waseem, Muhammad Arif Nadeem
Efficient electrocatalytic CO2 reduction reaction (eCO2RR) to various products, such as carbon monoxide (CO), is crucial for mitigating greenhouse gas emissions and enabling renewable energy storage.
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Effects of surface oxygen vacancy on CO2 adsorption and its activation towards C2H4 using metal (Cu, Pd, CuPd) cluster-loaded TiO2 catalysts: A first principles study

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03507K, Paper
Sajjad Hussain, Lina Zhang, Zhengzheng Xie, Jianjun Yang, Qiuye Li
The conversion of the highly selective CO2 reduction reaction (CO2RR) into desired value-added multicarbon compounds, like C2H4, is crucial, but it is mainly constrained by high energy barrier for C-C...
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Mechanistic Insights into CO2 Activation on Pristine, Vacancy-containing and Doped Goldene: A Single-Atom Layer of Gold

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03087G, Paper
Kamal Kumar, Nora Henriette De Leeuw, Jost Adam, Abhishek Kumar Mishra
Goldene, a one-atom-thick gold sheet, is an emerging graphene-like flat 2-dimensional material. In this study, the geometrical and electronic properties, as well as CO2 adsorption characteristics, of the pristine,...
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Review on strategies for improving the added value and expanding the scope of CO2 electroreduction products

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00857F, Review Article
Minghang Jiang, Huaizhu Wang, Mengfei Zhu, Xiaojun Luo, Yi He, Mengjun Wang, Caijun Wu, Liyun Zhang, Xiao Li, Xuemei Liao, Zhenju Jiang, Zhong Jin
This review summarizes promising strategies including the design of catalysts and the construction of coupled electrocatalytic reaction systems, aimed at achieving the selective production of various products from CO2 electroreduction.
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Varied CO2 photoreduction activity over UiO-66-NH2 with different aggregation morphology

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04919E, Communication
Shuran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guangjuan Xu, Wei Xie, Na Xu, Yanhong Xu, Yaqian Lan
UiO-66-NH2 with different aggregation morphology are prepared to verify the morphology of photocatalysts could influence the charge transfer. Among them, UiO-66-NH2 with the poor aggregation exhibits superior performances over CO2...
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Separation of Rare Earth Elements and Nickel Harnessing Electrochemistry and Reactive CO2 Capture and Mineralization

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04632C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akanksha Srivastava, Prarabdh Jain, Greeshma Gadikota, Prince Ochonma, Christopher Noe, Tianhe Yin
The aim is to probe the chemical mechanisms underlying the use of multifunctional solvents to simultaneously capture and convert CO2 into insoluble Rare Earth Element (REE)-carbonates, while forming soluble complexes...
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Carboxylative cyclization of atmospheric CO2 with alkynol catalyzed by a 1-methylhydantoin anion-functionalized ionic liquid via chelative interactions

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03586K, Communication
Yujun Guo, Tingting Chen, Yingjie Xu
[1-MHy]− acts as a “pincer ligand” to form chelative interactions with –OH to enhance MBY activation, thus ensuring efficient [P4442][1-MHy]-catalyzed reaction of atmospheric pressure CO2 with MBY under metal- and solvent-free conditions.
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Crystal-Facet Modulated Pathway of CO2 Photoreduction on Bi4NbO8Cl Nanosheets Boosting Production of Value-Added Solar Fuels

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05581K, Communication
Yong Zhou, Haoqiang Chi, Zhengdao Li, Yong Cai Zhang, Zhigang Zou, Yong Yang, Xinxin Lu, Peiting Hao
Two ultrathin nanosheets of Bi4NbO8Cl were successfully synthesized for photocatalytic conversion of CO2 into solar fuel. featuring differently exposed (001) and (201) facets. In contrast to bulk Bi4NbO8Cl, which produced...
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Efficient electrocoupling of CO2 and N2 to urea by a gas-penetrable Bi nanosheet-wrapped Cu hollow fiber

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Chem. Commun., 2024, 60,13420-13423
DOI: 10.1039/D4CC04595E, Communication
Jinning Wang, Yuyu Wang, Fang Wang, Jinfu Ma, Zhengguo Zhang, Shixiong Min
A gas-penetrable electrode of Bi nanosheet-wrapped Cu hollow fiber (Bi NSAs@Cu HF) exhibits high activity and stability for urea production from the electrocoupling of CO2 and N2.
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Universal synthesis of pure-phase IB-group Sn-based alloys with modulable electrocatalytic CO2 reduction products

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Chem. Commun., 2024, 60,13436-13439
DOI: 10.1039/D4CC05317F, Communication
Luyao Yang, Wenqing Zhang, Ximei Lv, Qianqian Zhao, Xiaojing Liu, Shulin Zhao, Yuhui Chen
A universal method for synthesizing a range of pure-phase IB-group Sn-based alloy catalysts (Cu3Sn, Ag4Sn, and AuSn) for electrochemical reduction of CO2.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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Revealing the Influencing Mechanism of CO2 on SCR of NOx with NH3 over FeW Mixed Oxides Catalyst

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01468E, Paper
Hui Wang, Yujie Qiao, Xiang Li, Zhenping Qu
The effect of CO2, another major component of the exhaust gas, on the elimination of NOx over FeW oxides catalyst has been studied. It reveals that the presence of CO2...
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Construction of NiCo2S4−xPx nanowire arrays for efficient hydrogen evolution reactions in both acidic and alkaline media

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00361F, Paper
Guanglei Liu, Yutong Feng, Yifan Yang, Yuan Wang, Huixiang Liu, Can Li, Mingxin Ye, Jianfeng Shen
Construction of NiCo2S4−xPx nanowire arrays for improved HER performances in both acidic and alkaline media.
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Core–shell magnetic zinc-based molecularly imprinted polymer: a robust heterogeneous catalytic nanoreactor toward the CO2 fixation reaction

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Environ. Sci.: Nano, 2024, 11,1622-1635
DOI: 10.1039/D3EN00554B, Paper
Tahereh Nasiriani, Neda Adabi Nigjeh, Ahmad Shaabani
This study deals with the synthesis of a core–shell magnetic zinc-based molecularly imprinted polymer (M-Zn-MIP) as a robust heterogeneous catalytic nanoreactor. The catalytic activity of the M-Zn-MIP was explored in the CO2 fixation reaction.
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Construction of CsPbBr3/carboxyl-modified rGO heterostructures for efficient photocatalytic reduction of CO2 to methanol

By pubs.rsc.org
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CrystEngComm, 2024, 26,1994-2002
DOI: 10.1039/D4CE00036F, Paper
Meng Li, Jingtao Xu, Yang Song, Yuanyuan Li, Jin Wang, Feiyong Chen
Construction of monodispersed CsPbBr3 NCs and carboxyl-modified rGO composites led to the production of CO and CH3OH with an Relectron of 359 μmol g−1 h−1 by photocatalytic CO2 reduction.
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Thermal fluctuation-induced selective CO2 uptake of seemingly nonporous N,C-protected dipeptide crystals as elucidated by in situ X-ray crystallographic analysis

By pubs.rsc.org
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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01018J, Paper
Kazuaki Yamanaka, Ryusei Oketani, Yuya Mori, Takashi Sato, Seiji Tsuzuki, Hiroki Takahashi, Hirohito Tsue
A novel N,C-protected dipeptide deposited nonporous but yet CO2-sorbing molecular crystals, of which the CO2 sorption state was disclosed.
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Coral-mimetic production of aragonite films from CO2 captured by biogenic polyamines

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CrystEngComm, 2024, 26,2065-2071
DOI: 10.1039/D4CE00126E, Paper
Open Access
Kohei Takashina, Hiroto Watanabe, Yuya Oaki, Yoshikazu Ohno, Ko Yasumoto, Hiroaki Imai
We designed CaCO3 films comprised of aragonite nanorods by mimicking the microstructure and the formation process of the calcareous skeleton of a stony coral in the sea.
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Coordinatively unsaturated 5-nitroisophthalate based cobalt(II) coordination polymers: efficient catalytic CO2 fixation and Hantzsch condensation

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00102H, Paper
Subham Sahoo, Rajesh Patra, Debajit Sarma
Labile-coordinated water-based CPs have been synthesized. SSICG-6 serves as an excellent heterogeneous catalyst in CO2 cycloaddition and one-pot Hantzsch condensation reactions compared to other 1D-reported CPs due to the presence of OMSs.
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In situ P-doping induced Se vacancies enhance the supercapacitor performance of NiCo2Se4

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CrystEngComm, 2024, 26,2197-2206
DOI: 10.1039/D4CE00048J, Paper
Miaomiao Wang, Weizhe Liu, Li Zhang, Huanli Liu, Xiao Yang
In this paper, we report the synthesis of P-doped NiCo2Sex nanomaterials with rich Se vacancies induced by P doping, which greatly improves the supercapacitor performance of electrode materials.
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Bifunctional conjugated polymer photocatalysts for visible light water oxidation and CO2 reduction: function- and site-selective hybridisation of Ru(II) complex catalysts

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J. Mater. Chem. A, 2024, 12,30279-30288
DOI: 10.1039/D4TA04014G, Paper
Kotaro Ishihara, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Shunsuke Nozawa, Akinori Saeki, Ryu Abe
Function-/site-selective hybridisation of two specific Ru(II) complex catalysts on donor–acceptor conjugated polymers enables bifunctional visible-light water oxidation and CO2 reduction.
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Tuning the acidity and textural properties of polyethyleneimine-supported adsorbents for enhanced economical CO2 capture

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J. Mater. Chem. A, 2024, 12,30309-30317
DOI: 10.1039/D4TA05215C, Paper
Bitan Ray, Sathyapal R. Churipard, Arjun Cherevotan, Diku Raj Deka, Devender Goud, Harishankar Kopperi, Sebastian C. Peter
The acidity and textural properties of polyethyleneimine-supported adsorbents are tuned to enhance the capture of carbon dioxide in an economical way.
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Synthesis of a Cu@ZnO1−x/Al2O3 catalyst with high-density ZnO1−x–Cu interfacial sites for enhanced CO2 hydrogenation to methanol

By pubs.rsc.org
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J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper
Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
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Exploring reaction mechanisms for CO2 reduction on carbides

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J. Mater. Chem. A, 2024, 12,30340-30350
DOI: 10.1039/D4TA05592F, Paper
Naveed Ashraf, Atef Iqbal, Younes Abghoui
The electrocatalytic conversion of carbon dioxide (CO2) into valuable fuels offers immense promise in pursuing sustainable energy solutions.
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Controlling CO2 flux in a CO2-permeable membrane with a H2O driving force

By pubs.rsc.org
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J. Mater. Chem. A, 2024, 12,30821-30830
DOI: 10.1039/D4TA05021E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jacqueline A. Penn, Wenting Hu, Ian S. Metcalfe, Greg A. Mutch
A H2O driving force in the opposite direction to CO2 permeation exerts control over CO2 flux in a molten-salt membrane fabricated using hydroxides.
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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

By pubs.rsc.org
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J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Lignin-based porous carbon adsorbents for CO2 capture

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00923A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Barker-Rothschild, Jingqian Chen, Zhangmin Wan, Scott Renneckar, Ingo Burgert, Yong Ding, Yi Lu, Orlando J. Rojas
This review covers the state-of-the-art in the production of lignin-based carbon adsorbents for CO2 capture, discussing lignin chemistry and properties, traditional synthesis approaches to emerging methods, and fundamentals for rational design.
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Novel magneto-electrocatalyst Cr2CO2-MXene for boosting nitrogen reduction to ammonia

By pubs.rsc.org
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Mater. Horiz., 2024, 11,1769-1778
DOI: 10.1039/D3MH01945D, Communication
Neng Li, Zhongyong Zhang, Zheng Wang, Bin Liu, Deyong Zhou, Xing Zhou, Peng Zhang, Xiujian Zhao
Gibbs free energy for electrocatalytic nitrogen reduction on Cr2CO2 with four magnetic states: NM, FM, Inter-AFM, and In-AFM.
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Unlock flow-type reversible aqueous Zn–CO2 batteries

By pubs.rsc.org
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Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00219A, Communication
Muhammad Kashif Aslam, Herui Wang, Zhihao Nie, Sheng Chen, Qiang Li, Jingjing Duan
A flow-type reversible aqueous Zn–CO2 battery using a Pd/SnO2@C cathode catalyst has been assembled and demonstrates an ultra-high power density.
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Hierarchical surface-modification of nano-Cu toward one pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions

By pubs.rsc.org
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Mater. Horiz., 2024, 11,1957-1963
DOI: 10.1039/D3MH01921G, Communication
Zhi-Qiang Wang, ChengHua Deng, Bo Li, Hai-Qiang Luo, Peng Hao, Xiao Liu, Jian-Gong Ma, Peng Cheng
One pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions to synthesize high value-added dihydrobenzofurans are realized through the hierarchically constructed Cu–Ag nanoalloy with a MOF cover as an efficient catalyst.
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Per Capita Income, Consumption Patterns, and CO2 Emissions [electronic journal].

By encore.st-andrews.ac.uk
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National Bureau of Economic Research


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COMMIT TO A CREDIBLE PATH OF RISING CO2 PRICES [electronic journal].

By encore.st-andrews.ac.uk
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Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation

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Inorg. Chem. Front., 2024, 11,2071-2080
DOI: 10.1039/D3QI02527F, Research Article
Ying Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu Wang
A series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.
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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article
Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Development of In–Cu binary oxide catalysts for hydrogenating CO2via thermocatalytic and electrocatalytic routes

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Inorg. Chem. Front., 2024, 11,2319-2338
DOI: 10.1039/D3QI02499G, Research Article
Open Access
Marco Pietro Mezzapesa, Fabio Salomone, Hilmar Guzmán, Federica Zammillo, Roberto Millini, Letizia Bua, Gianluigi Marra, Alessandra Tacca, Rosamaria Marrazzo, Nunzio Russo, Raffaele Pirone, Simelys Hernández, Samir Bensaid
Carbon dioxide (CO2) hydrogenation to obtain valuable chemicals and fuels via thermocatalysis or electrocatalysis is a promising and sustainable method for CO2 utilization.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOH* creates favorable conditions for CO formation and desorption.
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Visible-light-responsive hybrid photocatalysts for quantitative conversion of CO2 to highly concentrated formate solutions

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Chem. Sci., 2024, 15,18146-18160
DOI: 10.1039/D4SC05289G, Edge Article
Open Access
Ewan McQueen, Noritaka Sakakibara, Kei Kamogawa, Martijn A. Zwijnenburg, Yusuke Tamaki, Osamu Ishitani, Reiner Sebastian Sprick
This highly efficient hybrid photocatalytic system can quantitatively convert CO2 to formate and produce 0.4 M of formate solution without additional concentration enrichment.
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