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Synthesis of Deuteriodifluoromethylthiolated Isocoumarins-1- imines and Isocoumarins Enabled by Multi-Component Reagents System (MCRS)

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00328D, Communication
Xuemin Li, Haofeng Shi, Jiaxin He, Jialiang Wu, Fengxia Sun, Yunfei Du
The combining use of BnSCF2D, mCPBA and Tf2O serves as an efficient multi-component reagents system (MCRS) for the synthesis of deuteriodifluoromethylthiolated isocoumarins-1-imines/isocoumarins via intramolecular cyclization/ deuteriodifluoromethylthiolation of 2-alkynylbenzamide/2-alkynylbenzoates. The approach...
The content of this RSS Feed (c) The Royal Society of Chemistry




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New Generation of Highly Reactive Allylborating Agents For Cu(I)-Catalyzed Allylation of Chiral Sulfinylimines

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00291A, Paper
Michael S. Alexeev, Tatyana V. Strelkova, Michail M. Ilyin, Jr., Yulia V. Nelyubina, Ivan A. Bespalov, Michael Medvedev, Victor N Khrustalev, Nikolai Kuznetsov
The implementation of selective catalytic processes with highly active reagents is an attractive strategy that meets modern principles of sustainable development of chemistry. In the current study, we for the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Built-in Browser Support for Responsive Images

Take advantage of the new element and new features of in your next responsive website.




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Year-end blues for beleagued airlines

The results of IndiGo and SpiceJet hold clues to the mid-term future of the country’s airline industry




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The making of ‘agile’ airlines

How adoption of AI, ML can empower flying




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Air India sale: Who will bag the Maharaja's crown?

Financial bid winner for sale of the State-owned airlines to be declared in three weeks; sources say it may take longer




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Those magnificent flying machines

The aviation industry’s roller-coaster ride




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Lost your baggage in transit? You might find it in Alabama

Every year, nearly 25 million bags are lost in transit out of 4.3 billion 




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Mishandled baggage rates spike

Transfer bags continue to account for most mishandled bags




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Post-pandemic, OTAs are coming of age

Are they finally paying up or paying off?




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Navigating newer disruptions with maximum agility

Focusing on hyper-personalisation, using the right communication tools and platforms, engaging with the customers at the right time and place will give a much-needed fillip to the industry




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Sarvam AI launches Sarvam 1 for Indic languages

The custom training corpus, Sarvam-2T comprised of 20 percent datasets in Hindi as well as English and programming languages so the AI model can perform multilingual tasks




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 Instagram downgrades quality of less popular videos

Last year, Meta had admitted in a blog to having separate encoding configurations for different videos based on how popular they were




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Rapid assessment of pulse polio campaign shows high vaccine coverage, highlights gaps in Chennai

Chennai accounted for nearly 21% of the non-vaccinated children, highlighting the gaps in an urban area and the need for targeted community outreach




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Acute Flaccid Paralysis surveillance as a crucial defence against polio in India | Explained

India needs to continue efforts to maintain its polio-free status, and AFP surveillance has to remain a cornerstone of its strategy




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Ayushman Bharat: All seniors above 70 can avail health coverage except those in Delhi, West Bengal

Senior citizens eligible for PM-JAY regardless of income; Ayushman Vaya Vandana card will help cut out-of-pocket health spends; on Ayurveda Day, PM launches initiatives to validate traditional herbal medicine, promote Indian medical systems




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AIIMS-Bibinagar to boost tuberculosis care in Telangana with aerial aid

Inaugurated virtually by Prime Minister Narendra Modi, the drone service is part of a series of health projects designed to enhance access to essential services in remote and underserved areas




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Following WHO guidelines for sodium content in packaged food could prevent 3 lakh deaths in India in 10 years: study

Additionally, about 1.7 million new cardiovascular disease cases and 7,00,000 new chronic kidney disease cases could be prevented compared to current practices, the study said




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More than 50,000 vaccinated against mpox in DR Congo, Rwanda: WHO

The outbreak is still not under control, the African Union’s health watchdog has warned, appealing for resources to avoid a “more severe” pandemic than Covid-19




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How to overcome your device dependency and manage a successful digital detox

There are four key strategies that are key to helping you achieve a healthier digital balance: replacement practices, social bonds, mindfulness and viewing digital well-being as a journey




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ICMR announces ‘First in the World Challenge’ to encourage scientists to find innovative ideas to tackle health issues

The Council said that the scheme proposes to foster novel, out of the box, futuristic ideas, new knowledge generation, discovery / development of breakthrough health technologies




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Can mid-level healthcare providers compensate for physician shortages in rural India?

To make up for doctor shortages, several countries around the world have introduced a cadre of MLHPs into their health systems; however, in India, mainstreaming of MLHPs has time and again been met with resistance from organised medicine 




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Severe staff shortage leaves Tamil Nadu’s obstetricians and gynaecologists overworked

Doctors are forced to take turns doing frequent 24-hour shifts — in some cases two to three 24-hour shifts a week. Inquiries with government OB-GYNs reveal that several health facilities have been short-staffed for years, and vacant posts remain unfilled




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Shabana-Javed's Recipe For A Happy Marriage

'As we grow older, we fight much less with each other.''The magic mantra is 'Drop it!'''I would recommend it for all relationships.''In anger, we can say many hurtful things that can leave a deep scar, so dropping it is the healthy way of preventing that from happening.'




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Aditi Sings Ang Laga De, Noodle Sa Dil!

'There must have been some wonderful genetic disorder due to which I was attracted towards filmi songs.'




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'I damaged my voice on purpose'

'Pandi was promised something, that is not happening, so his anger is not of a villain's.' 'That's how all normal humans would react, or they stay silent.''Our violence is our silence. So in this world, everybody is innocent.'




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What Happened To Alka Yagnik: A Doctor...

'The earlier you get your treatment done, the better the chance of recovery.'




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'People Said A Lot Of Things Against Me'

'I believe one should never disrespect their elders but if the person does not know how to talk to people, then I am sorry, I cannot take it.'




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Why Janhvi Got Aggressive!

'It went from me being scared and intimidated by him to me being very aggressive and passionate.'





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Instagram down: Users face issues while sending messages, say, 'Rehne do fir'

The issue began at approximately 5.14 pm on Tuesday.




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OnePlus 13 launched with Snapdragon 8 Gen 4 SoC: Price details, battery and other specifications

While the OnePlus 13 has only been revealed in China so far, speculations are that it will arrive on the global market in the coming months. In India, the phone is expected to be launched in January 2025.




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25 Billion Kilometers and Broken Voice: The Voyager 1 Saga

NASA's Voyager 1 Faces Technical Glitch in Deep Space, says Girish Linganna




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The never ending voyage

Sharmila Biswas seamlessly blended three dance forms in the performance.




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Magic once more with Surabhi

‘Maya Bazar’ and ‘Pataala Bhairavi’ attracted a lot of theatre lovers, says Velcheti Subrahmanyam.




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Of legacy and lineage

Finding similarities between cooking and dance, noted Kathak exponent Deepak Maharaj says both must come from the heart




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Tagore, once again

Renowned dancer Ananda Shankar Jayant speaks of the reasons to revisit ‘Kavyanjali - an ode to Tagore’.




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The dramatic language of Ottanthullal

Krishnapurath Murali's portrayals captured the essence of the story.




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How to integrate young managers into family businesses

Given our management curriculum’s focus on Western business processes and practices, managers need to be groomed to work with family-managed firms




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THE NEW MANAGER




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Customer management




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THE NEW MANAGER




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THE NEW MANAGER




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THE NEW MANAGER




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Risk Management: Learning to tackle operational surprises

Knowing what can go wrong is key to getting things done right




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Lessons for talent managers from Abdul Kalam

It is time managers revisit their stereotypical notions of who is talented and what talent is




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How engaged is the 21st century workplace?

A culture of merit, a flexible environment and empowering technology are key to engaging the workforce of today




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Engaging and retaining your high potentials

Providing meaningful roles and constant mentoring are essential




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Employee Engagement: What, why and how?

It is intrinsic and based on the belief system, attitude and values of the individual




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As farm labour diminishes, mechanisation is key for India’s agri-sector growth, says Mahindra & Mahindra’s Sikka 

Hemant Sikka says the farm machinery industry is expected to grow from ₹9,200 crores in financial year 2022 to ₹15,000 crores in financial year 2026.