The enanti­opure monopyrrolidine derivative (2S)-methyl (Z)-5-(2-tert-but­oxy-1-cyano-2-oxo­ethyl­idene)pyrrolidine-2-carboxyl­ate, C13H18N2O4, (1), represents a potential ligand and an attractive inter­mediate for the synthesis of chiral metal com­plexes. At the mol­ecular level, the com­pound features an intra­molecular N—H⋯O hydrogen bond; neighbouring mol­ecules inter­act via N—H⋯N contacts to form chains along [100]. Due to its elemental com­position, resonant scattering of the target com­pound is entirely insignificant for diffraction experiments with Mo Kα and small even for Cu Kα radiation. A preliminary study with the harder radiation type confirmed the chiral space group and the suitability of the single crystal chosen; as expected, the results concerning the absolute structure remained com­pletely inconclusive. A second data collection with the longer wavelength gave satisfactory quality indicators for the correct handedness of the mol­ecule, albeit with high standard uncertainties. The absolute configuration has been assessed independently: CD spectra for both enanti­omers of the target mol­ecule were calculated and the spectrum for the S-configured stereoisomer was in agreement with the experiment. The Cotton effect of (1) may be ascribed to π–π* transitions from HOMO to LUMO and from HOMO to LUMO+1. As both independent techniques agree with respect to the handedness of the target mol­ecule, the absolute structure may be assigned with a high degree of confidence.

The com­pound poly[2-hy­droxy-N-methyl­ethan-1-aminium [μ3-cyanido-κ3C:C:N-di-μ-cyanido-κ4C:N-dicuprate(I)]], {(C3H10NO)[Cu2(CN)3]}n or [meoenH]Cu2(CN)3, crystallizes in the tetra­gonal space group P43. The structure consists of a three-dimensional (3D) anionic CuICN network with noncoordinated protonated N-methyl­ethano­lamine cations providing charge neutrality. Pairs of cuprophilic Cu atoms are bridged by the C atoms of μ3-cyanide ligands, which link these units into a 43 spiral along the c axis. The spirals are linked together into a 3D anionic network by the two other cyanide groups. The cationic moieties are linked into their own 43 spiral via N—H⋯O and O—H⋯O hydrogen bonds, and the cations inter­act with the 3D network via an unusual pair of N—H⋯N hydrogen bonds to one of the μ2-cyanide groups. Thermogravimetric analysis indicates an initial loss of the base cation and one cyanide as HCN at temperatures in the range 130–250 °C to form CuCN. We show how loss of a specific cyanide group from the 3D CuCN structure could form the linear CuCN structure. Further heating leaves a residue of elemental copper, isolated as the oxide.

A new polymorph (form II) is reported for the 1:1 dimethyl sulfoxide solvate of 2,3,5,6-tetra­fluoro-1,4-di­iodo­benzene (TFDIB·DMSO or C6F4I2·C2H6SO). The structure is similar to that of a previously reported polymorph (form I) [Britton (2003). Acta Cryst. E59, o1332–o1333], containing layers of TFDIB mol­ecules with DMSO mol­ecules between, accepting I⋯O halogen bonds from two TFDIB mol­ecules. Re-examination of form I over the temperature range 300–120 K shows that it undergoes a phase transformation around 220 K, where the DMSO mol­ecules undergo re-orientation and become ordered. The unit cell expands by ca 0.5 Å along the c axis and contracts by ca 1.0 Å along the a axis, and the space-group symmetry is reduced from Pnma to P212121. Refinement of form I against data collected at 220 K captures the (average) structure of the crystal prior to the phase transformation, with the DMSO mol­ecules showing four distinct disorder com­ponents, corresponding to an overlay of the 297 and 120 K structures. Assessment of the inter­molecular inter­action energies using the PIXEL method indicates that the various orientations of the DMSO mol­ecules have very similar total inter­action energies with the molecules of the TFDIB framework. The phase transformation is driven by inter­actions between DMSO mol­ecules, whereby re-orientation at lower temperature yields significantly closer and more stabilizing inter­actions between neighbouring DMSO mol­ecules, which lock in an ordered arrangement along the shortened a axis.

A method is described for indexing grazing-incidence X-ray diffraction data of epitaxially grown thin films comprising various crystal orientations and/or polymorphs by measuring reciprocal-lattice vectors.

While the U.S. Environmental Protection Agencys guideline for protecting the public from a toxic form of mercury is justifiable based on the latest scientific evidence, some children of women who consume large amounts of fish and seafood during pregnancy may be at special risk of neurological problems.

Several strong earthquakes around the world have resulted in a phenomenon called soil liquefaction, the seismic generation of excess porewater pressures and softening of granular soils, often to the point that they may not be able to support the foundations of buildings and other infrastructure.

Although individual anglers – people who fish recreationally – generally take small numbers of fish, collectively, a large number of them can have a substantial impact on the overall stock.

A new report from the National Academies of Sciences, Engineering, and Medicine outlines how to examine whether specific levels of nutrients or other food substances (NOFSs) can ameliorate the risk of chronic disease and recommends ways to develop dietary reference intakes (DRI) based on chronic disease outcomes.

Producing more precise county-level estimates of crops and farmland cash rents will require integrating multiple data sources using model-based predictions that are more transparent and reproducible, says a new report from the National Academies of Sciences, Engineering, and Medicine.

The U.S. should take bold steps to improve measurement, monitoring, and inventories of methane emissions caused by human activities, says a new report from the National Academies of Sciences, Engineering, and Medicine.

Perk Labs has formally launched new verticals and unveiled the...

Using 'gardening' techniques to actively restore endangered coral reefs is ecologically sound and economically feasible, according to recent research.

High quality landscape assessments of areas protected under the Natura 2000 network are critical for effective long-term management plans. In a recent study, scientists have presented a integrated assessment of a Natura 2000 site in Sicily, Italy, which not only considers preservation of environmental features, as required by Natura 2000, but also human features, such as places of historical interest or industrial activity.

A standardised method to help choose the most cost-effective measures to remediate contaminated sites has been developed by Austrian researchers. The method takes into account a wide range of factors, including the principles of sustainability.

A recent study has described a simple method to screen the toxicity of materials used in consumer products. Using utility meter products as examples, the study found, for example, that stainless steel and polyvinyl chloride (PVC) had high toxicity potentials and suggests less toxic, but equally effective and priced, alternatives that could be used instead.

Research into mercury has identified two genes in bacteria that appear to be required for turning the metal into its most toxic form, methylmercury. The study adds to a growing body of research that helps us to understand the transformations that mercury undergoes in the environment and the microbes involved in these transformations.

High quality landscape assessments of areas protected under the Natura 2000 network are critical for effective long-term management plans. In a recent study, scientists have presented a integrated assessment of a Natura 2000 site in Sicily, Italy, which not only considers preservation of environmental features, as required by Natura 2000, but also human features, such as places of historical interest or industrial activity.

Storage of carbon in soil helps to keep land fertile and regulates the climate, and is therefore an important ecosystem service. However, mapping of soil carbon stocks currently uses unreliable measures. This study used data from a national survey of English grasslands to show that soil carbon stocks can be accurately predicted using simple measures of soil and climatic conditions.

The presence of plastics in aquatic environments is a growing concern across the EU. This study explored the amount of microplastic particles present in raw and treated water at three water-treatment plants in the Czech Republic. While treated water contained fewer particles than raw1 fresh water, the amount found in treated water was not negligible, and largely comprised tiny particles of <10 micrometres (μm) in diameter. Ways to filter microplastics from potable water must be identified and their risk to humans, sources and routes into drinking water determined, say the researchers.

New research has identified 25 variables that influence noise in urban areas. By combining these into an equation, the study produced an accurate tool to describe urban sound environments that could be useful in urban planning.

It is difficult to compare estimates of noise exposure across EU Member States because the methods used to produce the data vary between countries. A new study has investigated five methods of estimating noise exposure and identified some of the reasons for variation in the data they produce.

Methods for assessing the sustainability of tourist destinations have been developed. In a new Spanish study, researchers describe a framework for analysing sustainability that is designed for policymakers and tourism managers, and, as a case study, apply it to the region of Andalusia.

Researchers have developed a straightforward approach to help small to medium enterprises (SMEs) analyse their energy use and increase efficiency. They tested the methodology on 280 businesses in Europe, which, as a result, invested more than €10m in energy-saving measures. The measures reduced energy use by 6 500 toe (tonnes of oil equivalent) per year and avoided 13 500 tonnes of CO2 emissions.

Researchers have developed a methodology that allows the analysis of how an existing product design meets design guidelines required for the circular-economy perspective, and which guidelines would need to be incorporated to create a better circular-design product. The results, based on a case study of small electrical equipment in Spain, indicate that the most urgent priority is to incorporate circular-design guidelines related to extending life span and to product/components re-use, while there is a moderate need to include guidelines related to the use of simple removable connections or a modular product structure.

A potential method for reducing greenhouse gas (GHG) emissions associated with extracting energy from oil shale has been highlighted by a recent study. A ‘self-fuelling’ method that recycles waste gas could cut GHGs emissions by 50% compared to the conventional oil shale product and 70% compared to crude oil.

For thousands of years, vast amounts of methane – a potent greenhouse gas – have been stored in frozen deposits on land and under the ocean in the Arctic. A new study has found that rapidly rising temperatures are accelerating the release of methane by thawing subsea ‘permafrost’, releasing nearly 8 million tonnes into the atmosphere each year and potentially increasing global warming.

Scientists have found that retreating glaciers and melting permafrost in Alaska are releasing up to 70% more methane – a potent greenhouse gas – than previously thought. If this estimate is true for the rest of the Arctic, this could have serious implications for global warming, say the scientists.

Decision-making about complex environmental problems like desertification, which also have important social and economic implications, could be improved by employing methods outlined in a new study. The study outlines the steps taken by researchers on behalf of the Canary Islands government in devising a policy strategy for tackling desertification and describes a three-step methodology and participatory decision-making process.

Higher temperatures being brought about by global warming are increasing methane emissions from the extensive northern European peatlands, a recent study has found. The researchers also say that future estimations of greenhouse gas emissions can be improved via better land-cover classification — i.e. determining how much peatland is fenland or bogland.

The challenge of measuring the ‘absence of waste’ makes it particularly difficult to monitor and evaluate waste prevention policies. Researchers have examined the strengths and weaknesses of nine methods of assessing waste prevention, and recommend a hybrid approach, which combines the best of many methods, as particularly valuable.

Life-cycle indicators to monitor selected waste streams' impacts on the environment have been developed by the European Commission’s Joint Research Centre (JRC). These are presented in a recent study which describes a method for analysing waste's impacts using these indicators. The study also reveals the need for better statistics and more detailed categorisation of waste streams to effectively inform decision making in waste management.

Which types of buildings will require the least energy for heating and cooling under climate change? A study in Vienna, Austria, looked at the balance between heating and cooling demand in four different types of buildings. The research provides a method that could be useful for other European cities trying to adapt to climate change.

A three-step chemical process could successfully recover high-purity silicon from recycled photovoltaic (PV) solar panels, new tests show. The scientists behind the research say that recycling not only helps the PV industry meet regulatory requirements, but also reduces pressure on demand for raw materials.

Shortages of indium, a key metal found in thin-film solar cells, could limit their large-scale deployment in the future. A new study has outlined four ways that indium supplies could be increased to meet future demand. For example, indium could be extracted more efficiently from zinc ores, or historic wastes containing indium could be processed to extract the element.

In-depth soil information is increasingly required to achieve an array of environmental and economic goals. In particular, accurate estimates of soil carbon stocks are necessary to guide land-management practices and climate- related policymaking. To help meet this need, Australian scientists have developed a new sensing method to analyse cylindrical soil samples (soil cores), known as the Soil Condition ANalysis System (SCANS). By integrating a novel automated soil- core sensing system (CSS) with advanced statistical analytics and modelling, the SCANS provides a level of detail that is difficult to achieve with existing alternatives. SCANS is not only rapid, accurate and inexpensive1, but is likely to be a useful tool for farmers, land managers and policymakers, as the improved assessment of soil functions, structures and carbon stocks will facilitate more informed, sustainable decision-making.

Some 'intangible' ecosystem services, such as the aesthetic and cultural value, as well as the recreational use of land, are particularly difficult to price. New research has proposed three explorative methods to value these more intangible services using landscape evaluation, statistics on level of recreational use and the price of real estate in the area.

A new study has proposed a method to place monetary value on green infrastructure at both a project and regional scale, which illustrates the value of investing in green infrastructure to the public and other stakeholders.

There is increasing policy demand for the ‘scaling-up’ of ecosystem service valuations to a national or regional level, but available methods for doing this are limited. A new study has proposed a new scaling-up methodology and tested it by assessing the impact of climate change on European wetlands.

The use of important ecosystem services, such as carbon storage or hunting, can be estimated through ecosystem accounting methods, a new study demonstrates. The researchers tested models that could help policymakers to understand the capacity of ecosystems to generate ecosystem services, and how these services are used over time.

A process to help identify and value cultural ecosystem services has been developed by researchers and is demonstrated in a recent Black Sea case study. This highlighted the value of anchovies to Turkish identity: respondents to a survey said that they would be willing to pay 135 Turkish lira (€49) per year in order to fund environmental management that protects this culturally important species.

An innovative reforestation technique has been used successfully to restore patches of forest in an area of Sardinia where traditional reforestation methods have previously failed. It was the first time the technique, known as the Miyawaki method, has been used to restore forests in a Mediterranean region.

Researchers have developed a method to assess the sustainability of regeneration projects that could potentially be administered by a computer. The method tailors the universal goals of sustainability to specific local conditions.

A standardised method to help choose the most cost-effective measures to remediate contaminated sites has been developed by Austrian researchers. The method takes into account a wide range of factors, including the principles of sustainability.

A new five-step method has been developed for assessing the resource efficiency of products and improving the reuse, recycling and recovery of material at a product’s end of life. The Resource Efficiency Assessment of Products (REAPro) method allows the identification and testing of practical measures to improve resource efficiency at both the product and policy level.

The drive to increase renewable energy production can sometimes be at loggerheads with the desire to preserve natural landscapes. In this study, researchers from across Europe assessed the environmental impacts of renewable energies in the Alps, making key recommendations to resolve conflicts between different users of habitats.