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Photo-controlled RAFT polymerization mediated by organic/inorganic hybrid photoredox catalysts: enhanced catalytic efficiency

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00171F, Paper
Wulong Wang, Sheng Zhong, Guicheng Wang, Hongliang Cao, Yun Gao, Weian Zhang
Photo-controlled RAFT polymerization mediated by an organic/inorganic hybrid photoredox catalyst (ZnTPP–POSS) was performed and showed enhanced catalytic efficiency compared with the ZnTPP photocatalyst.
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Surfactant-free synthesis of layered double hydroxide-armored latex particles

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00140F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
X. G. Qiao, P.-Y. Dugas, V. Prevot, E. Bourgeat-Lami
MgAl-layered double hydroxide (LDH)-armored latexes were produced by Pickering emulsion polymerization of styrene using 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) as auxiliary comonomers.
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Using the dynamic behavior of macrocyclic monomers with a bis(hindered amino)disulfide linker for the preparation of end-functionalized polymers

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00366B, Paper
Hirogi Yokochi, Rikito Takashima, Daisuke Aoki, Hideyuki Otsuka
End-functionalized polymers were synthesized by simply heating a mixture of a macrocyclic compound with one bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) moiety and bifunctional acyclic BiTEMPS compounds as sources of repeat units and terminal groups, respectively.
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Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00249F, Communication
Zhonghua Cheng, Lei Wang, Yan He, Xingjia Chen, Xiaojun Wu, Hangxun Xu, Yaozu Liao, Meifang Zhu
A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts.
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Preparation of aryl polysulfonates via a highly efficient SuFEx click reaction, their controllable degradation and functionalized behavior

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00435A, Communication
Zhenlei Cao, Feng Zhou, Pei-Yang Gu, Dongyun Chen, Jinghui He, John R. Cappiello, Peng Wu, Qingfeng Xu, Jianmei Lu
Polysulfonates obtained from SuFEx click reaction can be degraded using DBU. The degradation process was further utilized to prepare functional polymers.
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Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00174K, Paper
Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai, Bao-Tsan Ko
Catalyst 1 was reported for the first time to be effective for nickel-catalyzed CO2/CHO copolymerization at 1 atm CO2 pressure.
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Enhanced thermomechanical property of a self-healing polymer via self-assembly of a reversibly cross-linkable block copolymer

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00310G, Paper
Hyang Moo Lee, Suguna Perumal, Gi Young Kim, Jin Chul Kim, Young-Ryul Kim, Minsoo P. Kim, Hyunhyup Ko, Yecheol Rho, In Woo Cheong
Introduction of a self-healable block copolymer increases the mechanical property whilst maintaining self-healing efficiency.
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Smart functionalized phosphonic acid based copolymers: new structures for old purposes

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00337A, Paper
Xavier Solimando, Yohann Catel, Norbert Moszner, Jean-Jacques Robin, Sophie Monge
Innovative well-defined acidic photopolymerizable phosphorus-based copolymers were prepared and tested in well-known dental applications to improve the adhesion of dental self-etch adhesives (SEAs).
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A general method to greatly enhance ultrasound-responsiveness for common polymeric assemblies

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00254B, Paper
Jinkang Dou, Ruiqi Yang, Kun Du, Li Jiang, Xiayun Huang, Daoyong Chen
Ultrasound-controlled drug release is a very promising technique for controlled drug delivery due to the unique advantages of ultrasound as the stimulus.
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Hydrogen-bonded supramolecular micelle-mediated drug delivery enhances the efficacy and safety of cancer chemotherapy

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Polym. Chem., 2020, 11,2791-2798
DOI: 10.1039/D0PY00082E, Paper
Chih-Chia Cheng, Ya-Ting Sun, Ai-Wei Lee, Shan-You Huang, Wen-Lu Fan, Yu-Hsuan Chiao, Chih-Wei Chiu, Juin-Yih Lai
Multiple hydrogen-bonded supramolecular polymers tend to form stable spherical micelles with oppositely charged anticancer drugs in biological environments, which improves cellular drug uptake and more effectively induces apoptosis in cancer cells.
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Temporal control of RAFT polymerization via magnetic catalysis

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Polym. Chem., 2020, 11,2838-2846
DOI: 10.1039/D0PY00220H, Paper
Amin Reyhani, Omid Mazaheri, Masood S. Alivand, Kathryn A. Mumford, Greg Qiao
Magnetic core–shell structured Fe3O4@Fe(II)–MOF nanoparticles have enabled the temporal control of RAFT polymerization via an “on–off” process.
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Polymerization of dopamine accompanying its coupling to induce self-assembly of block copolymer and application in drug delivery

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Polym. Chem., 2020, 11,2811-2821
DOI: 10.1039/D0PY00085J, Paper
Yudian Qiu, Zongyuan Zhu, Yalei Miao, Panke Zhang, Xu Jia, Zhongyi Liu, Xubo Zhao
The polymerization of dopamine and its coupling occur in succession, which synergistically induces the self-assembly of block copolymer to yield ordered structures, including micelles and vesicles.
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Mussel-inspired coordination functional polymer brushes-decorated rGO-stabilized silver nanoparticles composite for antibacterial application

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Polym. Chem., 2020, 11,2822-2830
DOI: 10.1039/D0PY00180E, Paper
Shengnan Zhou, Haixun Ji, Linjing Liu, Sijia Feng, Yuqin Fu, Yu Yang, Changli Lü
A catechol-terminated coordination functional polymer-modified rGO supported AgNPs composite was fabricated. Grafted polymer brushes improve the material's hydrophilicity and dispersion stability of AgNPs on rGO, enhancing antibacterial activity.
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Vesicular assemblies of thermoresponsive amphiphilic polypeptide copolymers for guest encapsulation and release

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Polym. Chem., 2020, 11,2889-2903
DOI: 10.1039/D0PY00135J, Paper
Mahammad Anas, Somdeb Jana, Tarun K. Mandal
Thermoresponsive amphiphilic polypeptide copolymers are synthesized via different polymerization techniques for their self-assembly into vesicular aggregates for guest encapsulation and release.
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Self-supported rhodium catalysts based on a microporous metal–organic framework for polymerization of phenylacetylene and its derivatives

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Polym. Chem., 2020, 11,2904-2913
DOI: 10.1039/D0PY00170H, Paper
Li Zhang, Qingbin Cao, Fei Gao, Yuping Dong, Xiaofang Li
Highly efficient, cis-selective, stable, recyclable and reusable heterogeneous single-site MOF-supported rhodium catalysts polymerize PA and its derivatives, producing cis-transoidal PPAs and their functional derivatives having a helical configuration or AIE properties.
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Synthesis of a side-chain hole transporting polymer through Mitsunobu post-functionalization for efficient inverted perovskite solar cells

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Polym. Chem., 2020, 11,2883-2888
DOI: 10.1039/D0PY00134A, Paper
Liuyuan Lan, Xiang Deng, Jie Zhang, Jingdong Luo, Alex K.-Y. Jen
Mitsunobu post-functionalization was utilized to construct a new efficient dopant-free side-chain hole transporting polymer for inverted perovskite solar cells, exhibiting a power conversion efficiency of 17.75% and a high fill factor over 81%.
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Synthesis of biscarboxylic acid functionalised EDTA mimicking polymers and their ability to form Zr(IV) chelation mediated nanostructures

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Polym. Chem., 2020, 11,2799-2810
DOI: 10.1039/D0PY00304B, Paper
Meike N. Leiske, Julia A. Walker, Aadarash Zia, Nicholas L. Fletcher, Kristofer J. Thurecht, Thomas P. Davis, Kristian Kempe
We present a new biscarboxylic acid acrylate, which is used for the synthesis of double hydrophilic EDTA-mimicking block copolymers capable of self-assembly upon zirconium complexation.
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Well-controlled polymerization of tri-vinyl dynamic covalent boroxine monomer: one dynamic covalent boroxine moiety toward a tunable penta-responsive polymer

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Polym. Chem., 2020, 11,2914-2922
DOI: 10.1039/D0PY00401D, Paper
Shun-Shun Li, Xin-Hu Lv, Xiao-Li Sun, Wen-Ming Wan, Hongli Bao
Attributed to dynamic characteristics of dynamic covalent boroxine, well-controlled polymerization of tri-vinyl monomer and molecular design of penta-responsive polymer with only one functional moiety are achieved.
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A high performance phenyl-free LED photoinitiator for cationic or hybrid photopolymerization and its application in LED cationic 3D printing

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Polym. Chem., 2020, 11,2855-2863
DOI: 10.1039/D0PY00142B, Paper
Liqun Tang, Jun Nie, Xiaoqun Zhu
In this work, a high performance LED photoinitiator, 1,3-bis(1-methyl-1H-pyrrol-2-yl)prop-2-en-1-one (BMO), without a benzene ring was synthesized through a one-step aldehyde–ketone condensation reaction.
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Mechanical activation of polymers containing two adjacent mechanophores

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Polym. Chem., 2020, 11,2864-2868
DOI: 10.1039/D0PY00279H, Paper
Richard Stevenson, Min Zhang, Guillaume De Bo
Polymers containing two adjacent mechanophores cleave at the same as a single-mechanophore chains.
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Influence of surface charge on the formulation of elongated PEG-b-PDLLA nanoparticles

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Polym. Chem., 2020, 11,2775-2780
DOI: 10.1039/D0PY00280A, Communication
Open Access
Roxane Ridolfo, David S. Williams, Jan C. M. van Hest
Amphiphilic PEG-PDLLA copolymers undergo assembly into polymersomes and can be transformed into tubular shapes using dialysis. By fine-tuning the shape change conditions also amine- and carboxylic acid modified polymersomes can now be effectively turned into tubes.
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Biosignal-responsive polymer nanorods that specifically recognize hydrogen polysulfide (H2Sn) from reactive sulfur species

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Polym. Chem., 2020, 11,2781-2785
DOI: 10.1039/D0PY00360C, Communication
Xi Liu, Wei Sang, Kunbing Ouyang, Qiang Yan
We report a new block copolymer bearing p-fluoronitrobenzoate (FNB) pendants that is capable of responding to the H2Sn biosignal in an extraordinarily selective and sensitive manner.
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Incorporating trifunctional 1,6-heptadiyne moiety into polyacetylene ionomer for improving its physical and conductive properties

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00109K, Paper
Hongfei Li, Hengchen Zhang, Xiaojuan Liao, Ruyi Sun, Meiran Xie
A trifunctional diyne comonomer can regulate the structure and optimize the physical state of polyacetylene ionomers, which exhibit a high ionic conductivity of 2.6 × 10−5–1.0 × 10−3 S cm−1 at 30 °C.
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Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00322K, Paper
Haoyu Yu, Jianwei Shao, Dong Chen, Li Wang, Wantai Yang
TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.
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Amide transformation as an efficient postpolymerization modification approach for the synthesis of functional polyacetylenes

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00398K, Paper
Juntao Ren, Heng Liu, Xuequan Zhang, Yanming Hu, Guangyuan Zhou, Toshio Masuda
Modification of a precursor polyacetylene with various amines and alcohols through amide transformation gives access to a series of functional polymers showing nonlinear optical, luminescence, enhanced surface energy, and redox active properties.
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Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00453G, Paper
Yongjun Shin, Matthew L. Becker
A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)2(THF)2 catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.
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Hierarchical self-assembled nanostructures of lactone-derived thiobarbiturate homopolymers for stimuli-responsive delivery applications

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00367K, Paper
Piyali Mandal, Diptendu Patra, Raja Shunmugam
Hierarchical self-assembled nanostructures of lactone-derived thiobarbiturate homopolymers for stimuli-responsive delivery applications are shown.
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Tacticity dependence of single chain polymer folding

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00133C, Paper
Open Access
Denis Danilov, Elaheh Sedghamiz, Heike Fliegl, Hendrik Frisch, Christopher Barner-Kowollik, Wolfgang Wenzel
Precision polymerization techniques offer the exciting opportunity to manufacture single-chain nanoparticles (SCNPs) with intramolecular crosslinks placed in specific positions along the polymer chain.
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Self-assembly of strawberry-like organic–inorganic hybrid particle clusters with directionally distributed bimetal and facile transformation of the core and corona

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00237B, Paper
Shuxing Mei, Mingwang Pan, Juan Wang, Xiaopeng Zhang, Shaofeng Song, Chao Li, Gang Liu
Controllable structure of organic–inorganic hybrid particle clusters were successfully fabricated by self-assembly which derived from the strong interaction between carboxyl groups of the organic particles and amino groups of the inorganic particles.
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A 3D printed drug delivery implant formed from a dynamic supramolecular polyurethane formulation

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00068J, Paper
S. Salimi, Y. Wu, M. I. Evangelista Barreiros, A. A. Natfji, S. Khaled, R. Wildman, L. R. Hart, F. Greco, E. A. Clark, C. J. Roberts, W. Hayes
Prototype drug eluting implants have been 3D printed using a supramolecular polyurethane-PEG formulation. The implants are capable of releasing a pharmaceutical active with effective drug release over a period of up to 8.5 months.
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Multi-photon polymerization of bio-inspired, thymol-functionalized hybrid materials with biocompatible and antimicrobial activity

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00281J, Communication
Open Access
Kostas Parkatzidis, Maria Chatzinikolaidou, Eleftherios Koufakis, Maria Kaliva, Maria Farsari, Maria Vamvakaki
Thymyl-methacrylate functionalized, hybrid 3D scaffolds, fabricated by multi-photon lithography, exhibit excellent biocompatibility and antimicrobial action for bone and dental tissue engineering.
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Epoxy-functional diblock copolymer spheres, worms and vesicles via polymerization-induced self-assembly in mineral oil

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00380H, Paper
Philip J. Docherty, Chloé Girou, Matthew J. Derry, Steven P. Armes
Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) spheres, worms or vesicles can be prepared by RAFT dispersion polymerization of glycidyl methacrylate in mineral oil at 70 °C.
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Comprehensive theoretical and experimental study of near infrared absorbing copolymers based on dithienosilole

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00330A, Paper
Katarzyna Brymora, Wissem Khelifi, Sylvie Blanc, Lionel Hirsch, Antoine Bousquet, Christine Lartigau-Dagron, Frederic Castet
In recent contributions [Eur. Polym. J. 2013, 49, 4176; Macromolecules 2019, 52, 13, 4820], we reported a series of low band gap copolymers with the objective of shifting the absorption...
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Correction: Flow-facilitated ring opening metathesis polymerization (ROMP) and post-polymerization modification reactions

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY90065F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Selesha I. Subnaik, Christopher E. Hobbs
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Fluorescent chemosensors based on conjugated polymers with N-heterocyclic moieties: two decades of progress

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00336K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Taisheng Wang, Na Zhang, Wei Bai, Yinyin Bao
A brief summary of representative fluorescent chemosensors based on conjugated polymers with N-heterocyclic moieties, followed by a discussion on the limitations and challenges of current systems, as well as possible future research directions.
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Optimizing the Thermoelectric Performance of Conjugated Polymer Backbones via Incorporating Tailored Platinum (II) Acetylides

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00464B, Paper
Chunfa Liu, Xiaojun Yin, Jianwen Liu, Chunmei Gao, Lei Wang
Efforts to improve the electrical conductivity (σ) of the organic semiconductors propose the critical challenge for high performance organic thermoelectric (TE) devices. Herein, five new conjugated polymers incorporated with different...
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Photo-induced copper mediated copolymerization of activated-ester methacrylate polymers and their use as reactive precursors to prepare multi-dentate ligands for the water transfer of inorganic nanoparticles

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Polym. Chem., 2020, 11,2969-2985
DOI: 10.1039/D0PY00212G, Paper
Binh T. Mai, Markus J. Barthel, Aidin Lak, Tommaso Avellini, Ana Maria Panaite, Emille M. Rodrigues, Luca Goldoni, Teresa Pellegrino
Polymers bearing activated ester groups are synthesized using photo-ATRP and used as precursors for direct synthesis of multi-phosphonic acid functionalized ligands which are able to transfer different nanoparticles with distinct cores into water.
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Viscoelastic and thermoreversible networks crosslinked by non-covalent interactions between “clickable” nucleic acid oligomers and DNA

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Polym. Chem., 2020, 11,2959-2968
DOI: 10.1039/D0PY00165A, Paper
Alex J. Anderson, Heidi R. Culver, Stephanie J. Bryant, Christopher N. Bowman
An approach to efficient and scalable production of oligonucleotide-based gel networks is presented.
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Effects of tacticity and chiral center-to-dipole distance on mesogen-free liquid crystalline self-assembly of sulfonyl-containing comb-like polymers

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Polym. Chem., 2020, 11,3018-3031
DOI: 10.1039/D0PY00199F, Paper
Caleb A. Bohannon, Man-Hin Kwok, Ruipeng Li, Lei Zhu, Bin Zhao
Mesogen-free comb-like polyethers bearing strongly interacting mono- and di-sulfonylated side chains exhibit well-defined liquid crystalline self-assembly.
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Synthesis of well-defined heteroglycopolymers via combining sequential click reactions and PPM: the effects of linker and heterogeneity on Con A binding

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Polym. Chem., 2020, 11,3054-3065
DOI: 10.1039/D0PY00302F, Paper
Meina Liu, Xingyou Wang, Dengyun Miao, Caiyun Wang, Wei Deng
A versatile post- polymerization modification strategy to synthesize well-defined glycopolymers via the combination of RAFT polymerization and sequential CuAAC and thiol–ene click reactions was developed.
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Metallopolymer-block-oligosaccharide for sub-10 nm microphase separation

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Polym. Chem., 2020, 11,2995-3002
DOI: 10.1039/D0PY00271B, Paper
Satoshi Katsuhara, Hiroaki Mamiya, Takuya Yamamoto, Kenji Tajima, Takuya Isono, Toshifumi Satoh
The novel high-χ BCPs comprising poly(vinyl ferrocene) and oligosaccharides formed hexagonal cylinder morphology with d values of ∼8 nm. Lamellar morphology with d values of ∼9 nm was also realized by mixing these polymers and glucose.
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Double-click synthesis of polysiloxane third-order nonlinear optical polymers with donor–acceptor chromophores

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Polym. Chem., 2020, 11,3046-3053
DOI: 10.1039/C9PY01771B, Paper
Zhitao Li, Dong Wang, Daniele Ramella, Hong Gao, Hui Cao, Yuzhen Zhao, Zongcheng Miao, Zhou Yang, Wanli He
A series of third-order nonlinear polysiloxane polymer materials were prepared by thiol–ene click polymerization and [2 + 2] click chemistry. All the polymers exhibit good electron transfer capabilities and nonlinear optical properties.
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Two-stage thiol-based click reactions for the preparation and adhesion of hydrogels

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Polym. Chem., 2020, 11,2986-2994
DOI: 10.1039/C9PY01503E, Paper
Wen Jing Yang, Wenya Xu, Xi Tao, Wen Wang, Yaqin Hu, Xue Li, En-Tang Kang, Lianhui Wang
Two-stage thiol-based click reactions have been employed as a facile strategy for hydrogel preparation and self-adhesion.
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Synthesis, thermoresponsivity and multi-tunable hierarchical self-assembly of multi-responsive (AB)mC miktobrush-coil terpolymers

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Polym. Chem., 2020, 11,3003-3017
DOI: 10.1039/D0PY00245C, Paper
Xiaomin Zhu, Jian Zhang, Cheng Miao, Siyu Li, Youliang Zhao
Stimuli-responsive miktobrush-coil terpolymers can exhibit unique physical properties and hierarchical self-assembly behaviors dependent on composition, concentration and external stimuli.
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Post-polymerization modification of polymethacrylates enabled by keto–enol tautomerization

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Polym. Chem., 2020, 11,2955-2958
DOI: 10.1039/D0PY00383B, Communication
Charles P. Easterling, Guilhem Coste, Jose E. Sanchez, Gail E. Fanucci, Brent S. Sumerlin
We report a post-polymerization modification strategy to functionalize methacrylic copolymers through enol-ester transesterification.
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Gold nanoparticles standing on PEG/PAMAM/thiol-functionalized nanographene oxide as aqueous catalysts

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00471E, Paper
Bingjie Hao, Guolin Lu, Sen Zhang, Yongjun Li, Aishun Ding, Xiaoyu Huang
Gold nanoparticles were aptly in situ grown on PEG/PAMAM/thiol-functionalized nanographene oxide platforms for aqueous catalysis.
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Polymerization-induced self-assembly for the fabrication of polymeric nano-objects with enhanced structural stability by cross-linking

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00368A, Review Article
Wen-Jian Zhang, Jamshid Kadirkhanov, Chang-Hui Wang, Sheng-Gang Ding, Chun-Yan Hong, Fei Wang, Ye-Zi You
Polymerization-induced self-assembly (PISA) has been established as a robust strategy to synthesize block copolymer nano-objects with varying morphologies, size, and surface chemistry, which greatly enlarges the library of functional nano-objects...
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Effect of the side, ethylene glycol and hydroxyl groups on the polymerization kinetics of oligo(ethylene glycol methacrylates). An experimental and modeling investigation

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00498G, Paper
Mohammad Siddiqui, Dimitris Achilias, Halim Hamid Redhwi
Polymers based on methacrylates bearing short oligo(ethylene glycol) side parts constitute a modern class of stimuli-responsive, biocompatible materials exhibiting several important biological applications. A study of their polymerization kinetics considering...
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Morphological Evolution and Mechanical Properties of "Anchor Chain" Nanodomain Structure of Reactive Amphiphilic Triblock Copolymer in Epoxy Resin

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00365D, Paper
Quan Zhou, Qi Liu, Yueru Yu, Yuxiao Zhuang, Yizhe Lv, Hanliang Xiao, Ning Song, Lizhong Ni
A novel epoxy-reactive amphiphilic poly(3,4-epoxy cyclohexyl methyl methacrylate)-block-poly(dimethylsiloxane)-block-poly(3,4-epoxy cyclohexylmethyl methacrylate) (PMETHB-b-PDMS-b-PMETHB) triblock polymer was synthesized via atomic transfer radical polymerization (ATRP) with a controlled molecular chain length and low dispersion,...
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Organocatalyzed ring opening polymerization of regio-isomeric lactones: reactivity and thermodynamics considerations

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9PY01777A, Paper
Marie A. F. Delgove, Ola Wróblewska, Jules Stouten, Christian A. M. R. van Slagmaat, Jurrie Noordijk, Stefaan de Wildeman, Katrien V. Bernaerts
Organocatalysts are increasingly gaining attention for the ring opening polymerization (ROP) of lactones due to numerous advantages. In this work, the goal is to expand the scope of catalysts for...
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