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The Role of Temperature and Adsorbate on Negative Gas Adsorption in the Mesoporous Metal-Organic Framework DUT-49

Faraday Discuss., 2020, Accepted Manuscript
DOI: 10.1039/D0FD00013B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simon Krause, Jack D. Evans, Volodymyr Bon, Irene Senkovska, François-Xavier Coudert, Daniel M Többens, Dirk Wallacher, Nico Grimm, Stefan Kaskel
Unusual adsorption phenomena, such as breathing and negative gas adsorption (NGA), are rare and challenge our understanding of the thermodynamics of adsorption in deformable porous solids. In particular, NGA appears...
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