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Heterojunction lithiation engineering and diffusion-induced defect passivation for highly efficient Sb2(S,Se)3 solar cells

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, 17,8402-8412
DOI: 10.1039/D4EE03135K, Paper
Cong Liu, Anweng Gong, Chen Zuo, Tao Liu, Xiaoyang Liang, Donglou Ren, Kai Shen, Jianzha Zheng, Qifan Xue, Zhiqiang Li, Ruud E. I. Schropp, Bingsuo Zou, Yaohua Mai
A heterojunction lithiation strategy has been developed to achieve a certified efficiency of 10.50%, which is the record efficiency for all of the Sb-based solar cells.
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Three-step thermodynamic vs. two-step kinetics-limited sulfur reactions in all-solid-state sodium batteries

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03160A, Paper
Tongtai Ji, Qingsong Tu, Yang Zhao, Dominik Wierzbicki, Vincent Plisson, Ying Wang, Jiwei Wang, Kenneth S. Burch, Yong Yang, Hongli Zhu
This study unveils the intrinsic three-step thermodynamic and the two-step kinetics-limited pathways in all-solid-state sodium–sulfur batteries, providing crucial insights into sulfur reaction mechanisms for high-performance energy storage solutions.
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Theoretical calculations-driven rational screening of d-block single-atom electrocatalysts based on d-p orbital hybridization for durable aqueous zinc-iodine batteries

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Published On ::

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04119D, Paper
Jin Yang, Yuanhong Kang, Fanxiang Meng, weiwei meng, guanhong Chen, Minghao Zhang, Zeheng Lv, Zhipeng Wen, Chengchao Li, Jinbao Zhao, Yang Yang
Aqueous Zn−iodine (Zn-I2) batteries, featuring intrinsically high-safety aqueous electrolytes and eco-friendly cathode/anode materials, however are restricted by the shuttling of polyiodide and sluggish redox kinetics of iodine redox. Although various...
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Superhalide structure and iodide-proof interphase via electrolyte regulation enable ultrastable zinc-iodine batteries

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Energy Environ. Sci., 2024, 17,8643-8657
DOI: 10.1039/D4EE02192D, Paper
Wenjing Deng, Renfei Feng, Xiaolei Wang
A superhalide electrolyte structure and iodide-proof solid electrolyte interphase are introduced to simultaneously obtain efficient conversion activity and anode stability for reversible zinc–iodine batteries.
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Microenvironment engineering of covalent organic framework based single/dual-atom catalysts toward sustainable energy conversion and storage

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Energy Environ. Sci., 2024, 17,8482-8528
DOI: 10.1039/D4EE03704A, Review Article
Ligang Wang, Jialu Li, Shufang Ji, Yuli Xiong, Dingsheng Wang
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
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Engineering ultrafast exciton dynamics to boost organic photovoltaic performance

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Energy Environ. Sci., 2024, 17,8776-8786
DOI: 10.1039/D4EE03315A, Paper
Yu Guo, Guangchao Han, Jing Guo, Haotian Guo, Yuang Fu, Xiaodan Miao, Zhen Wang, Dongsheng Li, Shuixing Li, Xiaomin Xu, Xinhui Lu, Hongzheng Chen, Yuanping Yi, Philip C. Y. Chow
Y-type acceptors exhibiting faster migration (shorter τ) of local excitons (LEs) in disordered regions of aggregates to intermolecular charge-transfer (ICT) excitons in ordered regions can achieve higher efficiencies in organic solar cells.
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Towards efficient and stable organic solar cells: fixing the morphology problem in block copolymer active layers with synergistic strategies supported by interpretable machine learning

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Energy Environ. Sci., 2024, 17,8954-8965
DOI: 10.1039/D4EE03168G, Paper
Yu Cui, Qunping Fan, Hao Feng, Tao Li, Dmitry Yu. Paraschuk, Wei Ma, Han Yan
Interpretable machine learning identifies the causal structure–property relationships and key control factors in block copolymer organic solar cells with excellent power conversion efficiency and thermal stability.
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Advancing high-temperature electrostatic energy storage via linker engineering of metal–organic frameworks in polymer nanocomposites

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04085F, Paper
Zongliang Xie, Zhiyuan Huang, He Li, Tianlei Xu, Haoyu Zhao, Yunfei Wang, Pang Xi, Zhiqiang Cao, Virginia Altoe, Liana M Klivansky, Zaiyu Wang, Steven Shelton, Shiqi Lai, Peng Liu, Chenhui Zhu, Michael D. Connolly, Corie Y. Ralston, Xiaodan Gu, Zongren Peng, Jian Zhang, Yi Liu
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
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Hospital in Coimbatore introduces machine for advanced radiation therapy

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 20:13:46 +0530


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Happiness in the true sense

By www.thehindu.com
Published On :: Sun, 03 Nov 2024 00:47:00 +0530

Amid a cloud of gloomy faces, a lone glimmer


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Big Tech’s fail — unsafe online spaces for women

By www.thehindu.com
Published On :: Tue, 05 Nov 2024 00:16:00 +0530

The U.S. presidential election and the campaign has again highlighted a key issue — of technology and online spaces posing a threat to the safety and the dignity of women


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Lakshmi Swaminathan on how legendary architect Didi Contractor imagined spaces

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 09:00:00 +0530

‘Didi evocatively narrated her designs as stories as she drew. By living her ideals in day-to-day life, she introduced me to an elegantly simple lifestyle,’ says Didi’s student Lakshmi Swaminathan


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New Editor-in-Chief for Reaction Chemistry & Engineering

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE90011A, Editorial
Dionisios G. Vlachos, Maria Southall, Klavs F. Jensen
Executive Editor Maria Southall welcomes Dionisios Vlachos as the new Editor-in-Chief of Reaction Chemistry & Engineering and pays tribute to the leadership and many contributions of departing inaugural Editor-in-Chief Klavs Jensen.
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Development of an automated platform for monitoring microfluidic reactors through multi-reactor integration and online (chip-)LC/MS-detection

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00004H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hannes Westphal, Simon Schmidt, Sanjay Lama, Matthias Polack, Chris Weise, Toni Oestereich, Rico Warias, Tanja Gulder, Detlev Belder
Biocatalysis with packed-bed microreactors: a novel method combining microreactor technology, multi-reactor integration, and online (chip-)LC/MS analysis in a sequential automated workflow.
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TiO2 nanopowder and nanofilm catalysts in the disinfection and mineralization of S. aureus with solar-simulated radiation

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00540B, Paper
Raed Shqier, Ahed Zyoud, Muath H. S. Helal, Heba Nassar, Raed Alkowni, Mohyeddin Assali, Shaher Zyoud, Naser Qamhieh, Abdul Razack Hajamohideen, Shadi Sawalha, Samer H. Zyoud, Hikmat S. Hilal
TiO2 films photo-catalyze S. aureus rupture and mineralization of resulting organic materials.
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General synthesis of secondary imines via reductive coupling of carbonyl and nitro compounds employing a reusable cobalt catalyst

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React. Chem. Eng., 2024, 9,925-929
DOI: 10.1039/D3RE00509G, Paper
Chaochong Zhang, Yurong He, Peng Zhou, Yuandie Ma, Ziliang Yuan, Guoqiang She, Zhe Zheng, Juncheng Hu, Qingqing Jiang, Jason Chun-Ho Lam, Bo Han, Zehui Zhang, Bing Liu
Reusable nitrogen-doped carbon-encapsulated Co nanoparticle catalysts are found robust for the synthesis of secondary imines via the reductive amination of carbonyl compounds with NH3 or directly with nitro compounds.
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A safe and new strategy for N-arylation of 2,4-thiazolidinediones via microwave irradiation using base catalyst K2CO3 in DMF

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React. Chem. Eng., 2024, 9,842-848
DOI: 10.1039/D3RE00641G, Paper
Ragini C. Patil, Nita M. Khiratkar, Sumeer Ahmed, Joazaizulfazli Jamalis, Aso Hameed Hasan, Malika Berredjem, Sarkar M. A. Kawsar, Ajmal R. Bhat
Green efforts as an alternative to existing conventional methods for providing new tools, knowledge and design of organic synthesis, will contribute to the economy and protecting the environment and health.
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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

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React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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From microkinetic model to process: understanding the role of the boron nitride surface and gas phase chemistry in the oxidative dehydrogenation of propane

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React. Chem. Eng., 2024, 9,795-802
DOI: 10.1039/D3RE00600J, Paper
Unni Kurumbail, William P. McDermott, Edgard A. Lebrón-Rodríguez, Ive Hermans
In the oxidative dehydrogenation of propane over boron nitride, propylene selectivity is lost due to unselective gas-phase chemistry.
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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

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React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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Comprehensive Study of Lumped Kinetic Models and Bio-Oil Characterization in Microwave-Assisted Pyrolysis of Sargassum sp.

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D3RE00674C, Paper
Teta Fathya Widawati, Muhammad Fuad Refki, Rochmadi Rochmadi, Arief Budiman
Indonesia, renowned for its tropical marine environments, boasts a rich diversity of macroalgae, with Sargassum being a major contributor. Currently, Sargassum's primary application revolves around alginate extraction, prompting a systematic...
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Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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Thermokinetic analyses of metal-sensitive reactions in a ceramic flow calorimeter

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper
Open Access
Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Automated kinetic model identification via cloud services using model-based design of experiments

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00047A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Emmanuel Agunloye, Panagiotis Petsagkourakis, Muhammad Yusuf, Ricardo Labes, Thomas Chamberlain, Frans L. Muller, Richard A. Bourne, Federico Galvanin
Industry 4.0 has birthed a new era for the chemical manufacturing sector, transforming reactor design and integrating digital twin into process control.
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Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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A sequential lumped kinetic modelling approach for the co-pyrolysis of plastic mixtures with a heavy refinery intermediate product in a tubular reactor

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00075G, Paper
Open Access
Sebastian-Mark Lorbach, Andreas E. Lechleitner, Teresa Schubert, Markus Lehner
A novel sequential approach for the lumped kinetic modelling of a plastic pyrolysis process in a tubular reactor.
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High-efficiency non-thermal plasma synthesis of imine macrocycles

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00061G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Patrycja Roszkowska, Abbie M. Scholes, James L. Walsh, Timothy L. Easun, Anna G. Slater
Non-thermal plasma synthesis offers efficient access to imine macrocycles.
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Synthesis and kinetic study of 1,3,2-dioxathiolane 2,2-dioxide in microreactors

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00123K, Paper
Ting Wang, Junnan Wang, Chengxiang He, Zhongdong Wang, Yating Li, Chunying Zhu, Youguang Ma, Taotao Fu
1,3,2-dioxathiolane 2,2-dioxide (DTD) is an essential intermediate in organic synthesis and plays a vital role in improving the performance and service life of lithium-ion batteries. A large amount of heat...
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MRF’s Q2 net declines 20% on high input costs

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 15:54:11 +0530

MRF’s profit before exceptional items and taxes was ₹611 crore, compared to ₹773 crore in the September 2023 quarter


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Data Patterns reports 12% decline in PAT in Q2’25

By www.thehindubusinessline.com
Published On :: Sat, 09 Nov 2024 18:50:59 +0530

Revenue for the quarter was impacted due to deferment of delivery schedule by the customer of completed products


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Asian Paints profit declines 43.7% to ₹693.7 crore in Q2

By www.thehindubusinessline.com
Published On :: Sat, 09 Nov 2024 21:51:18 +0530

Asian Paints had logged a net profit of ₹1,232.39 crore during the July-September period a year ago


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Singapore Airlines to invest additional ₹3,195 crore in Air India post-Vistara merger

By www.thehindubusinessline.com
Published On :: Sun, 10 Nov 2024 15:07:19 +0530

The merger will result in Singapore Airlines having a 25.1% stake in the enlarged Air India


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How to choose the right vine

By www.thehindu.com
Published On :: Fri, 18 Apr 2014 18:56:13 +0530

Vines are among the most versatile of landscaping elements, lending themselves to a wide range of uses, says garden expert Vrinda Kumble


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The online green thumb

By www.thehindu.com
Published On :: Tue, 18 Aug 2015 16:51:03 +0530

Tanya Brar is on a mission to beautify Bengaluru’s balcony gardens and restore its former glory.


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Multi-omics analysis reveals that agaro-oligosaccharides with different degrees of polymerization alleviate colitis in mice by regulating intestinal flora and arginine synthesis

By pubs.rsc.org
Published On ::

Food Funct., 2024, 15,10628-10643
DOI: 10.1039/D4FO03650F, Paper
Long Yuan, Chunhui Liu, Bolun Li, Sai Wang, Jianan Sun, Xiangzhao Mao
Inflammatory bowel disease (IBD) is a common chronic disease with a complex etiology, characterized by body weight loss, intestinal barrier damage, and an imbalance of intestinal flora, posing a significant threat to people's health.
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Oral delivery of electrohydrodynamically encapsulated Lactiplantibacillus plantarum CRD7 modulates gut health, antioxidant activity, and cytokines-related inflammation and immunity in mice

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Published On ::

Food Funct., 2024, 15,10761-10781
DOI: 10.1039/D4FO02732A, Paper
Vinay Venkatesh Varada, Sachin Kumar, Sravani Balaga, Antony Johnson Thanippilly, Heartwin A. Pushpadass, Rashmi H. M., Babu Lal Jangir, Nitin Tyagi, Ashish Kumar Samanta
The current study aimed to evaluate the effects of L. plantarum CRD7 on performance and gut health biomarkers in a Swiss albino mouse model.
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In vivo mechanism of interaction between trimethylamine lyase expresssion and glycolytic pathways

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Published On ::

Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO03809F, Paper
Qian Li, Di Wu, Yu Song, Lu Zhang, Ting Wang, Min Zhang
Recent findings have confirmed that the interaction between host and gut microbiota can alter the formation of the disease-associated metabolite, trimethylamine (TMA), via intestinal microbial TMA lyase. Nevertheless, little is...
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A probiotic multi-strain mixture combined with hydroxyectoine improves intestinal barrier function by alleviating inflammation in lipopolysaccharide stimulated differentiated Caco-2 cells

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Published On ::

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03130J, Paper
Azza Dabous, Antonietta Stellavato, Donatella Cimini, Valentina Vassallo, Maria D'Agostino, Chiara Schiraldi
Freeze-dried formula containing three probiotic strains and hydroxyectoine reduces LPS-induced inflammation in Caco-2 cells, assessed via RT-PCR, western blot, ELISA, and immunofluorescence for tight junction integrity.
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Investigation of the hypoglycemic bioactive components of Phyllanthi Fructus through biological assessment combined with ultrafiltration affinity mass spectrometry

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Published On ::

Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO04198D, Paper
Yifan Zhang, Qiang Yu, Peng Tan, Shimin Tian, Jun-zhi Lin, Mengqi Li, Li Han, Haozhou Huang, Ding-kun Zhang
Phyllanthi Fructus (PF) is a tropical fruit with the potential to effectively reduce postprandial blood glucose, making it highly promising for the development of functional foods. However, the lack of...
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Lactobacillus plantarum 69-2 combined with α-lactalbumin hydrolysate alleviates DSS-induced ulcerative colitis through the TLR4/NF-κB inflammatory pathway and the gut microbiota in mice

By pubs.rsc.org
Published On ::

Food Funct., 2024, 15,10987-11004
DOI: 10.1039/D4FO02975E, Paper
Yue Ma, Chuanbing Hu, Jing Zhang, Cong Xu, Lizhi Ma, Yunhe Chang, Muhammad Altaf Hussain, Jiage Ma, Juncai Hou, Zhanmei Jiang
Ulcerative colitis (UC), an inflammatory bowel disease, seriously affects people's quality of life.
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Lacticaseibacillus plantarum postbiotics prepared by the combined technique of pasteurization and ultrasound: effective measures to alleviate obesity based on the SCFAs-GPR41/GPR43 signaling pathway

By pubs.rsc.org
Published On ::

Food Funct., 2024, 15,11005-11019
DOI: 10.1039/D4FO03591G, Paper
Chao Miao, Linge Wang, Huabing Wang, Yu Shen, Chaoxin Man, Wei Zhang, Yu Zhang, Qianyu Zhao, Yujun Jiang
Postbiotics prepared by ultrasound and pasteurization are used for the alleviation of obesity.
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The co-fermentation of whole-grain black barley and quinoa improves murine cognitive impairment induced by a high-fat diet via altering gut microbial ecology and suppressing neuroinflammation

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Published On ::

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO02704C, Paper
Fenfen Wei, Huibin Jiang, Chuang Zhu, Lingyue Zhong, Zihan Lin, Yan Wu, Lihua Song
A high-fat diet (HFD) is associated with various adverse health outcomes, including cognitive impairment and an elevated risk of neurodegenerative conditions.
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In vitro gastrointestinal digestion of marine oil emulsions and liposomal solutions: fate of LC-PUFAs upon lipolysis

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Food Funct., 2024, 15,11291-11304
DOI: 10.1039/D4FO03161J, Paper
Open Access
Sawsan Amara, Maureen Gerlei, Carole Jeandel, Moulay Sahaka, Frédéric Carrière, Michel Linder
Marine liposomes are more resistant than triacylglycerol emulsion to lipolysis under gastric condition. They can protect LC-PUFA (EPA and DHA) and are a better gastric-stable delivery system for their intestinal absorption than TAG.
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Ergothioneine improves cognitive function by ameliorating mitochondrial damage and decreasing neuroinflammation in a D-galactose-induced aging model

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Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO02321H, Paper
Fangyang Chen, Botao Wang, Xin Sun, Yage Wang, Ruiyan Wang, Kaikai Li
EGT intervention significantly improved D-galactose induced oxidative stress, neuroinflammation, and mitochondrial function, resulting in the alleviation of memory injury.
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Oral administration of cranberry-derived exosomes attenuates murine premature ovarian failure in association with changes in the specific gut microbiota and diminution in ovarian granulosa cell PANoptosis

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Published On ::

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03468F, Paper
Open Access
Zeyu Cui, Te Liu, Yichao Wen, Weihao Li, Jianghong Xu, Yingjuan Chen, Danping Chen, Ying Zhu
We confirmed that oral administration of cranberry-derived exosomes attenuated murine POF by modulating the gut microbiota and decreasing ovarian granulosa cell PANoptosis.
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