nds Fisherman finds pike inside bigger pike he caught – Video By english.pravda.ru Published On :: Mon, 21 Oct 2024 17:24:00 +0300 In the Astrakhan region of Russia, fishermen showed what can be found inside a huge pike. The men said that they thus wanted to dispel the myth about jewelry, watches and other valuable items that other fishermen allegedly find in the pike that they catch. The video appeared on pages of The Astrakhan Hunting and Fishing community. "Many have seen fake videos online in which they find watches, chains, lures, jewelry inside the pike. Here, there is indeed a fish in the belly, we even know what kind, because its tail is sticking out of the throat," the fisherman said. Full Article Society
nds Utimaco research finds a low level of trust for IoT devices, citing work needed to communicate digital safety By www.retailtechnologyreview.com Published On :: Utimaco has released new consumer research that has found a low level of trust around Internet of Things (IoT) devices. This has highlighted the need for more education from industry into how smart devices are secured with the latest digital security solutions. Full Article Mobile Computers Surveillance and Security Critical Issues
nds Think Tank launches new SMART formats to help brands elevate their packaging design By www.retailtechnologyreview.com Published On :: Think Tank, the UK bespoke packaging design agency, is launching new SMART packaging formats designed to help brands elevate their packaging design and boost their commercial reach. Full Article Retail Supply Chain
nds Global survey of security pros finds 87% of organisations impacted by cyber threats they couldn’t detect or neutralise last year By www.retailtechnologyreview.com Published On :: Fri, 13 Nov 8240 17:28:37 +0000 Red Canary, the managed detection and response (MDR) provider, has released a new report, Security Operations Trends Report, providing insight into critical challenges facing modern cybersecurity teams. Partnering with independent research company Coleman Parkes, Red Canary surveyed 700 security leaders from the US, UK, New Zealand, Australia and Nordics. Full Article Surveillance and Security Critical Issues Cyber Security
nds New Forter report finds UK consumer ‘Trust Premium’ rises, but checkout friction and unfriendly policies are costing British retailers By www.retailtechnologyreview.com Published On :: Forter, the Trust Platform for digital commerce, has released findings from its 2024 Consumer Trust Premium Report, which explores the evolving relationship between consumer shopping habits and brand trust, based on 2,000 survey respondents in the US and UK. Full Article Internet Retailing Retail Supply Chain Critical Issues
nds Russia's largest bank sends huge package of documents to China for its first branch By english.pravda.ru Published On :: Mon, 26 Dec 2022 17:58:00 +0300 Sberbank — Russia's largest state-owned bank — has the only foreign branch in India. In early November it was reported that Sberbank was going to open a branch in China. According to Alexander Vedyakhin, deputy chairman of the board, all the necessary documents have been sent to China, RBC reports. "We have been communicating with the People's Bank of China a lot lately. We have sent a massive package of documents there, as the Chinese regulator is very meticulous about documents. I hope that by the end of 2023 we will be able to open a branch in China. It usually takes 1.5-2 years, but we hope that by the end of 2023 we will already have a branch in this country,” Alexander Vedyakhin said. Sberbank opened a representative office in China in 2010; A representative office of Sberbank appeared in Germany in 2009; Sberbank has only one branch abroad — in New Delhi, India. After the start of the Russian special operation in Ukraine, Sberbank came under sanctions from Western states: the United States and Great Britain froze the bank's assets and banned citizens from doing business with it, whereas the EU disconnected Sberbank from the SWIFT interbank data exchange system. Full Article Business
nds Austria's Raiffeisen Bank finds itself in unprecedented situation in Russia By english.pravda.ru Published On :: Thu, 30 Mar 2023 15:11:00 +0300 Austria's Raiffeisen Bank International considers selling the Russian division or withdrawing it from the structure of the group. Raiffeisen's "daughter" will continue running "certain banking activities" in Russia to maintain license. At the moment, the bank can not get rid of all of its business in Russia, but is striving for this to happen, RBI CEO Johann Strobl said. The RBI Group in Russia is represented by Raiffeisenbank, as well as leasing, insurance and management companies. The company's subdivisions employ over 9,000 people. Full Article Business
nds Ikea extends trademark rights in Russia until 2033 By english.pravda.ru Published On :: Wed, 07 Feb 2024 15:09:00 +0300 IKEA extended the right to its trademark in Russia until August 2033. The IKEA trademark package included: the yellow-blue logo, a full list of company services and the right to officially sell its products in Russia. The headquarters of the corporation in the Netherlands submitted an application to Rospatent on August 1, 2023. The application was approved on February 2. Full Article Business
nds PervasID’s TrackMaster replaces manual handheld with accurate handsfree real-time location tracking solution By www.retailtechnologyreview.com Published On :: PervasID, provider of passive Radio Frequency Identification (RFID) reader systems for automating inventory and asset tracking, has launched a new advanced version of TrackMaster, claimed to provide greatly enhanced return on investment performance. Full Article RFID Data Capture
nds Highly competitive landscape for new POS software projects By www.retailtechnologyreview.com Published On :: Mon, 13 Nov 800 17:02:45 -0001 Competition between vendors to provide POS software remains fierce, with more than 125 suppliers working with major retail and hospitality chains, according to Global POS Software 2023, the latest study from strategic research and consulting firm RBR Data Services, a division of Datos Insights. Full Article EPoS Systems Data Capture Critical Issues
nds Mood Media research finds Shoppers need inspiration By www.retailtechnologyreview.com Published On :: Nearly two-thirds of shoppers step into a store without a specific purchase in mind, looking to be inspired by retailers who can craft the ideal ambience through digital screens and interactive kiosks. Full Article Kiosk Technology Data Capture Critical Issues
nds Brother UK launches new MPS offering to support growing demands By www.retailtechnologyreview.com Published On :: Business technology solutions provider Brother UK has launched three new managed print services (MPS) solutions to enhance its support for resellers amid growing demand for print-as-a-service. Full Article Print and Label
nds SureColor-S9100 designed to meet the rigorous demands of professional signage production By www.retailtechnologyreview.com Published On :: Mon, 13 Nov 7200 17:26:56 +0000 Epson, the printing technology solutions provider, has introduced its latest breakthrough in the signage printing market, the SC-S9100. Full Article Print and Label
nds SnapFulfil lands yet another distinguished supply chain and logistics award By www.retailtechnologyreview.com Published On :: The Top Supply Chain Projects 2024 (formerly known as SDCE 100) profiles innovative application success projects designed to automate, optimise, streamline and improve the supply chain. Full Article Retail Supply Chain Exhibitions and Events
nds eCommerce Expo & Technology for Marketing: Where the UK's top marketing and eCommerce minds meet By www.retailtechnologyreview.com Published On :: The UK's largest eCommerce and marketing event, eCommerce Expo & Technology for Marketing, will take place on 18-19 September 2024, at ExCeL, London. Full Article Exhibitions and Events Internet Retailing Retail Supply Chain
nds Consumers feel increasingly familiar with AI but less informed on quantum technology, finds survey By www.retailtechnologyreview.com Published On :: Mon, 13 Nov 7780 17:29:58 +0000 New research by BSI reveals growing public confidence in AI capabilities, with over half (51%) of respondents saying AI could perform some aspects of their job, up from 38% in 2023.Whilst the survey highlighted some concerns related to deployment, it showed that people are optimistic about AI’s capabilities.... Full Article Retail Supply Chain Data Capture Critical Issues
nds Max! Millie! How Four-Legged Friends Can 'Heel' Military Veterans By www.newswise.com Published On :: Sun, 10 Nov 2024 21:25:54 EST Dogs are the bounding balls of energy that greet us at the door, and the beloved companions that curl up with us at night, yet for many military veterans, they're also a vital support, helping manage their everyday wellbeing and promote positive mental health. Full Article
nds First-Generation Nursing Student Dallas Martin Finds Success at UA Little Rock By www.newswise.com Published On :: Mon, 11 Nov 2024 10:50:47 EST Dallas Martin, a first-generation senior nursing major from Helena, Arkansas, really does it all. This wife and mom of two is a full-time student at UA Little Rock, set to graduate in December with her bachelor's degree in nursing, while also working full-time as a physician's registered nurse in oncology and hematology at Carti Cancer Center in Little Rock. Full Article
nds N. Korean Leader Defends ICBM Test By world.kbs.co.kr Published On :: Thu, 31 Oct 2024 13:20:19 +0900 [Inter-Korea] : North Korean leader Kim Jong-un has defended Thursday’s intercontinental ballistic missile(ICBM) test, calling it an appropriate military action that shows other countries the North is serious about counteracting threats to its security. The state-run Korean Central News Agency(KCNA) said Kim made the ...[more...] Full Article Inter-Korea
nds 2024 Paris Paralympics Ends with Closing Ceremony By world.kbs.co.kr Published On :: Mon, 09 Sep 2024 10:42:05 +0900 [Sports] : The 2024 Paris Paralympics came to a close on Sunday after a 12-day run. The global sports festival wrapped up Sunday night with a glitzy closing ceremony at the Stade de France in Saint-Denis, near Paris. About 44-hundred athletes with disabilities competed in 22 sporting events, representing 169 ...[more...] Full Article Sports
nds How Many Languages Are There? Literally Thousands By people.howstuffworks.com Published On :: Fri, 01 Nov 2024 10:30:03 -0400 Languages exist as ever-evolving systems of human communication that go beyond complex grammar or words you could learn from a quick search on Google Translate. Language consists of body language, social cues and mother tongue idioms that are shaped by culture and context. That said, how many languages are there in our vast world? Full Article
nds 'Exhuma,' 'Handsome Guys' Win Prizes at 57th Sitges Int'l Fantastic Film Festival of Catalonia By world.kbs.co.kr Published On :: Tue, 15 Oct 2024 12:06:05 +0900 [Culture] : Two South Korean films, "Exhuma" and "Handsome Guys," won prizes at the 57th Sitges International Fantastic Film Festival of Catalonia, Spain. According to the South Korean film distributor Showbox on Tuesday, director Jang Jae-hyun's occult thriller "Exhuma," which was invited to the official competition ...[more...] Full Article Culture
nds Aquarius Moon Traits: Understanding the Emotional Landscape By entertainment.howstuffworks.com Published On :: Sat, 09 Nov 2024 05:30:03 -0500 Explore the Aquarius Moon's traits, emotional depth, and how it influences relationships, creativity, and personal growth in astrology. Unlock its mysterious power. Full Article
nds BGS receives award at the World Landslide Forum 2023 - British Geological Survey By news.google.com Published On :: Thu, 30 Nov 2023 11:06:19 GMT BGS receives award at the World Landslide Forum 2023 British Geological Survey Full Article
nds Earthquake hits Midlands as British Geological Survey confirm magnitude - Birmingham Live By news.google.com Published On :: Fri, 19 Apr 2024 07:00:00 GMT Earthquake hits Midlands as British Geological Survey confirm magnitude Birmingham Live Full Article
nds Funding awarded for study on hydrogen storage potential in the East Midlands - British Geological Survey By news.google.com Published On :: Mon, 19 Aug 2024 07:00:00 GMT Funding awarded for study on hydrogen storage potential in the East Midlands British Geological Survey Full Article
nds Density functional theory investigation of the phase transition, elastic and thermal characteristics for AuMTe2(M = Ga, In) chalcopyrite compounds By journals.iucr.org Published On :: This study presents the first theoretical predictions of the phase transitions, elastic properties, and thermal behavior of AuMTe2 (M = Ga, In) chalcopyrite compounds. Using density functional theory and the quasi-harmonic Debye model, key mechanical and thermodynamic properties are analyzed, offering insights valuable for future experimental validation. Full Article text
nds Polymorph sampling with coupling to extended variables: enhanced sampling of polymorph energy landscapes and free energy perturbation of polymorph ensembles By journals.iucr.org Published On :: 2024-10-15 A novel approach to computationally enhance the sampling of molecular crystal structures is proposed and tested. This method is based on the use of extended variables coupled to a Monte Carlo based crystal polymorph generator. Inspired by the established technique of quasi-random sampling of polymorphs using the rigid molecule constraint, this approach represents molecular clusters as extended variables within a thermal reservoir. Polymorph unit-cell variables are generated using pseudo-random sampling. Within this framework, a harmonic coupling between the extended variables and polymorph configurations is established. The extended variables remain fixed during the inner loop dedicated to polymorph sampling, enforcing a stepwise propagation of the extended variables to maintain system exploration. The final processing step results in a polymorph energy landscape, where the raw structures sampled to create the extended variable trajectory are re-optimized without the thermal coupling term. The foundational principles of this approach are described and its effectiveness using both a Metropolis Monte Carlo type algorithm and modifications that incorporate replica exchange is demonstrated. A comparison is provided with pseudo-random sampling of polymorphs for the molecule coumarin. The choice to test a design of this algorithm as relevant for enhanced sampling of crystal structures was due to the obvious relation between molecular structure variables and corresponding crystal polymorphs as representative of the inherent vapor to crystal transitions that exist in nature. Additionally, it is shown that the trajectories of extended variables can be harnessed to extract fluctuation properties that can lead to valuable insights. A novel thermodynamic variable is introduced: the free energy difference between ensembles of Z' = 1 and Z' = 2 crystal polymorphs. Full Article text
nds Specific radiation damage to halogenated inhibitors and ligands in protein–ligand crystal structures By journals.iucr.org Published On :: This article reports an investigation into the effects of specific radiation damage to halogenated ligands in crystal structures of protein-inhibitor complexes. Full Article text
nds L3-edge X-ray spectroscopy of rhodium and palladium compounds By journals.iucr.org Published On :: 2024-06-26 L3-edge high-energy-resolution fluorescence-detection X-ray absorption near-edge structure (XANES) spectra for palladium and rhodium compounds are presented, with focus on their electronic structures. The data are compared with transmission XANES spectra recorded at the K-edge. A correlation between the absorption edge energy and the metal ion oxidation state is not observed. Despite the different filling of the 4d orbitals and different local coordination, the Rh and Pd compounds show remarkably similar spectral shapes. Calculation of the density of states and of the L3-XANES data reproduce the experimental results. Full Article text
nds Further evaluation of the shape of atomic Hirshfeld surfaces: M⋯H contacts and homoatomic bonds By journals.iucr.org Published On :: 2024-08-08 It is well known that Hirshfeld surfaces provide an easy and straightforward way of analysing intermolecular interactions in the crystal environment. The use of atomic Hirshfeld surfaces has also demonstrated that such surfaces carry information related to chemical bonds which allow a deeper evaluation of the structures. Here we briefly summarize the approach of atomic Hirshfeld surfaces while further evaluating the kind of information that can be retrieved from them. We show that the analysis of the metal-centre Hirshfeld surfaces from structures refined via Hirshfeld Atom Refinement (HAR) allow accurate evaluation of contacts of type M⋯H, and that such contacts can be related to the overall shape of the surfaces. The compounds analysed were tetraaquabis(3-carboxypropionato)metal(II), [M(C4H3O4)2(H2O)4], for metal(II)/M = manganese/Mn, cobalt/Co, nickel/Ni and zinc/Zn. We also evaluate the sensitivity of the surfaces by an investigation of seemingly flat surfaces through analysis of the curvature functions in the direction of C—C bonds. The obtained values not only demonstrate variations in curvature but also show a correlation with the hybridization of the C atoms involved in the bond. Full Article text
nds Coordination variety of phenyltetrazolato and dimethylamido ligands in dimeric Ti, Zr, and Ta complexes By journals.iucr.org Published On :: 2024-08-23 Three structurally diverse 5-phenyltetrazolato (Tz) Ti, Zr, and Ta complexes, namely, (C2H8N)[Ti2(C7H5N4)5(C2H6N)4]·1.45C6H6 or (Me2NH2)[Ti2(NMe2)4(2,3-μ-Tz)3(2-η1-Tz)2]·1.45C6H6, (1·1.45C6H6), [Zr2(C7H5N4)6(C2H6N)2(C2H7N)2]·1.12C6H6·0.382CH2Cl2 or [Zr2(Me2NH)2(NMe2)2(2,3-μ-Tz)3(2-η1-Tz)2(1,2-η2-Tz)]·1.12C6H6·0.38CH2Cl2 (2·1.12C6H6·0.38CH2Cl2), and (C2H8N)2[Ta2(C7H5N4)8(C2H6N)2O]·0.25C7H8 or (Me2NH2)2[Ta2(NMe2)2(2,3-μ-Tz)2(2-η1-Tz)6O]·0.25C7H8 (3·0.25C7H8), where TzH is 5-phenyl-1H-tetrazole, have been synthesized and structurally characterized. All three complexes are dinuclear; the Ti center in 1 is six-coordinate, whereas the Zr and Ta atoms in 2 and 3 are seven-coordinate. The coordination environments of the Ti centers in 1 are similar, and so are the ligations of the Ta centers in 3. In contrast, the two Zr centers in 2 bear a different number of ligands, one of which is a bidentate η2-5-phenyltetrazolato ligand that has not been observed previously for d-block elements. The dimethylamido ligand, present in the starting materials, remained unchanged, or was converted to dimethylamine and dimethylammonium during the synthesis. Dimethylamine coordinates as a neutral ligand, whereas dimethylammonium is retained as a hydrogen-bonded entity bridging Tz ligands. Full Article text
nds From femtoseconds to minutes: time-resolved macromolecular crystallography at XFELs and synchrotrons By journals.iucr.org Published On :: 2024-01-24 Over the last decade, the development of time-resolved serial crystallography (TR-SX) at X-ray free-electron lasers (XFELs) and synchrotrons has allowed researchers to study phenomena occurring in proteins on the femtosecond-to-minute timescale, taking advantage of many technical and methodological breakthroughs. Protein crystals of various sizes are presented to the X-ray beam in either a static or a moving medium. Photoactive proteins were naturally the initial systems to be studied in TR-SX experiments using pump–probe schemes, where the pump is a pulse of visible light. Other reaction initiations through small-molecule diffusion are gaining momentum. Here, selected examples of XFEL and synchrotron time-resolved crystallography studies will be used to highlight the specificities of the various instruments and methods with respect to time resolution, and are compared with cryo-trapping studies. Full Article text
nds Current developments and trends in quantum crystallography By journals.iucr.org Published On :: 2024-06-18 Quantum crystallography is an emerging research field of science that has its origin in the early days of quantum physics and modern crystallography when it was almost immediately envisaged that X-ray radiation could be somehow exploited to determine the electron distribution of atoms and molecules. Today it can be seen as a composite research area at the intersection of crystallography, quantum chemistry, solid-state physics, applied mathematics and computer science, with the goal of investigating quantum problems, phenomena and features of the crystalline state. In this article, the state-of-the-art of quantum crystallography will be described by presenting developments and applications of novel techniques that have been introduced in the last 15 years. The focus will be on advances in the framework of multipole model strategies, wavefunction-/density matrix-based approaches and quantum chemical topological techniques. Finally, possible future improvements and expansions in the field will be discussed, also considering new emerging experimental and computational technologies. Full Article text
nds Solvatomorphism in a series of copper(II) complexes with the 5-phenylimidazole/perchlorate system as ligands By journals.iucr.org Published On :: 2024-07-30 In the course of an investigation of the supramolecular behaviour of copper(II) complexes with the 5-phenylimidazole/perchlorate ligand system (`blend') remarkable solvatomorphism has been observed. By employing a variety of crystallization solvents (polar protic, polar/non-polar aprotic), a series of 12 crystalline solvatomorphs with the general formula [Cu(ClO4)2(LH)4]·x(solvent) have been obtained [LH = 5-phenylimidazole, x(solvent) = 3.3(H2O) (1), 2(methanol) (2), 2(ethanol) (3), 2(1-propanol) (4), 2(2-propanol) (5), 2(2-butanol) (6), 2(dimethylformamide) (7), 2(acetone) (8), 2(tetrahydrofurane) (9), 2(1,4-dioxane) (10), 2(ethyl acetate) (11) and 1(diethyl ether) (12)]. The structures have been solved using single-crystal X-ray diffraction and the complexes were characterized by thermal analysis and infrared spectroscopy. The solvatomorphs are isostructural (triclinic, P1), with the exception of compound 9 (monoclinic, P21/n). The supramolecular structures and the role of the various solvents is discussed. All potential hydrogen-bond functionalities, both of the [Cu(ClO4)2(LH)4] units and of the solvents, are utilized in the course of the crystallization process. The supramolecular assembly in all structures is directed by strong recurring Nimidazole–H⋯Operchlorate motifs leading to robust scaffolds composed of the [Cu(ClO4)2(LH)4] host complexes. The solvents are located in channels and, with the exception of the disordered waters in 1 and the diethyl ether in 12, participate in hydrogen-bonding formation with the [Cu(ClO4)2(LH)4] complexes, serving as both hydrogen-bond acceptors and donors (for the polar protic solvents in 2–6), or solely as hydrogen-bond acceptors (for the polar/non-polar aprotic solvents in 7–11), linking the complexes and contributing to the stability of the crystalline compounds. Full Article text
nds Crystal structure of a three-coordinate lithium complex with monodentate phenyloxazoline and hexamethyldisilylamide ligands By journals.iucr.org Published On :: 2024-05-17 The reaction of lithium hexamethyldisilylamide, [Li{N(Si(CH3)3)2}] (LiHMDS), with 4,4-dimethyl-2-phenyl-2-oxazoline (Phox, C11H13NO) in hexane produced colourless crystals of bis(4,4-dimethyl-2-phenyl-2-oxazoline-κN)(hexamethyldisilylamido-κN)lithium, [Li(C6H18NSi2)(C11H13NO)2] or [Li{N(Si(CH3)3)2}(Phox)2] in high yield (89%). Despite the 1:1 proportion of the starting materials in the reaction mixture, the product formed with a 1:2 amide:oxazoline ratio. In the unit cell of the C2/c space group, the neutral molecules lie on twofold rotation axes coinciding with the Li—N(amide) bonds. The lithium(I) centre adopts a trigonal–planar coordination geometry with three nitrogen donor atoms, one from the HMDS anion and two from the oxazolines. All ligands are monodentate. In the phenyloxazoline units, the dihedral angle defined by the five-membered heterocyclic rings is 35.81 (5)°, while the phenyl substituents are approximately face-to-face, separated by 3.908 (5) Å. In the amide, the methyl groups assume a nearly eclipsed arrangement to minimize steric repulsion with the analogous substituents on the oxazoline rings. The non-covalent interactions in the solid-state structure of [Li{N(Si(CH3)3)2}(Phox)2] were assessed by Hirshfeld surface analysis and fingerprint plots. This new compound is attractive for catalysis due to its unique structural features. Full Article text
nds Two chromium(II) acetate complexes with N-heterocyclic carbene (NHC) coligands By journals.iucr.org Published On :: 2024-06-28 Tetrakis(μ-acetato-κ2O:O')bis{[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene-κC2]chromium(II)} tetrahydrofuran disolvate, [Cr2(C2H3O2)4(C27H36N4)2]·2C4H8O or [Cr2(OAc)4(IDipp)2]·2C4H8O (1), and tetrakis(μ-acetato-κ2O:O')bis{[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene-κC2]chromium(II)}, {Cr2(C2H3O2)4(C21H24N2)2] or [Cr2(OAc)4(IMes)2] (2), were synthesized from anhydrous chromium(II) acetate [Cr2(OAc)4] and the corresponding NHC (NHC = N-heterocyclic carbene) in toluene as solvent. Both complexes crystallize in the triclinic system, space group Poverline{1}. The molecular structures consist of Cr2(OAc)4 paddle-wheels that carry two terminal NHC ligands. This leads to a square-pyramidal coordination of the chromium atoms. Full Article text
nds Crystal structures of the (η2:η2-cycloocta-1,5-diene)(η6-toluene)iridium(I) cation and μ-chlorido-iridium(III) complexes of 2-(phosphinito)- and 2-(phosphinomethyl)anthraquinone ligands By journals.iucr.org Published On :: 2024-09-30 When reacted in dry, degassed toluene, [Ir(COD)Cl]2 (COD = cycloocta-1,5-diene) and 2 equivalents of 2-(di-tert-butylphosphinito)anthraquinone (tBuPOAQH) were found to form a unique tri-iridium compound consisting of one monoanionic dinuclear tri-μ-chlorido complex bearing one bidentate tBuPOAQ ligand per iridium, which was charge-balanced by an outer sphere [Ir(toluene)(COD)]+ ion, the structure of which has not previously been reported. This product, which is a toluene solvate, namely, (η2:η2-cycloocta-1,5-diene)(η6-toluene)iridium(I) tri-μ-chlorido-bis({3-[(di-tert-butylphosphanyl)oxy]-9,10-dioxoanthracen-2-yl}hydridoiridium(III)) toluene monosolvate, [Ir(C7H8)(C8H12)][Ir2H2(C22H24O3P)2Cl3]·C7H8 or [Ir(toluene)(COD)][Ir(κ-P,C-tBuPOAQ)(H)]2(μ-Cl)3]·toluene, formed as small orange platelets at room temperature, crystallizing in the triclinic space group Poverline{1}. The cation and anion are linked via weak C—H⋯O interactions. The stronger intermolecular attractions are likely the offset parallel π–π interactions, which occur between the toluene ligands of pairs of inverted cations and between pairs of inverted anthraquinone moieties, the latter of which are capped by toluene solvate molecules, making for π-stacks of four molecules each. The related ligand, 2-(di-tert-butylphosphinomethyl)-anthraquinone (tBuPCAQH), did not form crystals suitable for X-ray diffraction under analogous reaction conditions. However, when the reaction was conducted in chloroform, yellow needles readily formed following addition of 1 atm of carbon monoxide. Diffraction studies revealed a neutral, dinuclear, di-μ-chlorido complex, di-μ-chlorido-bis(carbonyl{3-[(di-tert-butylphosphanyl)oxy]-9,10-dioxoanthracen-2-yl}hydridoiridium(I)), [Ir2H2(C23H26O2P)2Cl2(CO)2] or [Ir(κ-P,C-tBuPCAQ)(H)(CO)(μ-Cl)]2, Ir2C48H54Cl2O6P2, again crystallizing in space group Poverline{1}. Offset parallel π–π interactions between anthraquinone groups of adjacent molecules link the molecules in one dimension. Full Article text
nds Crystal structures of seven mixed-valence gold compounds of the form [(R1R2R3PE)2AuI]+[AuIIIX4]− (R = tert-butyl or isopropyl, E = S or Se, and X = Cl or Br) By journals.iucr.org Published On :: 2024-09-30 During our studies of the oxidation of gold(I) complexes of trialkylphosphane chalcogenides, general formula R1R2R3PEAuX, (R = tert-butyl or isopropyl, E = S or Se, X = Cl or Br) with PhICl2 or elemental bromine, we have isolated a set of seven mixed-valence by-products, the bis(trialkylphosphane chalcogenido)gold(I) tetrahalogenidoaurates(III) [(R1R2R3PE)2Au]+[AuX4]−. These correspond to the addition of one halogen atom per gold atom of the AuI precursor. Compound 1, bis(triisopropylphosphane sulfide)gold(I) tetrachloridoaurate(III), [Au(C9H21PS)2][AuCl4] or [(iPr3PS)2Au][AuCl4], crystallizes in space group P21/n with Z = 4; the gold(I) atoms of the two cations lie on twofold rotation axes, and the gold(III) atoms of the two anions lie on inversion centres. Compound 2, bis(tert-butyldiisopropylphosphane sulfide)gold(I) tetrachloridoaurate(III), [Au(C10H23PS)2][AuCl4] or [(tBuiPr2PS)2Au][AuCl4], crystallizes in space group P1 with Z = 4; the asymmetric unit contains two cations and two anions with no imposed symmetry. A least-squares fit of the two cations gave an r.m.s. deviation of 0.19 Å. Compound 3, bis(tri-tert-butylphosphane sulfide)gold(I) tetrachloridoaurate(III), [Au(C12H27PS)2][AuCl4] or [(tBu3PS)2Au][AuCl4], crystallizes in space group P1 with Z = 1; both gold atoms lie on inversion centres. Compound 4a, bis(tert-butyldiisopropylphosphane sulfide)gold(I) tetrabromidoaurate(III), [Au(C10H23PS)2][AuBr4] or [(tBuiPr2PS)2Au][AuBr4], crystallizes in space group P21/c with Z = 4; the cation lies on a general position, whereas the gold(III) atoms of the two anions lie on inversion centres. Compound 4b, bis(tert-butyldiisopropylphosphane selenide)gold(I) tetrabromidoaurate(III), [Au(C10H23PSe)2][AuBr4] or [(tBuiPr2PSe)2Au][AuBr4], is isotypic with 4a. Compound 5a, bis(tri-tert-butylphosphane sulfide)gold(I) tetrabromidoaurate(III), [Au(C12H27PS)2][AuBr4] or [(tBu3PS)2Au][AuBr4], is isotypic with compound 4a. Compound 5a, bis(tri-tert-butylphosphane sulfide)gold(I) tetrabromidoaurate(III), [Au(C12H27PS)2][AuBr4] or [(tBu3PS)2Au][AuBr4], crystallizes in space group P1 with Z = 1; both gold atoms lie on inversion centres. Compound 5b, bis(tri-tert-butylphosphane selenide)gold(I) tetrabromidoaurate(III), [Au(C12H27PSe)2][AuBr4] or [(tBu3PSe)2Au][AuBr4], is isotypic with 5a. All AuI atoms are linearly coordinated and all AuIII atoms exhibit a square-planar coordination environment. The ligands at the AuI atoms are antiperiplanar to each other across the S⋯S vectors. There are several short intramolecular H⋯Au and H⋯E contacts. Average bond lengths (Å) are: P—S = 2.0322, P—Se = 2.1933, S—Au = 2.2915, and Se—Au = 2.4037. The complex three-dimensional packing of 1 involves two short C—Hmethine⋯Cl contacts (and some slightly longer contacts). For 2, four C—Hmethine⋯Cl interactions combine to produce zigzag chains of residues parallel to the c axis. Additionally, an S⋯Cl contact is observed that might qualify as a ‘chalcogen bond’. The packing of 3 is three-dimensional, but can be broken down into two layer structures, each involving an S⋯Cl and an H⋯Cl contact. For the bromido derivatives 4a/b and 5a/b, loose associations of the anions form part of the packing patterns. For all four compounds, these combine with an E⋯Br contact to form layers parallel to the ab plane. Full Article text
nds Upgraded front ends for SLS 2.0 with next-generation high-power diaphragms and slits By journals.iucr.org Published On :: 2024-10-22 The upgrade of the Swiss Light Source, called SLS 2.0, necessitates comprehensive updates to all 18 user front ends. This upgrade is driven by the increased power of the synchrotron beam, reduced floor space, changing source points, new safety regulations and enhanced beam properties, including a brightness increase by up to a factor of 40. While some existing front-end components are being thoroughly refurbished and upgraded for safety reasons, other components, especially those designed to tailor the new synchrotron beam, are being completely rebuilt. These new designs feature innovative and enhanced cooling systems to manage the high-power load and meet new requirements such as mechanical stability and compact footprints. Full Article text
nds Tranglo expands payment services to Oman, Qatar, and Bahrain By thepaypers.com Published On :: Mon, 11 Nov 2024 11:34:00 +0100 Tranglo, a global cross-border payments company, has expanded... Full Article
nds Tide expands platform with acquisition of UK payroll solution Onfolk By thepaypers.com Published On :: Tue, 22 Oct 2024 13:15:00 +0100 Tide, a UK-based business... Full Article
nds The Global Payments and Fintech Trends Report 2024 By thepaypers.com Published On :: Fri, 09 Feb 2024 11:39:00 +0100 The inaugural edition of the Global Payments and Fintech Trends Report offers a comprehensive overview of the key trends in fintech and payments for the year 2024 and beyond. Full Article
nds Emerging Technologies and Trends in Identity Verification, KYC, and KYB Report 2024 By thepaypers.com Published On :: Thu, 16 May 2024 09:00:00 +0100 The inaugural edition of the Emerging Technologies and Trends in Identity Verification (IDV), KYC, and KYB Report 2024 offers a comprehensive overview of the key technology trends and best practices in digital onboarding for consumers and businesses in 2024. Full Article
nds Key Players In the EU Payments Landscape – 2024 Edition By thepaypers.com Published On :: Tue, 02 Jul 2024 08:30:00 +0100 The 2024 'Key Players in the EU Payments Landscape' report by PA EU, Deloitte, and The Paypers ranks key players in EU's payments markets. Full Article
nds Thunes expands cross-border payment network to Egypt By thepaypers.com Published On :: Fri, 18 Oct 2024 11:56:00 +0100 Thunes has announced the expansion of its Direct Global Network... Full Article
nds Directors Guild finds TV diversity hiring stalled By www.scpr.org Published On :: Wed, 17 Sep 2014 12:38:26 -0700 In this Saturday, Sept. 6, 2014 file photo, Paris Barclay attends the LA Premiere Screening of "Sons Of Anarchy" at TCL Chinese Theatre, in Los Angeles. A new guild study says that women and minorities were largely shut out of the ranks of TV directors again last season. In a Wednesday, Sept. 17, 2014 statement, Directors Guild President Barclay said it can be "shockingly difficult" to persuade those who control industry hiring to make even small improvements.; Credit: Paul A. Hebert/Paul A. Hebert/Invision/AP A new guild study says women and minorities were largely shut out of the ranks of TV directors again last season. The Directors Guild of America report released Wednesday said employers have made no significant improvement in diversity hiring for TV series in the last four years. According to the study, white males directed the vast majority of the 3,500 cable, broadcast and high-budget online episodes made for the 2013-14 season. The same holds true for the three previous years, according to guild findings. In a statement, Directors Guild President Paris Barclay said it can be "shockingly difficult" to persuade those who control industry hiring to make even small improvements. Full Article
nds Tintin on acid: Charles Burns ends his dark trilogy with 'Sugar Skull' By www.scpr.org Published On :: Thu, 18 Sep 2014 18:11:40 -0700 Graphic novelist and artist Charles Burns, at the Mohn Broadcast Center, 9/18/2014. He's just completed his trilogy with the new book Sugar Skull.; Credit: John Rabe Graphic novelist Charles Burns stopped by the Mohn Broadcast Center to talk with Off-Ramp host John Rabe about "Sugar Skull," which completes the trilogy that includes "X'ed Out" and "The Hive." He's doing a signing tonight (Thurday, Sept. 18) at Skylight Books, 1818 N. Vermont Avenue in Los Feliz. Why the trilogy? Burns says, "I had finished another book, "Black Hole," which was this very long graphic novel, all in black and white, and I wanted to do something in color, so I conceived a series of books, based on a series of my life, late '70s, the Punk Era. It started that way, and then it turned into something else." RELATED: Miniaturist Alan Wolfson, or "Honey! I shrunk the strip club!" The look of Burns' books: ... is drawn from one of his childhood favorites, the Belgian Tintin, who had all sorts of politically incorrect adventures: "It's called the clear-line school of comics. And it's exactly what it sounds like: very clear lines, but perfectly rendered in color." If there's more shadow in Burns' books than in Herge's, that's because the lines between good and bad, dark and light, reality and unreality are blurrier in Burns. The trilogy moves back and forth in time and place, including between the normal world and a bizarre world in which a character named Johnny 23 struggles with many of the same issues the protagonist in the real world, Doug, faces... including a pregnant girlfriend. (From Sugar Skull, by Charles Burns. ) Are they two separate stories or Doug's subconscious world? Burns won't say. "That's for the reader to figure out. I don't really ever clearly explain those things at all, and I like to leave those things open. Interpretation is great, as far as I'm concerned." Burns turns 59 on Sept. 27. How does he like approaching 60? "As far as the day-to-day landscape, things are more settled in. But as far as my sweltering, swelling, itching brain, that hasn't changed at all unfortunately." Full Article
nds Strategic Lithium-Boron Acquisition Expands Exploration Footprint in Nevada By www.streetwisereports.com Published On :: Tue, 22 Oct 2024 00:00:00 PST Source: Streetwise Reports 10/22/2024 Canter Resources Corp. (CRC:CSE; CNRCF:OTC; 601:FRA) has completed its acquisition of the Railroad Valley lithium-boron claims (RV project). Read why the company CEO says this aligns with Canter's long-term growth strategy.Canter Resources Corp. (CRC:CSE; CNRCF:OTC; 601:FRA) has completed its acquisition of the Railroad Valley lithium-boron claims (RV project). The RV project claim block shares a common border with land controlled by 3 Proton Lithium (3PL), a private critical mineral explorer in Railroad Valley. Canter intends to complete follow-up sampling at the project in the fourth quarter of 2024, 164 kilometers from their exploration base in Tonopah, Nevada. In the company news release, Joness Lang, CEO of Canter Resources, commented on the acquisition, stating, "We are excited to have expanded our lithium-boron exploration footprint in Nevada with this strategic acquisition in a highly prospective, yet underexplored area. While our primary focus remains on advancing our flagship Columbus project, we see value in adding low-cost, high-potential projects that strengthen our portfolio and align with our long-term growth strategy." Lithium-Boron Market Trends and Opportunities Visual Capitalist reported on September 29 that cobalt, a critical mineral used in battery production, had "gained significant attention in recent years due to its wide range of commercial, industrial, and military applications." The growing demand for cobalt in the electric vehicle (EV) sector was highlighted, with "the EV sector accounting for 40% of the global cobalt market," reinforcing its importance in the global transition to electrification. Additionally, 87% of China's cobalt consumption was "dedicated to the lithium-ion battery industry." On October 1, Ahead of the Herd emphasized a favorable environment for risk assets, noting, "The combination of interest-rate cuts from the Federal Reserve, resilient economic growth, and the un-inversion of the yield curve" as contributing factors. The S&P/TSX Global Mining Index gained 14% since September 6, marking its biggest jump of the year, with central banks cutting interest rates and the U.S. signaling more battery metal funding. Ahead of the Herd also stated that "majors, mid-tiers, and juniors all looked ripe for a rebound" in this risk-tolerant environment. On October 8, Forbes reported that "a 50% rise in the price of a downtrodden lithium producer has boosted investor hopes that a revival in the battery metal is possible" after two difficult years of oversupply and low prices. Lithium was "once the hottest metal in the commodity sector" and had begun showing "signs of recovery as investor interest picks up again." Despite the downturn, the long-term outlook for lithium remained strong, with Forbes emphasizing its essential role "for the future of electric vehicles and battery technology." According to Barry Dawes of Martin Place Securities that same day, "the lithium market is showing strong signs of upturn," with the possibility of "lithium shortages post-2027," highlighting the sector's future growth potential. Canter's Catalysts Driving Growth As outlined in their investor presentation, Canter Resources' Railroad Valley acquisition aligns with the company's strategy of expanding its critical minerals portfolio at a low cost while leveraging geological similarities to proven lithium-producing regions. The Railroad Valley project holds promise due to its favorable geological features, such as volcanic calderas and closed-basin characteristics, which are known to enhance lithium and boron concentration. According to the company's investor presentation, this acquisition bolsters Canter's portfolio as it continues to focus on the Columbus project. The upcoming follow-up sampling and the planned Q4 2024 exploration at the Railroad Valley site further demonstrate the company's commitment to expanding its exploration activities. Canter's continued exploration efforts are expected to provide the data necessary to identify lithium-boron deposits across its portfolio, enhancing long-term growth potential. Analysts On Canter *According to Technical Analyst Clive Maund, who issued an opinion on October 16, Canter Resources Corp. was viewed as an "Immediate Strong Buy." Maund pointed out that the company's stock was priced at "some 8% of its price at its late 2023 peak," making it a highly favorable entry point. He emphasized that despite the severe bear market in lithium, Canter had made "considerable progress" on its projects, which positioned the company to benefit as lithium prices stabilized. Maund highlighted that Canter's Columbus Basin Project, located in a region with favorable geology, "looks set to provide a 'kicker' for the stock," especially following positive Phase II drilling results. On October 15, Jeff Clark from The Gold Advisor also shared a positive assessment of Canter Resources. Clark noted that the company had reported "significant findings from its Phase II Geoprobe drilling program" at the Columbus Project, including the highest boron concentration to date and consistent lithium values. He highlighted Canter's potential to make a major discovery at Columbus, particularly due to the structural similarities between this project and other successful lithium-boron operations in the region. Clark added that Canter's "low-cost shallow drilling" had laid the foundation for a deeper and more extensive exploration phase. He affirmed that Canter's market cap of CA$3.85M represented an "incredible bargain" considering the company's potential. In What is Chen Buying? What is Chen Selling?, published on October 16, analyst Chen Lin provided a positive outlook on Canter Resources' drilling results. He highlighted that Phase II drilling at the Columbus Lithium-Boron Project returned "the highest dissolved boron concentration to date," which further underscored the project's potential. Lin emphasized the promising geochemical similarities between Canter's Columbus Basin and other major lithium-boron-producing regions, stating that these results "bolster the company’s hypothesis" and position Canter as a key player in the critical minerals market. [OWNERSHIP_CHART-10988] Ownership and Share Structure According to the company, managers and insiders own about 9.6% of Canter Resources, and strategic investors (including the founding group and Michael Gentile & Advisors) own about 12%. The investors with the largest stake are all insiders. They are CEO and Director Joness Lang with 3.38%, Director and Strategic Adviser Warwick Smith with 2.14%, Director and Technical Adviser Kenneth Cunningham with 1.95%, Chief Financial Officer Alnesh Mohan with 0.97%, and Director and Technical Adviser Eric Saderholm with 0.58%, and Gentile, who owns about 4% personally. Four institutions or funds, including Euro Pacific Asset Management, collectively hold 3%. Retail investors own the remaining. The Canadian explorer has 51.29 million outstanding shares, 46.41 million free float traded shares with a CA$4.11 million market cap. Over the past 52 weeks, Canter has traded between CA$0.07 and CA$0.99 per share. Sign up for our FREE newsletter at: www.streetwisereports.com/get-newsImportant Disclosures: As of the date of this article, officers and/or employees of Streetwise Reports LLC (including members of their household) own securities of Canter Resources Corp. James Guttman wrote this article for Streetwise Reports LLC and provides services to Streetwise Reports as an employee. This article does not constitute investment advice and is not a solicitation for any investment. Streetwise Reports does not render general or specific investment advice and the information on Streetwise Reports should not be considered a recommendation to buy or sell any security. Each reader is encouraged to consult with his or her personal financial adviser and perform their own comprehensive investment research. By opening this page, each reader accepts and agrees to Streetwise Reports' terms of use and full legal disclaimer. Streetwise Reports does not endorse or recommend the business, products, services or securities of any company. For additional disclosures, please click here. * Disclosure for the quote from the Clive Maund article published on October 16, 2024 For the quoted article (published on October 16, 2024), the Company has paid Street Smart, an affiliate of Streetwise Reports, US$2,500. Author Certification and Compensation: [Clive Maund of clivemaund.com] is being compensated as an independent contractor by Street Smart, an affiliate of Streetwise Reports, for writing the article quoted. Maund received his UK Technical Analysts’ Diploma in 1989. The recommendations and opinions expressed in the article accurately reflect the personal, independent, and objective views of the author regarding any and all of the designated securities discussed. No part of the compensation received by the author was, is, or will be directly or indirectly related to the specific recommendations or views expressed Clivemaund.com Disclosures The quoted article represents the opinion and analysis of Mr. Maund, based on data available to him, at the time of writing. Mr. Maund's opinions are his own, and are not a recommendation or an offer to buy or sell securities. As trading and investing in any financial markets may involve serious risk of loss, Mr. Maund recommends that you consult with a qualified investment advisor, one licensed by appropriate regulatory agencies in your legal jurisdiction and do your own due diligence and research when making any kind of a transaction with financial ramifications. Although a qualified and experienced stock market analyst, Clive Maund is not a Registered Securities Advisor. Therefore Mr. Maund's opinions on the market and stocks cannot be only be construed as a recommendation or solicitation to buy and sell securities. ( Companies Mentioned: CRC:CSE; CNRCF:OTC; 601:FRA, ) Full Article
nds Off-Ramp Recommends: Spending a day with your "dad" By www.scpr.org Published On :: Thu, 15 Jun 2017 12:22:48 -0700 Off-Ramp's Rosalie Atkinson, her dad, and her dad's mustache circa quite a few facial hair fads ago. (Credit: Rosalie Atkinson); Credit: Rosalie Atkinson | Off-Ramp®These cool tips would have landed in your in-box with no extra effort on your part IF you'd subscribed to Off-Ramp's weekly e-newsletter. We send out a recommendation every week, along with all the latest Off-Ramp news. Sign up now! Father's Day is coming quick! But before you run to Walgreen's Sunday morning to find they are sold out of touching cards for the father figure in your life, let us help you curate a fun day out with dad. Thinking about significant-figure holidays, there seems to be more of a method for planning Mother's Day surprises. You get the breakfast-in-bed together quietly for mom or grandma or aunt, etc., wake her up early on a Sunday, she quickly scrambles to hide the fact that she decided to sleep pantsless, then you present her with some poorly made waffles and juice which she will inevitably spill on her white sheets. But what about your father-figure? A card? Yes. Maybe a golf ball? Okay. A mug you Amazon Prime'd to him in a last-ditch effort that says "Captain Dad?" Don't do that. It might be weird to ask the men in our life, "What the hell do you want?" under the veil of Father's Day, so to spare you we've compiled some ideas. Idea #1: Take your father to get pampered! Spa days are are not gender-specific and when was the last time someone even looked at your dad's feet? Hollywood salon Hammer & Nails focuses on men's cuticle care. Treat your dad to a MANi-pedi, and he'll also enjoy a glass of bourbon, a personal flatscreen TV with noise-cancelling headphones, all while relaxing in an over-sized leather chair. Although Hammer & Nails targets men, women are also welcome. 8257 Melrose Ave, Los Angeles, CA 90046. Idea #2: Take in a tasting. Greenbar Distillery is LA's first spirit distillery since the Prohibition was repealed in 1933. They boast the "World's largest portfolio of organic spirits." Take a tour, pose with their gigantic copper stills and whiskey barrels, sign up for a class, or just taste some of their 16 spirits and five bitters. Their tours are reserved for Saturday so consider this a pregame to your other Father's Day plans. 2459 E 8th St, Los Angeles, California, 90021. Idea #3: Younger kids? Let's play! Sunday, the Autry Museum of the American West is opening a new exhibit about the history of play. Experience the next generation of toys and games, but also see how they differ across generations and cultures. The exhibit is very interactive and the museum is in beautiful Griffith Park, so there are plenty of hiking trails, picnic spots, or viewpoints to snap some pictures with your man/men. 234 Museum Drive, Los Angeles, CA 90065 . Idea #4: The Abbey's annual Father's Day Brunch. For the past six years, The Abbey in West Hollywood has hosted a brunch in celebration of LGBT families or those considering starting one. There will be a breakfast buffet from 9am-1pm and attendees can get more info about fostering opportunities. $18 per person. 692 N Robertson Blvd, West Hollywood, CA 90069 . Much love to all the dads, uncles, grandpas, friends, and men nurturing other people! This content is from Southern California Public Radio. View the original story at SCPR.org. Full Article