nato MSHA: Final rule on electronic detonators in metal and nonmetal mines now in effect By www.safetyandhealthmagazine.com Published On :: Thu, 19 Mar 2020 00:00:00 -0400 Washington — The Mine Safety and Health Administration’s direct final rule concerning advances in electronic detonators in metal and nonmetal mines has gone into effect, the agency announced March 18. Full Article
nato Bipartisan group of senators to FMCSA: ‘Explore improvements’ to HOS rules By www.safetyandhealthmagazine.com Published On :: Thu, 31 May 2018 00:00:00 -0400 Washington — A bipartisan group of 30 senators is calling for Federal Motor Carrier Safety Administration Administrator Raymond Martinez to “explore improvements” to hours-of-service regulations for commercial truck drivers. Full Article
nato OSHA COVID-19-related fines: Senators claim penalties ‘inadequate,’ ask Scalia to respond By www.safetyandhealthmagazine.com Published On :: Wed, 14 Oct 2020 00:00:00 -0400 Washington — Two dozen Democratic senators have taken issue with the dollar amounts OSHA has chosen to levy against employers in its individual COVID-19-related fines. Full Article
nato Conduit stub-up eliminator By www.safetyandhealthmagazine.com Published On :: Sun, 23 Apr 2017 00:00:00 -0400 Stub-EASE is designed to reduce tripping, slipping and falling injuries on conduit stub-ups by safely removing stub-ups from a raceway. Full Article
nato Laminator Offers Smaller Footprint, Flexibility, Easier Sanitation and Maintenance By www.foodengineeringmag.com Published On :: Mon, 30 Sep 2024 10:32:24 -0400 With precise, automatic and synchronized control of dough sheet length, conveyor speed and number of laminations, the operator has an efficient and effective process, resulting in consistent, high-quality product. Full Article
nato Donato Pompo Named Coverings Advocate Leader By www.floortrendsmag.com Published On :: Mon, 10 Apr 2017 00:00:00 -0400 Donato Pompo earned the top prize for Coverings Advocate Leader at Coverings 2017. Full Article
nato Open Source Coordinator, Experienced Professionals, Cambridge, UK, Marketing & Communications By careers.peopleclick.com Published On :: Wednesday, November 25, 2020 4:23:14 PM EST We are looking for a talented and creative Open Source Coordinator who will support the Open Source Software organization. The ideal candidate will bring strong detail oriented execution and organizational skills to help drive the impact of Arm in the Open Source community. About the roleThe position reports to the Director Open Source Communities. The position has working relationships with, but not limited: Software Engineering groups, Global Event Teams, Enterprise Marketing, Legal, Procurement, Finance, Business Line Groups, IT, as well as external service providers.Responsible for coordinating activities within the Open Source Office and supporting various aspects of events (including industry trade shows, special events and conferences) and multifaceted projects.Some knowledge in project management is highly beneficialWorking with globally dispersed teams, engaging engineering leads to drive Arm’s Open Source presence at a variety of events from large commercial to grass root community Full Article
nato Workshop 14: Anatomical Historian Alice Dreger By audioboom.com Published On :: Wed, 06 Apr 2016 04:01:00 -0000 Alice Dreger is a historian of science, anatomy, and medicine, known for her work studying and advocating for people born with atypical sex disorders. She famously resigned from Northwestern University in protest of academic censorship, and gained some infamy on Twitter for live-tweeting her son's sex education class. We had a delightful chat with her about her writing process in advance of the paperback release of her book, Galileo's Middle Finger: Heretics, Activists, and the Search for Justice in Science. Learn more about your ad choices. Visit podcastchoices.com/adchoices Full Article
nato NATO's lost atomic bombs threaten the world By english.pravda.ru Published On :: Fri, 24 Dec 2021 19:35:00 +0300 According to international experts, the world has returned to the Cold War, but this time, the state of affairs is even more dramatic than it used to be. Airplanes with nuclear warheads on board are on duty again, like 30 years ago. The danger of such flights lies not only in the possible use of nuclear weapons. Nuclear bombs may go missing, as it had repeatedly happened in the past. Atomic bombs for Spain Several years ago, a Canadian diver, while diving into the sea near the Haida Gwaii archipelago, was horrified to find something that looked like an air nuclear bomb. The diver was right. In 1950, an American B-36 bomber was forced to jettison an atomic bomb into the Pacific Ocean due to a fire on board. Full Article History traditions
nato Russian forces destroy large batch of NATO arms in Odessa By english.pravda.ru Published On :: Tue, 05 Nov 2024 20:01:00 +0300 The Russian army is advancing from all sides near the settlemnt of Kurakhovo. "The pressure of the Russians on Kurakhovo has increased with new directions that threaten the logistics of the city. The Russian troops have deployed a huge number of resources in several areas of the front. They are actively storming the eastern part of Kurakhovo reaching into eastern outskirts of the city while trying to break through in the Ostrovsky area," Ukraine's DeepState website said. The Russian Armed Forces are trying to reach the Ilyinka-Berestki line in order to take control of the north of the city. Full Article Incidents
nato Russian admiral says Kursk submarine sank due to collision with NATO sub By english.pravda.ru Published On :: Mon, 22 Nov 2021 14:19:00 +0300 Admiral Vyacheslav Popov, the former commander of the Northern Fleet of the Russian Navy, said that the Kursk submarine (nuclear submarine K-141 Kursk) sank in 2000 as a result of the collision with a NATO submarine. The name of the Western submarine is known almost for sure, Popov said in an interview with RIA Novosti. The ex-commander-in-chief of the Northern Fleet suggested that the submarine that collided with the Kursk was tracking the sub. The Western submarine could not ensure the required level of safety under the conditions of the sea and other circumstances, so it came too close to the Kursk. According to the admiral, the sub was later found off the coast of Norway. Popov added that the manoeuvre of the Russian nuclear submarine could also lead to the "loss of contact." According to the admiral, he can reveal the name of the NATO submarine with almost 100 percent certainty, but said that he would not do it for a number of reasons. Full Article History traditions
nato Bill Clinton tried to bribe Boris Yeltsin for NATO to expand eastwards By english.pravda.ru Published On :: Wed, 22 Feb 2023 16:55:00 +0300 Former US President Bill Clinton offered Russian President Boris Yeltsin large investments in Russia in the 1990s in exchange for NATO's eastward expansion and Moscow's approval of that expansion. A number of declassified documents testifying to USA's plans to buy off Russia became available on the website of the US Presidential Library. According to the documents, Yeltsin responded to Clinton's suggestion by saying that such a measure was like a bribe in exchange for Russia's consent to NATO's expansion to the detriment of her own interests. Full Article History traditions
nato Slovak Prime Minister appears on Russian TV accusing NATO and EU of supporting Ukraine By english.pravda.ru Published On :: Thu, 31 Oct 2024 14:29:00 +0300 Robert Fico became the first NATO leader to have given an interview to Russian media after the start of the special military operation and he made some very bold statements in it. The West fails to bring Russia to its knees Slovak Prime Minister Robert Fico gave an interview to Russian journalist Olga Skabeeva on the state-run Rossiya-1 TV channel. He started his interview with a Slovak proverb that says that "no one on their knees can be considered defeated — perhaps they are just tying their shoelaces." Full Article World
nato Andy Kim Wins in New Jersey, Becoming First Korean American Senator By world.kbs.co.kr Published On :: Wed, 06 Nov 2024 11:12:11 +0900 [International] : Democratic Rep. Andy Kim was elected to the U.S. Senate on Tuesday, becoming the first Korean American to serve in the Senate. With elections for the Senate and the House of Representatives taking place the same day as the U.S. presidential election, Kim defeated Curtis Bashaw in the New Jersey senatorial ...[more...] Full Article International
nato NATO, S. Korea and Other Indo-Pacific Partners Condemn N. Korea's Troop Deployment By world.kbs.co.kr Published On :: Sat, 09 Nov 2024 12:55:46 +0900 [International] : The North Atlantic Treaty Organization(NATO), along with its Indo-Pacific partners, including South Korea, strongly denounced North Korea's troop deployment to Russia in support of its military offensive against Ukraine. In a statement on Friday, NATO's top decision-making North Atlantic Council(NAC) ...[more...] Full Article International
nato Crystal structure and Hirshfeld surface analysis of bis(benzoylacetonato)(ethanol)dioxidouranium(VI) By journals.iucr.org Published On :: In the complex, the ligand binds to the metal through an oxygen atom. The geometry of the seven-coordinate U atom is pentagonal bipyramidal, with the uranyl O atoms in apical positions. Full Article text
nato {N-[1-(2-Oxidophenyl)ethylidene]-dl-alaninato}(pentane-1,5-diyl)silicon(IV) By journals.iucr.org Published On :: 2024-03-19 The title SiIV complex, C16H21NO3Si, is built up by a tridentate dinegative Schiff base ligand bound to a silacyclohexane unit. The coordination geometry of the pentacoordinated SiIV atom is a distorted trigonal bipyramid. The presence of the silacyclohexane ring in the complex leads to an unusual coordination geometry of the SiIV atom with the N atom from the Schiff base ligand and an alkyl-C atom in apical positions of the trigonal bipyramid. There is a disorder of the methyl group at the imine bond with two orientations resolved for the H atoms [major orientation = 0.55 (3)]. In the crystal, C—H⋯O interactions are found within corrugated layers of molecules parallel to the ab plane. Full Article text
nato mer-Bis(quinoline-2-carboxaldehyde 4-ethylthiosemicarbazonato)nickel(II) methanol 0.33-solvate 0.67-hydrate By journals.iucr.org Published On :: 2024-04-26 In the title compound, [Ni(C13H13N4S)2]·0.33CH3OH·0.67H2O, the NiII atom is coordinated by two tridentate quinoline-2-carboxaldehyde 4-ethylthiosemicarbazonate ligands in a distorted octahedral shape. At 100 K, the crystal symmetry is monoclinic (space group P21/n). A mixture of water and methanol crystallizes with the title complex, and one of the ethyl groups in the coordinating ligands is disordered over two positions, with an occupancy ratio of 58:42. There is intermolecular hydrogen bonding between the solvent molecules and the amine and thiolate groups in the ligands. No other significant interactions are present in the crystal packing. Full Article text
nato Chlorido[5,10,15,20-tetrakis(quinoline-7-carboxamido)porphinato]iron(III) By journals.iucr.org Published On :: 2024-06-04 The title compound, [Fe(C84H52N12O4)Cl], crystallizes in space group C2/c. The central FeIII cation (site symmetry 2) is coordinated in a fivefold manner, with four pyrrole N atoms of the porphyrin core in the basal sites and one Cl atom (site symmetry 2) in the apical position, which completes a slightly distorted square-pyramidal environment. The porphyrin macrocycle shows a characteristic ruffled-shape distortion and the iron atom is displaced out of the porphyrin plane by 0.42 Å with the average Fe—N distance being 2.054 (4) Å; the Fe—Cl bond length is 2.2042 (7) Å. Intermolecular C—H⋯N and C—H⋯O hydrogen bonds occur in the crystal structure. Full Article text
nato Synthesis, crystal structure and properties of chloridotetrakis(pyridine-3-carbonitrile)thiocyanatoiron(II) By journals.iucr.org Published On :: 2023-11-21 Reaction of FeCl2·4H2O with KSCN and 3-cyanopyridine (pyridine-3-carbonitrile) in ethanol accidentally leads to the formation of single crystals of Fe(NCS)(Cl)(3-cyanopyridine)4 or [FeCl(NCS)(C6H4N2)4]. The asymmetric unit of this compound consists of one FeII cation, one chloride and one thiocyanate anion that are located on a fourfold rotation axis as well as of one 3-cyanopyridine coligand in a general position. The FeII cations are sixfold coordinated by one chloride anion and one terminally N-bonding thiocyanate anion in trans-positions and four 3-cyanopyridine coligands that coordinate via the pyridine N atom to the FeII cations. The complexes are arranged in columns with the chloride anions, with the thiocyanate anions always oriented in the same direction, which shows the non-centrosymmetry of this structure. No pronounced intermolecular interactions are observed between the complexes. Initially, FeCl2 and KSCN were reacted in a 1:2 ratio, which lead to a sample that contains the title compound as the major phase together with a small amount of an unknown crystalline phase, as proven by powder X-ray diffraction (PXRD). If FeCl2 and KSCN is reacted in a 1:1 ratio, the title compound is obtained as a nearly pure phase. IR investigations reveal that the CN stretching vibration for the thiocyanate anion is observed at 2074 cm−1, and that of the cyano group at 2238 cm−1, which also proves that the anionic ligands are only terminally bonded and that the cyano group is not involved in the metal coordination. Measurements with thermogravimetry and differential thermoanalysis reveal that the title compound decomposes at 169°C when heated at a rate of 4°C min−1 and that the 3-cyanopyridine ligands are emitted in two separate poorly resolved steps. After the first step, an intermediate compound with the composition Fe(NCS)(Cl)(3-cyanopyridine)2 of unknown structure is formed, for which the CN stretching vibration of the thiocyanate anion is observed at 2025 cm−1, whereas the CN stretching vibration of the cyano group remain constant. This strongly indicates that the FeII cations are linked by μ-1,3-bridging thiocyanate anions into chains or layers. Full Article text
nato Synthesis, crystal structure and properties of poly[(μ-2-methylpyridine N-oxide-κ2O:O)bis(μ-thiocyanato-κ2N:S)cobalt(II)] By journals.iucr.org Published On :: 2024-01-01 The title compound, [Co(NCS)2(C6H7NO)]n or Co(NCS)2(2-methylpyridine N-oxide), was prepared by the reaction of Co(NCS)2 and 2-methylpyridine N-oxide in methanol. All crystals obtained by this procedure show reticular pseudo-merohedric twinning, but after recrystallization, one crystal was found that had a minor component with only a very few overlapping reflections. The asymmetric unit consists of one CoII cation, two thiocyanate anions and one 2-methylpyridine N-oxide coligand in general positions. The CoII cations are octahedrally coordinated by two O-bonding 2-methylpyridine N-oxide ligands, as well as two S- and two N-bonding thiocyanate anions, and are connected via μ-1,3(N,S)-bridging thiocyanate anions into chains that are linked by μ-1,1(O,O) bridging coligands into layers. No pronounced directional intermolecular interactions are observed between the layers. The 2-methylpyridine coligand is disordered over two orientations and was refined using a split model with restraints. Powder X-ray diffraction (PXRD) indicates that a pure sample was obtained and IR spectroscopy confirms that bridging thiocyanate anions are present. Thermogravimetry and differential thermoanalysis (TG-DTA) shows one poorly resolved mass loss in the TG curve that is accompanied by an exothermic and an endothermic signal in the DTA curve, which indicate the decomposition of the 2-methylpyridine N-oxide coligands. Full Article text
nato Synthesis and crystal structure of [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](isocyanato-κN)gold(I) By journals.iucr.org Published On :: 2024-01-19 The title complex, [Au(NCO)(C27H36N2)], was synthesized by ligand metathesis from [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) chloride and sodium cyanate in anhydrous tetrahydrofuran and crystallized from toluene at 233 K in the orthorhombic space group P212121, as a neutral complex with the central Au atom di-coordinated by an N-heterocyclic carbene [Au—C = 1.963 (2) Å] and an isocyanate [Au—N 1.999 (2) Å] ligands, with a linear CAuNCO moiety. The crystal packing is consolidated by C—H⋯O hydrogen bonds. Full Article text
nato Synthesis and crystal structure of diisothiocyanatotetrakis(4-methylpyridine N-oxide)cobalt(II) and diisothiocyanatotris(4-methylpyridine N-oxide)cobalt(II) showing two different metal coor By journals.iucr.org Published On :: 2024-01-26 The reaction of Co(NCS)2 with 4-methylpyridine N-oxide (C6H7NO) leads to the formation of two compounds, namely, tetrakis(4-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)4] (1), and tris(4-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)3] (2). The asymmetric unit of 1 consists of one CoII cation located on a centre of inversion, as well as one thiocyanate anion and two 4-methylpyridine N-oxide coligands in general positions. The CoII cations are octahedrally coordinated by two terminal N-bonding thiocyanate anions in trans positions and four 4-methylpyridine N-oxide ligands. In the extended structure, these complexes are linked by C—H⋯O and C—H⋯S interactions. In compound 2, two crystallographically independent complexes are present, which occupy general positions. In each of these complexes, the CoII cations are coordinated in a trigonal–bipyramidal manner by two terminal N-bonding thiocyanate anions in axial positions and by three 4-methylpyridine N-oxide ligands in equatorial positions. In the crystal, these complex molecules are linked by C—H⋯S interactions. For compound 2, a nonmerohedral twin refinement was performed. Powder X-ray diffraction (PXRD) reveals that 2 was nearly obtained as a pure phase, which is not possible for compound 1. Differential thermoanalysis and thermogravimetry data (DTA–TG) show that compound 2 start to decompose at about 518 K. Full Article text
nato Synthesis, crystal structure and Hirshfeld surface analysis of sodium bis(malonato)borate monohydrate By journals.iucr.org Published On :: 2024-01-26 In the title salt, poly[aqua[μ4-bis(malonato)borato]sodium], {[Na(C6H4BO8)]·H2O}n or Na+·[B(C3H2O4)2]−·H2O, the sodium cation exhibits fivefold coordination by four carbonyl O atoms of the bis(malonato)borate anions and a water O atom. The tetrahedral B atom at the centre of the anion leads to the formation of a polymeric three-dimensional framework, which is consolidated by C—H⋯O and O—H⋯O hydrogen bonds. A Hirshfeld surface analysis indicates that the most significant contacts in the crystal packing are H⋯O/O⋯H (49.7%), Na⋯O/O⋯Na (16.1%), O⋯O (12.6%), H⋯H (10.7%) and C⋯O/O⋯C (7.3%). Full Article text
nato Synthesis, crystal structure and properties of the trigonal–bipyramidal complex tris(2-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II) By journals.iucr.org Published On :: 2024-04-11 Reaction of Co(NCS)2 with 2-methylpyridine N-oxide in a 1:3 ratio in n-butanol leads to the formation of crystals of tris(2-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)3]. The asymmetric unit of the title compound consists of one CoII cation two thiocyanate anions and three crystallographically independent 2-methylpyridine N-oxide coligands in general positions. The CoII cations are trigonal–bipyramidally coordinated by two terminal N-bonding thiocyanate anions in the trans-positions and three 2-methylpyridine N-oxide coligands into discrete complexes. These complexes are linked by intermolecular C–H⋯S interactions into double chains that elongate in the c-axis direction. Powder X-ray diffraction (PXRD) measurements prove that all batches are always contaminated with an additional and unknown crystalline phase. Thermogravimetry and differential analysis of crystals selected by hand reveal that the title compound decomposes at about 229°C in an exothermic reaction. At about 113°C a small endothermic signal is observed that, according to differential scanning calorimetry (DSC) measurements, is irreversible. PXRD measurements of the residue prove that a poorly crystalline and unknown phase has formed and thermomicroscopy indicates that some phase transition occurs that is accompanied with a color change of the title compound. Full Article text
nato Synthesis, crystal structure and thermal properties of the dinuclear complex bis(μ-4-methylpyridine N-oxide-κ2O:O)bis[(methanol-κO)(4-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II)] By journals.iucr.org Published On :: 2024-04-18 Reaction of Co(NCS)2 with 4-methylpyridine N-oxide in methanol leads to the formation of crystals of the title compound, [Co2(NCS)4(C6H7NO)4(CH4O)2] or Co2(NCS)4(4-methylpyridine N-oxide)4(methanol)2. The asymmetric unit consist of one CoII cation, two thiocyanate anions, two 4-methylpyridine N-oxide coligands and one methanol molecule in general positions. The H atoms of one of the methyl groups are disordered and were refined using a split model. The CoII cations octahedrally coordinate two terminal N-bonded thiocyanate anions, three 4-methylpyridine N-oxide coligands and one methanol molecule. Each two CoII cations are linked by pairs of μ-1,1(O,O)-bridging 4-methylpyridine N-oxide coligands into dinuclear units that are located on centers of inversion. Powder X-ray diffraction (PXRD) investigations prove that the title compound is contaminated with a small amount of Co(NCS)2(4-methylpyridine N-oxide)3. Thermogravimetric investigations reveal that the methanol molecules are removed in the beginning, leading to a compound with the composition Co(NCS)2(4-methylpyridine N-oxide), which has been reported in the literature and which is of poor crystallinity. Full Article text
nato Crystal structure of (6,9-diacetyl-5,10,15,20-tetraphenylsecochlorinato)nickel(II) By journals.iucr.org Published On :: 2024-05-24 Title compound 1Ni, [Ni(C46H32N4O2)], a secochlorin nickel complex, was prepared by diol cleavage of a precursor trans-dihydroxydimethylchlorin. Two crystallographically independent molecules in the structure are related by pseudo-A lattice centering, with molecules differing mainly by a rotation of one of the acetyls and an adjacent phenyl groups. The two molecules have virtually identical conformations characterized by noticeable in-plane deformation in the A1g mode and a prominent out-of-plane deformation in the B1u (ruffling) mode. Directional interactions between molecules are scarce, limited to just a few C—H⋯O contacts, and intermolecular interactions are mostly dispersive in nature. Full Article text
nato Synthesis, crystal structure and thermal properties of a new polymorphic modification of diisothiocyanatotetrakis(4-methylpyridine)cobalt(II) By journals.iucr.org Published On :: 2024-05-31 The title compound, [Co(NCS)2(C6H7N)4] or Co(NCS)2(4-methylpyridine)4, was prepared by the reaction of Co(NCS)2 with 4-methylpyridine in water and is isotypic to one of the polymorphs of Ni(NCS)2(4-methylpyridine)4 [Kerr & Williams (1977). Acta Cryst. B33, 3589–3592 and Soldatov et al. (2004). Cryst. Growth Des. 4, 1185–1194]. Comparison of the experimental X-ray powder pattern with that calculated from the single-crystal data proves that a pure phase has been obtained. The asymmetric unit consists of one CoII cation, two crystallographically independent thiocyanate anions and four independent 4-methylpyridine ligands, all located in general positions. The CoII cations are sixfold coordinated to two terminally N-bonded thiocyanate anions and four 4-methylpyridine coligands within slightly distorted octahedra. Between the complexes, a number of weak C—H⋯N and C—H⋯S contacts are found. This structure represent a polymorphic modification of Co(NCS)2(4-methylpyridine)4 already reported in the CCD [Harris et al. (2003). NASA Technical Reports, 211890]. In contrast to this form, the crystal structure of the new polymorph shows a denser packing, indicating that it is thermodynamically stable at least at low temperatures. Thermogravimetric and differential thermoanalysis reveal that the title compound starts to decomposes at about 100°C and that the coligands are removed in separate steps without any sign of a polymorphic transition before decomposition. Full Article text
nato Syntheses and crystal structures of the five- and sixfold coordinated complexes diisoselenocyanatotris(2-methylpyridine N-oxide)cobalt(II) and diisoselenocyanatotetrakis(2-methylpyridine N- By journals.iucr.org Published On :: 2024-06-07 The reaction of CoBr2, KNCSe and 2-methylpyridine N-oxide (C6H7NO) in ethanol leads to the formation of crystals of [Co(NCSe)2(C6H7NO)3] (1) and [Co(NCSe)2(C6H7NO)4] (2) from the same reaction mixture. The asymmetric unit of 1 is built up of one CoII cation, two NCSe− isoselenocyanate anions and three 2-methylpyridine N-oxide coligands, with all atoms located on general positions. The asymmetric unit of 2 consists of two cobalt cations, four isoselenocanate anions and eight 2-methylpyridine N-oxide coligands in general positions, because two crystallographically independent complexes are present. In compound 1, the CoII cations are fivefold coordinated to two terminally N-bonded anionic ligands and three 2-methylpyridine N-oxide coligands within a slightly distorted trigonal–bipyramidal coordination, forming discrete complexes with the O atoms occupying the equatorial sites. In compound 2, each of the two complexes is coordinated to two terminally N-bonded isoselenocyanate anions and four 2-methylpyridine N-oxide coligands within a slightly distorted cis-CoN2O4 octahedral coordination geometry. In the crystal structures of 1 and 2, the complexes are linked by weak C—H⋯Se and C—H⋯O contacts. Powder X-ray diffraction reveals that neither of the two compounds were obtained as a pure crystalline phase. Full Article text
nato Synthesis, crystal structure and thermal properties of catena-poly[[bis(4-methylpyridine)nickel(II)]-di-μ-thiocyanato], which shows an alternating all-trans and cis–cis–trans-coordination of the NiS2Np2Nt2 octahedra (p = 4-me By journals.iucr.org Published On :: 2024-06-21 The title compound, [Ni(NCS)2(C6H7N)2]n, was prepared by the reaction of Ni(NCS)2 with 4-methylpyridine in water. Its asymmetric unit consists of two crystallographically independent NiII cations, of which one is located on a twofold rotational axis whereas the second occupies a center of inversion, two independent thiocyanate anions and two independent 4-methylpyridine coligands in general positions. Each NiII cation is octahedrally coordinated by two 4-methylpyridine coligands as well as two N- and two S-bonded thiocyanate anions. One of the cations shows an all-trans, the other a cis–cis–trans configuration. The metal centers are linked by pairs of μ-1,3-bridging thiocyanate anions into [101] chains. X-ray powder diffraction shows that a pure crystalline phase has been obtained and thermogravimetry coupled to differential thermoanalysis reveals that the title compound loses half of the 4-methylpyridine coligands and transforms into Ni(NCS)2(C6H7N). Nearly pure samples of this compound can be obtained by thermal annealing and a Rietveld refinement demonstrated that it is isotypic to its recently reported Cd analog [Neumann et al., (2020). CrystEngComm. 22, 184–194] In its crystal structure, the metal cations are linked by one μ-1,3(N,S)- and one μ-1,3,3(N,S,S)-bridging thiocyanate anion into single chains that condense via the μ-1,3,3(N,S,S)-bridging anionic ligands into double chains. Full Article text
nato Synthesis and crystal structure of poly[ethanol(μ-4-methylpyridine N-oxide)di-μ-thiocyanato-cobalt(II)] By journals.iucr.org Published On :: 2024-09-20 Reaction of 4-methylpyridine N-oxide and Co(NCS)2 in ethanol as solvent accidentally leads to the formation of single crystals of Co(NCS)2(4-methylpyridine N-oxide)(ethanol) or [Co(NCS)2(C6H7NO)(C2H6O)]n. The asymmetric unit of the title compound consists of one CoII cation, two crystallographically independent thiocyanate anions, one 4-methylpyridine N-oxide coligand and one ethanol molecule on general positions. The cobalt cations are sixfold coordinated by one terminal and two bridging thiocyanate anions, two bridging 4-methylpyridine N-oxide coligands and one ethanol molecule, with a slightly distorted octahedral geometry. The cobalt cations are linked by single μ-1,3(N,S)-bridging thiocyanate anions into corrugated chains, that are further connected into layers by pairs of μ-1,1(O,O)-bridging 4-methylpyridine N-oxide coligands. The layers are parallel to the bc plane and are separated by the methyl groups of the 4-methylpyridine N-oxide coligands. Within the layers, intralayer hydrogen bonding is observed. Full Article text
nato Synthesis, crystal structure and properties of μ-tetrathioantimonato-bis[(cyclam)zinc(II)] perchlorate 0.8-hydrate By journals.iucr.org Published On :: 2024-10-11 The reaction of Zn(ClO4)2·6H2O with Na3SbS4·9H2O in a water/acetonitrile mixture leads to the formation of the title compound, (μ-tetrathioantimonato-κ2S:S')bis[(1,4,8,11-tetraazacyclotetradecane-κ4N)zinc(II)] perchlorate 0.8-hydrate, [Zn2(SbS4)(C10H24N4)2]ClO4·0.8H2O or [(Zn-cyclam)2(SbS4)]+[ClO4]−·0.8H2O. The asymmetric unit consists of two crystallographically independent [SbS4]3– anions, two independent perchlorate anions and two independent water molecules as well as four crystallographically independent Zn(cyclam)2+ cations that are located in general positions. Both perchlorate anions and one cyclam ligand are disordered and were refined with a split mode using restraints. The water molecules are partially occupied. Two Zn(cyclam)2+ cations are linked via the [SbS4]3– anions into [Zn2(cyclam)2SbS4]+ cations that are charged-balanced by the [ClO4]− anions. The water molecules of crystallization are hydrogen bonded to the [SbS4]3– anions. The cations, anions and water molecules are linked by N—H⋯O, N—H⋯S and O—H⋯S hydrogen bonds into a three-dimensional network. Powder X-ray diffraction proves that a pure sample had been obtained that was additionally investigated for its spectroscopic properties. Full Article text
nato Crystal structure and Hirshfeld surface analysis of bis(benzoylacetonato)(ethanol)dioxidouranium(VI) By journals.iucr.org Published On :: 2024-11-05 A new uranium metal–organic complex salt, [U(C10H9O2)2O2(C2H6O)], with benzoyl acetone, namely, bis(benzoylacetonato)(ethanol)dioxidouranium(VI), was synthesized. The compound has monoclinic P21/n symmetry. The geometry of the seven-coordinate U atom is pentagonal bipyramidal, with the uranyl oxygen atoms in apical positions. In the complex, the ligands bind to the metal through oxygen atoms. Additional weak O—H⋯O contacts between the cations and anions consolidate the three-dimensional arrangement of the structure. On the Hirshfeld surface, the largest contributions come from the short contacts such as van der Waals forces, including H⋯H, O⋯H and C⋯H. Interactions including C⋯C and O⋯C contacts were also observed; however, their contribution to the overall cohesion of the crystal structure is minor. A packing analysis was performed to check the strength of the crystal packing. Full Article text
nato Mike Gravel, Former Alaska Senator And Anti-War Advocate, Dies At Age 91 By www.scpr.org Published On :: Sun, 27 Jun 2021 09:20:07 -0700 Former Alaska Sen. Mike Gravel, who read the Pentagon Papers into the Congressional Record and confronted Barack Obama about nuclear weapons during a later presidential run, has died. He was 91.; Credit: Charles Dharapak/AP The Associated Press | NPRSEASIDE, Calif. — Mike Gravel, a former U.S. senator from Alaska who read the Pentagon Papers into the Congressional Record and confronted Barack Obama about nuclear weapons during a later presidential run, has died. He was 91. Gravel, who represented Alaska as a Democrat in the Senate from 1969 to 1981, died Saturday, according to his daughter, Lynne Mosier. Gravel had been living in Seaside, California, and was in failing health, said Theodore W. Johnson, a former aide. Gravel's two terms came during tumultuous years for Alaska when construction of the trans-Alaska oil pipeline was authorized and when Congress was deciding how to settle Alaska Native land claims and whether to classify enormous amounts of federal land as parks, preserves and monuments. He had the unenviable position of being an Alaska Democrat when some residents were burning President Jimmy Carter in effigy for his measures to place large sections of public lands in the state under protection from development. Gravel feuded with Alaska's other senator, Republican Ted Stevens, on the land matter, preferring to fight Carter's actions and rejecting Stevens' advocacy for a compromise. In the end, Congress passed the Alaska National Interest Lands Conservation Act of 1980, a compromise that set aside millions of acres for national parks, wildlife refuges and other protected areas. It was one of the last bills Carter signed before leaving office. Gravel's Senate tenure also was notable for his anti-war activity. In 1971, he led a one-man filibuster to protest the Vietnam-era draft and he read into the Congressional Record 4,100 pages of the 7,000-page leaked document known as the Pentagon Papers, the Defense Department's history of the country's early involvement in Vietnam. Gravel reentered national politics decades after his time in the Senate to twice run for president. Gravel, then 75, and his wife, Whitney, took public transportation in 2006 to announce he was running for president as a Democrat in the 2008 election ultimately won by Obama. He launched his quest for the 2008 Democratic presidential nomination as a critic of the Iraq war. "I believe America is doing harm every day our troops remain in Iraq — harm to ourselves and to the prospects for peace in the world," Gravel said in 2006. He hitched his campaign to an effort that would give all policy decisions to the people through a direct vote, including health care reform and declarations of war. Gravel garnered attention for his fiery comments at Democratic forums. In one 2007 debate, the issue of the possibility of using nuclear weapons against Iran came up, and Gravel confronted then-Sen. Obama. "Tell me, Barack, who do you want to nuke?" Gravel said. Obama replied: "I'm not planning to nuke anybody right now, Mike." Gravel then ran as a Libertarian candidate after he was excluded from later Democratic debates. In an email to supporters, he said the Democratic Party "no longer represents my vision for our great country." "It is a party that continues to sustain war, the military-industrial complex and imperialism — all of which I find anathema to my views," he said. He failed to get the Libertarian nomination. Gravel briefly ran for the Democratic nomination for president in 2020. He again criticized American wars and vowed to slash military spending. His last campaign was notable in that both his campaign manager and chief of staff were just 18 at the time of his short-lived candidacy. "There was never any ... plan that he would do anything more than participate in the debates. He didn't plan to campaign, but he wanted to get his ideas before a larger audience," Johnson said. Gravel failed to qualify for the debates. He endorsed Vermont Sen. Bernie Sanders in the contest eventually won by now-President Joe Biden. Gravel was born Maurice Robert Gravel in Springfield, Massachusetts, on May 13, 1930. In Alaska, he served as a state representative, including a stint as House speaker, in the mid-1960s. He won his first Senate term after defeating incumbent Sen. Ernest Gruening, a former territorial governor, in the 1968 Democratic primary. Gravel served two terms until he was defeated in the 1980 Democratic primary by Gruening's grandson, Clark Gruening, who lost the election to Republican Frank Murkowski. Copyright 2021 NPR. To see more, visit https://www.npr.org. This content is from Southern California Public Radio. View the original story at SCPR.org. Full Article
nato Some Pollinator Populations Declining - Improved Monitoring and More Biological Knowledge Needed to Better Assess Their Status By Published On :: Wed, 18 Oct 2006 05:00:00 GMT Long-term population trends for some North American pollinators -- bees, birds, bats, and other animals and insects that spread pollen so plant fertilization can occur -- are demonstrably downward, says a new report from the National Research Council. Full Article
nato Exclusive interview: Spinato's, on frozen pizzas and broccoli crust By www.snackandbakery.com Published On :: Thu, 24 Jan 2019 12:39:00 -0500 We recently were able to talk to Anthony Spinato, president of Spinato's Fine Foods, Tempe, AZ, about their new broccoli pizza crust and other frozen pizza aspects. Full Article
nato Laminators and sheeters key to producing today's in-demand baked goods By www.snackandbakery.com Published On :: Mon, 08 Dec 2014 00:00:00 -0500 Laminators and sheeters continue as essential components of many bakery operations, thanks to several prevailing consumer trends. Full Article
nato New and updated laminators and sheeters provide flexibility and convenience features By www.snackandbakery.com Published On :: Fri, 15 Dec 2017 12:00:00 -0500 Ease of cleaning, maintenance and access, as well as the ability to produce a wider variety of items, are among the top desires of companies looking to purchase dough laminators and sheeters for production of snack foods and baked goods. Full Article
nato New dough laminators and sheeters offer advances in product flexibility By www.snackandbakery.com Published On :: Tue, 11 Dec 2018 13:25:00 -0500 Dough comes in many styles, and today's laminators and sheeters need to accommodate an increasing range of requirements. Full Article
nato Snack and bakery manufacturers search for sanitation, versatility with laminators and sheeters By www.snackandbakery.com Published On :: Mon, 09 Dec 2019 10:54:00 -0500 Effectively and efficiently handling dough is integral to many snack and bakery operations. And the needs producers have today are diverse. Full Article
nato Safe and automated dough laminators and sheeters By www.snackandbakery.com Published On :: Thu, 17 Dec 2020 09:00:00 -0500 Automation, ease of operation, simple cleanability, hygienic design, operator safety, and the ability to process nontraditional and healthier ingredients are among the top of mind requests for snack and bakery operators looking to buy or upgrade laminators or sheeters. Full Article
nato Laminators and sheeters offer bakers, snack manufactures production versatility By www.snackandbakery.com Published On :: Wed, 09 Dec 2015 00:00:00 -0500 Consumer demand for artisanal baked goods and better-for-you snacks are making new laminators and sheeters must-have equipment for many manufacturers. Full Article
nato Reading Bakery Systems introduces 90-degree Laminator By www.snackandbakery.com Published On :: Thu, 26 Sep 2024 15:40:00 -0400 The new laminator is said to offer a smaller footprint, flexibility, and easier sanitation and maintenance. Full Article
nato New and improved dough laminators and sheeters By www.snackandbakery.com Published On :: Thu, 15 Dec 2016 00:00:00 -0500 New designs that allow for flexible width, more compact production space, easier cleaning and better sanitation, all while featuring more technologically advanced controls, have been foremost on the minds of snack and bakery companies in recent months and years when replacing or upgrading their sheeters and laminators. Full Article
nato Marquis Who's Who Honors Indira Narayanan, MBBS, MD, FNNF, FIAP, FNAMS, is Recognized for Expertise in Neonatology, Global Newborn Health and nutrition, and Higher Education By www.24-7pressrelease.com Published On :: Mon, 08 Apr 2024 08:00:00 GMT Dr. Indira Narayanan, MBBS, MD, FNNF, FIAP, FNAMS, is lauded for her work in newborn care and global maternal and newborn health and nutrition Full Article
nato Mandi Collins Recognized by Marquis Who's Who for Excellence in Anatomical Services and Education By www.24-7pressrelease.com Published On :: Tue, 16 Jan 2024 08:00:00 GMT Mandi Collins celebrated for her impact on community engagement and anatomical donation programs Full Article
nato Orange County Convention Center Adds Sustainability Coordinator By www.internationaldriveorlando.com Published On :: Thu, 14 Jun 2012 13:18:28 GMT Abby Gulden has been named sustainability coordinator at the Orange County Convention Center (OCCC). In this new role, Gulden will work directly with event planners and the Center to promote green initiatives. Full Article News
nato Statute of Limitations Ends Inquiry Into Senator's Comp Claim By ww3.workcompcentral.com Published On :: Mon, 15 Jul 2024 00:00:00 -0700 The Connecticut Division of Criminal Justice said it ended an inquiry into a state senator who allegedly did not disclose that he was working while collecting workers’ compensation benefits, saying… Full Article
nato Senators Float Classifying Substance Abuse as Occupational Hazard By ww3.workcompcentral.com Published On :: Tue, 03 Sep 2024 00:00:00 -0700 Two senators in Connecticut announced plans to introduce legislation that would treat substance abuse as an occupational hazard. “If a worker is injured on the job, they receive treatment, but if… Full Article
nato Nonsignatory Can't Compel Arbitration of Wrongful Death Claim By ww3.workcompcentral.com Published On :: Fri, 21 Jun 2024 00:00:00 -0700 A Texas appellate court ruled that a nonsignatory to an agreement could not compel arbitration of a family’s wrongful death claims despite its purported adoption of an occupational injury benefit… Full Article