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Quasi-quantum dot-induced stabilization of α-CsPbI3 perovskite for high-efficiency solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02807J, Paper
Cheng Liu, Yi Yang, Xin Liu, Yong Ding, Zulqarnain Arain, Xinye Li, Yuanlong Li, Zian Zhou, Songyuan Dai, Mohammad Khaja Nazeeruddin
Quasi-quantum dots α-CsPbI3 films are in situ prepared by using a new ligand with ultralow contents. By increasing the film hydrophobicity and surface Gibbs energy, the device with efficiency of 13.5% keeps stable under ambient condition for 30 days.
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A disorder-free conformation boosts phonon and charge transfer in an electron-deficient-core-based non-fullerene acceptor

J. Mater. Chem. A, 2020, 8,8566-8574
DOI: 10.1039/D0TA01260B, Paper
Chujun Zhang, Jun Yuan, Ka Lok Chiu, Hang Yin, Weifang Liu, Guanhaojie Zheng, Johnny Ka Wai Ho, Suzhen Huang, Gaoxing Yu, Feng Gao, Yingping Zou, Shu Kong So
A disorder-free molecular conformation caused by alkyl side chains facilitates electron transport, heat transfer and reduces electronic disorder.
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Moisture-tolerant and high-quality α-CsPbI3 films for efficient and stable perovskite solar modules

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01968B, Paper
Ruihao Chen, Yong Hui, Binghui Wu, Yongke Wang, Xiaofeng Huang, Zhongyuan Xu, Pengpeng Ruan, Wuyong Zhang, Fangwen Cheng, Weijie Zhang, Jun Yin, Jing Li, Nanfeng Zheng
Crown ether effectively stabilizes the cubic phase of CsPbI3 to inhibit the moisture invasion and phase transformation of CsPbI3 films, producing large-area devices and improving device performance.
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Decoupled electrolytes towards enhanced energy and high temperature performance of thermally regenerative ammonia batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03236K, Paper
Weiguang Wang, Gequn Shu, Xiuping Zhu, Hua Tian
An electrolyte decoupling strategy is proposed for ammonia batteries to restrain the self-discharge and enhance energy density as well as power generation at high temperatures.
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Hexagonal boron nitride induces anion trapping in a polyethylene oxide based solid polymer electrolyte for lithium dendrite inhibition

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03677C, Paper
Yuhan Li, Libo Zhang, Zongjie Sun, Guoxin Gao, Shiyao Lu, Min Zhu, Yanfeng Zhang, Zhiyu Jia, Chunhui Xiao, Huaitian Bu, Kai Xi, Shujiang Ding
Lithium ion conductivity and mechanical strength of a PEO based composite solid polymer electrolyte are improved by adding h-BN.
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Two-dimensional covalent–organic frameworks for ultrahigh iodine capture

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA13980J, Communication
Jinheng Li, Huixin Zhang, Lingyan Zhang, Ke Wang, Zhengkang Wang, Guiyan Liu, Yanli Zhao, Yongfei Zeng
Two new two-dimensional covalent–organic frameworks are synthesized using a three-connected building block, showing ultrahigh iodine capture capacities of 5.625 g g−1 and 4.820 g g−1 on account of physical–chemical adsorption.
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An asymmetrical A–DAD–A-type acceptor simultaneously enhances voltage and current for efficient organic solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03128C, Paper
Hanjian Lai, Hui Chen, Yulin Zhu, Lin Chen, Hsin-Hsiang Huang, Feng He
This work provides a strategy of symmetry breaking in an A–DAD–A-type acceptor with a PCE of 15.43%, which is the highest value reported to date for asymmetrical fused-ring acceptors.
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Co-gel strategy for preparing hierarchically porous silica/polyimide nanocomposite aerogel with thermal insulation and flame retardancy

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA13011J, Paper
Xinhai Zhang, Xingxing Ni, Chenxi Li, Bo You, Gang Sun
Co-gel strategy for preparing hierarchically porous silica/polyimide aerogel with low density, high specific modulus, hydrophobicity, flame retardancy, and thermal insulation.
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Optical in-situ monitoring during the synthesis of halide perovskite solar cells reveals formation kinetics and evolution of optoelectronic properties

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01237H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Klara Suchan, Justus Just, Pascal Becker, Eva Lisa Unger, Thomas Unold
The formation mechanism and the evolution of optoelectronic properties during annealing of chlorine-derived methylammonium lead iodide (MAPbI3-xClx) is investigated in detail combining in-situ und ex-situ optical and structural characterization. Using...
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Water-responsive materials for sustainable energy applications

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02896G, Review Article
Yaewon Park, Xi Chen
Water-responsive (WR) materials that mechanically change volume in response to changes in relative humidity (RH) can generate significantly higher energy actuation over natural muscles and conventional actuators. Recent proof-of-concept demonstrations...
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Three-dimensional interconnected V6O13 nest with V5+-rich state for ultrahigh Zn ion storage

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03165H, Paper
Pingge He, Jiaohao Liu, Xudong Zhao, Zhenping Ding, Peng Gao, Li-Zhen Fan
Aqueous zinc ion batteries (ZIBs) have attracted intensive attention due to their low cost, environmental friendliness and high safety. However, exploring suitable cathode materials and deep understanding of their energy...
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Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02833A, Paper
Hongxia Liu, Meng Wang, Jiantai Ma, Gongxuan Lu
New high active low-cost Pd-Sn alloy catalyst for hydrogen evolution from toxic formaldehyde driven by visible light was developed via alloying of Pd with abundance element Sn.
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Synchronous surface and bulk composition management for red-shifted light absorption and suppressed interfacial recombination in perovskite solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02449J, Paper
Jun-Xing Zhong, Jin-Feng Liao, Yong Jiang, Lianzhou Wang, Dai-Bin Kuang, Wu-Qiang Wu
Perovskite solar cells with a reverse vertical gradient distribution of α/δ-FAPbI3 achieved a record efficiency of up to 21.9% owing to synergistic advantages of expanded photon harvesting and robust surface defect passivation.
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Effect of the interfacial protective layer on the NaFe0.5Ni0.5O2 cathode for rechargeable sodium-ion batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02837A, Paper
Iqra Moeez, Dieky Susanto, Ghulam Ali, Hun-Gi Jung, Hee-Dae Lim, Kyung Yoon Chung
Ni-based cathode materials have received significant attentions as the advanced electrode materials for NIBs. However, they suffered from the rapid capacity fading due to the side reactions mainly occurring at cathode-electrolyte interphase (CEI).
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Formation of Ga double grading in submicron Cu(In,Ga)Se2 solar cells by pre-depositing a CuGaSe2 layer

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02710C, Paper
Yifan Kong, Jianmin Li, Zengyang Ma, Zheng Chi, Xudong Xiao
By introducing a pre-deposited CuGaSe2 layer, a steep Ga back grading has been formed in a submicron CIGS layer with a high-temperature process for the first time.
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The rational and effective design of nonfullerene acceptors guided by a semi-empirical model for an organic solar cell with an efficiency over 15%

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03087B, Paper
Xin Ke, Lingxian Meng, Xiangjian Wan, Mingpeng Li, Yanna Sun, Ziqi Guo, Simin Wu, Hongtao Zhang, Chenxi Li, Yongsheng Chen
Guided by a semi-empirical model, two small-molecule acceptors were rationally designed and an impressive PCE of 15.05% was achieved.
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Fe/Fe3C nanoparticle-decorated N-doped carbon nanofibers for improving the nitrogen selectivity of electrocatalytic nitrate reduction

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02317E, Paper
Yue Lan, Junliang Chen, Hui Zhang, Wei-xian Zhang, Jianping Yang
N-doped carbon nanofibers embedded with Fe/Fe3C nanodomains demonstrate superior electrocatalytic nitrate reduction ability and nitrogen selectivity.
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A Cu2B2 monolayer with planar hypercoordinate motifs: an efficient catalyst for CO electroreduction to ethanol

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02471F, Paper
Jingjing Jia, Haijun Zhang, Zhongxu Wang, Jingxiang Zhao, Zhen Zhou
By means of first-principles computations, we identified that metallic Cu2B2 monolayer with planar heptacoordinate motifs could effectively reduce CO to ethanol through the “carbene” mechanism with a low limiting potential and a small barrier for C–C coupling.
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Semiconducting polymer contributes favorably to the Seebeck coefficient in multi-component, high-performance n-type thermoelectric nanocomposites

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02388D, Paper
Junhui Tang, Ruisi Chen, Lidong Chen, Guillermo C. Bazan, Ziqi Liang
n-Type Co NWs/N2200 TENCs yield a high S, mainly from the semiconducting polymer, yet σ is limited by poor connectivity between inorganic and organic domains. By adding flexible n-doped SWCNTs to yield more conductive paths, σ and mechanical bendability are greatly enhanced.
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Rational design of high nitrogen-doped and core–shell/mesoporous carbon nanospheres with high rate capability and cycling longevity for pseudocapacitive sodium storage

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03229H, Paper
Jiayi Mao, Dechao Niu, Nan Jiang, Guangyu Jiang, Meiwan Chen, Yongsheng Li, Jianlin Shi
A facile soft-template strategy is developed to construct high-nitrogen-doped and core–shell/mesoporous carbon nanospheres for high-rate and long-term stable sodium-ion batteries.
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Perovskite-Sensitized β-Ga2O3 Nanorod Arrays for Highly Selective and Sensitive NO2 Detection at High Temperature

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02691C, Paper
Bo Zhang, Hui-Jan Lin, Haiyong Gao, Xingxu Lu, Chang-Yong Nam, Pu-Xian Gao
Amongst various gaseous pollutants, NO2 is one of the major exhausts originating from fossil fuel and gas combustions in vehicle engines and power plants at high temperature. Under such scenario,...
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High Performance Potassium-Sulfur Batteries and Its Reaction Mechanism

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03602A, Paper
Xinxin Zhao, Youran Hong, Mingren Cheng, Shiwen Wang, Lei zheng, Jiangwei Wang, Yunhua Xu
Benefiting from the high natural abundance and high theoretical specific capacities of potassium and sulfur, potassium-sulfur (K-S) battery is deemed as a promising energy storage system for large-scale energy storage...
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Smart Porous Wood Supported Flower-like NiS/Ni Conjuction with Vitrimer Co-effect as Multifunctional Material with Reshaping, Shape-memory and Self-healing for High-Performance Supercapacitors, Catalysts and Sensors

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03664A, Paper
Chuanyin Xiong, Bingbing Li, Heguang Liu, Wei Zhao, Chao Duan, Haiwei Wu, Yong Ni
Wood-based materials are attracting more and more attention for applications in energy storage, due to their environment friendly and numerous channels structure. However, the poor conductivity and flexibility of wood...
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Flexible and transparent sensors for ultra-low NO2 detection at room temperature under visible lights

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02934C, Paper
Xiao-Xue Wang, Hua-Yao Li, Xin Guo
Metal oxide based gas sensors should mostly work at high temperatures; the high working temperature possesses safety concerns and high energy consumption, which makes portable and wearable devices almost impossible,...
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Polyimide/ZIF-7 Mixed-Matrix Membranes: Understanding in-situ Confined Formation of ZIF-7 Phases inside Polymer and Their Effects on Gas Separations

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02761H, Paper
Sunghwan Park, Kie Yong Cho, Hae-Kwon Jeong
Polymer-modification-enabled in-situ metal-organic framework formation (PMMOF) is potentially a paradigm-shifting preparation method for polymer/MOF mixed-matrix membranes (MMMs). However, the actual reaction conditions of in-situ formation of MOF in the confined...
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The fabrication of IMo6@iPAF-1 as an enzyme mimic in heterogeneous catalysis for oxidative desulfurization under O2 or air

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA14066B, Paper
Yue Li, Jian Song, Mengting Jiang, Mbage Bawa, Xiaohong Wang, Yuyang Tian, Guangshan Zhu
Na5[IMo6O24]·3H2O and a porous aromatic framework (iPAF-1) were used to build an off-the-shelf building material (IMo6@iPAF-1) to realize the highly efficient oxidation of organic sulfurs like oxygenase.
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Recent progress in carbonyl-based organic polymers as promising electrode materials for lithium-ion batteries (LIBs)

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03321A, Review Article
Hao Wang, Chang-Jiang Yao, Hai-Jing Nie, Ke-Zhi Wang, Yu-Wu Zhong, Pengwan Chen, Shilin Mei, Qichun Zhang
Lithium-ion batteries (LIBs) have been demonstrated as one of the most promising energy storage devices for applications in electric vehicles, smart grids, large-scale energy storage systems, and portable electronics.
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Ferrites: emerging light absorbers for solar water splitting

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01554G, Review Article
Jeong Hun Kim, Hyo Eun Kim, Jin Hyun Kim, Jae Sung Lee
Ferrites are promising photoelectrode materials for solar water splitting to produce clean and storable hydrogen energy.
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Power and carbon monoxide co-production by a proton-conducting solid oxide fuel cell with La0.6Sr0.2Cr0.85Ni0.15O3−δ for on-cell dry reforming of CH4 by CO2

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03458D, Paper
Tong Wei, Peng Qiu, Lichao Jia, Yuan Tan, Xin Yang, Shichen Sun, Fanglin Chen, Jian Li
Highly efficient on-cell dry reforming of CH4 for power and CO co-production by H-SOFCs is achieved with an engineered LSCN@Ni layer.
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Understanding the structural phase transitions in lithium vanadium phosphate cathode for lithium-ion batteries

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/C9TA12435G, Paper
Woong Oh, Hyunyoung Park, Bong-Soo Jin, Ranjith Thangavel, Won-Sub Yoon
Developing high-energy lithium-ion batteries with long stability is critical for realizing sustainable energy applications; however, it remains highly challenging. Exploring multi-redox based electrode materials can help to achieve high capacity...
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In Situ Confinement of Pt within Three-Dimensional MoO2@Porous Carbon for Efficient Hydrogen Evolution

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02507K, Paper
Yimin Jiang, Miao Yang, Meijiao Qu, Yi Wang, Zhouchunyu Yang, Qingliang Feng, Xia Deng, Wei Shen, Ming Li, Rongxing He
Promoting the industrialization and widespread application of Pt-based catalysts is essential to electrochemical water-splitting systems. However, the development of cost-effective Pt-based catalysts still remains a high challenge. Here we report...
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Surface-Functionalized Palladium Catalysts for Electrochemical CO2 Reduction

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03427D, Paper
Rong Xia, Sheng Zhang, Xinbin Ma, Feng Jiao
Rational design and synthesis of efficient catalysts for electrochemical CO2 reduction is a critical step towards practical CO2 electrolyzer systems. In this work, we report a strategy to tune the...
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Rational Design of Well-Dispersed Ultrafine CoS2 Nanocrystals in Micro-Mesoporous Carbon Spheres with Synergistic Effect for High-Performance Lithium-Sulfur Batteries

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02692A, Paper
Zhanshuang Jin, Ming Zhao, Tianning Lin, Bingqiu Liu, Qi Zhang, Lingyu Zhang, Lihua Chen, Lu Li, Zhong-Min Su, Chungang Wang
The physical confinement and chemical catalysis of lithium polysulfides (LiPSs) are effective ways to improve the performance of lithium-sulfur (Li-S) batteries. How to effectively combine physical confinement and chemical catalysis...
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VS4 with chain crystal structure used as an intercalation cathode for an aqueous Zn-ion battery

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02645J, Communication
Qiancheng Zhu, Qin Xiao, Bowen Zhang, Zhengcong Yan, Xi Liu, Shuo Chen, Zhifeng Ren, Ying Yu
Non-aqueous lithium-ion batteries are currently widely used throughout society, but aqueous batteries could be more feasible for grid-scale applications or even electric cars when factors like cost and safety are...
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Hydrophilic ultrafiltration membranes with surface-bound eosin Y for an integrated synthesis-separation system of aqueous RAFT photopolymerization

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03112G, Paper
Yujie Zhao, Senlin Shao, Jiangbin Xia, Ya Huang, Yu Chi Zhang, Xue Li, Tao Cai
The photocatalyst-based ultrafiltration membrane fitted integrated synthesis–separation system holds the promises to bridge the gap between the precision of PET-RAFT polymerization and the efficiency of membrane separation process.
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Catalyst design strategies for stable electrochemical CO2 reduction reaction

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02633F, Review Article
Woong Choi, Da Hye Won, Yun Jeong Hwang
The gradual increase in the atmospheric CO2 concentration due to the combustion of fossil fuels is an urgent issue that poses a threat to human beings. Recently, the electrochemical CO2...
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Nitrogen-doped phosphorene for electrocatalytic ammonia synthesis

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03237A, Paper
Guang-Rui Xu, Hao Li, Abdulaziz Bati, Munkhjargal Bat-Erdene, Md Julker Nine, Dusan Losic, Yu Chen, Joseph G Shapter, Munkhbayar Batmunkh, Tianyi Ma
The rapid surface oxidation of phosphorene under ambient conditions is considered to be serious issue for many applications, but here is used as a strategy to achieve efficient heteroatom doping....
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Aliovalent Fluorine Doping and Anodization-Induced Amorphization Enable Bifunctional Catalysts for Efficient Water Splitting

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA00876A, Paper
Chenglin Zhong, Zhen Han, Tongtong Wang, Qin-chao Wang, Zihan Shen, Qingwen Zhou, Jiaao Wang, Shuo Zhang, Xin Jin, Shengwen Li, Peng Wang, Daqiang Gao, Yong-Ning Zhou, Huigang Zhang
High-efficiency non-precious electrocatalysts are urgently demanded in hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Transition metal oxides catalysts have shown high activity for the OER in alkaline medium,...
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Creating compressive stress at the NiOOH/NiO interface for water oxidation

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA04244G, Communication
Chunguang Kuai, Yan Zhang, Li-Li Han, Huolin Xin, Chengjun Sun, Dennis Nordlund, Shizhang Qiao, Xiwen Du, Feng Lin
Enhancing the oxygen evolution reaction (OER) performance of NiO materials will greatly expand their applications as low-cost, bifunctional electrocatalysts for water splitting reactions. Introducing stress into the surface layer of...
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Bimetallic-MOF Catalyst for Efficient CO2 Photoreduction from Simulated Flue Gas to Value-added Formate

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA00205D, Paper
Shao-hong Guo, Xiang-Juan Qi, Hui-Min Zhou, Jie Zhou, Xiao-Hui Wang, Man Dong, Xue Zhao, Chun-Yi Sun, Xinlong Wang, Zhong-Min Su
Direct CO2 conversion from flue gas into high-value products is of great significance not only in relieving environmental burden but alleviating energy crisis by a low-cost and saving-energy avenue, yet...
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Latest News: Reynolds New Ambassador for Young People's Literature

Jason Reynolds has been appointed as the seventh National Ambassador for Young People’s Literature for 2020-2021. The Newbery Honor recipient succeeds Jacqueline Woodson, who served as National Ambassador in 2018-2019.

Reynolds is the author of 13 books for young people including his most recent, “Look Both Ways: A Tale Told in Ten Blocks,” a National Book Award finalist, which was named a Best Book of 2019 by NPR, The New York Times, The Washington Post and TIME. 

Click here for more information.




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Best CSS Frameworks for Building Better Websites

When building a website, using a CSS framework is a real time saver as it provides you with tools every web designer and front-end developer needs when crafting a site (other than good web hosting). A CSS framework is a software framework created to allow for easier, more standards-compliant web design using HTML/CSS. Many popular …

Best CSS Frameworks for Building Better Websites Read More »




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Gilead scouting for partners in India, Pakistan for remdesivir

Recent clinical trial results and the decision by the US Food and Drug Administration to issue 'Emergency Use Authorisation' for remdesivir have highlighted the urgency of this work and the importance of planning for access to remdesivir globally, Gilead said.




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Hydroxychloroquine no wonder drug for treating COVID-19, can be fatal: Experts

While frantic efforts are underway to develop a vaccine and doctors all over try and control the spread of the disease for which there is yet no cure, hydroxychloroquine, or HCQ, has emerged as a prime focus area of treatment.




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Bilateral deals might not be equitable for Covid-19: MPP executive director Charles Gore

The Medicines Patent Pool is a United Nations-backed public health organisation that helps middle- and low-income countries get access to critical drugs. MPP executive director Charles Gore told ET’s Divya Rajagopal about the organisation’s plan to ensure equitable access of Covid-19 drugs and vaccines.




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Dr Reddy's gets USFDA inspection closure report for Srikakulam plant

The US Food and Drug Administration (USFDA) had issued a warning letter to the facility in November, 2015, after inspecting it in 2014.




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Sufficient trouble: compositions for computer, live instruments, and voice / Brian Belet

MEDIA PhonCD B411 sel




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Ergo: new music for piano & Chinese folk instruments / Zhen Chen

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Anasa: True colors ; Unforgettable / George Tsontakis

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Blood, forgotten / Mark Nowakowski ; Emily Ondracek-Peterson, solo violin ; Voxare String Quartet

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