ration How generational differences shape workplaces By www.mprnews.org Published On :: Mon, 04 Nov 2024 18:52:00 +0000 Gen Z does a good job taking sick days, unlike their older coworkers. MPR News host Angela Davis talks about how the mix of generations in today’s workforce is redefining how we work. Full Article
ration 7 inspirational hymns for Veterans Day By www.christianpost.com Published On :: Sun, 10 Nov 2024 08:30:16 -0500 Here are seven hymns that are relevant to the themes of Veterans Day, such as the desire for peace and the importance of service. Full Article
ration The Universal Declaration of Human Rights: 75th anniversary (part 1) By www.christianpost.com Published On :: Fri, 22 Sep 2023 09:52:41 -0400 The UDHR articulates in its 30 articles every human being’s basic, fundamental rights and freedoms and affirms those rights as universal and unalienable. The UDHR directly led to the development of the concept of international human rights law. Full Article
ration Long-term considerations in brain injury settlements By english.pravda.ru Published On :: Wed, 31 Mar 2021 16:49:00 +0300 In the last few years, we’ve seen increasing awareness of the lasting consequences of serious brain injuries, in part due to high-profile cases connected to the NFL. For those who have recently suffered a brain injury, though, it can be hard to think about what the future will hold, even though planning for long-term care needs is an important step. In particular, if you’re currently involved in a legal case seeking to recover damages after incurring a brain injury, it’s vital that your legal team consult appropriate medical professionals to ensure the calculation of damages will cover your future care needs. Current Injury Future Risk Traumatic brain injuries (TBIs) vary widely in severity and can result in many different symptoms. Among the most common symptoms of TBI, however, are headaches and dizziness, memory loss, lack of concentration, and agitation and other personality changes. Symptoms of TBI may be temporary, lasting for weeks or months after the initial injury, or may result in permanent impairment, which is why it’s so important to work with a lawyer well-versed in TBI cases. Full Article Health
ration Operation Z: What is that? By english.pravda.ru Published On :: Wed, 16 Mar 2022 13:21:00 +0300 The Z marking, which one may see painted on the Russian military vehicles in Ukraine, has become one of the most talked-about symbols lately. White Z markings on Russian tanks, infantry vehicles, etc, have given the name to Russia's special operation in Ukraine — Operation Z. The day, when Putin ordered to begin the operation was dubbed as Day Z. At first, no one could give a precise explanation to what Z signs on Russian tanks mean. Many assumed that the Russian military decided to paint such markings to be able to distinguish the Russian military hardware from Ukrainian arms as the two countries use the same military technology — the Ukrainian military use same models of tanks or trucks as the Russian military do. Full Article Society
ration US skinhead mercenary admits Russia had good reason to launch special operation By english.pravda.ru Published On :: Mon, 21 Nov 2022 21:02:00 +0300 Kent McLellan, a 32-year-old American neo-Nazi who fought in the Donbass as part of the Nazi Right Sector* movement, who then joined Azov Battalion* after Russia launched the special operation in Ukraine, returned to Florida and started sharing his experience with media outlets. Some of his interviews do not fit into the framework of what American propaganda says about the Ukrainian conflict. In a conversation with Juan Sinmiedo, Ken "Boneface" McLellan busted myths about the coup on the Maidan, about today's Ukraine, and about how many neo-fascists Ukraine has actually sheltered. Full Article Society
ration DWC's New Deputy Commissioner for Operations and External Relations By www.tdi.texas.gov Published On :: Thu, 14 Dec 2023 00:00:00 CST Texas Workers' Compensation Commissioner Jeff Nelson has announced the appointment of Matthew Posey as DWC's new Deputy Commissioner of Operations and External Relations. Full Article
ration Boston Dynamics presents humanoid robot of new generation By english.pravda.ru Published On :: Thu, 18 Apr 2024 13:03:00 +0300 Boston Dynamics presented the new robot. The company refused from the old hydraulic platform to introduce the new electric one under the same name, Atlas. The new robot is completely electronic, there are no hydraulic systems involved. The new robot will be stronger and more maneuverable as all developments of the previous generation of the robot will be improved. The company is ambitious to introduce humanoid robots and create infrastructure for them, including software. Full Article Science
ration Head of Nuclear Center: Russian Tsar Laser to be operational by 2029 By english.pravda.ru Published On :: Tue, 13 Aug 2024 12:29:00 +0300 The UFL-2M laser system, which is often called the "Tsar Laser" due to its unique technical specifications and power performance, will be fully operational by approximately 2028-2029, Valentin Kostyukov, Director of the Russian Federal Nuclear Center said in an interview with Russia-24 TV channel. "We have launched the first stage of physical foundations associated with engineering systems," Kostyukov said, admitting that the system will yield results in the next four to five years. The UFL-2M laser system was developed at the Sarov Nuclear Center. The system is needed for modeling and designing new types of nuclear weapons. It is used to study the processes that occur at the moment of explosion. There are only three countries in the world that have such technology: the United States, France, and Russia. Full Article Science
ration Fattah-2: New generation of Iranian weapons to respond to aggressor By english.pravda.ru Published On :: Thu, 03 Oct 2024 19:58:00 +0300 On the first day of October, Iran fired more than 200 missiles at Israel. The missiles reached their targets in 10-12 minutes. According to the Chief of Staff of the Iranian Armed Forces said, the attacks were conducted to hit Navatim and Netzarim air bases, where F-35 aircraft, radars and tank assembly centers are based. It is believed that Iran used new Fattah-2 hypersonic missiles for the attack. The hypersonic ballistic missile flies at a speed of about 6,000 km per hour (up to 5 Mach); its flight range amounts to 1,400 km. Full Article World
ration Docket No. 2851 - Consideration of a Request to Change the Title Insurance Basic Premium Rates By www.tdi.texas.gov Published On :: Tue, 21 Jan 2025 20:00:00 GMT TLTA's petition to change basic title rates Full Article
ration Toshiba’s next-generation S300 Pro Surveillance HDDs for large-scale video surveillance systems By www.retailtechnologyreview.com Published On :: Toshiba Electronics Europe GmbH (Toshiba) has introduced its next-generation S300 Pro Surveillance Hard Disk Drives (HDDs) targeting the latest requirements in the surveillance storage market. Full Article Surveillance and Security
ration Rising e-commerce packaging costs and the European Union’s new Packaging & Packaging Waste Regulations (P&PWR) require careful consideration By www.retailtechnologyreview.com Published On :: By Jo Bradley, Business Development Manager at Sparck Technologies.Companies can be schizophrenic about packaging and its costs. On the one hand, product packaging is closely scrutinised – a battleground between buyers seeking to drive costs down and marketers looking for ever greater impact and ‘shelf appeal’. Full Article Internet Retailing Critical Issues Retail Supply Chain
ration SATO Europe launches RAIN RFID asset management solution ASETRA to boost operational efficiency By www.retailtechnologyreview.com Published On :: SATO has launched its RAIN RFID1-based asset management solution ASETRA in Europe. The easy to deploy system comprising RFID tags, RFID printers and desktop reader/writers accurately and easily tracks and manages assets through the supply chain. Full Article RFID Data Capture Print & Label
ration Manhattan Active Point of Sale unveils the next generation of store associate experience By www.retailtechnologyreview.com Published On :: Wed, 13 Nov 4897 17:05:48 +0000 Manhattan Associates Inc. has announced significant enhancements to its Manhattan Active Point of Sale (POS) application designed to meet the dynamic needs of modern store associates. Full Article EPoS Systems Retail Supply Chain
ration Janam launches next-generation self-credentialing kiosk By www.retailtechnologyreview.com Published On :: Mon, 13 Nov 4800 16:48:50 +0000 Janam Technologies, provider of rugged mobile computers and contactless access solutions, has introduced the newest addition to its Guardian family of access management hardware solutions. Full Article Kiosk Technology
ration Mood Media research finds Shoppers need inspiration By www.retailtechnologyreview.com Published On :: Nearly two-thirds of shoppers step into a store without a specific purchase in mind, looking to be inspired by retailers who can craft the ideal ambience through digital screens and interactive kiosks. Full Article Kiosk Technology Data Capture Critical Issues
ration Russia not going to limit special operation to easternmost regions of former Ukraine By english.pravda.ru Published On :: Thu, 25 Apr 2024 18:43:00 +0300 Russian military social media began to promote the Sever (North) group of troops of the Russian Armed Forces. The group is known for its tactical sign N and its goal is an offensive on Kharkiv. North military grouping created for Kharkiv operation The creation of the group of troops North (N) means that the Russian forces are preparing personnel in the Belgorod region for an offensive on Kharkiv. Ukrainian sources say that the Russian Army does not need to capture Kharkiv, but this is not true to fact. Taking the city will let the Russian forces ensure the collapse of the entire eastern front of the Ukrainian Armed Forces. In addition, keeping Kharkiv under control will ensure security for the Belgorod region of Russia that Ukraine has been shelling regularly. The Russian authorities can no longer ignore civilian casualties. There are other signs that indicate preparations for an offensive: Full Article Incidents
ration Ukraine's Kursk operation failure will lead to tremendous consequences By english.pravda.ru Published On :: Wed, 14 Aug 2024 18:35:00 +0300 The Ukrainian Foreign Ministry stated that Kyiv was not interested in appropriating the territories of the Kursk region of Russia. This means that the march of the Ukrainian Armed Forces "to Kursk and Voronezh" is over with. "Ukraine is not interested in appropriating the territories of the Kursk region" — Ukrainian Foreign Ministry 'Ukraine does not need what is foreign' Ukrainian Foreign Ministry spokesman Georgy Tykhy said that the offensive of the Ukrainian Armed Forces in the Kursk region was needed "to protect the lives of our people" rather than to capture Russian territories. Full Article Incidents
ration NMFTA influences next generation of cybersecurity professionals at CyberTruck Challenge By www.retailtechnologyreview.com Published On :: Sat, 13 Nov 4460 17:20:54 +0000 The National Motor Freight Traffic Association, Inc. (NMFTA) served as the lead sponsor for the CyberTruck Challenge. This year marked the third year that NMFTA had served in this sponsorship role. Full Article Surveillance and Security Exhibitions and Events Cyber Security
ration Russian general killed in special military operation zone By english.pravda.ru Published On :: Fri, 08 Nov 2024 20:34:00 +0300 Major General Pavel Klimenko was killed in the zone of the special military operation in Ukraine. He commanded the 5th separate motorized rifle brigade, which was previously part of the People's Militia of the Donetsk People's Republic. No circumstances of the general's death were provided. Pavel Klimenko held the title of Hero of the DPR, had two Orders of Courage, the Order of Alexander Nevsky and the Medal "For Bravery". Full Article Incidents
ration gStore by GreyOrange unveils SoftFence - Next-generation virtual shielding for RFID-driven retail operations By www.retailtechnologyreview.com Published On :: GreyOrange Inc. has introduced SoftFence, a virtual shielding technology from its retail software as a service (SaaS) platform, gStore. Full Article RFID Data Capture Retail Supply Chain Cloud Computing
ration Global study from Checkout.com reveals Generation Alpha’s rising influence in Digital Economy By www.retailtechnologyreview.com Published On :: Sat, 13 Nov 6060 17:29:50 +0000 A global study by Checkout.com, the global digital payments company, highlights the consumer buying behaviour which is powering today’s digital economy. The research, conducted across the UK, US, UAE and China, reveals a number of trends, including the growing spending power of Generation Alpha. Full Article Data Capture Retail Supply Chain Critical Issues Payment Technology
ration Expert Available: Potential International Trade Changes Under New Trump Administration By www.newswise.com Published On :: Fri, 08 Nov 2024 11:45:22 EST University of Georgia School of Law Assistant Professor of Law & Faculty Co-Director of the Dean Rusk International Law Center Desiree LeClercq, who specializes in international labor law and worked in the Office of the U.S. Trade Representative during the previous Trump administration, as well as in the International Labor Organization and at the National Labor Relations Board, is available for further commentary at desireelc@uga.edu. Full Article
ration First-Generation Nursing Student Dallas Martin Finds Success at UA Little Rock By www.newswise.com Published On :: Mon, 11 Nov 2024 10:50:47 EST Dallas Martin, a first-generation senior nursing major from Helena, Arkansas, really does it all. This wife and mom of two is a full-time student at UA Little Rock, set to graduate in December with her bachelor's degree in nursing, while also working full-time as a physician's registered nurse in oncology and hematology at Carti Cancer Center in Little Rock. Full Article
ration Transport Ministry Restricts Aircraft Operation during College Entrance Exam By world.kbs.co.kr Published On :: Tue, 12 Nov 2024 12:05:20 +0900 [Domestic] : The transport ministry will restrict the takeoff and landing of all aircraft for about half an hour on Thursday to prevent distractions during the English listening portion of the annual College Scholastic Ability Test. The ministry said Tuesday that the restrictions will be in place from 1:05 p.m. to 1:40 ...[more...] Full Article Domestic
ration S. Korea, US to Conduct Joint Studies for Artemis Moon Exploration Program By world.kbs.co.kr Published On :: Wed, 30 Oct 2024 15:25:17 +0900 [Science] : South Korea and the United States will conduct joint studies related to the Artemis moon exploration program. According to the Korea AeroSpace Administration on Wednesday, it has signed a study agreement on the Artemis program with U.S. National Aeronautics and Space Administration(NASA). The agreement ...[more...] Full Article Science
ration Ukraine Commander: Numerous Reports of N. Korean Soldiers Preparing to Participate in Combat Operations By world.kbs.co.kr Published On :: Sun, 10 Nov 2024 12:56:09 +0900 [International] : Ukraine's top military commander, Oleksandr Syrskyi, reportedly said that his country has numerous reports of North Korean soldiers preparing to participate in combat operations alongside Russian forces. Reuters said on Sunday that Syrskyi made the remarks in a Facebook post on Saturday. In the ...[more...] Full Article International
ration Streamline Your Business Operations with Cutting-edge Routing Software By auto.howstuffworks.com Published On :: Tue, 20 Feb 2024 18:33:02 -0500 Efficient route planning is crucial for businesses to stay competitive and meet customer demands. Thankfully, there are several free routing software options available that can help streamline your business operations. Whether you're a small business owner or a logistics manager, these tools can be invaluable in optimizing your routes and maximizing productivity. Full Article
ration New geological collaboration for Ordnance Survey - Ordnance Survey By news.google.com Published On :: Wed, 29 May 2024 07:00:00 GMT New geological collaboration for Ordnance Survey Ordnance Survey Full Article
ration BGS announces collaboration with Ordnance Survey - British Geological Survey By news.google.com Published On :: Wed, 29 May 2024 07:00:00 GMT BGS announces collaboration with Ordnance Survey British Geological Survey Full Article
ration Exploiting fourth-generation synchrotron radiation for enzyme and photoreceptor characterization By journals.iucr.org Published On :: (Time-resolved) macromolecular crystallography at the new ESRF-ID29 beamline is described. Full Article text
ration The seventh blind test of crystal structure prediction: structure generation methods By journals.iucr.org Published On :: The results of the seventh blind test of crystal structure prediction are presented, focusing on structure generation methods. Full Article text
ration Selective Acceleration and Inhibition of Crystal Growth of Glass Carbamazepine by Low-Concentration Poly(ethylene oxide):Effects of Drug Polymorph By journals.iucr.org Published On :: Low-concentration poly(ethylene oxide) exhibit the polymorph-dependent effects on both the surface and bulk crystal growth of carbamazepine polymorphs. These polymorph-dependent effects of PEO were mainly attributed to the polymer enrichment at the interface and different crystal surface-polymer interactions. Full Article text
ration The seventh blind test of crystal structure prediction: structure generation methods By journals.iucr.org Published On :: 2024-12-01 A seventh blind test of crystal structure prediction was organized by the Cambridge Crystallographic Data Centre featuring seven target systems of varying complexity: a silicon and iodine-containing molecule, a copper coordination complex, a near-rigid molecule, a cocrystal, a polymorphic small agrochemical, a highly flexible polymorphic drug candidate, and a polymorphic morpholine salt. In this first of two parts focusing on structure generation methods, many crystal structure prediction (CSP) methods performed well for the small but flexible agrochemical compound, successfully reproducing the experimentally observed crystal structures, while few groups were successful for the systems of higher complexity. A powder X-ray diffraction (PXRD) assisted exercise demonstrated the use of CSP in successfully determining a crystal structure from a low-quality PXRD pattern. The use of CSP in the prediction of likely cocrystal stoichiometry was also explored, demonstrating multiple possible approaches. Crystallographic disorder emerged as an important theme throughout the test as both a challenge for analysis and a major achievement where two groups blindly predicted the existence of disorder for the first time. Additionally, large-scale comparisons of the sets of predicted crystal structures also showed that some methods yield sets that largely contain the same crystal structures. Full Article text
ration Multi-species cryoEM calibration and workflow verification standard By journals.iucr.org Published On :: 2024-10-31 Cryogenic electron microscopy (cryoEM) is a rapidly growing structural biology modality that has been successful in revealing molecular details of biological systems. However, unlike established biophysical and analytical techniques with calibration standards, cryoEM has lacked comprehensive biological test samples. Here, a cryoEM calibration sample consisting of a mixture of compatible macromolecules is introduced that can not only be used for resolution optimization, but also provides multiple reference points for evaluating instrument performance, data quality and image-processing workflows in a single experiment. This combined test specimen provides researchers with a reference point for validating their cryoEM pipeline, benchmarking their methodologies and testing new algorithms. Full Article text
ration The effects of low boron incorporation on the structural and optical properties of BxGa1−xN/SiC epitaxial layers By journals.iucr.org Published On :: The effect of boron in BxGa1−xN/SiC heteroepitaxy was established by X-ray diffraction reciprocal-space maps on symmetric 0002 and asymmetric 11 {overline 2} 4 reflections. The density of screw and edge threading dislocations was quantified in the framework of the mosaic model. Full Article text
ration Characterization and calibration of DECTRIS PILATUS3 X CdTe 2M high-Z hybrid pixel detector for high-precision powder diffraction measurements By journals.iucr.org Published On :: The performance of a high-Z photon-counting detector for powder diffraction measurements at high (>50 keV) energies is characterized, and the appropriate corrections are described in order to obtain data of higher quality than have previously been obtained from 2D detectors in these energy ranges. Full Article text
ration Optimal operation guidelines for direct recovery of high-purity precursor from spent lithium-ion batteries: hybrid operation model of population balance equation and data-driven classifier By journals.iucr.org Published On :: This study proposes an operation optimization framework for impurity-free recycling of spent lithium-ion batteries. Using a hybrid population balance equation integrated with a data-driven condition classifier, the study firstly identifies the optimal batch and semi-batch operation conditions that significantly reduce the operation time with 100% purity of product; detailed guidelines are given for industrial applications. Full Article text
ration Crystal structure of N-terminally hexahistidine-tagged Onchocerca volvulus macrophage migration inhibitory factor-1 By journals.iucr.org Published On :: N-terminally hexahistidine-tagged O. volvulus macrophage migration inhibitory factor-1 has a unique jellyfish-like structure with the prototypical macrophage migration inhibitory factor trimer as the `head' and a C-terminal extension as the `tail'. Full Article text
ration The effects of low boron incorporation on the structural and optical properties of BxGa1−xN/SiC epitaxial layers By journals.iucr.org Published On :: 2024-11-04 BGaN epilayers with boron contents up to 5.6% were grown on SiC substrates by metal–organic chemical vapor deposition. The effects of boron incorporation on the structural and optical properties were studied by high-resolution X-ray diffraction (XRD), atomic force microscopy (AFM), Raman spectroscopy and photoluminescence (PL) spectroscopy. XRD reciprocal-space maps around the symmetric 0002 and asymmetric 11 {overline 2} 4 reflections allowed evaluation of the lattice constants and lattice mismatch with respect to the underlying substrate. XRD rocking curves and AFM measurements indicated the mosaic microstructure of the epilayer. The impact of boron content on crystallite size, tilt and twist is evaluated and the correlation with threading dislocation density is discussed. The deterioration of optical properties with increasing boron content was assessed by Raman and PL spectroscopy. Full Article text
ration Influence of device configuration and noise on a machine learning predictor for the selection of nanoparticle small-angle X-ray scattering models By journals.iucr.org Published On :: 2024-09-23 Small-angle X-ray scattering (SAXS) is a widely used method for nanoparticle characterization. A common approach to analysing nanoparticles in solution by SAXS involves fitting the curve using a parametric model that relates real-space parameters, such as nanoparticle size and electron density, to intensity values in reciprocal space. Selecting the optimal model is a crucial step in terms of analysis quality and can be time-consuming and complex. Several studies have proposed effective methods, based on machine learning, to automate the model selection step. Deploying these methods in software intended for both researchers and industry raises several issues. The diversity of SAXS instrumentation requires assessment of the robustness of these methods on data from various machine configurations, involving significant variations in the q-space ranges and highly variable signal-to-noise ratios (SNR) from one data set to another. In the case of laboratory instrumentation, data acquisition can be time-consuming and there is no universal criterion for defining an optimal acquisition time. This paper presents an approach that revisits the nanoparticle model selection method proposed by Monge et al. [Acta Cryst. (2024), A80, 202–212], evaluating and enhancing its robustness on data from device configurations not seen during training, by expanding the data set used for training. The influence of SNR on predictor robustness is then assessed, improved, and used to propose a stopping criterion for optimizing the trade-off between exposure time and data quality. Full Article text
ration Image registration for in situ X-ray nano-imaging of a composite battery cathode with deformation By journals.iucr.org Published On :: 2024-02-01 The structural and chemical evolution of battery electrodes at the nanoscale plays an important role in affecting the cell performance. Nano-resolution X-ray microscopy has been demonstrated as a powerful technique for characterizing the evolution of battery electrodes under operating conditions with sensitivity to their morphology, compositional distribution and redox heterogeneity. In real-world batteries, the electrode could deform upon battery operation, causing challenges for the image registration which is necessary for several experimental modalities, e.g. XANES imaging. To address this challenge, this work develops a deep-learning-based method for automatic particle identification and tracking. This approach was not only able to facilitate image registration with good robustness but also allowed quantification of the degree of sample deformation. The effectiveness of the method was first demonstrated using synthetic datasets with known ground truth. The method was then applied to an experimental dataset collected on an operating lithium battery cell, revealing a high degree of intra- and interparticle chemical complexity in operating batteries. Full Article text
ration Ultrashort large-bandwidth X-ray free-electron laser generation with a dielectric-lined waveguide By journals.iucr.org Published On :: 2024-02-09 Large-bandwidth pulses produced by cutting-edge X-ray free-electron lasers (FELs) are of great importance in research fields like material science and biology. In this paper, a new method to generate high-power ultrashort FEL pulses with tunable spectral bandwidth with spectral coherence using a dielectric-lined waveguide without interfering operation of linacs is proposed. By exploiting the passive and dephasingless wakefield at terahertz frequency excited by the beam, stable energy modulation can be achieved in the electron beam and large-bandwidth high-intensity soft X-ray radiation can be generated. Three-dimensional start-to-end simulations have been carried out and the results show that coherent radiation pulses with duration of a few femtoseconds and bandwidths ranging from 1.01% to 2.16% can be achieved by changing the undulator taper profile. Full Article text
ration High-pressure X-ray photon correlation spectroscopy at fourth-generation synchrotron sources By journals.iucr.org Published On :: 2024-04-10 A new experimental setup combining X-ray photon correlation spectroscopy (XPCS) in the hard X-ray regime and a high-pressure sample environment has been developed to monitor the pressure dependence of the internal motion of complex systems down to the atomic scale in the multi-gigapascal range, from room temperature to 600 K. The high flux of coherent high-energy X-rays at fourth-generation synchrotron sources solves the problems caused by the absorption of diamond anvil cells used to generate high pressure, enabling the measurement of the intermediate scattering function over six orders of magnitude in time, from 10−3 s to 103 s. The constraints posed by the high-pressure generation such as the preservation of X-ray coherence, as well as the sample, pressure and temperature stability, are discussed, and the feasibility of high-pressure XPCS is demonstrated through results obtained on metallic glasses. Full Article text
ration Synchrotron infrared nanospectroscopy in fourth-generation storage rings By journals.iucr.org Published On :: 2024-04-17 Fourth-generation synchrotron storage rings represent a significant milestone in synchrotron technology, offering outstandingly bright and tightly focused X-ray beams for a wide range of scientific applications. However, due to their inherently tight magnetic lattices, these storage rings have posed critical challenges for accessing lower-energy radiation, such as infrared (IR) and THz. Here the first-ever IR beamline to be installed and to operate at a fourth-generation synchrotron storage ring is introduced. This work encompasses several notable advancements, including a thorough examination of the new IR source at Sirius, a detailed description of the radiation extraction scheme, and the successful validation of our optical concept through both measurements and simulations. This optimal optical setup has enabled us to achieve an exceptionally wide frequency range for our nanospectroscopy experiments. Through the utilization of synchrotron IR nanospectroscopy on biological and hard matter samples, the practicality and effectiveness of this beamline has been successfully demonstrated. The advantages of fourth-generation synchrotron IR sources, which can now operate with unparalleled stability as a result of the stringent requirements for producing low-emittance X-rays, are emphasized. Full Article text
ration Hard X-ray operation of X-ray gas monitors at the European XFEL By journals.iucr.org Published On :: 2024-06-05 X-ray gas monitors (XGMs) are operated at the European XFEL for non-invasive single-shot pulse energy measurements and average beam-position monitoring. The underlying measurement principle is the photo-ionization of rare gas atoms at low gas pressures and the detection of the photo-ions and photo-electrons created. These are essential for tuning and sustaining self-amplified spontaneous emission (SASE) operation, machine radiation safety, and sorting single-shot experimental data according to pulse energy. In this paper, the first results from XGM operation at photon energies up to 30 keV are presented, which are far beyond the original specification of this device. Here, the Huge Aperture MultiPlier (HAMP) is used for single-shot pulse energy measurements since the standard X-ray gas monitor detectors (XGMDs) do not provide a sufficient signal-to-noise ratio, even at the highest operating gas pressures. A single-shot correlation coefficient of 0.98 is measured between consecutive XGMs operated with HAMP, which is as good as measuring with the standard XGMD detectors. An intra-train non-linearity of the HAMP signal is discovered, and operation parameters to mitigate this effect are studied. The upper repetition rate limit of HAMP operation at 2.25 MHz is also determined. Finally, the possibilities and limits for future XGM operation at photon energies up to 50 keV are discussed. Full Article text
ration Mapping of lithium ion concentrations in 3D structures through development of in situ correlative imaging of X-ray Compton scattering-computed tomography By journals.iucr.org Published On :: 2024-06-05 Understanding the correlation between chemical and microstructural properties is critical for unraveling the fundamental relationship between materials chemistry and physical structures that can benefit materials science and engineering. Here, we demonstrate novel in situ correlative imaging of the X-ray Compton scattering computed tomography (XCS-CT) technique for studying this fundamental relationship. XCS-CT can image light elements that do not usually exhibit strong signals using other X-ray characterization techniques. This paper describes the XCS-CT setup and data analysis method for calculating the valence electron momentum density and lithium-ion concentration, and provides two examples of spatially and temporally resolved chemical properties inside batteries in 3D. XCS-CT was applied to study two types of rechargeable lithium batteries in standard coin cell casings: (1) a lithium-ion battery containing a cathode of bespoke microstructure and liquid electrolyte, and (2) a solid-state battery containing a solid-polymer electrolyte. The XCS-CT technique is beneficial to a wide variety of materials and systems to map chemical composition changes in 3D structures. Full Article text
ration Self-calibration strategies for reducing systematic slope measurement errors of autocollimators in deflectometric profilometry By journals.iucr.org Published On :: 2024-06-05 Deflectometric profilometers are used to precisely measure the form of beam shaping optics of synchrotrons and X-ray free-electron lasers. They often utilize autocollimators which measure slope by evaluating the displacement of a reticle image on a detector. Based on our privileged access to the raw image data of an autocollimator, novel strategies to reduce the systematic measurement errors by using a set of overlapping images of the reticle obtained at different positions on the detector are discussed. It is demonstrated that imaging properties such as, for example, geometrical distortions and vignetting, can be extracted from this redundant set of images without recourse to external calibration facilities. This approach is based on the fact that the properties of the reticle itself do not change – all changes in the reticle image are due to the imaging process. Firstly, by combining interpolation and correlation, it is possible to determine the shift of a reticle image relative to a reference image with minimal error propagation. Secondly, the intensity of the reticle image is analysed as a function of its position on the CCD and a vignetting correction is calculated. Thirdly, the size of the reticle image is analysed as a function of its position and an imaging distortion correction is derived. It is demonstrated that, for different measurement ranges and aperture diameters of the autocollimator, reductions in the systematic errors of up to a factor of four to five can be achieved without recourse to external measurements. Full Article text
ration Asymmetric electrostatic dodecapole: compact bandpass filter with low aberrations for momentum microscopy By journals.iucr.org Published On :: 2024-06-20 Imaging energy filters in photoelectron microscopes and momentum microscopes use spherical fields with deflection angles of 90°, 180° and even 2 × 180°. These instruments are optimized for high energy resolution, and exhibit image aberrations when operated in high transmission mode at medium energy resolution. Here, a new approach is presented for bandpass-filtered imaging in real or reciprocal space using an electrostatic dodecapole with an asymmetric electrode array. In addition to energy-dispersive beam deflection, this multipole allows aberration correction up to the third order. Here, its use is described as a bandpass prefilter in a time-of-flight momentum microscope at the hard X-ray beamline P22 of PETRA III. The entire instrument is housed in a straight vacuum tube because the deflection angle is only 4° and the beam displacement in the filter is only ∼8 mm. The multipole is framed by transfer lenses in the entrance and exit branches. Two sets of 16 different-sized entrance and exit apertures on piezomotor-driven mounts allow selection of the desired bandpass. For pass energies between 100 and 1400 eV and slit widths between 0.5 and 4 mm, the transmitted kinetic energy intervals are between 10 eV and a few hundred electronvolts (full width at half-maximum). The filter eliminates all higher or lower energy signals outside the selected bandpass, significantly improving the signal-to-background ratio in the time-of-flight analyzer. Full Article text