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Hydrogen-bonded organic frameworks with extended conjugate systems for boosted photocatalytic degradation

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Published On ::

New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper
Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
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Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

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Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
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Facile synthesis of spiro-pyrazolone-tetrahydrofurans/pyrans: ipso-cyclization of arylidene pyrazolones with haloalcohols

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Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00447G, Paper
Kavyashree Kuppayya Gond, Mahagundappa Rachappa Maddani
Facile synthesis of spiro-pyrazolone-tetrahydrofurans & pyrans by base-mediated cascade ipso-cyclization of haloalcohols & arylidine pyrazolones is realised. Features include brief reaction time, practicality, good yields and mild reaction conditions.
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A robust dual-network hydrogel electrolyte coupled with a porous carbon material for flexible quasi-solid-state zinc ion hybrid supercapacitors

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00310A, Paper
Chenchen Ji, Xinhong Lin, Yang Hong, Junfeng Liu, Aoteng Liu, Yijia Yao, Sicheng Liu, Hongyu Mi
A hydrogel electrolyte was designed by constructing a multi-crosslinked network. The quasi-solid-state ZHSC based on the hydrogel electrolyte and HSSPC delivers a high specific capacity, high energy/power densities, and good cycle stability.
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Catalytic oxidative desulfurization performance of a modified nano-sized β zeolite loaded with different structural polyoxometalates

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00214H, Paper
Jinhong Li, Haonan Li, Zhimei Song, Ying Guo, Mengxiao Tai, Mei Han, Xinyao Wang, Lidong Chen, Dongmei Ren
HPW/β-T+S has the best desulfurization activity among the composite catalysts supported by polyoxometalates with different structures.
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Enhance your prompts with Vertex AI Prompt Optimizer

By developers.googleblog.com
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Vertex AI Prompt Optimizer, a new managed automated prompt engineering service, can help save time and effort in prompt engineering while ensuring performing prompts ready for your generative AI applications.


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Announcing Build with Google AI release 3: A Season of Gemma!

By developers.googleblog.com
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The season showcases new applications of Gemma, including a personal AI code assistant and projects for non-English tasks and business email processing.


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Towards Global Understanding – Advancing Multilingual AI with Gemma 2 and a $150K Challenge

By developers.googleblog.com
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Google is building AI models, focusing on Gemma, to bridge communication gaps across languages.


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Want a smoother checkout with Google Pay? Configure your payment options!

By developers.googleblog.com
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Configure accepted payment methods for Google Pay, with options for authentication methods, card networks, and card types, and upcoming features for enhanced control and customization.


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Now in Developer Preview: Enhancing Chat with the Google Chat API

By developers.googleblog.com
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The Google Chat API has been launched, allowing developers to build Chat apps that enable real-time collaboration between Google Chat and other systems.


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Evolving the Responsible Generative AI Toolkit with new tools for every LLM

By developers.googleblog.com
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The Responsible Generative AI Toolkit is being expanded with new features to support responsible AI development across all LLMs, including SynthID Text for watermarking.


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Bringing AI Agents to production with Gemini API

By developers.googleblog.com
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AgentOps uses the Gemini API to provide cost-effective and powerful LLM-powered agent observability for enterprises.


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Gemini API and Google AI Studio now offer Grounding with Google Search

By developers.googleblog.com
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Grounding with Google Search for the Gemini API and Google AI Studio enhances the accuracy and freshness of Gemini's responses by leveraging Google Search data.


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Supercharging AI Coding Assistants with Gemini Models' Long Context

By developers.googleblog.com
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Sourcegraph's Cody AI assistant, integrated with Google's Gemini 1.5 Flash, can evaluate the advantages of using long-context windows in AI models for code generation and understanding.


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CONNECTING with craft

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 18:30:40 +0530

Adults in the city are taking to crafting with as much gung-ho as they did when they were children. Crafting plays a therapeutic role, allows for me time and gadget-free time, finds BHUMIKA K.


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Going wild with his camera

By www.thehindu.com
Published On :: Sat, 26 Nov 2022 12:45:25 +0530

Photographer Suryaprakash S believes he becomes one with nature when he is in the wild, capturing animals on his lens


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Weekend with food, music and more in Bengaluru

By www.thehindu.com
Published On :: Thu, 23 Feb 2023 14:19:49 +0530


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International dance day 2023: Senior women from Kochi are falling in love with dance all over again

By www.thehindu.com
Published On :: Fri, 28 Apr 2023 11:50:28 +0530

More older women are now learning to dance, gathering together at apartment complexes and signing up for online classes, as they discover the benefits of movement


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Broadway Cinemas opens in Coimbatore with IMAX Laser and EPIQ Premium Large Format screens

By www.thehindu.com
Published On :: Tue, 27 Jun 2023 16:41:57 +0530

With state-of-the-art laser projection and 12-channel sound with EPIQ premium large format, Broadway Cinemas offers an immersive movie experience


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Still ticking: HMT watches are trending again with Varchas, a limited edition series

By www.thehindu.com
Published On :: Fri, 21 Jul 2023 19:42:46 +0530

Amidst rumours of shutting shop, the watches of HMT, which started over 60 years ago, are still ticking as collectors vie for their new Tiffany blue launch


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Constructing a core–shell Pt@MnOx/SiO2 catalyst for benzene catalytic combustion with excellent SO2 resistance: new insights into active sites

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00071D, Paper
Dan Yang, Fang Dong, Jie Wang, Zhicheng Tang, Jiyi Zhang
The construction of a core–shell Pt@MnOx/SiO2 protective structure catalyst can protect the active Pt site well from SO2 toxicity.
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Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Construction of a nontoxic nano-pesticide and its co-application with natural predators for perfect cooperative pest management: an innovative strategy for pesticide reduction

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00060A, Paper
Shangyuan Wu, Qinhong Jiang, Chunyang Huang, Hailin Yang, Changhua Zhang, Meizhen Yin, Jie Shen, Shuo Yan, Hu Li
The current study develops a nano-pesticide that is nontoxic toward the predatory stinkbug but with enhanced bioactivity toward the common cutworm, which proposes to co-apply the nano-pesticide with predator as an innovative pest control technique.
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3D architectured zinc–chromium layered double hydroxide with nickel cobalt sulfide composite for the electrochemical detection of ronidazole

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00804E, Paper
Thangavelu Sakthi Priya, Tse-Wei Chen, Shen-Ming Chen, Thangavelu Kokulnathan, Bih-Show Lou, Riaz Ullah, Wedad A. Al-onazi, Mohamed S. Elshikh
Antibiotic overuse prompts mutation, and ecotoxicity, requiring precise ronidazole (RZ) detection; we developed zinc chromium layered double hydroxide with nickel cobalt sulfide (ZC/NCS) based electrochemical sensor to monitor RZ in diverse matrices.
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Interaction of disposable face mask (nano)microplastics with antibiotics: performance and mechanisms

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00775H, Paper
Ting Zhang, Xi Chen, Angrui Jiang, Jingfan Qi, Zhaoyang You, Kinjal J. Shah
The adsorption of ciprofloxacin (CIP), sulfamethoxazole (SMX) and tetracycline (TC) on disposable face mask (nano-)microplastics occurs in the order SMX > CIP > TC, which correlates with the octanol–water partition coefficient of antibiotics.
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Green Chemistry: Advancing Planetary Phosphorus Sustainability through the Synergy of Graphene Oxide Modified with Magnetic Nanoparticles (M@GO) for Extracting Tertiary Effluent Phosphorus in Sewage Treatment Plants.

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00859B, Paper
Open Access
Andrea Muñoz-Garcia, Pablo Montoro Leal, María Mar López Guerrero, Carlos Vereda-Alonso, Elisa Vereda Alonso
Securing the enduring sustainability of global phosphorus (P) utilization has become a key societal priority. The application of green chemistry and green engineering presents an opportunity to mitigate these challenges...
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Characterization of black carbon and silica nanoparticle interactions with human plasma proteins

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00773A, Communication
Si-si Chen, Hong-juan Chen, Xue-wen Guo, Wei-juan Zheng, Hong-zhen Lian
Black carbon and silica nanoparticles, modeling different sources of PM, differ in protein corona composition and effects on protein structure.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Mixing mechanisms of lead nanoparticles with mineral particles: implication of atmospheric transportation of lead

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1452-1461
DOI: 10.1039/D3EN00805C, Paper
Yongpeng Ji, Qiuju Shi, Baocong Zhao, Ziqi Wu, Jiaxin Wang, Weina Zhang, Jiangyao Chen, Yuemeng Ji, Taicheng An
Lead nanoparticles rapidly mix with sand and dust (SD) particles to form mixed particles during SD storms period and have significant potential to be transported by SD particles in atmosphere.
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Co-transport of ferrihydrite–organic matter colloids with Sb(V) in saturated porous media: implications for antimony mobility

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, 11,1462-1476
DOI: 10.1039/D3EN00701D, Paper
Wenjian Mao, Dengjun Wang, Pan Wu, Jian Zhu, Peng Liao, Kaidi Lai, Zihan Ding, Yuqin Zhang, Zhongxu He, Ruyi Zheng, Yonglin Chen
Schematic diagram of the mechanism of Fe–NOM–Sb(V) colloids formation and transport in the natural environment.
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Magnetic and structural characteristics associated with the transformation of As(V)-coprecipitated ferrihydrite to hematite: implications for magnetic enhancement in soils and sediments

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00739A, Paper
Guoqing Zhang, Yixuan Tang, Jinru Lin, Jiaxing Xu, Zidan Yuan, Lingyun Chen, Fei Wu, Chengshuai Liu, Zongmin Zhu, Xiangyang Bi, Wei Zou, Zhiguo Cao, Kai Jiang, Yuanming Pan, Roman Chernikov, Yongfeng Jia, Shaofeng Wang
The transformation of metastable ferrihydrite to stable hematite has been linked to magnetic enhancement in soils and sediments.
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Cooperative catalytic behavior of CoS and Bi2S3 nanoparticles on Zr:BiVO4 photoanodes for enhanced photoelectrochemical sulfite oxidation coupled with pharmaceutical pollution degradation

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00018H, Paper
Prabhakarn Arunachalam, Maged N. Shaddad, Mabrook S. Amer, Abdulaziz M. Alsalman, Madhavan Jagannathan
Photoelectrocatalysis is a promising advancing technology that converts energy into electricity and purifies the environment. A photoelectrochemical reaction (PEC) that splits water and degrades pharmaceutical pollutants can be achieved using...
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Sulfur-doped porous carbon sheets embedded with rich iron sites for 1O2 dominated peroxymonosulfate activation

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00971H, Paper
Yadan Song, Yalong Liu, Yangju Li, Haipeng Hu, Kexin Huang, Zhe Zhang, Zhongxian Li, Wanning Cao, Kai Jiang, Dapeng Wu
Porous carbon films co-doped with iron, nitrogen, and sulfur were synthesized via a one-step pyrolysis process, which have multiple active sites and can produce bulk 1O2 through PMS activation, which is effective in phenol degradation.
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Adsorption of nucleotides and nucleic acids on goethite nanoparticle: mode, sites and relationship with phosphate and non-phosphate structure

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00891F, Paper
Huajun Feng, Shanshan Ma, Zaiming Chen, Yungui Li, Meizhen Wang, Yangcheng Ding
The impact of iron (hydr)oxide adsorption on nucleotides and nucleic acids (NNA) in the environment varies. However, there is a lack of quantitative reports on how iron (hydr)oxide adsorption changes...
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Introduction of new guest molecules into BEDT-TTF radical-cation salts with tris(oxalato)ferrate

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CrystEngComm, 2024, 26,1962-1975
DOI: 10.1039/D4CE00099D, Paper
Open Access
Toby J. Blundell, Elizabeth K. Rusbridge, Rebecca E. Pemberton, Michael J. Brannan, Alexander L. Morritt, Joseph O. Ogar, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Lee Martin
We present the crystal structures of five new BEDT-TTF radical-cation salts with tris(oxalato)ferrate anions using solid or liquid additives toluene, phenol, benzaldehyde, 4-bromobenzaldehyde, and kojic acid.
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“Feather-duster” like ZnIn2S4/TiO2 heterostructured nanocomposites with enhanced visible-light photocatalytic performance

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2025-2032
DOI: 10.1039/D3CE01239E, Paper
Wenjie Liu, Lei Li, Jingru Li, Fang Wang, Chun-Shuai Cao, Jianzhou Gui, Alex T. Kuvarega, Bhekie B. Mamba, Dan Liu
The ZnIn2S4/TiO2 heterostructures show an increased surface area and strengthened interface contacts, facilitating efficient photogenerated carrier separation and leading to high photocatalytic performance under visible light irradiation.
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Crystallization behaviour and growth mechanisms of spinel crystals in vanadium slag with high MgO content

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00189C, Paper
Jiang Diao, Haoran Tao, Zhiqiu Lai, Yiyu Qiu, Lian Chen, Hongyi Li, Bing Xie
In this study, MgO content and FeO/SiO2 ratio were found to significantly increase the integrated crystallization rate of spinel phase in vanadium slag.
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FeS nanosheets assembled with 1T-MoS2 nanoflowers on iron foam for efficient overall water splitting

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01315D, Paper
Bo Feng, Shuting Jin, Jihui Lang, Jian Wang, Jie Hua, Yunfei Sun, Wei Zhang, Jin Wang, Jian Cao
The exploration of highly efficient noble-metal-free catalysts for overall water splitting is crucial for industrial application.
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Co-doped modified LiLuF4:Eu microcrystalline scintillation with flexible film for high resolution X-ray imaging

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00211C, Paper
Xixi Huang, Jinhai Yang, Hao Lu, Xieming Xu, Shuaihua Wang, Shaofan Wu
X-ray detectors based on scintillators are widely used in the fields of medical imaging, high-energy physics, geological exploration, and industrial detection. The development of scintillation materials with different characteristics has...
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
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Gefitinib salts/cocrystals with phenolic acids as a promising solid-state approach to improve solubility

By pubs.rsc.org
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CrystEngComm, 2024, 26,2112-2122
DOI: 10.1039/D4CE00039K, Paper
Yao Zou, Xin Meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lu, Guanhua Du
In this study, we designed and synthesized a series of gefitinib (GEF) salts and cocrystals with phenolic acids, comprising two salts, one cocrystal, and two salt cocrystals. All these forms exhibited significant improvements in solubility compared to pure GEF.
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Chemical solution deposition of a (GaAl)2O3 single layer with high thickness and silver-enhanced crystal quality

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao Tang, Wesam A. AlQanbar, Mohamed Ben Hassine, Yi Lu, Haicheng Cao, Chuanju Wang, Zixian Jiang, Tingang Liu, Na Xiao, Mingtao Nong, Vishal Khandelwal, Xiaohang Li
A new study presents a revolutionary CSD method to create thick (180 nm) single-layer (GaAl)2O3 films with enhanced crystal quality through silver doping.
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Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

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Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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S-scheme heterojunction based on CuWO4/WO3 microspheres with improved photocatalytic property under visible light

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00301B, Paper
Yangang Sun, Jianhua Ge, jiaqi xu, Jinguo Wang
Dye wastewater green treatment has always been one of the research hotspots in the environmental protection and remediation field. The photocatalytic degradation and mineralization of organic dyes are considered to...
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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Meta takes aim at Twitter with the launch of Threads

By www.thehindubusinessline.com
Published On :: Thu, 06 Jul 2023 09:27:45 +0530

Threads passes 5 million sign ups in four hours: CEO Zuckerberg


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