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When microplastics/plastics meet metal–organic frameworks: turning threats into opportunities

Chem. Sci., 2024, 15,17781-17798
DOI: 10.1039/D4SC05205F, Review Article
Open Access
Pengfei Wu, Mengting Guo, Ran-Wei Zhang, Qing Huang, Guibin Wang, Ya-Qian Lan
The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
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Is aromaticity loss necessary for transition-metal promoted arene–alkene cycloadditions?

Chem. Sci., 2024, 15,18093-18098
DOI: 10.1039/D4SC05337K, Edge Article
Open Access
João V. Schober, Croix J. Laconsay, Judy I. Wu
Diene- and ene-like reactivity in transition metal coordinated arenes can be expected when there is a notable degree of aromaticity loss at the complexed arene.
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On-demand controlled bidirectional DNAzyme path for ultra-sensitive heavy metal ion detection

Chem. Sci., 2024, 15,18170-18178
DOI: 10.1039/D4SC04404E, Edge Article
Open Access
Jing Xu, Yujin Li, Futing Wang, Xinqi Luo, Wei Zhang, Yifan Lyu, Hongfen Yang, Ren Cai, Weihong Tan
A bidirectional self-powered biosensor is constructed for the quasi-simultaneous detection of Pb2+ and Hg2+ based on MoS2@CuS heterostructures as an accelerator and hybridization chain reaction as a signal amplification strategy.
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Unified enantiospecific synthesis of drimane meroterpenoids enabled by enzyme catalysis and transition metal catalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06060A, Edge Article
Open Access
Yipeng You, Xue-Jie Zhang, Wen Xiao, Thittaya Kunthic, Zheng Xiang, Chen Xu
A unified synthetic strategy for drimane meroterpenoids was developed by combining heterologous biosynthesis, enzymatic oxidation, and transition metal catalysis. Six drimane meroterpenoids were synthesized in a concise and enantiospecific manner.
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Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06820C, Review Article
Open Access
Seungwon Sun, Jisu Choe, Jaeheung Cho
In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...
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Probing water adsorption and stability under steam flow of Zr-based metal-organic frameworks using 91Zr solid-state NMR spectroscopy

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04589K, Edge Article
Open Access
Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique Pourpoint
The stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...
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A metabologenomics strategy for rapid discovery of polyketides derived from modular polyketide synthases

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04174G, Edge Article
Open Access
Run-Zhou Liu, Zhihan Zhang, Min Li, Lihan Zhang
A metabologenomics workflow using mass defect filtering (MDF) and bioinformatics-based structural prediction was established for rapid screening of modular polyketide natural products, and led to the identification of 22 polyketides.
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Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article
Open Access
Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06083K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa Jung
The modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.
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Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05396F, Edge Article
Open Access
Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff Zaleski
Using a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...
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Share Market Highlights 18 April 2024: Sensex falls 330 pts, Nifty at 22,000; media, metal stocks shine, FMCG, healthcare drag

Sensex, Nifty updates on 18th April 2024: Equity benchmarks BSE Sensex and NSE Nifty extended losses on Thursday. As per provisional figures, BSE Sensex fell 332.23 pts or 0.46 per cent to trade at 72,611.45 as of 3.35 pm and Nifty 50 declined 103.70 pts or 0.47 per cent to trade at 22,044.20., Bharti Airtel, Power Grid Corp, M&M, BPCL, and Tata Steel were the top gainers, while Nestle, Apollo Hospitals, Axis Bank, HCL Technologies, and ONGC were the major laggards. The stocks that hit a 52-week high on the NSE include AAA Tech (19.33 per cent), Just Dial (12.95 per cent), Indo Tech (10 per cent) and Hi-Tech Gear (10 per cent).




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Immunotherapy approach shows potential in some people with metastatic solid tumors

A new cellular immunotherapy approach shrank tumors in 3 of 7 patients with metastatic colon cancer, in a small NCI clinical trial. Normal white blood cells from each patient were genetically engineered to produce receptors that recognize and attack their specific cancer cells.




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RSC - Metallomics latest articles




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After storm over allegations, Australia Today clarifies ban was by Meta platforms, not Canadian government 

The Ministry of External Affairs, which had slammed Canada over the allegations last week, has been silent over clarification




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P3MOT-decorated metal-porphyrin-based zirconium-MOF for the efficient electrochemical detection of 4-nitrobenzaldehyde

Anal. Methods, 2024, 16,2093-2100
DOI: 10.1039/D4AY00152D, Paper
Wen-yi Chen, Xin-yu Huang, Qian Sun, En-qing Gao
Developed a novel hybrid P3MOT@PCN-222(Fe) via in situ polymerization for 4-NBA detection. Showcased broad detection range, high sensitivity, selectivity and stability, laying groundwork for environmental monitoring.
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A three-dimensional network structure of metal-based nanozymes for the construction of colorimetric sensors for the detection of antioxidants

Anal. Methods, 2024, 16,2292-2300
DOI: 10.1039/D3AY02199H, Paper
Shuo Qin, Bin Liu, Yuting Xue, Ruixue Zhao, Guo Wang, Kai Li, Lirong Zheng, Pingyang Wang, Tianhao Tang, Yue Yang, Zhengbo Chen, Xia Zuo
Although many excellent nanozymes have been developed, designing and synthesizing highly active nanozymes is still challenging.
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Direct solid sample analysis of low-cost jewelry using spectroanalytical techniques: exploratory chemical data evaluation and metal migration with synthetic sweat

Anal. Methods, 2024, 16,2286-2291
DOI: 10.1039/D4AY00325J, Paper
Thaila Lorena de Araújo, Fabiola Manhas Verbi Pereira, Edenir Rodrigues Pereira-Filho
Jewelry samples were directly analyzed using LIBS and XRF.
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Dual-functional porphyrinic zirconium-based metal–organic framework for the fluorescent sensing of histidine enantiomers and Hg2+

Anal. Methods, 2024, 16,2386-2399
DOI: 10.1039/D3AY02241B, Paper
Shili Qin, Fanshu Meng, Fenglong Jin, Xidi Xu, Ming Zhao, Hongtao Chu, Lidi Gao, Shuren Liu
L-Cys/PCN-222 as a novel and dual-functional fluorescent sensor was developed. It not only showed a higher chiral fluorescent recognition of L-histidine but also performed as a visual sensor for Hg2+ in actual surface water.
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Solvation effect enabled visualized discrimination of multiple metal ions

Anal. Methods, 2024, 16,2301-2310
DOI: 10.1039/D4AY00060A, Paper
Yang Cheng, Yuan Liu, Jiguang Li, Yudong Li, Da Lei, Dezhong Li, Xincun Dou
Highly efficient detection of environmental residual potentially toxic species is of concern worldwide as their presence in an excessive amount would greatly endanger the health of human beings as well as environmental sustainability.
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Detection of Free DNA Based on Metal-Enhanced Fluorescence Triggered by CRISPR-Cas12a and Colorimetric Analysis

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00149D, Paper
Ming-Qiu Zheng, Yuyao Li, Liling Zhang, Cheng-Yu Li, Menghan Liu, Hongwu Tang
The CRISPR-Cas system has been found to be extremely sensitive and there is an urgent demand to extend its potential in bioassay. Herein, we developed a novel nanobiosensor to detect...
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Development, biological evaluation, and molecular modelling of some benzene-sulfonamide derivatives as protein tyrosine phosphatase-1B inhibitors for managing diabetes mellitus and associated metabolic disorders

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00594E, Research Article
Nagat Ghareb, Khaled M. Darwish, Mohamed S. Nafie, Ranwa Elrayess, Noha M. Abourobe, Shaimaa A. Fattah, Reem M. Hazem, Eman T. Mehanna, Ranza Elrayess
One benzene-sulfonamide derivative exhibited potent protein tyrosine phosphatase-1B inhibition for managing diabetes mellitus and associated metabolic disorders.
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Miniaturized click chemistry and direct screening facilitate the discovery of triazole piperazine SARS-CoV-2 Mpro inhibitors with improved metabolic stability

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00555D, Research Article
Shenghua Gao, Letian Song, Bing Ye, Mianling Yang, Junyi Li, Manyu Gu, Ann E. Tollefson, Karoly Toth, Peng Zhan, Xinyong Liu
The continuous mutational nature of SARS-CoV-2 and its inter-species' similarities emphasize the urgent need to design and develop more direct-acting antiviral agents against highly infectious variants.
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Metal-free synthesis of N-fused quinazolino-quinazoline-diones as a MALAT1 RNA triple helix intercalator

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00614C, Research Article
Vijay Babu Pathi, Pranotosh Das, Abhyuday Guin, Manish Debnath, Biswadip Banerji
The development of chemical scaffolds that target highly conserved MALAT1 RNA received attention due to its significance in splicing, nuclear organization, and gene expression in disease progression pathways.
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569: Apple’s Web Apps, Meta Quest and Vision Pro, and Missing Sticky Headers

How do you point out things in a UI? Are Arc Boosts the end of the web? What do you think of VR and AR / Vision Pro and Meta Quest? And what do you do when the sticky header goes missing?




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Passengers depending on non-Railway sources of information for timetable miss CSMT Express

Non-railway websites or apps do not immediately update changes in train timetables, say officials




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IndiaAI, Meta launch AI center in IIT Jodhpur; will promote student start-ups




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I am…Padmakumar – Metal craftsman




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Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01681E, Research Article
Lu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai Zhou
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.
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Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01488J, Research Article
Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
A photoinduced FeCl3/HCl synergistic catalytic method enables C(sp3)–S bond formation via reductive cross-coupling of activated/inert C(sp3)–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).
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Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01702A, Research Article
Yiting Zhou, Bin Liu
We present a metal-free and mild three-component reaction involving vinylarenes, NHC–BH3 complexes, hydrosilanes, and 4-cyanopyridine. Remarkably, this reaction was performed with simple and inexpensive benzophenone.
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Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Org. Chem. Front., 2024, 11,6340-6346
DOI: 10.1039/D4QO01376J, Research Article
Qinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong Lian
We developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.
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Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions

Org. Chem. Front., 2024, 11,6437-6443
DOI: 10.1039/D4QO01265H, Research Article
Dabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou Cai
In this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.
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Transition-metal-catalyzed C–Ge coupling reactions

Org. Chem. Front., 2024, 11,6558-6572
DOI: 10.1039/D4QO01637H, Review Article
Jie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan He
This review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.
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Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis

Org. Chem. Front., 2024, 11,6534-6557
DOI: 10.1039/D4QO01686F, Review Article
Jinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun Xie
This review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.
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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
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Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01714E, Research Article
Ke Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang Sun
Transition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.
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Effective BPA degradation in water: the integration of bimetallic UiO-66 Ce–Zr

RSC Adv., 2024, 14,35090-35096
DOI: 10.1039/D4RA06460G, Paper
Open Access
Leidy Marcela Gallo, Juan L. Obeso, Nora S. Portillo-Vélez, Carlos E. Garduño-Albino, Catalina V. Flores, Leonardo Herrera-Zuñiga, Alejandro Islas-Jácome, Ricardo A. Peralta, Carolina Leyva
In this work, a bimetallic MOF UiO-66 Ce–Zr to degrade bisphenol A (BPA) in water was synthesised. The material exhibited a remarkable degradation efficiency of 84.3% under UV irradiation for 240 minutes.
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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
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Harnessing the UiO-67 metal–organic framework for advanced detection of cadmium ions in water bodies

RSC Adv., 2024, 14,35618-35627
DOI: 10.1039/D4RA06811D, Paper
Open Access
Bhuvaneswari Selvaraj, Lakshmi Priya G., Selva Balasubramanian
Heavy metal ions are hazardous pollutants that pose serious threats to ecosystems and human health, making it imperative to detect and monitor their presence in water for environmental protection.
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Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
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Synthesis of Cu/Mn/Ce polymetallic oxide catalysts and catalytic ozone treatment of wastewater

RSC Adv., 2024, 14,35993-36004
DOI: 10.1039/D4RA06052K, Paper
Open Access
Jinlong Zhong, Xue feng Mao, Guanyu Wang, Heng Li, Junfang Li, Sijian Qu, Jianwei Zhao
Non-homogeneous ozone-catalyzed oxidation technology is one of the effective ways of treating wastewater, the core of which lies in the development of efficient ozone oxidation catalysts.
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Stability and magnetic properties of transition metal (V, Cr, Mn, and Fe) doped cobalt oxide clusters: a density functional theory investigation

RSC Adv., 2024, 14,36031-36039
DOI: 10.1039/D4RA05482B, Paper
Open Access
Nguyen Thi Mai, Tran Dang Thanh, Do Hung Manh, Nguyen Thi Ngoc Anh, Ngo Thi Lan, Phung Thi Thu, Nguyen Thanh Tung
Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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Polyether-based polyurethane electrolyte for lithium metal battery: a perspective

RSC Adv., 2024, 14,36152-36160
DOI: 10.1039/D4RA06863G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peng Cui, Yifan Li, YuXing Liu, Siqi Wang, Xingyu Tang, Yihong Ye, Hance Su, Chun Sun
Mechanism of increasing ionic conductivity of polyether-based polyurethane electrolyte.
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Distance-based paper microfluidic devices for rapid visual quantification of heavy metals in herbal supplements and cosmetics

RSC Adv., 2024, 14,36142-36151
DOI: 10.1039/D4RA05358C, Paper
Open Access
Yanawut Manmana, Mirek Macka, Nantana Nuchtavorn
The ion exchange paper shows strongly retain anionic metallochromic reagents, enabling clear endpoint detection on DμPADs. This method allows rapid heavy metal screening in real samples, with the predeposited reagents stable for at least 2 months.
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RBI’s gold holdings now exceed India’s annual demand for the precious metals

Central bank embarks on gold buying spree, adds 25 tonnes to forex reserves



  • Gold & Silver

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Will ‘one nation, one gold rate’ add to the yellow metal’s sheen?

Industry moots policy to bring transparency that can boost customer confidence



  • Gold & Silver

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A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02734E, Paper
Hui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang Tang
A biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.
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Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT01765J, Paper
Romain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim Storr
The synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...
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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
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