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One-pot spatial engineering of multi-enzymes in metal–organic frameworks for enhanced cascade activity

J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper
Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics

J. Mater. Chem. A, 2024, 12,30872-30884
DOI: 10.1039/D4TA05266H, Paper
Haijiao Lin, Hui Wang, Yongguang Yang, Yuxuan Zhang, Ling Li, Youwei Zhao, Wenming Zhang
Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article
Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Your hair-stylist, tattoo artist, tailor can help monitor metabolic health, says Dr Sarin

In his book “Own Your Body,” Dr Shiv Sarin advocates for educating these professionals to look for signs like black lines, skin tags, and waist-to-hip ratios, which could indicate underlying health issues




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META Award winner Hunkaro is back in Bengaluru

The idea of the play came about with the disturbing realisation that the lockdown reduced not only the attention span of people but also the capacity and need to listen




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Observation and enhancement through alkali metal doping of p-type conductivity in the layered oxyselenides Sr2ZnO2Cu2Se2 and Ba2Zn1−xO2−xCu2Se2

J. Mater. Chem. C, 2024, 12,17574-17586
DOI: 10.1039/D4TC02458C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zahida Malik, Sarah Broadley, Sebastian J. C. Herkelrath, Daniel W. Newbrook, Liam Kemp, George Rutt, Zoltán A. Gál, Jack N. Blandy, Joke Hadermann, Daniel W. Davies, Robert D. Smyth, David O. Scanlon, Ruomeng Huang, Simon J. Clarke, Geoffrey Hyett
The optoelectronic properties of two layered copper oxyselenide compounds, with nominal composition Sr2ZnO2Cu2Se2 and Ba2ZnO2Cu2Se2, have been investigated to determine their suitability as p-type conductors.
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Silver-incorporated NiCo metal–organic frameworks with controlled morphology for enhanced cycling in flexible supercapacitor applications

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC02970D, Paper
Chu Chu, Wenjing Zhang, Xuehua Yan, Yingnan Yan, Jianmei Pan, Zohreh Shahnavaz, Jamile Mohammadi Moradian
The specific capacitance of NCA15-MOF/NF was 1317 F g−1, which was significantly higher compared to the NCA0-MOF/NF. After 15 000 charge–discharge cycles, the NCA15-MOF/NF retained 89% of its initial specific capacitance.
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Application of metal organic frameworks (MOFs) and their derivatives in the cathode materials of aqueous zinc-ion batteries

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03273J, Review Article
Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu, Yanxiang Wang
Metal–organic frameworks (MOFs) are regarded as potential candidate materials for the cathodes of aqueous zinc-ion batteries. This review presents the applications of MOFs and their derivatives in the cathodes of aqueous zinc-ion batteries.
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A metal–organic framework enhanced single network organohydrogel with superior low-temperature adaptability and UV-blocking capability towards human-motion sensing

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper
Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH2 nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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Nanomaterial-based regulation of redox metabolism for enhancing cancer therapy

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00404C, Review Article
Xiaodan Jia, Yue Wang, Yue Qiao, Xiue Jiang, Jinghong Li
This review provides a comprehensive summary of the dysregulation of redox metabolism in cancer cells and the advantages and the latest advances in nanomaterial-assisted redox metabolic regulation therapy.
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Understanding deNOx mechanisms in transition metal exchanged zeolites

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00468F, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jamal Abdul Nasir, Andrew M. Beale, C. Richard A. Catlow
Transition metal-containing zeolites have received considerable attention, owing to their application in the selective catalytic reduction of NOx. To understand their chemistry, both structural and mechanistic aspects at the atomic level are needed.
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Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

Chem. Soc. Rev., 2024, 53,10450-10490
DOI: 10.1039/D4CS00527A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Denis Leybo, Ubong J. Etim, Matteo Monai, Simon R. Bare, Ziyi Zhong, Charlotte Vogt
Metal–support interactions (MSI) impact catalyst activity, stability, and selectivity. This review critically evaluates recent findings, theoretical advances, and MSI tuning strategies, offering new perspectives for future research in the field.
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From cyclotrons to chromatography and beyond: a guide to the production and purification of theranostic radiometals

Chem. Soc. Rev., 2024, 53,10409-10449
DOI: 10.1039/D4CS00802B, Tutorial Review
Brooke L. McNeil, Caterina F. Ramogida
This tutorial review explores the fundamentals and applications behind the production and purification of radiometals in the burgeoning field of radio-theranostics.
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Multidimensionally ordered mesoporous intermetallics: Frontier nanoarchitectonics for advanced catalysis

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00484A, Tutorial Review
Hao Lv, Ben Liu
This perspective summarizes recent progress in rational design and synthesis of multidimensionally ordered mesoporous intermetallics, and propose new frontier nanoarchitectonics for designing high-performance functional nanocatalysts.
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Metal–phenolic network composites: from fundamentals to applications

Chem. Soc. Rev., 2024, 53,10800-10826
DOI: 10.1039/D3CS00273J, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhixing Lin, Hai Liu, Joseph J. Richardson, Wanjun Xu, Jingqu Chen, Jiajing Zhou, Frank Caruso
This review provides a guideline for the rational design of metal–phenolic network (MPN) composites—which are fabricated from MPN and one or more functional components (e.g., drugs, proteins)—for various applications across diverse disciplines.
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Mechanism and stereoselectivity in metal and enzyme catalyzed carbene insertion into X–H and C(sp2)–H bonds

Chem. Soc. Rev., 2024, 53,11004-11044
DOI: 10.1039/D4CS00742E, Review Article
Reena Balhara, Ritwika Chatterjee, Garima Jindal
This review provides a mechanistic overview of asymmetric Fe, Cu, Pd, Rh, Au and heme-based enzymes catalyzed carbene insertion reactions to construct  C–X (X = O, N, S, etc.) and C–C bonds, focusing on the stereochemical models.
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Experimental factors influencing the bioaccessibility and the oxidative potential of transition metals from welding fumes

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D3EM00546A, Paper
Manuella Ghanem, Laurent Y. Alleman, Davy Rousset, Esperanza Perdrix, Patrice Coddeville
Experimental conditions such as extraction methods and storage conditions induce biases on the measurement of the oxidative potential and the bioaccessibility of transition metals from welding fumes.
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Enhanced photocatalysis of metal/covalent organic frameworks by plasmonic nanoparticles and homo/hetero-junctions

Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article
Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
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In situ self-reconstructed hierarchical bimetallic oxyhydroxide nanosheets of metallic sulfides for high-efficiency electrochemical water splitting

Mater. Horiz., 2024, 11,1797-1807
DOI: 10.1039/D3MH02090H, Communication
Yaning Fan, Junjun Zhang, Jie Han, Mengyuan Zhang, Weiwei Bao, Hui Su, Nailiang Wang, Pengfei Zhang, Zhenghong Luo
The obtained bimetallic sulfide catalyst can be reconstituted as FeCoOOH, which has high efficacy for water splitting. The activation energy barrier of key reaction steps can be effectively reduced by dual-metal cooperation.
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Non-Hermitian metagrating for perfect absorption of elastic waves

Mater. Horiz., 2024, 11,1658-1667
DOI: 10.1039/D3MH01866K, Communication
Jiali Cheng, Yabin Hu, Bing Li
With only a specific small amount of loss, perfect absorption of elastic waves can be achieved by a compact NHMG composed of only a single type of unit cell, enabling cloaking for arbitrary-shaped targets.
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Biphenyl Tetracarboxylic Acid based Metal-Organic Frameworks: A Case of Topology-Dependent Thermal Expansion

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication
Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
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Aggregation-induced emission organic metal halide complex for X-ray scintillation

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication
Open Access
Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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Bicolour, large area, inkjet-printed metal halide perovskite light emitting diodes

Mater. Horiz., 2024, 11,1989-1996
DOI: 10.1039/D3MH02025H, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vincent R. F. Schröder, Nicolas Fratzscher, Nicolas Zorn Morales, Daniel Steffen Rühl, Felix Hermerschmidt, Eva L. Unger, Emil J. W. List-Kratochvil
Using a sequential inkjet printing process, we realize bicoloured PeLEDs by selectively dissolving a bromide-based perovskite film with an iodide-based perovskite ink, resulting in red light-emitting features on a green light-emitting background.
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'Stall Speed' and 'Escape Velocity': Empty Metaphors or Empirical Realities? [electronic journal].




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The Primary Cause of European Inflation in 1500-1700: Precious Metals or Population? The English Evidence [electronic journal].




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1484.12.3-2020 - IEEE Standard for Learning Technology--Extensible Markup Language (XML) Schema Definition Language Binding for Learning Object Metadata - Redline [electronic journal].

IEEE / Institute of Electrical and Electronics Engineers Incorporated




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Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols

Inorg. Chem. Front., 2024, 11,1998-2006
DOI: 10.1039/D4QI00113C, Research Article
Mengna Li, Benlai Wu, Maochun Hong
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
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Recent progress on the photocatalytic hydrogen evolution reaction over a metal sulfide cocatalyst-mediated carbon nitride system

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00255E, Review Article
Xunhuai Huang, Junpeng Song, Guanyu Wu, Zhihuan Miao, Yanhua Song, Zhao Mo
Modification strategy and synthesis method of a metal sulfide-mediated carbon nitride photocatalytic H2 production system.
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Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article
Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00511B, Research Article
Open Access
Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi
A cyanido-bridged Co–W assembly with π–π interactions showed a thermal phase transition and a photo–induced metamagnetism based on a charge transfer–induced spin transition.
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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article
Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands

Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan

Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article
Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
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Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
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A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries

Inorg. Chem. Front., 2024, 11,2300-2311
DOI: 10.1039/D4QI00391H, Research Article
Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
The introduction of Al2O3 regulates the solvation structure of Na+, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
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Stable Calcium Ellagate Metal-Organic Framework as High Performance Green Memorizer Bearing High Working Temperature

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article
Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
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A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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Trump effect: Base metal prices surge on demand spike after slumping post-Trump win

Aluminium, zinc and copper futures climb on November 7, the day after Trump’s election, say PTI reports




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Centre admonishes X, Meta on bomb hoax posts

X and Meta officials were severely reprimanded for not divulging information in time about the bomb threats