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[ASAP] From Industrial Method to the Use of Silylated P(III) Reagents for the Synthesis of Relevant Phosphonylated Molecules

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00490




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[ASAP] Safety Case Study. Intrinsic Instability of Concentrated Solutions of Alcoholic Hydrogen Chloride: Potential Hazards Associated with Methanol

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00034




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[ASAP] Improved Synthesis of 6-Chloro-5-methylpyridin-2-amine: A Key Intermediate for Making Lumacaftor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00556




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[ASAP] <italic toggle="yes">N</italic>-Acyl-5,5-Dimethylhydantoins: Mild Acyl-Transfer Reagents for the Synthesis of Ketones Using Pd–PEPPSI or Pd/Phosphine Catalysts

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00054




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[ASAP] Scalable Synthesis of <italic toggle="yes">S</italic>-Fluoromethyl Benzenesulfonothioate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00101




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[ASAP] Continuous Process for Preparing the Difluoromethylating Reagent [(DMPU)<sub>2</sub>Zn(CF<sub>2</sub>H)<sub>2</sub>] and Improved Synthesis of the ICHF<sub>2</sub> Precursor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00089




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Enhancing the methane low-temperature conversion on the Zn/ZSM-5 in the presence of methanol by regulating methanol-to-aromatics reaction pathway

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00449A, Paper
Zhixiang Xi, Bingjie Zhou, Yue Yu, Binbo Jiang, Zhengliang Huang, Zuwei Liao, Jingdai Wang, Yao Yang, Jingyuan Sun, Yongrong Yang
Co-reaction method provides efficient strategy for methane conversion in mild condition, which is of urgent importance of direct valorization of natural gas to liquid hydrocarbons. However, vague mechanism and neglect...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synergistic photocatalysis–Fenton reaction for selective conversion of methane to methanol at room temperature

Catal. Sci. Technol., 2020, 10,2329-2332
DOI: 10.1039/D0CY00028K, Communication
Yi Zeng, Hang Chen Liu, Jing Sheng Wang, Xing Yang Wu, Song Ling Wang
Combining the photocatalysis and Fenton reaction highly promote the yield and selectivity of CH3OH from CH4 with solar light at room temperature, up to 471 μmol g−1 h−1 and 83%, respectively.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effect of ceria morphology on the performance of MnOx/CeO2 catalysts in catalytic combustion of N,N-dimethylformamide

Catal. Sci. Technol., 2020, 10,2473-2483
DOI: 10.1039/C9CY02384D, Paper
Fengying Huang, Dongsheng Ye, Xiaohan Guo, Wangcheng Zhan, Yun Guo, Li Wang, Yunsong Wang, Yanglong Guo
MnOx/CeO2 catalysts were prepared by a deposition–precipitation method, through loading MnOx into ceria supports with different morphologies (nanorods (NRs), nanocubes (NCs) and nano-octahedrons (NOs)).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes

Catal. Sci. Technol., 2020, 10,2583-2592
DOI: 10.1039/D0CY00471E, Paper
Chandran Rajendran, Govindaswamy Satishkumar, Charlotte Lang, Eric M. Gaigneaux
AlSBA-15 catalysts possessing Brønsted acid and Lewis acid–base bifunctionalities catalyze the direct arylation of benzyl alcohols to diarylmethanes with an 85% product yield through C–O bond activation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile sulfolane-modified resins for enhanced dimethoxymethane carbonylation

Catal. Sci. Technol., 2020, 10,2561-2572
DOI: 10.1039/D0CY00201A, Paper
Jie Yao, Lei Shi, Wenjie Deng, Jiaqi Fan, Yan Wang, Weizhe Gao, Dongxi Zhang, Wenliang Zhu, Zhongmin Liu
A simple resin modification method for 50 h DMM carbonylation with a high STY of 3.15 mmolMMAc (gcat h)−1 and 100% MMAc selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

Catal. Sci. Technol., 2020, 10,2615-2626
DOI: 10.1039/C9CY02407G, Paper
Dan Zhao, Guoqiang Zhang, Lifei Yan, Lingqi Kong, Huayan Zheng, Jie Mi, Zhong Li
The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Origin of CO2 as the main carbon source in syngas-to-methanol process over Cu: theoretical evidence from a combined DFT and microkinetic modeling study

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00602E, Paper
Dongyang Xu, Panpan Wu, Bo Yang
A theoretical study combining DFT and microkinetic modeling provides evidence that CO2 is the main carbon source in methanol synthesis from syngas (CO, CO2 and H2) over Cu.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ru nanoparticles supported on amorphous ZrO2 for CO2 methanation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00233J, Paper
Hironori Nagase, Rei Naito, Shohei Tada, Ryuji Kikuchi, Kakeru Fujiwara, Masahiko Nishijima, Tetsuo Honma
The influence of support materials and preparation methods on CO2 methanation activity was investigated using Ru nanoparticles supported on amorphous ZrO2 (am-ZrO2), crystalline ZrO2 (cr-ZrO2), and SiO2. Among them, Ru/am-ZrO2...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00707B, Paper
Miguel González-Lainez, M. Victoria Jiménez, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Compound [IrBr(CO)2(κC-tBuImCH2PyCH2OMe)] featuring a flexible pyridine/OMe functionalized NHC ligand κ1C coordinated efficiently catalyzes the selective N-monomethylation of nitroarenes using methanol as both the reducing agent and the C1 source. A...
The content of this RSS Feed (c) The Royal Society of Chemistry




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CO activation and methanation mechanism on hexagonal close-packed Co catalysts: effect of functionals, carbon deposition and surface structure

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00499E, Paper
Hai-Yan Su, Changlin Yu, Jin-Xun Liu, Yonghui Zhao, Xiufang Ma, Jie Luo, Chenghua Sun, Wei-Xue Li, Keju Sun
Regardless of the functionals used and the presence of graphitic carbon, the CO methanation rate on Co(0001) is mainly controlled by CHO decomposition.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methylcellulose – a versatile printing material that enables biofabrication of tissue equivalents with high shape fidelity

Biomater. Sci., 2020, 8,2102-2110
DOI: 10.1039/D0BM00027B, Minireview
Open Access
T. Ahlfeld, V. Guduric, S. Duin, A. R. Akkineni, K. Schütz, D. Kilian, J. Emmermacher, N. Cubo-Mateo, S. Dani, M. v. Witzleben, J. Spangenberg, R. Abdelgaber, R. F. Richter, A. Lode, M. Gelinsky
This minireview highlights the use of the polysaccharide methylcellulose for biofabrication applications. Its properties are useful for printing of dissolvable support structures as well as the development of novel bioinks.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainable release of vancomycin from micro-arc oxidised 3D-printed porous Ti6Al4V for treating methicillin-resistant Staphylococcus aureus bone infection and enhancing osteogenesis in a rabbit tibia osteomyelitis model

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/C9BM01968E, Paper
Teng Zhang, Qingguang Wei, Hua Zhou, Wenhao Zhou, Daoyang Fan, Xinhong Lin, Zehao Jing, Hong Cai, Yan Cheng, Xiaoguang Liu, Weishi Li, Chunli Song, Yun Tian, Nanfang Xu, Yufeng Zheng, Zhongjun Liu
Sustainable release of vancomycin from micro-arc oxidised 3D-printed porous Ti6A14V for treating MRSA bone infection and enhancing osteogenesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methanol extract of Iphiona aucheri ameliorates CCl4 induced hepatic injuries by regulation of genes in rats

Toxicol. Res., 2019, 8,815-832
DOI: 10.1039/C9TX00157C, Paper
Jawaid Ahmed Zai, Muhammad Rashid Khan, Zaib un Nisa Mughal, Riffat Batool, Irum Naz, Sonia Maryam, Zartash Zahra
Alteration in expression of ER stress associated genes, inflammatory genes and antioxidant biochemical induced with CCl4 in liver of rats were restored towards the control rats by co-administration of methanol extract of Iphiona aucheri to rats.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ternary PtFeCo alloys on graphene with high electrocatalytic activities for methanol oxidation

Nanoscale, 2020, 12,9824-9832
DOI: 10.1039/D0NR00757A, Paper
Hongfei Wang, Kefu Zhang, Jun Qiu, Juan Wu, Jingwen Shao, Huijuan Wang, Yujuan Zhang, Jie Han, Yong Zhang, Lifeng Yan
Ternary PtFeCo alloys as alternatives to conventional Pt electrocatalysts are highly important in the field of the methanol oxidation reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nanosphere-shaped ammonio methacrylate copolymers: converting a pharmaceutical inactive ingredient to efficient therapeutics for experimental colitis

Nanoscale, 2020, 12,9590-9602
DOI: 10.1039/D0NR00465K, Paper
Brice Moulari, Maryam A. Shetab Boushehri, Jean-Paul Pais de Barros, Thilo Faber, Arnaud Béduneau, Laurent Lagrost, Yann Pellequer, Alf Lamprecht
Even in the absence of any drug load, nanosphere-shaped ammonio methacrylate copolymers can mitigate murine experimental colitis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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First Methodist circuit rider built ante-bellum home




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Catholics 'needed competition,' so supported Methodists




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Bronson Methodist Church 100 years old




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Old Methodist church named for Indian




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Methodology for economic impact estimation




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Using stated choice methods in the design of payments for environmental service schemes




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Aerial view: First United Methodist Church (3rd Street and 2nd Avenue North). houses, cars, trees




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Aerial view: Mirror Lake area; Standard Business College; First Avenue Methodist Church; 1919 and 1911 High School buildings, the Water tower and many houses. Suwanee Hotel not built yet




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First Avenue Methodist Church with tiny palm trees




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First Methodist Episcopal Church from street




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First Methodist Episcopal Church with fire hydrant, street marker




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First United Methodist Church (3rd Street and 2nd Avenue North) rising behind the foliage




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First United Methodist Church (3rd Street and 2nd Avenue North), cars, foliage, a man walking




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Crowd of men looking at something under large elaborate tent next to Ponce de Leon Hotel; checkerboard hanging on wall of tent




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Crowd of men looking at something under large elaborate tent next to Ponce de Leon Hotel; checkerboard hanging on wall of tent




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Suwannee Hotel in center of Mirror Lake area. First Avenue Methodist Church and high school buildings also shown




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Interior: Unknown older man standing and two women sitting in house living room/dining room; chairs, desk, radio, bookcase, paintings and portraits, drapes, rugs, chandelier. One woman is listening to something through a wire? Other woman is reading




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Interior: Unknown older man standing and two women sitting in house living room/dining room; chairs, desk, radio, bookcase, paintings and portraits, drapes, rugs, chandelier. One woman is listening to something through a wire? Other woman is looking up fr




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Betty and Dick standing on sidewalk outside house wearing hats; toy train on ground, sign on house saying something about film and photo finishing




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Trinity Methodist Church, Arcadia, Fla




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First Methodist Church, Tampa, Fla




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Hyde Park Methodist Church, Tampa, Fla




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First Methodist Church, Tampa, Fla




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Florida Methodist Youth Camp, Prayer Chapel, Leesburg, Florida